Photoluminescence is a phenomenon of significant interest due to its wide range of technological applications in plasmonics, nanolasers, spasers, lasing spasers, loss compensation and gain in metamaterials, and luminescent media. Nanostructured materials are known to have very different luminescence characteristics to bulk samples or planar films. Here we show that by engineering a nanostructured meta-surface, we can choose the position of photoluminescence absorption and emission lines of thin gold films. The nanostructuring also aids to strong enhancement of the emission from gold, by a factor of 76 in our experiments. This enhancement is determined by the relative position of the engineered absorption and emission lines to the exciting laser wavelength and the intrinsic properties of the constituent material. These luminescence-engineered materials combined with a resonant material, as in the lasing spaser, or with the power of reconfigurable metamaterials promise huge potential as tunable nanoscale light sources.
We report that hybridizing semiconductor quantum dots with plasmonic metamaterial leads to a multi-fold intensity increase and narrowing of their photoluminescence spectrum. The luminescence enhancement is a clear manifestation of the cavity quantum electrodynamics Purcell effect that can be controlled by the metamaterial's design. This observation is an essential step towards understanding loss compensation in metamaterials with gain media and for developing metamaterial-enhanced gain media.
Plasmonic nanojunctions, consisting of adjacent metal structures with nanometre gaps, can support localised plasmon resonances that boost light matter interactions and concentrate electromagnetic fields at the nanoscale. In this regime, the optical response of the system is governed by poorly understood dynamical phenomena at the frontier between the bulk, molecular and atomic scales. Here, we report ubiquitous spectral fluctuations in the intrinsic light emission from photo-excited gold nanojunctions, which we attribute to the light-induced formation of domain boundaries and quantum-confined …
We propose a simple design of all-dielectric silicon-based planar metamaterial manifested an extremely sharp resonant reflection and transmission in the wavelength of about 1550 nm due to both low dissipative losses and involving a trapped mode operating method. The quality factor of the resonance exceeds in tens times the quality factor of resonances in known plasmonic structures. The designed metamaterial is envisioned for aggregating with a pumped active medium to achieve an enhancement of luminescence and to produce an all-dielectric analog of a "lasing spaser". We report that an essential…
Strong Stokes and anti-Stokes one-photon luminescence from single gold nanorods is measured in experiments. It is found that the intensity and polarization of the Stokes and anti-Stokes emissions are in strong correlation. Our experimental observation discovered a coherent process in light emission from single gold nanorods. We present a theoretical mode, based on the concept of cavity resonance, for consistently understanding both Stokes and anti-Stokes photoluminescence. Our theory is in good agreement of all our measurements.
Plasmonic antennas are key elements to control the luminescence of quantum emitters. However, the antenna's influence is often hidden by quenching losses. Here, the luminescence of a quantum dot coupled to a gold dimer antenna is investigated. Detailed analysis of the multiply excited states quantifies the antenna's influence on the excitation intensity and the luminescence quantum yield separately.
