Recent studies have developed fundamental limitations on nanoscale thermodynamics, in terms of a set of independent free energy relations. Here we show that free energy relations cannot properly describe quantum coherence in thermodynamic processes. By casting time-asymmetry as a quantifiable, fundamental resource of a quantum state we arrive at an additional, independent set of thermodynamic constraints that naturally extend the existing ones. These asymmetry relations reveal that the traditional Szilard engine argument does not extend automatically to quantum coherences, but instead only relational coherences in a multipartite scenario can contribute to thermodynamic work. We find that coherence transformations are always irreversible. Our results also reveal additional structural parallels between thermodynamics and the theory of entanglement.
In thermodynamics, quantum coherences - superpositions between energy eigenstates - behave in distinctly nonclassical ways. Recently mathematical frameworks have emerged to account for these features and have provided a range of novel insights. Here we describe how thermodynamic coherence splits into two kinds - "internal" coherence that admits an energetic value in terms of thermodynamic work, and "external" coherence that does not have energetic value, but instead corresponds to the functioning of the system as a quantum clock. For the latter form of coherence we provide dynamical constraint…
The first law of thermodynamics imposes not just a constraint on the energy-content of systems in extreme quantum regimes, but also symmetry-constraints related to the thermodynamic processing of quantum coherence. We show that this thermodynamic symmetry decomposes any quantum state into mode operators that quantify the coherence present in the state. We then establish general upper and lower bounds for the evolution of quantum coherence under arbitrary thermal operations, valid for any temperature. We identify primitive coherence manipulations and show that the transfer of coherence between …
One of the fundamental questions in the emerging field of quantum thermodynamics is the role played by coherence in energetic processes that occur at the quantum level. Here, we address this issue by investigating two different quantum versions of the first law of thermodynamics, derived from the classical definitions of work and heat. By doing so, we find out that there exists a mathematical inconsistency between both scenarios. We further show that the energetic contribution of the dynamics of coherence is the key ingredient to establish the consistency. Some examples involving two-level ato…
We showed that quantum mechanical superposition can sustain in the process of ion transfer in protein membrane for a substantial period, in spite of the presence of the interactions with environmental modes of molecular vibration. The spectral temperature, as defined in quantum thermodynamical framework plays a significant role in maintaining the coherence. The ratio of decoherence time and dwell time has been calculated, which can be directly related to the degree of coherence. The results shead new light to build quantum information system of entangled ionic states in the voltage gated biolo…
Thermodynamics is a highly successful macroscopic theory widely used across the natural sciences and for the construction of everyday devices, from car engines and fridges to power plants and solar cells. With thermodynamics predating quantum theory, research now aims to uncover the thermodynamic laws that govern finite size systems which may in addition host quantum effects. Here we identify information processing tasks, the so-called "projections", that can only be formulated within the framework of quantum mechanics. We show that the physical realisation of such projections can come with a …
Advantages of quantum effects in several technologies, such as computation and communication, have already been well appreciated, and some devices, such as quantum computers and communication links, exhibiting superiority to their classical counterparts have been demonstrated. The close relationship between information and energy motivates us to explore if similar quantum benefits can be found in energy technologies. Investigation of performance limits for a broader class of information-energy machines is the subject of the rapidly emerging field of quantum thermodynamics. Extension of classic…
Quantum thermodynamics, quantum correlations and quantum coherence in accelerating Unruh-DeWitt detectors in both steady and dynamical state
Mohammed V University in Rabat（拉巴特穆罕默德五世大学）；Prince Sattam bin Abdulaziz University（沙特王子萨塔姆·本·阿卜杜勒阿齐兹大学）；Ibnou Zohr University（伊本祖海尔大学）；Al-Ahliyya Amman University（安曼阿赫利耶大学）；King Khalid University（国王哈立德国立大学）
Energy is often partitioned into heat and work by two independent paths corresponding to the change in the eigenenergies or the probability distributions of a quantum system. The discrepancies of the heat and work for various quantum thermodynamic processes have not been well characterized in literature. Here we show how the work in quantum machines is differentially related to isochoric, isothermal, and adiabatic processes. We prove that the energy exchanges during the quantum isochoric and isothermal processes are simply depending on the change in the eigenenergies or the probability distrib…
