Symmetries play an essential role in identifying and characterizing topological states of matter. Here, we classify topologically two-dimensional (2D) insulators and semimetals with vanishing spin-orbit coupling using time-reversal ($\mathcal{T}$) and inversion ($\mathcal{I}$) symmetry. This allows us to link the presence of edge states in $\mathcal{I}$ and $\mathcal{T}$ symmetric 2D insulators, which are topologically trivial according to the Altland-Zirnbauer table, to a $\mathbb{Z}_2$ topological invariant. This invariant is directly related to the quantization of the Zak phase. It also predicts the generic presence of edge states in Dirac semimetals, in the absence of chiral symmetry. We then apply our findings to bilayer black phosphorus and show the occurrence of a gate-induced topological phase transition, where the $\mathbb{Z}_2$ invariant changes.
The recently discovered topological Dirac semimetal represents a new exotic quantum state of matter. Topological Dirac semimetals can be viewed as three dimensional analogues of graphene, in which the Dirac nodes are protected by crystalline symmetry. It has been found that quantum confinement effect can gap out Dirac nodes and convert Dirac semimetal to a band insulator. The band insulator is either normal insulator or quantum spin Hall insulator depending on the thin film thickness. We present the study of disorder effects in thin film of Dirac semimetals. It is found that moderate Anderson …
We propose a different route to time-reversal invariant Weyl semimetals employing multilayer heterostructures comprising ordinary "trivial" insulators and nontrivial insulators with \textit{pairs} of protected Dirac cones on the surface. We consider both the case of weak topological insualtors, where surface Dirac cones are pinned to time-reversal invariant momenta, and of topological crystalline insulators with unpinned surface Dirac cones. For both realizations we explain phenomenologically how the proposed construction leads to the emergence of a Weyl semimetal phase. We further formulate e…
In this Book Chapter (invited) we briefly review the basic concepts defining topological insulators and focus on elaborating on the key experimental results that revealed and established their symmetry protected (SPT) topological nature. We then present key experimental results that demonstrate magnetism, Kondo insulation, mirror chirality or topological crystalline order and superconductivity in spin-orbit topological insulator settings and how these new (bulk insulating) phases of matter arise through topological quantum phase transitions from Bloch band insulators via topological or Dirac s…
The recent explosion of research interest in Weyl semimetals has led to many proposed Weyl semimetal candidates and a few experimental observations of a Weyl semimetal in real materials. Through this experience, we have come to appreciate that typical Weyl semimetals host many Weyl points. For instance, the first Weyl semimetal observed in experiment, TaAs, hosts 24 Weyl points. Similarly, the Mo$_x$W$_{1-x}$Te$_2$ series, recently under study as the first Type II Weyl semimetal, has eight Weyl points. However, it is well-understood that for a Weyl semimetal without inversion symmetry but with…
By first-principles calculations, we find that Ba2X(X=Si, Ge) hosts a topological semimetal phase with one nodal ring in the kx=0 plane, which is protected by the glide mirror symmetry when spin-orbit coupling (SOC) is ignored. The corresponding drumheadlike surface flat band appears on the (100) surface in surface Green function calculation. Furthermore, a topological-semimetal-to-insulator transition (TSMIT) is found. The nodal line semimetal would evolve into topological insulator as SOC is turned on. The topologically protected metallic surface states emerge around the Gamma=0 point, which…
We show that, under the effect of an external magnetic field, a photogalvanic effect and the generation of second harmonic wave can be induced in inversion-symmetric and time reversal invariant Dirac semimetals. The mechanism responsible of these non linear optical responses is the magnetochiral effect. The origin of this magnetochiral effect is the band bending of the dispersion relation in real Dirac semimetals. Some observable consequences of this phenomenon are the appearance of a dc current on the surface of the system when it is irradiated with linearly polarized light or a rotation of t…
Three-dimensional topological gapless phases have attracted significant attention due to their unique electronic properties. A flagship example are Weyl semimetals, which require breaking time-reversal or inversion symmetry. In two dimensions, the dimensionality reduction requires imposing an additional symmetry, thereby weakening the phase. Like its three-dimensional counterpart, these two-dimensional Weyl semimetals present edge states directly related to Weyl nodes. The direct comparison with the edge states in zigzag-like terminated graphene ribbons is unavoidable, offering the question of…
The electronic bands are classified according to their topology. We compute the connection and curvature for the electronic bands and show that the physical properties are determined by topological invariants which are equivalent to the existence of the zero modes. We apply this method to the Topological Insulators and Topogical Superconductors.
