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arXiv 1508.07656cond-mat.stat-mechcond-mat.quant-gas
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二维盒子中无相互作用玻色气体的热力学

Thermodynamics of the Noninteracting Bose Gas in a Two-Dimensional Box

Heqiu Li, Qiujiang Guo, Ji Jiang, D. C. Johnston

摘要:

研究了二维盒子中N个粒子的无相互作用玻色气体在Dirichlet边界条件下的玻色-爱因斯坦凝聚(BEC).重复以前的工作,我们发现,BEC发生在有限的N在低温T没有发生相变。传统定义的无限三维系统的转变温度TE被示出为在具有有限N的二维系统中对应于基态的分数玻色子占据N 0/N随着T减小而缓慢和快速增加之间的交叉温度。我们进一步证明了在每个玻色子的固定面积下TE ~ 1/log(N),因此在热力学极限下,在有限T的二维情况下不存在显著的BEC。计算了该体系的Helmholtz自由能、熵S、压力p、p与能量密度之比U/A、定容热容CV和定压热容Cp、等温压缩系数kappa_T和热膨胀系数α_p,使用巨正则系综(GCE)和正则系综(CE)形式主义。GCE形式主义在大的N、T和A下对S、p、p/(U/A)、kappa_T和alpha_p给出了可接受的预测,但对于BEC变得显著的这三个参数的较小值则失败了,而CE形式主义甚至在发生BEC的低T和/或A下对有限系统的所有热力学性质给出了准确的结果。

英文摘要:

Bose-Einstein condensation (BEC) of a noninteracting Bose gas of N particles in a two-dimensional box with Dirichlet boundary conditions is studied. Confirming previous work, we find that BEC occurs at finite N at low temperatures T without the occurrence of a phase transition. The conventionally-defined transition temperature TE for an infinite 3D system is shown to correspond in a 2D system with finite N to a crossover temperature between a slow and rapid increase in the fractional boson occupation N0/N of the ground state with decreasing T. We further show that TE ~ 1/log(N) at fixed area per boson, so in the thermodynamic limit there is no significant BEC in 2D at finite T. Thus, paradoxically, BEC only occurs in 2D at finite N with no phase transition associated with it. Calculations of thermodynamic properties versus T and area A are presented, including Helmholtz free energy, entropy S , pressure p, ratio of p to the energy density U/A, heat capacity at constant volume (area) CV and at constant pressure Cp, isothermal compressibility kappa_T and thermal expansion coefficient alpha_p, obtained using both the grand canonical ensemble (GCE) and canonical ensemble (CE) formalisms. The GCE formalism gives acceptable predictions for S, p, p/(U/A), kappa_T and alpha_p at large N, T and A, but fails for smaller values of these three parameters for which BEC becomes significant, whereas the CE formalism gives accurate results for all thermodynamic properties of finite systems even at low T and/or A where BEC occurs.

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