The thermodynamic uncertainty relation, originally derived for classical Markov-jump processes, provides a trade-off relation between precision and dissipation, deepening our understanding of the performance of quantum thermal machines. Here, we examine the interplay of quantum system coherences and heat current fluctuations on the validity of the thermodynamics uncertainty relation in the quantum regime. To achieve the current statistics, we perform a full counting statistics simulation of the Redfield quantum master equation. We focus on steady-state quantum absorption refrigerators where nonzero coherence between eigenstates can either suppress or enhance the cooling power, compared with the incoherent limit. In either scenario, we find enhanced relative noise of the cooling power (standard deviation of the power over the mean) in the presence of system coherence, thereby corroborating the thermodynamic uncertainty relation. Our results indicate that fluctuations necessitate consideration when assessing the performance of quantum coherent thermal machines.
Models for quantum absorption refrigerators serve as test beds for exploring concepts and developing methods in quantum thermodynamics. Here, we depart from the minimal, ideal design and consider a generic multilevel model for a quantum absorption refrigerator, which potentially suffers from lossy processes. Based on a full-counting statistics approach, we derive a formal cooling condition for the refrigerator, which can be feasibly evaluated analytically and numerically. We exemplify our approach on a three-level model for a quantum absorption refrigerator that suffers from different forms of…
Absorption refrigerators transfer thermal energy from a cold reservoir to a hot reservoir using input energy from a third, so-called work reservoir. We examine the operation of quantum absorption refrigerators when coherences between eigenstates survive in the steady state limit. In our model, the working medium comprises a discrete, four-level system. We manifest that eigenbasis quantum coherences within this system generally suppress the cooling current in the refrigerator, while minimally affecting the coefficient of performance (cooling efficiency). We rationalize the behavior of the four-…
We show that the lower levels of a large-spin network with a collective anti-ferromagnetic interaction and collective couplings to three reservoirs may function as a quantum absorption refrigerator. In appropriate regimes, the steady-state cooling current of this refrigerator scales quadratically with the size of the working medium, i.e., the number of spins. The same scaling is observed for the noise and the entropy production rate.
We study two models of quantum absorption refrigerators with the main focus on discerning the role of noise-induced coherence on their thermodynamic performance. Analogously to the previous studies on quantum heat engines, we find the increase in the cooling power due to the mechanism of noise-induced coherence. We formulate conditions imposed on the microscopic parameters of the models under which they can be equivalently described by classical stochastic processes and compare the performance of the two classes of fridges (effectively classical vs. truly quantum). We find that the enhanced pe…
We consider absorption refrigerators consisting of simultaneously operating Carnot-type heat engine and refrigerator. Their maximum efficiency at given power (MEGP) is given by the product of MEGPs for the internal engine and refrigerator. The only subtlety of the derivation lies in the fact that the maximum cooling power of the absorption refrigerator is not limited just by the maximum power of the internal refrigerator but, due to the first law, also by that of the internal engine. As a specific example, we consider the simultaneous absorption refrigerators composed of low-dissipation (LD) h…
The inexorable miniaturisation of technologies, the relentless drive to improve efficiency and the enticing prospect of boosting performance through quantum effects are all compelling reasons to investigate microscopic machines. Thermal absorption machines are a particularly interesting class of device that operate autonomously and use only heat flows to perform a useful task. In the quantum regime, this provides a natural setting in which to quantify the thermodynamic cost of various operations such as cooling, timekeeping or entanglement generation. This article presents a pedagogical introd…
Absorption refrigerators transfer thermal energy from a cold bath to a hot bath without input power by utilizing heat from an additional "work" reservoir. Particularly interesting is a three-level design for a quantum absorption refrigerator, which can be optimized to reach the maximal (Carnot) cooling efficiency. Previous studies of three-level chillers focused on the behavior of the averaged cooling current. Here, we go beyond that and study the full counting statistics of heat exchange in a three-level chiller model. We explain how to obtain the complete cumulant generating function of the …
The relation between the geometry of refrigeration cycles and their performance is explored. The model studied is based on a coupled spin system. Small cycle times termed sudden refrigerators, develop coherence and inner friction. We explore the interplay between coherence and energy of the working medium employing a family of sudden cycles with decreasing cycle times. At the point of minimum ratio between energy and coherence the cycle changes geometry. This region of cycle times is characterised by short circuit cycles where heat is dissipated both to the hot and cold baths. We rationalise t…