In this work, we propose a ferromagnetic Bi$_2$Se$_3$ as a candidate to hold the coexistence of Weyl- and nodal-line semimetal phases, which breaks the time reversal symmetry. We demonstrate that the type-I Weyl semimetal phase, type-I-, type-II- and their hybrid nodal-line semimetal phases can arise by tuning the Zeeman exchange field strength and the Fermi velocity. Their topological responses under U(1) gauge field are also discussed. Our results raise a new way for realizing Weyl and nodal-line semimetals and will be helpful in understanding the topological transport phenomena in three-dim…
The Luttinger model of a quadratic-node semimetal for electrons with the $j=\frac32$ angular momentum under cubic symmetry is the parent, highest-symmetry low-energy model for a variety of topological and strongly correlated materials, such as HgTe, $α$-Sn, and iridate compounds. Previously, we have theoretically demonstrated that the Luttinger semimetal exhibits surface states. In the present work, we theoretically study the evolution of these surface states under symmetry-lowering perturbations: compressive strain and bulk-inversion asymmetry (BIA). This system is quite special in that each …
We report a gate-controlled transition of a semimetallic InAs/GaSb heterostructure to a topological insulator. The transition is induced by decreasing the degree of band inversion with front and back gate voltages. Temperature dependence of the longitudinal resistance peak shows the energy gap opening in the bulk region with increasing gate electric field. The suppression of bulk conduction and the transition to a topological insulator are confirmed by nonlocal resistance measurements using a dual lock-in technique, which allows us to rigorously compare the voltage distribution in the sample f…
Realizing stable two-dimensional (2D) Dirac points against spin-orbit coupling (SOC) has attracted much attention because it provides a platform to study the unique transport properties. In previous work, Young and Kane [Phys. Rev. Lett. \textbf{115}, 126803 (2015)] proposed stable 2D Dirac points with SOC, in which the Berry curvature and edge states vanish due to the coexistence of inversion and time-reversal symmetries. Herein, using the tight-binding model and k$\cdot$p effective Hamiltonian, we present that 2D Dirac points can survive in the presence of SOC without inversion symmetry. Suc…
We study the problem of phase transitions from 3D topological to normal insulators without inversion symmetry. In contrast with the conclusions of some previous work, we show that a Weyl semimetal always exists as an intermediate phase regardless of any constriant from lattice symmetries, although the interval of the critical region is sensitive to the choice of path in the parameter space and can be very narrow. We demonstrate this behavior by carrying out first-principles calculations on the noncentrosymmetric topological insulators LaBiTe$_3$ and LuBiTe$_3$ and the trivial insulator BiTeI. …
Revealing the ultrafast dynamics of three-dimensional (3D) Dirac fermions upon photoexcitation is critical for both fundamental science and device applications. So far, how the cooling of 3D Dirac fermions differs from that of two-dimensional (2D) Dirac fermions and whether there is population inversion are fundamental questions that remain to be answered. Here we reveal the ultrafast dynamics of Dirac fermions in a model 3D Dirac semimetal Cd$_3$As$_2$ by ultrafast time- and angle-resolved photoemission spectroscopy (TrARPES) with a tunable probe photon energy from 5.3 - 6.9 eV. The energy- a…
We propose magnetic second-order topological insulators (SOTIs). First, we study a three-dimensional model. It is pointed out that the previously proposed topological hinge insulator has actually surface states along the [001] direction in addition to hinge states. We gap out these surface states by introducing magnetization, obtaining a SOTI only with hinge states. The bulk topological number is the $Z_2$ index protected by the combined symmetry of the four-fold rotation and the inversion symmetry. We next study two dimensional magnetic SOTIs, where the corner states are robust also in the pr…
A band gap for electronic states in crystals governs various properties of solids, such as transport, optical and magnetic properties. Its estimation and control have been an important issue in solid state physics. The band gap can be controlled externally by various parameters, such as pressure, atomic compositions and external field. Sometimes, the gap even collapses by tuning some parameter. In the field of topological insulators, such closing of the gap at a time-reversal invariant momentum indicates a band inversion, i.e. it leads to a topological phase transition from a normal insulator …
We study the electronic properties of strongly spin-orbit coupled electrons on the elastic pyrochlore lattice. Akin to the Peierls transition in one-dimensional systems, the coupling of the lattice to the electronic degrees of freedom can stabilize a spontaneous deformation of the crystal. This deformation corresponds to a breathing mode, which breaks the inversion symmetry. We find that for intermediate values of the staggered strain, the inversion-symmetry broken phase realizes a topological Weyl semimetal. In the temperature-elasticity phase diagram, the Weyl semimetal shows a reentrant pha…