Thermal operations are an operational model of non-equilibrium quantum thermodynamics. In the absence of coherence between energy levels, exact state transition conditions under thermal operations are known in terms of a mathematical relation called thermo-majorization. But incorporating coherence has turned out to be challenging, even under the relatively tractable model wherein all Gibbs state-preserving quantum channels are included. Here we find a mathematical generalization of thermal operations at low temperatures, "cooling maps", for which we derive the necessary and sufficient state tr…
The first law of thermodynamics restates the law of conservation of energy. It partitions the change in energy of a system into two pieces, heat and work. While there is no ambiguity to define heat and work in classical thermodynamics, their classification in the quantum regime is not that obvious. Thus, the first law of thermodynamics becomes problematic in the quantum regime. However, recent studies have shown if contribution of quantum coherence is considered to the change of internal energy of the system, the first law of thermodynamics can be extended to the quantum domain. Here we invest…
Perturbative approach to the first law of quantum thermodynamics
Universidade Federal Fluminense（弗鲁米嫩塞联邦大学）；SENAI CIMATEC（塞纳伊西马特克中心）；EMBRAPII CIMATEC Competence Center in Quantum Technologies（量子技术能力中心（EMBRAPII CIMATEC））；Universidade Federal do Oeste da Bahia（巴伊亚西部联邦大学）
Quantum decoherence is seen as an undesired source of irreversibility that destroys quantum resources. Quantum coherences seem to be a property that vanishes at thermodynamic equilibrium. Away from equilibrium, quantum coherences challenge the classical notions of a thermodynamic bath in a Carnot engines, affect the efficiency of quantum transport, lead to violations of Fourier's law, and can be used to dynamically control the temperature of a state. However, the role of quantum coherence in thermodynamics is not fully understood. Here we show that the relative entropy of a state with quantum …
Quantum coherence associated with the superpositions of two different sets of eigenbasis vectors has been regarded as essential in thermodynamics. It is found that coherent factors can be determined by writing observables as an expansion in the basis vectors of the systemic density operator and Hamiltonian. We reveal the roles of coherence in finite-time thermodynamic processes, such as the spin precession and the spontaneous emission of a photon. Results show that the work in the spin precession and the heat in the spontaneous emission process are mainly generated by coherence.
We show that quantum coherence can increase the quantum efficiency of various thermodynamic systems. For example, we can enhance the quantum efficiency for a quantum dot photocell, a laser based solar cell and the photo-Carnot quantum heat engine. Our results are fully consistent with the laws of thermodynamics contrary to comments found in the paper of A.P. Kirk, Phys. Rev. Lett. 106, 048703 (2011).
Nanoscale heat engines are subject to large fluctuations which affect their precision. The Thermodynamic Uncertainty Relation (TUR) provides a trade-off between output power, fluctuations and entropic cost. This trade-off may be overcome by systems exhibiting quantum coherence. This letter provides a study of the TUR in a prototypical quantum heat engine, the Scovil & Schulz-DuBois maser. Comparison with a classical reference system allows us to determine the effect of quantum coherence on the performance of the heat engine. We identify analytically regions where coherence suppresses fluctuati…
Recent research on the thermodynamic arrow of time, at the microscopic scale, has questioned the universality of its direction. Theoretical studies showed that quantum correlations can be used to revert the natural heat flow (from the hot body to the cold one), posing an apparent challenge to the second law of thermodynamics. Such an "anomalous" heat current was observed in a recent experiment (arXiv:1711.03323), by employing two spin systems initially quantum correlated. Nevertheless, the precise relationship between this intriguing phenomenon and the initial conditions that allow it is not f…
We study the role of the initial quantum coherence in coherent processes generated by an external control of some parameters by looking on the thermodynamic work done. We start by taking in exam an active state and we isolate the contribution to the ergotropy coming from the quantum coherence among the energy eigenstates. It is shown to be related to the quantum relative entropy of coherence through an inequality which involves the completely passive state connected to the initial state. Finally, we extend the analysis to a general out-of-equilibrium process and we show how to take in account …
Recent studies have pointed out the intrinsic dependence of figures of merit of thermodynamic relevance -- such as work, heat and entropy production -- on the amount of quantum coherences that is made available to a system. However, whether coherences hinder or enhance the value taken by such quantifiers of thermodynamic performance is yet to be ascertained. We show that, when considering entropy production generated in a process taking a finite-size bipartite quantum system out of equilibrium through local non-unitary channels, no general monotonicity relationship exists between the entropy p…