We demonstrate that a quantum absorption refrigerator can be realized from the smallest quantum system, a qubit, by coupling it in a non-additive (strong) manner to three heat baths. This function is un-attainable for the qubit model under the weak system-bath coupling limit, when the dissipation is additive. In an optimal design, the reservoirs are engineered and characterized by a single frequency component. We obtain then closed expressions for the cooling window and refrigeration efficiency, as well as bounds for the maximal cooling efficiency and the efficiency at maximal power. Our resul…
For steady-state autonomous absorption refrigerators operating in the linear response regime, we show that there exists a hierarchy between the relative fluctuation of currents for cold, hot, and work terminals. Our proof requires the Onsager's reciprocity relation along with the refrigeration condition that sets the direction of the mean currents for each terminal. As a consequence, the universal bounds on the mean cooling power, obtained following the thermodynamic uncertainty relations, receive a hierarchy. Interestingly, within this hierarchy, the tightest bound is given in terms of the wo…
An autonomous quantum thermal machine comprising a trapped atom or ion placed inside an optical cavity is proposed and analysed. Such a machine can operate as a heat engine whose working medium is the quantised atomic motion, or as an absorption refrigerator which cools without any work input. Focusing on the refrigerator mode, we predict that it is possible with state-of-the-art technology to cool a trapped ion almost to its motional ground state using a thermal light source such as sunlight. We nonetheless find that a laser or similar reference system is necessary to stabilise the cavity fre…
Quantum speed limit, furnishing a lower bound on the required time for the evolution of a quantum system through the state space, imposes an ultimate natural limitation to the dynamics of physical devices. Quantum absorption refrigerators, on the other hand, have attracted a great deal of attention in the last few years. In this article, we discuss the effects of quantum speed limit on the performance of a quantum absorption refrigerator. In particular, we show that there exists a trade-off relation between the steady cooling rate of the refrigerator and the minimum time taken to reach the ste…
An implementation of quantum absorption chillers with three qubits has been recently proposed, that is ideally able to reach the Carnot performance regime. Here we study the working efficiency of such self-contained refrigerators, adopting a consistent treatment of dissipation effects. We demonstrate that the coefficient of performance at maximum cooling power is upper bounded by 3/4 of the Carnot performance. The result is independent of the details of the system and the equilibrium temperatures of the external baths. We provide design prescriptions that saturate the bound in the limit of a l…
Thermodynamics is a branch of science blessed by an unparalleled combination of generality of scope and formal simplicity. Based on few natural assumptions together with the four laws, it sets the boundaries between possible and impossible in macroscopic aggregates of matter. This triggered groundbreaking achievements in physics, chemistry and engineering over the last two centuries. Close analogues of those fundamental laws are now being established at the level of individual quantum systems, thus placing limits on the operation of quantum-mechanical devices. Here we study quantum absorption …
We investigate the effects of noise-induced coherence on average current and current fluctuations in a simple model of quantum absorption refrigerator with degenerate energy levels. We describe and explain the differences and similarities between the system behavior when it operates in the classical regime, where the populations and coherences in the corresponding quantum optical master equation decouple in a suitably chosen basis, and in the quantum regime, where such a transformation does not exist. The differences between the quantum and the classical case are observable only close to the m…
Clarifying the impact of quantumness in the operation and properties of thermal machines represents a major challenge. Here we envisage a toy model acting either as an information-driven fridge or as heat-powered information eraser in which coherences can be naturally introduced in by means of squeezed thermal reservoirs. We study the validity of the transient entropy production fluctuation theorem in the model with and without squeezing as well as its decomposition into adiabatic and non-adiabatic contributions. Squeezing modifies fluctuations and introduces extra mechanisms of entropy exchan…
We study the application of a counter-diabatic driving (CD) technique to enhance the thermodynamic efficiency and power of a quantum Otto refrigerator based on a superconducting qubit coupled to two resonant circuits. Although the CD technique is originally designed to counteract non-adiabatic coherent excitations in isolated systems, we find that it also works effectively in the open system dynamics, improving the coherence-induced losses of efficiency and power. We compare the CD dynamics with its classical counterpart, and find a deviation that arises because the CD is designed to follow th…