The fact that surface-induced damping rate of surface plasmon polaritons (SPPs) in metal nanoparticles increases with the decrease of particle size is well known. We show that this rate also increases with the degree of the mode confinement, hence damping of the higher order nonradiative SPP modes in spherical particles is greatly enhanced relative to damping of the fundamental (dipole) SPP mode. Since higher order modes are the ones responsible for quenching of luminescence in the vicinity of metal surfaces, the degree of quenching increases resulting in a substantial decrease in the amount o…
Remote excitation and emission of two-photon luminescence and second-harmonic generation are observed in micrometer long gold rod optical antennas upon local illumination with a tightly focused near-infrared femtosecond laser beam. We show that the nonlinear radiations can be emitted from the entire antenna and the measured far-field angular patterns bear the information regarding the nature and origins of the respective nonlinear processes. We demonstrate that the nonlinear responses are transported by the propagating surface plasmon at excitation frequency, enabling thereby polariton-mediate…
The two-photon luminescence (TPL) of gold nanoparticles (NP) was shown to result from the excitation of hot carriers, the plasmonic NP resonances playing an important role both for plasmon enhanced absorption and plasmon enhanced emission. However, the exact parameters enabling to control or optimize the NP nonlinear luminescence still need to be understood in detail. In this paper, we report the two-photon excited photoluminescence of single gold nanorods exhibiting identical aspect ratio (close to 4) and thus identical plasmonic resonances, but increasing volumes V (707 <V< 160 103 nm3 i.e. …
We experimentally and theoretically investigate exciton-field coupling for the surface plasmon polariton (SPP) in waveguide-confined (WC) anti-symmetric modes of hexagonal plasmonic crystals in InP-TiO-Au-TiO-Si heterostructures. The radiative decay time of the InP-based transverse magnetic (TM)-strained multi-quantum well (MQW) coupled to the SPP modes is observed to be 2.9-3.7 times shorter than that of a bare MQW wafer. Theoretically we find that 80 % of the enhanced PL is emitted into SPP modes, and 17 % of the enhanced luminescence is redirected into WC-anti-symmetric modes. In addition t…
Metal-halide perovskites are rapidly emerging as solution-processable optical materials for light emitting applications. Here we adopt a plasmonic metamaterial approach to enhance photoluminescence emission and extraction of methylammonium lead iodide (MAPbI3) thin films, based on the Purcell effect. We show that hybridization of the active metal-halide film with resonant nanoscale sized slits carved into a gold film can yield more than one order of magnitude enhancement of luminescence intensity, and nearly threefold reduction of luminescence lifetime. This shows the effectiveness of resonant…
This paper addresses recent experimental findings about luminescence of a gold tip in near-field interaction with a gold surface. Our electrochemically etched gold tips show a typical, intrinsic luminescence that we exploit to track the plasmon resonance modeled by a Lorentzian oscillator. Our experimental device is based on a spectrometer optically coupled to an atomic force microscope used in tuning fork mode. Our measurements provide evidence of a strong optical coupling between the tip and the surface. We demonstrate that this coupling strongly affects the luminescence (Intensity, waveleng…
Metal losses affect the performance of every plasmonic or metamaterial structure; dealing with them will determine the degree to which these structures will find practical applications.
Self-decoupled tetrapodal perylene molecules were designed, synthesized, and deposited on the Au(111) surface through the electrosprayionization technique. Photoluminescence and lifetime measurements show that the chromophore groups of the designed molecules are welldecoupled from the gold substrate. Preliminary scanning tunneling microscopy induced luminescence measurements indicate theobservation of molecule-specific emissions from isolated single tetrapodal perylene molecules adsorbed directly on Au(111). The emergenceof significant emission when the tip is positioned at the molecular cente…
We develop an approach to utilize anisotropic metamaterials to solve one of the fundamental problems of modern plasmonics -- parasitic scattering of surface waves into free-space modes, opening the road to truly two-dimensional plasmonic optics. We illustrate the developed formalism on examples of plasmonic refractor and plasmonic crystal, and discuss limitations of the developed technique and its possible applications for sensing and imaging structures, high-performance mode couplers, optical cloaking structures, and dynamically reconfigurable electro-plasmonic circuits.
A plasmonic "molecule" consisting of a radiative element coupled with a sub-radiant (dark) element is theoretically investigated. The plasmonic "molecule" shows close resemblance to the electromagnetically induced transparency (EIT) in an atomic system. Because of its sub-wavelength dimension, this EIT-like "molecule" can be used as building block to construct a "slow light" plasmonic metamaterial.
We demonstrate polarization controlled absorption in plasmonic bimetallic metamaterials. We fabricate and experimentally characterize Au/Ni ring resonator arrays, where by varying the wavelength and polarization of the incident wave, local electromagnetic fields and dissipation can be suppressed or enhanced in the Au and Ni areas of the rings.