We consider a finite-time quantum Otto heat engine that consists of two isochoric (thermal-contact) process, where the system is alternatively coupled to a hot squeezed and a cold thermal reservoir, and two unitary driven strokes, where the system is isolated from these two baths and its von Neumann entropy keeps constant. Both quantum inner friction and coherence are generated along the driven stroke and coherence cannot be fully erased after the finite-time hot isochore. Using full counting statistics, we present the probability distribution functions of heat injection and total work per cyc…
We study the limitations on coherence evolutions under the constraints of thermodynamic laws, and focus on the optimal thermal operations (TO) reaching the bounds. For qubit case, we find a thermal operation involving only a single-mode reservoir (STO) which maintains the maximum coherence allowed by general TO. For higher dimensions, we derive general bounds on coherence merging under TO, and find STO to reach the bounds. By applying the bound to a two-qubit system, we prove that erasing correlations while preserving the marginal states is not free in the resource theory of thermodynamics. Du…
Driving Quantum Heat Engines Beyond Classical Limits through Multilevel Coherence
Institute for Quantum Science and Engineering, Texas A&M University（德克萨斯农工大学量子科学与工程研究所）；Okinawa Institute of Science and Technology Graduate University（冲绳科学技术大学院大学）；Baylor University（贝勒大学）；Princeton University（普林斯顿大学）
The interplay between quantum-mechanical properties, such as coherence, and classical notions, such as energy, is a subtle topic at the forefront of quantum thermodynamics. The traditional Carnot argument limits the conversion of heat to work; here we critically assess the problem of converting coherence to work. Through a careful account of all resources involved in the thermodynamic transformations within a fully quantum-mechanical treatment, we show that there exist thermal machines extracting work from coherence arbitrarily well. Such machines only need to act on individual copies of a sta…
The thermodynamic uncertainty relation, originally derived for classical Markov-jump processes, provides a trade-off relation between precision and dissipation, deepening our understanding of the performance of quantum thermal machines. Here, we examine the interplay of quantum system coherences and heat current fluctuations on the validity of the thermodynamics uncertainty relation in the quantum regime. To achieve the current statistics, we perform a full counting statistics simulation of the Redfield quantum master equation. We focus on steady-state quantum absorption refrigerators where no…
The role of coherence in quantum thermodynamics has been extensively studied in the recent years and it is now well-understood that coherence between different energy eigenstates is a resource independent of other thermodynamics resources, such as work. A fundamental remaining open question is whether the laws of quantum mechanics and thermodynamics allow the existence of a coherence distillation machine, i.e., a machine that, by possibly consuming work, obtains pure coherent states from mixed states, at a nonzero rate. This is related to another fundamental question: Starting from many copies…
Exploiting the relative entropy of coherence, we isolate the coherent contribution in the energetics of a driven non-equilibrium quantum system. We prove that a division of the irreversible work can be made into a coherent and incoherent part, which provides an operational criterion for quantifying the coherent contribution in a generic non-equilibrium transformation on a closed quantum system. We then study such a contribution in two physical models of a driven qubit and kicked rotor. In addition, we also show that coherence generation is connected to the non-adiabaticity of a processes, for …
The introduction of the quantum analogue of a Carnot engine based on a bath comprising of particles with a small amount of coherence initiated an active line of research on the harnessing of different quantum resources for the enhancement of thermal machines beyond the standard reversible limit, with an emphasis on non-thermal baths containing quantum coherence. In our work, we investigate the impact of coherence on the thermodynamic tasks of a collision model which is composed of a system interacting, in the continuous time limit, with a series of coherent ancillas of two baths at different t…
The properties of coherence and polarization of light has been the subject of intense investigations and form the basis of many technological applications. These concepts which historically have been treated independently can now be formulated under a single classical theory. Here, we derive a quantum counterpart for this theory, with basis on a density matrix formulation, which describes jointly the coherence and polarization properties of an ensemble of photons. The method is used to show how the degree of polarization of a specific class of mixed states changes on propagation in free space,…