The introduction of the quantum analogue of a Carnot engine based on a bath comprising of particles with a small amount of coherence initiated an active line of research on the harnessing of different quantum resources for the enhancement of thermal machines beyond the standard reversible limit, with an emphasis on non-thermal baths containing quantum coherence. In our work, we investigate the impact of coherence on the thermodynamic tasks of a collision model which is composed of a system interacting, in the continuous time limit, with a series of coherent ancillas of two baths at different t…
We study the optimization of the performance of arbitrary periodically driven thermal machines. Within the assumption of fast modulation of the driving parameters, we derive the optimal cycle that universally maximizes the extracted power of heat engines, the cooling power of refrigerators, and in general any linear combination of the heat currents. We denote this optimal solution as ``generalized Otto cycle'' since it shares the basic structure with the standard Otto cycle, but it is characterized by a greater number of fast strokes. We bound this number in terms of the dimension of the Hilbe…
The rate of temperature decrease of a cooled quantum bath is studied as its temperature is reduced to the absolute zero. The III-law of thermodynamics is then quantified dynamically by evaluating the characteristic exponent ζ of the cooling process dT(t)/dt \sim -T^ζ when approaching the absolute zero, T \rightarrow 0. A continuous model of a quantum refrigerator is employed consisting of a working medium composed either by two coupled harmonic oscillators or two coupled 2-level systems. The refrigerator is a nonlinear device merging three currents from three heat baths: a cold bath to be cool…
The characterization and control of quantum effects in the performance of thermodynamic tasks may open new avenues for small thermal machines working in the nanoscale. We study the impact of coherence in the energy basis in the operation of a small thermal machine which can act either as a heat engine or as a refrigerator. We show that input coherence may enhance the machine performance and allow it to operate in otherwise forbidden regimes. Moreover, our results also indicate that, in some cases, coherence may also be detrimental, rendering optimization of particular models a crucial task for…
We study universal aspects of fluctuations in an ensemble of noninteracting continuous quantum thermal machines in the steady state limit. Considering an individual machine, such as a refrigerator, in which relative fluctuations (and high order cumulants) of the cooling heat current to the absorbed heat current, $η^{(n)}$, are upper-bounded, $η^{(n)}\leq η_C^n$ with $n\geq 2$ and $η_C$ the Carnot efficiency, we prove that an {\it ensemble} of $N$ distinct machines similarly satisfies this upper bound on the relative fluctuations of the ensemble, $η_N^{(n)}\leq η_C^n$. For an ensemble of distin…
The performance enhancements observed in various models of continuous quantum thermal machines have been linked to the buildup of coherences in a preferred basis. But, is this connection always an evidence of `quantum-thermodynamic supremacy'? By force of example, we show that this is not the case. In particular, we compare a power-driven three-level continuous quantum refrigerator with a four-level combined cycle, partly driven by power and partly by heat. We focus on the weak driving regime and find the four-level model to be superior since it can operate in parameter regimes in which the th…
We propose a double-well configuration for optical trapping of ultracold two-species Fermi-Bose atomic mixtures. Two signatures of macroscopic quantum coherence attributable to a superfluid phase transition for the Fermi gas are analyzed. The first signature is based upon tunneling of Fermi pairs when the power of the deconfining laser beam is significantly reduced. The second relies on the observation of interference fringes in a regime where the fermions are trapped in two sharply separated minima of the potential. Both signatures rely on small decoherence times for the Fermi samples, which …
We analyze the behavior of a network of quantum oscillators coupled with a number of external environments. We show that the dynamics is such that the quantum state of the network always obeys a local master equation with a simple analytical solution. We use this to study the emergence of thermodynamical laws in the stationary regime, achieved for sufficiently long times if the environments are dissipative. We show that the validity of the second law implies the impossibility of building a quantum refrigerator without moving parts (therefore, a quantum absorption refrigerators requires non-lin…
Generation of steady quantumness in the presence of an environment is of utmost importance if we are to build practical quantum devices. We propose a scheme of generating steady coherence and magic in a qubit system attached to a heat bath at a certain temperature through its interaction with another qubit system attached to a spin bath. Coherence generation in the reduced qubit is always possible in this model. The steady coherence in the reduced qubit attached to the heat bath may be used to enhance the subsequent transient performance of a quantum absorption refrigerator. For the case of ge…
We study the performance of quantum absorption refrigerators, paradigmatic autonomous quantum thermal machines, and reveal central impacts of strong couplings between the working system and the thermal baths. Using the reaction coordinate quantum master equation method, which treats system-bath interactions beyond weak coupling, we discover that reshaping of the window of performance is a central outcome of strong system-bath couplings. This alteration of the cooling window stems from the dominant role of parameter renormalization at strong couplings. We further show that strong coupling admit…
