Purely dissipative evolution equations are often cast as gradient flow structures, $\dot{\mathbf{z}}=K(\mathbf{z})DS(\mathbf{z})$, where the variable $\mathbf{z}$ of interest evolves towards the maximum of a functional $S$ according to a metric defined by an operator $K$. While the functional often follows immediately from physical considerations (e.g., the thermodynamic entropy), the operator $K$ and the associated geometry does not necessarily so (e.g., Wasserstein geometry for diffusion). In this paper, we present a variational statement in the sense of maximum entropy production that directly delivers a relationship between the operator $K$ and the constraints of the system. In particular, the Wasserstein metric naturally arises here from the conservation of mass or energy, and depends on the Onsager resistivity tensor, which, itself, may be understood as another metric, as in the Steepest Entropy Ascent formalism. This new variational principle is exemplified here for the simultaneous evolution of conserved and non-conserved quantities in open systems. It thus extends the classical Onsager flux-force relationships and the associated variational statement to variables that do not have a flux associated to them. We further show that the metric structure $K$ is intimately linked to the celebrated Freidlin-Wentzell theory of stochastically perturbed gradient flows, and that the proposed variational principle encloses an infinite-dimensional fluctuation-dissipation statement.
The rate of entropy production by a stochastic process quantifies how far it is from thermodynamic equilibrium. Equivalently, entropy production captures the degree to which detailed balance and time-reversal symmetry are broken. Despite abundant references to entropy production in the literature and its many applications in the study of non-equilibrium stochastic particle systems, a comprehensive list of typical examples illustrating the fundamentals of entropy production is lacking. Here, we present a brief, self-contained review of entropy production and calculate it from first principles i…
It is known that the thermal conductivity of a dilute gas can be derived by using kinetic theory. We present here a new derivation by starting with two known entropy production principles: the steepest entropy ascent (SEA) principle and the maximum entropy production (MEP) principle. A remarkable feature of the new derivation is that it does not require the specification of the existence of the temperature gradient. The known result is reproduced in a similar form.
In this note, we propose in the full generality a link between the BD entropy introduced by D. Bresch andB. Desjardins for the viscous shallow-water equations and the Bernis-Friedman (called BF) dissipative entropyintroduced to study the lubrications equations. Dierent dissipative entropies are obtained playing with the dragterms on the viscous shallow water equations. It helps for instance to prove global existence of nonnegativeweak solutions for the lubrication equations starting from the global existence of nonnegative weak solutions forappropriate viscous shallow-water equations.
By using entropy and entropy production, we calculate the steady flux of some phenomena. The method we use is a competition method, $S_S/τ+σ={\it maximum}$, where $S_S$ is system entropy, $σ$ is entropy production and $τ$ is microscopic interaction time. System entropy is calculated from the equilibrium state by studying the flux fluctuations. The phenomena we study include ionic conduction, atomic diffusion, thermal conduction and viscosity of a dilute gas.
It is known that the viscosity of a dilute gas can be derived by using kinetic theory. We present here a new derivation by using two entropy production principles: the steepest entropy ascent (SEA) principle and the maximum entropy production (MEP) principle. The known result is reproduced in a similar form.
We study a class of dissipative PDE's perturbed by an unbounded kick force. Under some natural assumptions, the restrictions of solutions to integer times form a homogeneous Markov process. Assuming that the noise is rough with respect to the space variables and has a non-degenerate law, we prove that the system in question satisfies a large deviation principle in tau-topology. Under some additional hypotheses, we establish a Gallavotti-Cohen type symmetry for the rate function of an entropy production functional and the strict positivity and finiteness of the mean entropy production in the st…
In this paper we further develop the fluctuating hydrodynamics proposed in arXiv:1511.03646 in a number of ways. We first work out in detail the classical limit of the hydrodynamical action, which exhibits many simplifications. In particular, this enables a transparent formulation of the action in physical spacetime in the presence of arbitrary external fields. It also helps to clarify issues related to field redefinitions and frame choices. We then propose that the action is invariant under a $Z_2$ symmetry to which we refer as the dynamical KMS symmetry. The dynamical KMS symmetry is physica…
We derive an Ito stochastic differential equation for entropy production in nonequilibrium Langevin processes. Introducing a random-time transformation, entropy production obeys a one-dimensional drift-diffusion equation, independent of the underlying physical model. This transformation allows us to identify generic properties of entropy production. It also leads to an exact uncertainty equality relating the Fano factor of entropy production and the Fano factor of the random time, which we also generalize to non steady-state conditions.
Dissipative processes abound in most areas of sciences and can often be abstractly written as $\partial_t z = K(z) δS(z)/δz$, which is a gradient flow of the entropy $S$. Although various techniques have been developed to compute the entropy, the calculation of the operator $K$ from underlying particle models is a major long-standing challenge. Here, we show that discretizations of diffusion operators $K$ can be numerically computed from particle fluctuations via an infinite-dimensional fluctuation-dissipation relation, provided the particles are in local equilibrium with Gaussian fluctuations…
An operator equality on the entropy production for general quantum Markovian master equations is derived without resorting quantum stochastic trajectory and priori quantum definition of entropy production. We find that, the equality can be still interpreted as a consequence of time-reversal asymmetry of the nonequilibrium processes of the systems. In contrast with the classical case, however, the first order expansion of the equality does not directly related to the mean entropy production, which arises from noncommute property of operators in quantum physics.
In this paper we take an idea presented in recent paper by Carlen, Carvalho, Le Roux, Loss, and Villani and push it one step forward to find an exact estimation on the entropy production. The new estimation essentially proves that Villani's conjecture is correct, or more precisely that a much worse bound to the entropy production is impossible in the general case.
We study the entropy production of Gibbs (equilibrium) measures for chaotic dynamical systems with folding of the phase space. The dynamical chaotic model is that generated by a hyperbolic non-invertible map $f$ on a general basic (possibly fractal) set $Λ$; the non-invertibility creates new phenomena and techniques than in the diffeomorphism case. We prove a formula for the \textit{entropy production}, involving an asymptotic logarithmic degree, with respect to the equilibrium measure $μ_ϕ$ associated to the potential $ϕ$. This formula helps us calculate the entropy production of the measure …
We investigate dissipative anomalies in a turbulent fluid governed by the compressible Navier-Stokes equation. We follow an exact approach pioneered by Onsager, which we explain as a non-perturbative application of the principle of renormalization-group invariance. In the limit of high Reynolds and Péclet numbers, the flow realizations are found to be described as distributional or "coarse-grained" solutions of the compressible Euler equations, with standard conservation laws broken by turbulent anomalies. The anomalous dissipation of kinetic energy is shown to be due not only to local cascade…
