We present an NMR study of the effect of S substitution in the high Tc superconductor K(x)Fe(2-y)Se(2-z)S(z) in a temperature range up to 250 K. We present NMR Knight shift and nuclear spin-lattice relaxation rate 1/T1 data, and compare our results to that of the non-substituted system K(x)Fe(2-y)Se(2).
We take advantage of the site-selective nature of the $^{75}$As and $^{63}$Cu NMR techniques to probe the Cu substitution effects on the local magnetic properties of the FeAs planes in Ba(Fe$_{1-x}$Cu$_x$)$_2$As$_2$. We show that the suppression of antiferromagnetic Fe spin fluctuations induced by Cu substitution is weaker than a naive expectation based on a simple rigid band picture, in which each Cu atom would donate 3 electrons to the FeAs planes. Comparison between $^{63}$Cu and $^{75}$As NMR data indicates that spin fluctuations are suppressed at the Cu and their neighboring Fe sites in t…
Emergent Phases of Nodeless and Nodal Superconductivity Separated by Antiferromagnetic Order in Iron-based Superconductor (Ca4Al2O6)Fe2(As1-xPx)2: 75As- and 31P-NMR Studies
我们报告$^{31}$ P-和$^{75}$ As-NMR研究（Ca $_4$ Al $_2$ O $_{6}$）Fe $_2$（As $_{1-x}$ P $_x$）$_2$与P等价取代As。我们提出了新的演化的紧急阶段，节点无超导（SC）在0 $\le x \le$ 0.4和节点的$x$ =1附近是密切分离的开始相称的条纹型反铁磁（AFM）的顺序在0.5 $\le x \le$ 0.95，作为一个等价的替代P为As降低了氮族元素的高度$h_{Pn}$从Fe平面测量。结果表明，原子力显微镜的有序化发生在1.32 π $\le h_{Pn} \le$ 1.42 π的条件下，这也适用于（Fe $Pn$）$^{-}$层中具有Fe $^{2+}$态的其他铁磷族化合物.这种新的相位演化与$h_{Pn}$的变化点的重要性，电子相关的出现SC以及AFM秩序。
Muon Spin Rotation ($μ$SR) and $^{19}$F Nuclear Magnetic Resonance (NMR) measurements were performed to investigate the effect of Mn for Fe substitutions in La$_{1-y}$Y$_{y}$Fe$_{1-x}$Mn$_x$AsO$_{0.89}$F$_{0.11}$ superconductors. While for $y = 0$ a very low critical concentration of Mn ($x = 0.2$%) is needed to quench superconductivity, as $y$ increases the negative chemical pressure introduced by Y for La substitution stabilizes superconductivity and for $y= 20$% it is suppressed at Mn contents an order of magnitude larger. A magnetic phase arises once superconductivity is suppressed both fo…
Enhancement of Superconducting Transition Temperature Due to Antiferromagnetic Spin Fluctuations in Iron-pnictides LaFe(As_{1-x}P_x)(O_{1-y}F_y) : 31P-NMR Studies
$^{75}$As Nuclear Magnetic (NMR) and Quadrupolar (NQR) Resonance were used, together with Mössbauer spectroscopy, to investigate the magnetic state induced by Mn for Fe substitutions in F-doped LaFe$_{1-x}$Mn$_{x}$AsO superconductors. The results show that $0.5$% of Mn doping is enough to suppress the superconducting transition temperature $T_c$ from 27 K to zero and to recover the magnetic structure observed in the parent undoped LaFeAsO. Also the tetragonal to orthorhombic transition of the parent compound is recovered by introducing Mn, as evidenced by a sharp drop of the NQR frequency. The…
Chemical substitution during growth is a well-established method to manipulate electronic states of quantum materials, and leads to rich spectra of phase diagrams in cuprate and iron-based superconductors. Here we report a novel and generic strategy to achieve nonvolatile electron doping in series of (i.e. 11 and 122 structures) Fe-based superconductors by ionic liquid gating induced protonation at room temperature. Accumulation of protons in bulk compounds induces superconductivity in the parent compounds, and enhances the Tc largely in some superconducting ones. Furthermore, the existence of…
We report $^{75}$As nuclear magnetic resonance (NMR) measurements of single-crystalline Ca(Fe$_{1-x}$Co$_x$)$_2$As$_2$ ($x$ = 0.023, 0.028, 0.033, and 0.059) annealed at 350~$^{\circ}$C for 7 days. From the observation of a characteristic shape of $^{75}$As NMR spectra in the stripe-type antiferromagnetic (AFM) state, as in the case of $x$ = 0 ($T_{\rm N}$ = 170 K), clear evidence for the commensurate AFM phase transition with the concomitant structural phase transition is observed in $x$ = 0.023 ($T_{\rm N}$ = 106 K) and $x$ = 0.028 ($T_{\rm N}$ = 53 K). Through the temperature dependence of …
Sc$_3$CoC$_4$ is the only superconductor in the group of the isotypic carbides Sc$_3M$C$_4$ ($M$ = Mn, Fe, Ru, Os, Co, Rh, Ir, Ni), rendering it into an ideal benchmark system to systematically study the prerequisites and mechanism of superconductivity in such quasi one-dimensional structures. To investigate the isotope effect, the substitution series Sc$_3$Co($^{12}$C$_{1-x}$$^{13}$C$_x$)$_4$ with $x$ = 0, 0.5 and 1 was synthesized by arc melting. The sample homogeneity was confirmed by powder X-ray diffraction and NMR spectroscopy. The resulting isotope coefficient based on magnetization stu…
We report neutron scattering measurements, which reveal spin-liquid polymorphism in a '11' iron chalcogenide superconductor, a poorly-metallic magnetic FeTe tuned towards superconductivity by substitution of a small amount of Tellurium with iso-electronic Sulphur. We observe liquid-like magnetic dynamics, which is described by a competition of two phases with different local structure, whose relative abundance depends on temperature. One is the ferromagnetic (FM) plaquette phase observed in the non-superconducting FeTe, which preserves the C$_4$ symmetry of the underlying square lattice and is…
Dynamics of the Local Moment Induced by Nonmagnetic Defects in Cuprates
本文研究了$_2$ O $_3$正常态中Li取代平面Cu所引起的磁缺陷的自旋动力学。用近邻的$^{89}$ Y { \it}和$^7$ Li NMR自旋晶格弛豫探测了Li附近的耦合Cu磁矩的涨落。数据表明，磁扰动波动作为一个单一的实体与相关时间$τ$的规模与当地的静态磁化率。这种行为让人联想到传统金属中磁性杂质的低$T$近藤态。令人惊讶的是，它延伸到远高于“近藤”温度的掺杂不足的赝隙的情况下。
To elucidate the origin of re-enhanced high-$T_c$ phase in the heavily electron-doped Fe-pnictides, systematic $^{75}$As NMR studies are performed on heavily electron-doped LaFe$Pn$O$_{0.75}$H$_{0.25}$ by controlling the pnictogen height ($h_{Pn}$) from the Fe plane through the substitution at $Pn$(=As) site with Sb or P. The measurements of nuclear spin relaxation rate (1/$T_1$) and Knight shift ($K$) reveal that the moderate spin fluctuations at high temperatures are suppressed toward low temperatures. Such characteristic spin fluctuations with gap like feature at low energies are more enlar…