We investigate the effects of periodic fields and disorder on topological properties of a Weyl-semimetal thin film. The two periodic fields, i.e., a periodic magnetic field and elliptically polarized light, are discussed respectively. By use of the Floquet theory, we find that both the two periodic drives can resonantly induce the topological transitions from normal insulator (NI) phases to Floquet topological insulator (FTI) phases. The Floquet topological transitions are characterized by variation of Chern number. Moreover, we show that the Floquet topological transitions can be explained by…
In this work we provide a new direct and non-numerical technique to obtain the surface Green's functions for three-dimensional systems. This technique is based on the ideas presented in Phys. Rev. B 100, 081106(R), in which we start with an infinite system and model the boundary using a plane-like infinite-amplitude potential. Such a configuration can be solved exactly using the T-matrix formalism. We apply our method to calculate the surface Green's function and the corresponding Fermi-arc states for Weyl semimetals. We also apply the technique to systems of lower dimensions, such as Kane-Mel…
Regarding three-dimensional (3D) topological insulators and semimetals as a stack of constituent 2D topological (or sometimes non-topological) layers is a useful viewpoint. Primarily, concrete theoretical models of the paradigmatic 3D topological phases such as Weyl semimetal (WSM), strong and weak topological insulators (STI/WTI), and Chern insulator (CI), are often constructed in that way. Secondarily, fabrication of the corresponding 3D topological material is also done in the same spirit; epitaxial growth technique is employed, making the resulting sample in the form of a thin film. Here, …
The notion of higher-order topological insulators has endowed materials with topological states beyond the first order. Particularly, a three-dimensional (3D) higher-order topological insulator can host topologically protected 1D hinge states, referred to as the second-order topological insulator, or 0D corner states, referred to as the third-order topological insulator. Similarly, a 3D higher-order topological semimetal can be envisaged if it hosts states on the 1D hinges. Here we report the realization of a second-order topological Weyl semimetal in a 3D-printed acoustic crystal, which posse…
Weyl semimetal TaAs, a congenial host to the massless Weyl fermions, spontaneously lacks the time-reversal and the inversion symmetry and thus effectuates topologically stable Weyl nodes, resembling magnetic monopoles in momentum space. Former experimental analysis had revealed that the near-zero spin-polarization of bulk TaAs experiences a boost in presence of point-contacts of non-magnetic metals along with the associated phenomena of tip-induced superconductivity, providing the impetus to study the large-area stacked interfaces of TaAs with Noble metals like Au and Ag. First-principles calc…
We use first principles calculations to study the electronic properties of rock salt rare earth monopnictides La$X$ ($X=$N, P, As, Sb, Bi). A new type of topological band crossing termed `linked nodal rings' is found in LaN when the small spin-orbital coupling (SOC) on nitrogen orbitals is neglected. Turning on SOC gaps the nodal rings at all but two points, which remain gapless due to $C_4$-symmetry and leads to a 3D Dirac semimetal. Interestingly, unlike LaN, compounds with other elements in the pnictogen group are found to be topological insulators (TIs), as a result of band reordering due …
Universal magnetotunnel conductance at a Weyl semimetal-layered Chern insulator junction
Indian Institute of Technology Kanpur（坎普尔印度理工学院）；International Centre for Theoretical Sciences, Tata Institute of Fundamental Research（塔塔基础科学国际理论中心）；Technion - Israel Institute of Technology（以色列理工学院）
A heterostructure consisting of a magnetic Weyl semimetal and a conventional superconductor exhibits an equilibrium current parallel to the superconductor interface and perpendicular to the magnetization. Analyzing a minimal model, which as a function of parameters may be in a trivial magnetic insulator phase, a Weyl semimetal phase, or a three-dimensional weak Chern insulator phase, we find that the equilibrium current is sensitive to the presence of surface states, such as the topological Fermi-arc states of the Weyl semimetal or the chiral surface states of the weak Chern insulator. While t…
We investigate multilayer systems of a normal insulator and a Weyl semimetal. We calculate the bulk band structure and determine phase diagrams by changing the thickness of the normal insulator and that of the Weyl semimetal layer using two models; one is from the effective model for a Weyl semimetal, and the other is the lattice model. We compare the results between the two models, and found that they agree well. As a result, we find that the multilayer system shows a qualitatively different behavior depending on the stacking direction relative to the displacement vector connecting between tw…
