8 pages, 4 figures, Invited Review in IAU Symposium 283, Planetary Nebulae: An Eye to the Future, eds. Manchado, Stanghellini, and Schoenberner (in press)
Many complex organic molecules and inorganic solid-state compounds have been observed in the circumstellar shell of stars (both C-rich and O-rich) in the transition phase between Asymptotic Giant Branch (AGB) stars and Planetary Nebulae (PNe). This short (~100-10.000 years) phase of stellar evolution represents a wonderful laboratory for astrochemistry and provides severe constraints on any model of gas-phase and solid-state chemistry. One of the major challenges of present day astrophysics and astrochemistry is to understand the formation pathways of these complex organic molecules and inorganic solid-state compounds (e.g., polycyclic aromatic hydrocarbons, fullerenes, and graphene in the case of a C-rich chemistry and oxides and crystalline silicates in O-rich environments) in space. In this review, I present an observational review of the molecular processes in the late stages of stellar evolution with a special emphasis on the first detections of fullerenes and graphene in PNe.
In this introduction to the Third Congress of Vienna on AGB stars I first try to highlight why it is so hard to cope with the AGB evolutionary phase. This phase is indeed dominated by three main physical processes concerning bulk motions of matter inside/around stars, namely envelope convection, mixing and mass loss. They are inextricably interlaced with each other in a circular sequence of reactions and counter-reactions which has so far undermined our attempts at calibrating such processes one independent of the other. The second part of this introduction is focused on Globular Clusters, ill…
Context. There is a class of binary post-asymptotic giant branch (post-AGB) stars that exhibit remarkable near-infrared (NIR) excess. Such stars are surrounded by Keplerian or quasi-Keplerian disks, as well as extended outflows composed of gas escaping from the disk. This class can be subdivided into disk- and outflow-dominated sources, depending on whether it is the disk or the outflow that represents most of the nebular mass, respectively. The chemistry of this type of source has been practically unknown thus far. Methods. We focused our observations on the 1.3, 2, 3 mm bands of the 30 m IRA…
A millimeter molecular line survey of three carbon-rich AGB stars and two oxygen-rich planetary nebulae has been carried out over the frequency range 80.5-115.5 GHz. Sixty eight different transitions were detected in the data from 27 different molecular species. The hyperfine structure of C2H and C13CH has been fitted to constrain the optical depth of their transitions. All other transitions have been constrained on the basis of their line profile shapes. Rotation temperatures and column densities have been calculated for all possible species, with adaptations to the methods applied in order t…
Condensation of circumstellar dust begins with formation of molecular clusters close to the stellar photosphere. These clusters are predicted to act as condensation cores at lower temperatures and allow efficient dust formation farther away from the star. Recent observations of metal oxides, such as AlO, AlOH, TiO, and TiO$_2$, whose emission can be traced at high angular resolutions with ALMA, have allowed first observational studies of the condensation process in oxygen-rich stars. We are now in the era when depletion of gas-phase species into dust can be observed directly. I review the most…
The effect of including molecular opacities of variable composition on the evolution of intermediate-mass AGB stars
从恒星演化模型的低和中等质量的渐近巨星分支（AGB）恒星的计算提供了元素丰度和产量的预测与观测比较。然而，有许多不确定性降低了这些预测的准确性。一个这样的不确定性涉及低温分子不透明度的处理，占表面丰度变化的C，N和O。一些先前的计算的中间质量AGB恒星模型，将有效的第三次疏浚和热底部燃烧包括分子不透明度的处理，不考虑消耗的C和O由于热底部燃烧。在这里，我们更新的分子不透明度的处理和调查的效果，这种改进对中等质量AGB恒星模型的计算。我们对两种质量（5 M $_{\odot}$和6 M $_{\odot}$）和两种金属丰度（$Z~=~0.001$和$Z~=~0.02$）进行测试，以量化两种混浊处理之间的变化。我们发现，几个进化属性（例如半径，$T_{\rm eff}$和$T_{\rm bce}$）是依赖于不透明处理。与$Z~=~0.02$模型相比，$Z~=~0.001$模型出现更大的结构差异，表明不透明处理在较低金属丰度下具有更显著的效果。由于结构的变化，同位素产量的预测略有影响，大多数同位素经历的变化高达60%的$Z~=~0.001$模型和20%的$Z~=~0.02$模型。尽管这种温和的影响，我们的结论是，它是更适合使用可变的分子不透明度进行热底部燃烧的模型。
