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arXiv 1604.02771cond-mat.softcond-mat.mtrl-sci
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堵塞填料的热连通网络

Thermalized connectivity networks of jammed packings

Clemens Buss, Claus Heussinger, Oskar Hallatschek

摘要:

排斥性弹性球的堵塞填充已经成为一个丰富的模型系统,在该系统中无序玻璃材料的弹性性质可以得到阐明。关于这类填充的大部分工作都集中在温度为零的情形。在这里,我们探讨了有限温度下相关连接网络的弹性性质,忽略了键的断裂和新键的形成。使用广泛的蒙特卡罗模拟,我们发现,随着温度的升高,所得到的弹簧网络收缩,并通过尖点表现出快速软化的体积模量。此外,剪切模量硬化在一个固定的体积合奏,但不是在一个固定的压力合奏。这些违反直觉的行为可以从等静压附近的软模式的特征光谱来理解,其类似于杆在其屈曲不稳定性附近的光谱。我们的研究结果提出了一个通用的机制,在边缘固体负热膨胀系数。我们讨论了键断裂的后果和热化和剪切之间的明显的类比。

英文摘要:

Jammed packings of repulsive elastic spheres have emerged as a rich model system within which elastic properties of disordered glassy materials may be elucidated. Most of the work on these packings have focused on the case of vanishing temperature. Here, we explore the elastic properties of the associated connectivity network for finite temperatures, ignoring the breaking of bonds and the formation of new ones. Using extensive Monte Carlo simulations, we find that, as the temperature is increased, the resulting spring network shrinks and exhibits a rapidly softening bulk modulus via a cusp. Moreover, the shear modulus stiffens in a fixed volume ensemble but not in a fixed pressure ensemble. These counter-intuitive behaviors may be understood from the characteristic spectrum of soft modes near isostaticity, which resembles the spectrum of a rod near its buckling instability. Our results suggest a generic mechanism for negative thermal expansion coefficients in marginal solids. We discuss the consequences of bond breaking and an apparent analogy between thermalization and shear.

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