We consider the physical situations where the resource theories of coherence and thermodynamics play competing roles. In particular, we study the creation of quantum coherence using unitary operations with limited thermodynamic resources. We first find the maximal coherence that can be created under unitary operations starting from a thermal state and find explicitly the unitary transformation that creates the maximal coherence. Since coherence is created by unitary operations starting from a thermal state, it requires some amount of energy. This motivates us to explore the trade-off between t…
We introduce a generalized approach to characterize the non-Markovianity of quantum dynamical maps via breakdown of monotonicity of thermodynamic functions. By adopting an entropy-based formulation of quantum thermodynamics, we use the relationship between heat and entropy to propose a measure of non-Markovianity based on the heat flow for single-qubit quantum evolutions. This measure can be applied for unital dynamical maps that do not invert the sign of the internal energy. Under certain conditions, it can also be extended for other thermodynamic functions, such as internal energy and work f…
The unavoidable interaction of a quantum system with its surrounding (bath) is not always detrimental for quantum properties. For instance, under some specific conditions (that we identify as indistinguishability), a many-body system can gain internal coherences thanks to the interaction with its bath. The most famous consequence of this phenomenon is superradiance. Beyond that, the thermodynamic effects on the system of these bath-induced coherences have been mostly unexplored. We show here, for a simple and common system (a pair of two-level systems), that the energetic and entropic impacts …
In order to study the temporal coherence of a single-mode dye-cavity photon condensate, a model is developed for the dynamics which treats the condensate mode on a quantum-mechanical level. The effects of driving-dissipation and Kerr interactions on the number fluctuations are studied analytically and numerically, including the finding of a long-$τ$ antibunching effect. Depending on the interaction strength, we quantitatively observe an exponential Schawlow-Townes-like decay or Gaussian Henry-like decay of phase correlations. The adequacy of a heuristic phasor model originating from laser phys…
We consider a microscopic collision model, i.e., a quantum system interacts with a hierarchical environment consisting of an auxiliary system and a reservoir. We show how the non-Markovian character of the system is influenced by the coupling strength of system-auxiliary system and auxiliary system-reservoir, initial system-environment correlations and the coherence of environment. Then we study the relation between non-Markovianity and thermodynamics properties, by studying the entropy change of system especially that from heat exchanges with memory effects, and we reveal the essence of entro…
We present a detailed thermodynamic analysis of a three-level quantum heat engine coupled continuously to hot and cold reservoirs. The system is driven by an oscillating external field and is described by the Markovian quantum master equation. We use the general form of the dissipator which is consistent with thermodynamics. We calculate the heat, power, and efficiency of the system for the heat-engine operating regime and also examine the thermodynamic uncertainty relation. The efficiency of the system is strongly dependent on the structure of the dissipator, and the correlations between diff…
We introduce unitary quantum gates for photon pair creation in spontaneous parametric down-conversion nonlinear crystals (NLs) and for photon path alignment. These are the two key ingredients for the method of "induced coherence without induced emission" and many ensuing variations thereof. The difficulty in doing so stems from an apparent mixing of the mode picture (such as the polarization of photons) and the Fock picture (such as the existence of the photons). We illustrate utility of these gates by obtaining quantum circuits for the experimental setups of the frustrated generation of photo…
I give a self-contained introduction to the resource theory approach to quantum thermodynamics. I will introduce in an elementary manner the technical machinery necessary to unpack and prove the core statements of the theory. The topics covered include the so-called `many second laws of thermodynamics', thermo-majorisation and symmetry constraints on the evolution of quantum coherence. Among the elementary applications, I explicitly work out the bounds on deterministic work extraction and formation, discuss the complete solution of the theory for a single qubit and present the irreversibility …
We find necessary and sufficient conditions to determine the inter-convertibility of quantum systems under time-translation covariant evolution, and use it to solve several problems in quantum thermodynamics both in the single-shot and asymptotic regimes. It is well known that the resource theory of quantum athermality is not reversible, but in PRL 111, 250404 (2013) it was claimed that the theory becomes reversible ``provided a sublinear amount of coherent superposition over energy levels is available". Here we show that if a sublinear amount of coherence among energy levels were considered f…
