arXivDaily arXiv每日学术速递 周一至周五更新
arXiv 1504.00685cond-mat.supr-con
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Bi $_{2} $ Rh $ _{3.5}$ S PDMATHAAC和Bi $_{2} $ Rh PDMATHAAD S $ _{2}$的超导电性与结构相变

Superconductivity versus structural phase transition in the closely related Bi$_{2} $Rh$ _{3.5}$S$ _{2}$ and Bi$_{2} $Rh$ _{3}$S$ _{2}$

Udhara S. Kaluarachchi, Weiwei Xie, Qisheng Lin, Valentin Taufour, Sergey L. Bud'ko, Gordon J. Miller, Paul C. Canfield

摘要:

用溶液法合成了Bi $_{2} $ Rh $ _{3}$ S $ _{2}$和Bi $_{2} $ Rh $ _{3.5}$ S $ _{2}$的单晶,并研究了这两种化合物的晶体结构、热力学和输运性质。在Bi $_{2} $ Rh $ _{3}$ S $ _{2}$的情况下,通过单晶衍射实验确定在约165 K处的结构一级转变,在电阻率、磁化强度和比热数据中具有清晰可见的特征。Bi $_{2} $ Rh $ _{3}$ S $ _{2}$在0.5 K以下没有超导转变。与此相反,没有结构相变在高温下观察到的Bi $_{2} $ Rh $ _{3.5}$ S $ _{2}$,但体超导性的临界温度,$T_{c}\approx$ 1.7 K观察。Bi $_{2} $ Rh $ _{3}$ S $ _{2}$的索末菲系数$γ$和德拜温度($\varTheta_{\textrm{D}}$)分别为9.4 mJ mol $^{-1}$ K $^{-2}$和209 K,Bi $_{2} $ Rh $ _{3.5}$ S $ _{2}$的索末菲系数$^{-1}$ K $^{-2}$和德拜温度分别为22 mJ mol $^{-1}$ K $^{-2}$和196 K。对Bi $_{2} $ Rh $ _{3.5}$ S $ _{2}$超导态比热的研究表明,Bi $_{2} $ Rh $ _{3.5}$ S $ _{2}$是一种弱耦合BCS超导体。

英文摘要:

Single crystals of Bi$_{2} $Rh$ _{3}$S$ _{2}$ and Bi$_{2} $Rh$ _{3.5}$S$ _{2}$ were synthesized by solution growth and the crystal structures, thermodynamic and transport properties of both compounds were studied. In the case of Bi$_{2} $Rh$ _{3}$S$ _{2}$, a structural first-order transition at around 165 K is identified by single crystal diffraction experiments, with clear signatures visible in resistivity, magnetization and specific heat data. No superconducting transition for Bi$_{2} $Rh$ _{3}$S$ _{2}$ was observed down to 0.5 K. In contrast, no structural phase transition at high temperature was observed for Bi$_{2} $Rh$ _{3.5}$S$ _{2}$, however bulk superconductivity with a critical temperature, $T_{c}\approx$ 1.7 K was observed. The Sommerfeld coefficient $γ$\ and the Debye temperature($\varTheta_{\textrm{D}}$) were found to be 9.4 mJ mol$^{-1}$ K$^{-2}$ and 209 K respectively for Bi$_{2} $Rh$ _{3}$S$ _{2}$, and 22 mJ mol$^{-1}$ K$^{-2}$ and 196 K respectively for Bi$_{2} $Rh$ _{3.5}$S$ _{2}$. Study of the specific heat in the superconducting state of Bi$_{2} $Rh$ _{3.5}$S$ _{2}$ suggests that Bi$_{2} $Rh$ _{3.5}$S$ _{2}$ is a weakly coupled, BCS superconductor.

机构、总结、中文摘要均由AI分析而来,可能存在错误,请以论文正文为准。

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