Noble metals that currently dominate the fields of plasmonics and metamaterials suffer from large ohmic losses. New plasmonic materials, such as doped oxides and nitrides, have smaller material loss, and, using them in place of metals carries promise of reduced-loss plasmonic and metamaterial structures, with sharper resonances and higher field concentration. This promise is put to a rigorous analytical test in this work which reveals that having low material loss is not sufficient to have a reduced modal loss in plasmonic structures. To reduce the modal loss it is absolutely necessary for the…
Plasmonics and metamaterials have attracted considerable attention over the past decade, owing to the revolutionary impacts that they bring to both the fundamental physics and practical applications in multiple disciplines. Although the two fields initially advanced along their individual trajectories in parallel, they started to interfere with each other when metamaterials reached the optical regime. The dynamic interplay between plasmonics and metamaterials has generated a number of innovative concepts and approaches, which are impossible with either area alone. This review presents the fund…
Plasmonic gratings and nano-particle arrays in a metal-insulator-metal structures are fabricated on an erbium doped silicon nitride layer. This material system enables simple fabrication of the structure, since the active nitride layer can be directly grown on metal. Enhancement of collected emission of up to 12 is observed on resonance, while broad off-resonant enhancement is also present. The output polarization behavior of the gratings and nano-particle arrays is investigated and matched to plasmonic resonances, and the behavior of coupled modes as a function of inter-particle distance is a…
The development of responsive metamaterials has enabled the realization of compact tunable photonic devices capable of manipulating the amplitude, polarization, wave vector, and frequency of light. Integration of semiconductors into the active regions of metallic resonators is a proven approach for creating nonlinear metamaterials through optoelectronic control of the semiconductor carrier density. Metal-free subwavelength resonant semiconductor structures offer an alternative approach to create dynamic metamaterials. We present InAs plasmonic disk arrays as a viable resonant metamaterial at t…
We theoretically investigate the optical properties of parity-time (PT)-symmetric three dimensional metamaterials composed of strongly-coupled planar plasmonic waveguides. By tuning the loss-gain balance, we show how the initially isotropic material becomes both asymmetric and unidirectional. The highly tunable optical dispersion of PT -symmetric metamaterials provides a foundation for designing an entirely new class of three-dimensional bulk synthetic media, with applications ranging from sub-diffraction-limited optical lenses to non-reciprocal nanophotonic devices.
Strongly anisotropic media with hyperbolic dispersion can be used for claddings of plasmonic waveguides. In order to analyze the fundamental properties of such waveguides, we analytically study 1D waveguides arranged of a hyperbolic metamaterial (HMM) in a HMM-Insulator-HMM (HIH) structure. We show that hyperbolic metamaterial claddings give flexibility in designing the properties of HIH waveguides. Our comparative study on 1D plasmonic waveguides reveals that HIH-type waveguides can have a higher performance than MIM or IMI waveguides.
We introduce two types of toroidal metamaterials which are invisible to surface plasmon polaritons (SPPs) propagating on a metal surface. The former is a toroidal handlebody bridging remote holes on the metal surface: It works as a kind of plasmonic counterpart of electromagnetic wormholes. The latter is a toroidal ring lying on the metal surface: This bridges two disconnected metal surfaces i.e. It connects a thin metal cylinder to a flat metal surface with a hole. Full-wave numerical simulations demonstrate that an electromagnetic field propagating inside these metamaterials does not disturb…
We propose a design for optical-frequency double-negative metamaterials (DMNs) in which the unit cell is formed by a single-layer plasmonic inclusion. By introducing some properly arranged stepwise modulations onto the inclusions, the effective permittivity and permeability of the material may become simultaneously negative due to the excitation of higher-order multipole plamonic (electrostatic) resonances. The approach opens a possibility to construct low-loss optical DNMs with great engineering simplicity.