Pursuing topological phases in natural and artificial materials is one of the central topics in modern physical science and engineering. In classical magnetic systems, spin waves (or magnons) and magnetic solitons (such as domain wall, vortex, skyrmion, etc) represent two important excitations. Recently, the topological insulator and semimetal states in magnon- and soliton-based crystals (or metamaterials) have attracted growing attention owing to their interesting dynamics and promising applications for designing robust spintronic devices. Here, we give an overview of current progress of topo…
We synthesized distorted octahedral(T') molybdenum ditelluride (MoTe2) and investigated its vibrational properties with Raman spectroscopy, density functional theory and symmetry analysis. Compared to the results from high temperature centrosymmetric monoclinic (T'mo) phase, four new Raman bands emerge in the low temperature orthorhombic (T'or) phase, which was recently predicted to be a type II Weyl semimetal. Crystal-angle-dependent, light-polarization-resolved measurements indicate that all the observed Raman peaks belong to two categories: those vibrating along the zigzag Mo atomic chain (…
For conventional topological phases, the boundary gapless modes are determined by bulk topological invariants. Based on developing an analytic method to solve higher-order boundary modes, we present $PT$-invariant $2$D topological insulators and $3$D topological semimetals that go beyond this bulk-boundary correspondence framework. With unchanged bulk topological invariant, their first-order boundaries undergo transitions separating different phases with second-order-boundary zero-modes. For the $2$D topological insulator, the helical edge modes appear at the transition point for two second-or…
We have experimentally realized novel space-time inversion (P-T) invariant Z2-type topological semimetal-bands, via an analogy between the momentum space and a controllable parameter space in superconducting quantum circuits. By measuring the whole energy spectrum of system, we imaged clearly an exotic tunable gapless band structure of topological semimetals. Two topological quantum phase transitions from a topological semimetal to two kinds of insulators can be manipulated by continuously tuning the different parameters in the experimental setup, one of which captures the Z2 topology of the P…
A three-dimensional (3D) nodal-loop semimetal phase is exploited to engineer a number of intriguing phases featuring different peculiar topological surface states. In particular, by introducing various two-dimensional gap terms to a 3D tight-binding model of a nodal-loop semimetal, we obtain a rich variety of topological phases of great interest to ongoing theoretical and experimental studies, including chiral insulator, degenerate-surface-loop insulator, second-order topological insulator, as well as Weyl semimetal with tunable Fermi arc profiles. The unique concept underlying our approach is…
Topological insulators (TIs) and Weyl semimetals (WSMs) are two realizations of topological matter usually appearing separately in nature. However, they are directly related to each other via a topological phase transition. In this paper, we investigate the question whether these two topological phases can exist together at the same time, with a combined, hybrid surface state at the joint boundaries. We analyze effective models of a 3D TI and an inversion symmetric WSM and couple them in a way that certain symmetries, like inversion, are preserved. A tunnel coupling approach enables us to obta…
The Weyl semimetal (WSM) is a newly proposed quantum state of matter. It has Weyl nodes in bulk excitations and Fermi arcs surface states. We study the effects of disorder and localization in WSMs and find three exotic phase transitions. (I) Two Weyl nodes near the Brillouin zone boundary can be annihilated pairwise by disorder scattering, resulting in the opening of a topologically nontrivial gap and a transition from a WSM to a three-dimensional (3D) quantum anomalous Hall state. (II) When the two Weyl nodes are well separated in momentum space, the emergent bulk extended states can give ris…
We study what kind of topological crystalline insulator phase emerges from nodal line semimetal phases in the face-centered cubic system which is not indicated by topological indices when spin-orbit coupling (SOC) is introduced. We construct an effective model which hosts two different nodal lines phases, and calculated mirror Chern numbers in it by introducing SOC. As a result, we find that the two nodal line phases with different nodal line configurations are mapped to different topological crystalline insulator phases. This result shows that turning off SOC and checking the nodal line confi…
We investigate the effect of a vertical electric field on a Dirac semimetal thin film. We show that through the interplay between the quantum confinement effect and the field-induced coupling between sub-bands, the sub-band gap can be tuned and inverted, during which the system undergoes a topological phase transition between a trivial band insulator and a quantum spin Hall insulator. Consequently, one can electrically switch the topological edge channels on and off, making the system a promising platform for constructing a topological field effect transistor.
