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arXiv 1705.04052cond-mat.mtrl-sci
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高度各向异性半导体GaTe纳米材料的合成及其外延特性

Synthesis of Highly Anisotropic Semiconducting GaTe Nanomaterials and Emerging Properties Enabled by Epitaxy

Hui Cai, Bin Chen, Gang Wang, Emmanuel Soignard, Afsaneh Khosravi, Marco Manca, Xavier Marie, Shery Chang, Bernhard Urbaszek, Sefaattin Tongay

摘要:

准一维材料是一类原子在二维空间中以链状结构排列的新型材料。例子包括最近发现的黑磷、来自过渡金属二硫属化物的ReS 2和ReSe 2、来自过渡金属三硫属化物的TiS 3和ZrS 3以及最近发现的GaTe。结构各向异性的存在会影响它们的物理性质,并导致方向依赖的光-物质相互作用、二向色性光学响应、高迁移率通道和各向异性热传导。尽管有许多关于各向同性TMDC和后过渡金属硫族化物(如MoS 2和GaSe)的气相生长的报道,但由于界面能的各向异性,伪1D材料的合成特别困难,这稳定了树枝状生长而不是具有明确取向的单晶生长。在具有优良光电探测性能的柔性云母衬底上生长了单斜GaTe。在这项工作中,我们证明了伪一维单斜GaTe层可以通过物理气相传输技术在各种其他衬底上合成,包括GaAs(111),Si(111)和c切蓝宝石。高分辨率透射电子显微镜(HRTEM)测量,以及角分辨微PL和显微拉曼技术,提供了第一次原子尺度的分辨率实验的伪一维结构的单斜GaTe和各向异性性能。有趣的是,生长在蓝宝石上的GaTe纳米材料表现出高效和窄的局部发射峰低于带隙能量,这被发现与选择类型的线和点缺陷,如PL和拉曼映射扫描证明。这使得在蓝宝石上生长的样品比在GaAs和Si上生长的样品更突出,这些样品表现出更规则的性质。

英文摘要:

Pseudo-one dimensional (pseudo-1D) materials are a new-class of materials where atoms are arranged in chain like structures in two-dimensions (2D). Examples include recently discovered black phosphorus, ReS2 and ReSe2 from transition metal dichalcogenides, TiS3 and ZrS3 from transition metal trichalcogenides and most recently GaTe. The presence of structural anisotropy impacts their physical properties and leads to direction dependent light-matter interactions, dichroic optical responses, high mobility channels, and anisotropic thermal conduction. Despite the numerous reports on the vapor phase growth of isotropic TMDCs and post transition metal chalcogenides such as MoS2 and GaSe, the synthesis of pseudo-1D materials is particularly difficult due to the anisotropy in interfacial energy, which stabilizes dendritic growth rather than single crystalline growth with well-defined orientation. The growth of monoclinic GaTe has been demonstrated on flexible mica substrates with superior photodetecting performance. In this work, we demonstrate that pseudo-1D monoclinic GaTe layers can be synthesized on a variety of other substrates including GaAs (111), Si (111) and c-cut sapphire by physical vapor transport techniques. High resolution transmission electron microscopy (HRTEM) measurements, together with angle resolved micro-PL and micro-Raman techniques, provide for the very first time atomic scale resolution experiments on pseudo-1D structures in monoclinic GaTe and anisotropic properties. Interestingly, GaTe nanomaterials grown on sapphire exhibit highly efficient and narrow localized emission peaks below the band gap energy, which are found to be related to select types of line and point defects as evidenced by PL and Raman mapping scans. It makes the samples grown on sapphire more prominent than those grown on GaAs and Si, which demonstrate more regular properties.

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