Single-photon and correlated two-photon sources are important elements for optical information systems. Nonlinear downconversion light sources are robust and stable emitters of single photons and entangled photon pairs. However, the rate of downconverted light emission, dictated by the properties of low-symmetry nonlinear crystals, is typically very small, leading to significant constrains in device design and integration. In this paper, we show that the principles for spontaneous emission control (i.e. Purcell effect) of isolated emitters in nanoscale structures, such as metamaterials, can be…
We derive general coupled-mode equations describing the nonlinear interaction of electromagnetic modes in media with loss and gain. Our approach is rigorously based on the Lorentz reciprocity theorem, and it can be applied to a broad range of metal-dielectric photonic structures, including plasmonic waveguides and metamaterials. We verify that our general results agree with the previous analysis of particular cases, and predict novel effects on self- and cross-phase modulation in multi-layer nonlinear fishnet metamaterials.
Hyperbolic plasmonic metamaterials provide numerous opportunities for designing unusual linear and nonlinear optical properties. We show that the modal overlap of fundamental and second-harmonic light in an anisotropic plasmonic metamaterial slab results in the broadband enhancement of radiated second-harmonic intensity by up to 2 orders of magnitudes for TM- and TE-polarized fundamental light, compared to a smooth Au film under TM-polarised illumination. The results open up possibilities to design tuneable frequency-doubling metamaterial with the goal to overcome limitations associated with c…
Electromagnetic absorbers have drawn increasing attention in many areas. A series of plasmonic and metamaterial structures can work as efficient narrow band absorbers due to the excitation of plasmonic or photonic resonances, providing a great potential for applications in designing selective thermal emitters, bio-sensing, etc. In other applications such as solar energy harvesting and photonic detection, the bandwidth of light absorbers is required to be quite broad. Under such a background, a variety of mechanisms of broadband/multiband absorption have been proposed, such as mixing multiple r…
A metamaterials-based approach to making a wide-angle absorber of infrared radiation is described. The technique is based on an anisotropic Perfectly Impedance Matched Negative Index Material (PIMNIM). It is shown analytically that a sub-wavelength in all three dimensions PIMNIM enables absorption of close to 100% for incidence angles up to $45°$ to the normal. A specific implementation of such frequency-tunable PIMNIM based on plasmonic metamaterials is presented. Applications to infrared imaging and coherent thermal sources are described.
We present optical investigations of hybrid plasmonic nanosystems consisting of lithographically defined plasmonic Au-waveguides or beamsplitters on GaAs substrates coupled to proximal self-assembled InGaAs quantum dots. We designed a sample structure that enabled us to precisely tune the distance between quantum dots and the sample surface during nano-fabrication and demonstrated that non-radiative processes do not play a major role for separations down to $\sim 10 nm$. A polarized laser beam focused on one end of the plasmonic nanostructure generates propagating surface plasmon polaritons th…
Multiresonant metasurfaces could enable many applications in filtering, sensing and nonlinear optics. However, developing a metasurface with more than one high-quality-factor or high-Q resonance at designated resonant wavelengths is challenging. Here, we experimentally demonstrate a plasmonic metasurface exhibiting different, narrow surface lattice resonances by exploiting the polarization degree of freedom where different lattice modes propagate along different dimensions of the lattice. The surface consists of aluminum nanostructures in a rectangular periodic lattice. The resulting surface l…
We show that a metallic plate with fractal-shaped slits can be homogenitized as a plasmonic metamaterial with plasmon frequency dictated by the fractal geometry. Owing to the all-dimensional subwavelength nature of the fractal pattern, our system supports both transverse-electric and transverse-magnetic surface plasmons. As a result, this structure can be employed to focus light sources with all-dimensional subwavelength resolutions and enhanced field strengths. Microwave experiments reveal that the best achievable resolution is only, and simulations demonstrate that similar effects can be rea…
This work investigates the problematic diffusion of metal atoms into phase change chalcogenides, which can destroy resonances in photonic devices. Interfaces between Ge2Sb2Te5 and metal layers were studied using X-ray reflectivity (XRR) and reflectometry of metal-Ge2Sb2Te5 layered stacks. The diffusion of metal atoms influences the crystallisation temperature and optical properties of phase change materials. When Au, Ag, Al, W structures are directly deposited on Ge2Sb2Te5 inter-diffusion occurs. Indeed, Au forms AuTe2 layers at the interface. Diffusion barrier layers, such as Si3N4 or stable …
We present an analytical study to the structure-modulated plasmonic angular momentum trapped on periodic metal-dielectric nano-wedges in the core region of a sectorial indefinite metamaterial. Employing a transfer-matrix calculation and a conformal-mapping technique, our theory is capable of dealing with realistic configurations of arbitrary sector numbers and rounded wedge tips. We demonstrate that in the deep-subwavelength regime strong electric field carrying high azimuthal variation can exist within only ten-nanometer length scale close to the structural center, and is naturally bounded by…
Metallic nanoslit arrays integrated on germanium metal-semiconductor-metal photodetectors show many folds of absorption enhancement for transverse-magnetic polarization in the telecommunication C-band. Such high enhancement is attributed to resonant interference of surface plasmon modes at the metal-semiconductor interface. Horizontal surface plasmon modes were reported earlier to inhibit photodetector performance. We computationally show, however, that horizontal modes enhance the efficiency of surface devices despite reducing transmitted light in the far field.