A pair of Dirac points (analogous to a vortex-antivortex pair) associated with opposite topological numbers (with $\pmπ$ Berry phases) can be merged together through parameter tuning and annihilated to gap the Dirac spectrum, offering a canonical example of a topological phase transition. Here, we report transport studies on thin films of BiSbTeSe$_2$ (BSTS), which is a 3D TI that hosts spin-helical gapless (semi-metallic) Dirac fermion surface states (SS) for sufficiently thick samples, with an observed resistivity close to $h/4e^2$ at the charge neutral point. When the sample thickness is re…
Recent ab initio calculations and experiments reported insulating-semimetallic phase transitions in multilayer phosphorene under a perpendicular dc field, pressure or doping, as a possible route to realize topological phases. In this work, we show that even a monolayer phosphorene may undergo Lifshitz transitions toward semimetallic and topological insulating phases, provided it is rapidly driven by in-plane time-periodic laser fields. Based on a four-orbital tight-binding description, we give an inversion-symmetry-based prescription in order to apprehend the topology of the photon-renormalize…
We investigate electromagnetic properties of a topological crystalline insulator (TCI) thin film under external electromagnetic fields. The TCI thin film is a topological insulator indexed by the mirror-Chern number. It is demonstrated that the gap closes together with the emergence of a pair of gapless cones carrying opposite chirarities by applying in-plane magnetic field. A pair of gapless points have opposite vortex numbers. This is a reminiscence of a pair of Weyl cones in 3D Weyl semimetal. We thus present an a magnetic-field induced semimetal-semiconductor transition in 2D material. Thi…
The three dimensional (3D) topological insulators are predicted to exhibit a 3D Dirac semimetal state in critical regime of topological to trivial phase transition. Here we demonstrate the first experimental evidence of 3D Dirac semimetal state in topological insulator Bi2Se3 with bulk carrier concentration of ~ 10^19 cm^{-3}, using magneto-transport measurements. At low temperatures, the resistivity of our Bi2Se3 crystal exhibits clear Shubnikov-de Haas (SdH) oscillations above 6T. The analysis of these oscillations through Lifshitz-Onsanger and Lifshitz-Kosevich theory reveals a non-trivial …
Recently, we have introduced in [A. M. Marques et al., Phys. Rev. B 103, 235425 (2021)] the concept of $2^n$-root topology and applied it to one-dimensional systems. These models require $n$ squaring operations to their Hamiltonians, intercalated with different constant energy downshifts at each level, in order to arrive at a decoupled block corresponding to a known topological insulator (TI) that acts as the source of the topological features of the starting $2^n$-root TI ($\sqrt[2^n]{\text{TI}}$). In the process, $n$ non-topological residual models with degenerate spectra and in-gap impurity…
We develop a theory for the nonlinear time domain response of a Weyl semimetal driven by an ultrafast optical pulse. At quadratic order in the driving field we find that the response near a band inversion transition contains a coherent oscillating component proportional field intensity and with a frequency that can be tuned over a wide range (from THz to the near IR) selected by the chemical potential. We illustrate the effect by calculating the induced current as a function of time for a model of a parity broken Weyl semimetal where large Berry curvature near the band inversion transition pro…
We review our recent works on the quantum transport, mainly in topological semimetals and also in topological insulators, organized according to the strength of the magnetic field. At weak magnetic fields, we explain the negative magnetoresistance in topological semimetals and topological insulators by using the semiclassical equations of motion with the nontrivial Berry curvature. We show that the negative magnetoresistance can exist without the chiral anomaly. At strong magnetic fields, we establish theories for the quantum oscillations in topological Weyl, Dirac, and nodal-line semimetals. …
Starting from a minimal model for a 2D nodal loop semimetal, we study the effect of chiral mass gap terms. The resulting Dirac loop anomalous Hall insulator's Chern number is the phase winding number of the mass gap terms on the loop. We provide simple lattice models, analyze the topological phases and generalize a previous index characterizing topological transitions. The responses of the Dirac loop anomalous Hall and quantum spin Hall insulators to a magnetic field's vector potential are also studied both in weak and strong field regimes, as well as the edge states in a ribbon geometry.
In ultra-thin film of topological insulator, the hybridization between the top and bottom surfaces opens an energy gap and forms two degenerate quantum anomalous Hall states, which give rise to a quantum spin Hall state. In this paper, we demonstrate that a Weyl semimetal can be realized in an ultra-thin film of topological insulator heterostructure in a similar way to that of the surface state of a strong three-dimensional (3D) topological insulator studied by Burkov and Balents . We find that the system realizes both 3D quantum anomalous Hall phase and 3D quantum spin Hall phase, and the Wey…
We report on a fully self-consistent Hartree-Fock calculation of interaction effects on the Moiré flat bands of twisted bilayer graphene, assuming that valley U(1) symmetry is respected. We use realistic band structures and interactions and focus on the charge neutrality point, where experiments have variously reported either insulating or semimetallic behavior. Restricting the search to orders for which the valley U(1) symmetry remains unbroken, we find three types of self-consistent solutions with competitive ground state energy (i) insulators that break $C_2 {\mathcal T}$ symmetry, includin…