We consider an array of the meta-atom consisting of two cut-wires and a split-ring resonator interacting with an electromagnetic field with two polarization components. We prove that such metamaterial system can be taken as a classical analogue of an atomic medium with a double- $Λ$-type four-level configuration coupled with four laser fields, exhibits an effect of plasmon induced transparency (PIT), and displays a similar behavior of atomic four-wave mixing (FWM). We demonstrate that when nonlinear varactors are mounted onto the gaps of the split-ring resonators the system can acquire giant s…
Nanostructured metal surfaces comprised of periodically arranged spherical voids are grown by electrochemical deposition through a self-assembled template. Detailed measurements of the angle- and orientation-dependent reflectivity reveal the spectral dispersion, from which we identify the presence of both delocalized Bragg- and localized Mie-plasmons. These couple strongly producing bonding and anti-bonding mixed plasmons with anomalous dispersion properties. Appropriate plasmon engineering of the void morphology selects the plasmon spatial and spectral positions, allowing these plasmonic crys…
We consider a simple configuration for realizing one-dimensional slow-light metamaterials with large bandwidth-delay products using stub-shaped Fabry-Perot resonators as building blocks. Each metaatom gives rise to large group indices due to a classical analog of the dressed-state picture of electromagnetically-induced transparency. By connecting up to eight metaatoms, we find bandwidth-delay products over unity and group indices approaching 100. Our approach is quite general and can be applied to any type of Fabry-Perot resonators and tuned to different operating wavelengths.
A tri-layer metamaterial perfect absorber of light, consisting of (Al/ZnS/Al) films with the top aluminium layer patterned as an array of circular disk nanoantennas, is investigated for resonantly enhancing Raman scattering from C-60 fullerene molecules deposited on the metamaterial. The metamaterial is designed to have resonant bands due to plasmonic and electromagnetic resonances at the Raman pump frequency (725 nm) as well as Stokes emission bands. The Raman scattering from C60 on the metamaterial with resonantly matched bands is measured to be enhanced by an order of magnitude more than fr…
By embedding four-rod resonators inside double-split ring resonators superlattice, a planar composite metamaterial possessing tripod plasmonic resonances is fabricated. Double Fano resonances are observed where a common subradiant driven oscillator is coupled with two superradiant oscillators. As a classical analogue of four-level tripod atomic system, the transmission spectrum of the composite metamaterial exhibits a double Fano-based coherent effect. Transfer of absorbed power between two superradiant oscillators is controlled by manipulating two coupling strengths conjugated through the pol…
Plasmonic color filters employing a single optically-thick nanostructured metal layer have recently generated considerable interest as an alternative to colorant-based color filtering technologies, due to their reliability, ease of fabrication, high color tunability. However, their relatively low transmission efficiency (~30%) is an important challenge that needs to be addressed. The present work reports, for the first time, a novel plasmonic subtractive color filtering scheme that exploits the counter-intuitive phenomenon of extraordinary low transmission (ELT) through an ultrathin nanostruct…
Photoelectric properties of metamaterials containing non-centrosymmetric, similarly oriented metallic nanoparticles embedded in a homogeneous semiconductor matrix are theoretically studied. Due to the asymmetric shape of the nanoparticle boundary, photoelectron emission acquires a preferred direction, resulting in a photocurrent flow in that direction when nanoparticles are uniformly illuminated by a homogeneous plane wave. This effect is a direct analogy of the photogalvanic (or bulk photovoltaic) effect known to exist in media with non-centrosymmetric crystal structure, such as doped lithium…
The toroidal dipole is an exquisite electromagnetic momentum apart from the classical multipoles family that can be localized and squeezed in an extremely tiny spot. This mode, in optical nanosystems, can be particularly distinguished as a non-radiating charge-current configuration, manifests in a head-to-tail fashion. Here going beyond conventional toroidal dipoles, we explained the possibility of the excitation of directional toroidal dipoles in plasmonic meta-atoms driven by controlling the oblique poloidal fluxes. We showed that the unique structural properties of the proposed asymmetric d…
Alternative materials are required to enhance the efficacy of plasmonic devices. We discuss the optical properties of a number of alloys, doped metals, intermetallics, silicides, metallic glasses and high pressure materials. We conclude that due to the probability of low frequency interband transitions, materials with partially occupied d-states perform poorly as plasmonic materials, ruling out many alloys, intermetallics and silicides as viable. The increased probability of electron-electron and electron-phonon scattering rules out many doped and glassy metals.
We consider plasmonic nanoantennas immersed in active host medium. Specifically shaped metal nanoantennas can exhibit strong magnetic properties in the optical spectral range due to the excitation of Magnetic Plasmon Resonance (MPR). A case when a metamaterial comprising such nanoantennas can demonstrate both "left-handiness" and negative permeability in the optical range is considered. We show that high losses predicted for optical "left- handed" materials can be compensated in the gain medium. Gains required to achieve local generation in such magnetic active metamaterials are calculated for…
A new configuration for metasurface construction is presented to achieve multi-functional capabilities including perfect absorption, bio/chem sensing, and surface-mode lasing. The reciprocal plasmonic metasurfaces discussed here are composed of two plasmonic surfaces of reciprocal geometries separated by a dielectric spacer. Compared to conventional metasurfaces this simple geometry exhibits an enhanced optical performance. The discussed reciprocal metasurface design further enables effective structural optimization and allows for a simple and scalable fabrication. The physical principle and p…
Recent advances in nano-fabrication techniques allow for the manufacture of optical metamaterials, bringing their unique and extra-ordinary properties to the visible regime and beyond. However, an analytical description of optical nano-plasmonic metamaterials is challenging due to the characteristic optical behaviour of metals. Here we present an analytical theory that allows to bring established microwave metamaterials models to optical wavelengths. This method is implemented for nano-scaled plasmonic wire-mesh and tri-helical metamaterials, and we obtain an accurate prediction for their disp…
We review the basic physics behind light interaction with plasmonic nanoparticles. The theoretical foundations of light scattering on one metallic particle (a plasmonic monomer) and two interacting particles (a plasmonic dimer) are systematically investigated. Expressions for effective particle susceptibility (polarizability) are derived, and applications of these results to plasmonic nanoantennas are outlined. In the long-wavelength limit, the effective macroscopic parameters of an array of plasmonic dimers are calculated. These parameters are attributable to an effective medium corresponding…
Rapid progress in plasmonics biosensors and immunosensors brings many methodologies to employ resonant subwavelength structures associated with the physics of multipoles, Fano resonances, and analogous moments. Here, we review a broad range of traditional and novel techniques that have been utilized for developing advanced biosensing tools including colloidal nanoparticles (NPs)-based systems to well-engineered arrays of meta-atoms and metamolecules. By describing some of the important and practical label-free biosensing methods based on subwavelength plasmonic technology, we discuss the emerg…
Axionic electrodynamics predicts many peculiar magnetoelectric-based properties. Hitherto, simple structures such as one-dimensional multilayers were employed to explore these axionic magnetoelectric responses, and Fabry-Pérot interference mechanism was frequently applied to augment these effects. In this Letter, we propose a new mechanism, metamaterial-enhanced axionic magnetoelectric response, by taking advantage of intense enhancement of localized electromagnetic fields associated with plasmonic resonances. Through numerical simulations, we show that plasmonic metamaterial can enhance axion…
Plasmonics is a rapidly emerging platform for quantum state engineering with the potential for building ultra-compact and hybrid optoelectronic devices. Recent experiments have shown that despite the presence of decoherence and loss, photon statistics and entanglement can be preserved in single plasmonic systems. This preserving ability should carry over to plasmonic metamaterials, whose properties are the result of many individual plasmonic systems acting collectively, and can be used to engineer optical states of light. Here, we report an experimental demonstration of quantum state filtering…
Plasmonics has conventionally been in the realm of metal-optics. However, conventional metals as plasmonic elements in the near-infrared (NIR) and visible spectral ranges suffer from problems such as large losses and incompatibility with semiconductor technology. Replacing metals with semiconductors can alleviate these problems if only semiconductors could exhibit negative real permittivity. Aluminum doped zinc oxide (AZO) is a low loss semiconductor that can show negative real permittivity in the NIR. A comparative assessment of AZO-based plasmonic devices such as superlens and hyperlens with…
Plasmonic metamaterials can be used to enhance mid-infrared sensors and detectors for immunosensing applications. The major challenge is to integrate these technologies in low-cost, compact, and promising platforms. In this study, as an emerging approach, we utilized toroidal resonant plasmonic metasurfaces to develop an ultrasensitive label-free analytical platform for the detection of specific antibiotics in the mid-IR regime. Taking advantage of unique sensitivity of robustly squeezed electromagnetic fields in toroidal meta-atoms, we validated that our proposed technique based on toroidal m…
The search for alternative plasmonic materials with improved optical properties over the traditional materials like silver and gold could ultimately lead to the long-awaited, real-life applications of plasmonic devices and metamaterials. In this work, we show that titanium nitride could perform as an alternative plasmonic material in the visible wavelength range. We evaluate the performances of various plasmonic and metamaterial structures with titanium nitride as a plasmonic component and show that transformation-optics devices and an important class of metamaterials with hyperbolic dispersio…
Whether dispersal of plasmonic nanoparticles (NPs) within a perovskite active layer can increase the efficiency of solar cells is a long-standing question. It is well known that inclusion of metallic NPs in an active layer can boost the surrounding near-field intensity around them owing to the dipolar localized surface plasmon resonance (LSPR, also called antenna effect), which can increase light absorption by solar cells. However, the use of plasmonic NPs in perovskite solar cells has been barely reported, and it is not known whether inserting plasmonic NPs into a perovskite active layer prod…
We demonstrate that ultrafast carrier excitation can drastically affect electronic structures and induce brief surface plasmonic response in non-plasmonic metals, potentially creating a plasmonic switch. Using first-principles molecular dynamics and Kubo-Greenwood formalism for laser-excited tungsten we show that carrier heating mobilizes d electrons into collective inter and intraband transitions leading to a sign flip in the imaginary optical conductivity, activating plasmonic properties for the initial non-plasmonic phase. The drive for the optical evolution can be visualized as an increasi…
As alternatives to conventional metals, new plasmonic materials offer many advantages in the rapidly growing fields of plasmonics and metamaterials. These advantages include low intrinsic loss, semiconductor-based design, compatibility with standard nanofabrication processes, tunability, and others. Transparent conducting oxides such as Al:ZnO, Ga:ZnO and indium-tin-oxide (ITO) enable many high-performance metamaterial devices operating in the near-IR. Transition-metal nitrides such as TiN or ZrN can be substitutes for conventional metals in the visible frequencies. In this paper we provide th…