The circumstellar environments of objects on the asymptotic giant branch and beyond are rich in molecular species. Nevertheless, methanol has never been detected in such an object, and is therefore often taken as a clear signpost for a young stellar object. However, we report the first detection of CH3OH in a post-AGB object, HD101584, using ALMA. Its emission, together with emissions from CO, SiO, SO, CS, and H2CO, comes from two extreme velocity spots on either side of the object where a high-velocity outflow appears to interact with the surrounding medium. We have derived molecular abundanc…
S-type AGB stars have a C/O ratio which suggests that they are transition objects between oxygen-rich M-type stars and carbon-rich C-type stars. As such, their circumstellar compositions of gas and dust are thought to be sensitive to their precise C/O ratio, and it is therefore of particular interest to examine their circumstellar properties. We present new Herschel HIFI and PACS sub-millimetre and far-infrared line observations of several molecular species towards the S-type AGB star W Aql. We use these observations, which probe a wide range of gas temperatures, to constrain the circumstellar…
Context. With the outstanding spatial resolution and sensitivity of the Atacama Large Millimeter/sub-millimeter Array (ALMA), molecular gas other than the abundant CO can be observed and resolved in circumstellar envelopes (CSEs) around evolved stars, such as the binary S-type Asymptotic Giant Branch (AGB) star W Aquilae. Aims. We aim to constrain the chemical composition of the CSE and determine the radial abundance distribution, the photospheric peak abundance, and isotopic ratios of a selection of chemically important molecular species in the innermost CSE of W Aql. The derived parameters a…
Emission and absorption line observations of molecules in late-type stars are a vital component in our understanding of stellar evolution, dust formation and mass loss in these objects. The molecular composition of the gas in the circumstellar envelopes of AGB stars reflects chemical processes in gas whose properties are strong functions of radius with density and temperature varying by more than ten and two orders of magnitude, respectively. In addition, the interstellar UV field plays a critical role in determining not only molecular abundances but also their radial distributions. In this ar…
More than half of the dust and heavy element enrichment in galaxies originates from the winds and outflows of evolved, low-to-intermediate mass stars on the asymptotic giant branch (AGB). However, numerous details of the physics of late-stage stellar mass loss remain poorly understood, ranging from the wind launching mechanism(s) to the geometry and timescales of the mass loss. One of the major challenges to understanding AGB winds is that the AGB evolutionary phase is characterized by the interplay between highly complex and dynamic processes, including radial pulsations, shocks, magnetic fie…
Internal chemical abundance spreads are one of fundamental properties of globular clusters (GCs) in the Galaxy. In order to understand the origin of such abundance spreads, we numerically investigate GC formation from massive molecular clouds (MCs) with fractal structures using our new hydrodynamical simulations with star formation and feedback effects of supernovae (SNe) and asymptotic giant branch (AGB) stars. We particularly investigate star formation from gas chemically contaminated by SNe and AGB stars within MCs with different initial conditions and environments. The principal results ar…
National Astronomical Observatories, Chinese Academy of Sciences（中国科学院国家天文台）；Institute for Frontiers in Astronomy and Astrophysics, Beijing Normal University（北京师范大学天文与前沿科学研究院）；Yunnan Observatories, Chinese Academy of Sciences (CAS)（中国科学院云南天文台）；University of Chinese Academy of Sciences（中国科学院大学）；Henan Normal University（河南师范大学）
The results of our second stage (1998-2018) of the detailed spectroscopy of peculiar supergiants identified with galactic infrared sources, performed mainly at the 6-meter BTA telescope are summarized. The main aspect of the program is a search for the evolutionary variations in the chemical composition of stars, past the AGB stage and the TDU, as well as an analysis of spectral manifestations of kinematic processes in their extended, often unstable, atmospheres and in the envelopes. The most significant result is detection of the s-process element excesses in seven single post-AGB stars, whic…
We present low spectral resolution molecular interferometric observations at 1.2 mm obtained with the Combined Array for Research in Millimetre-wave Astronomy (CARMA) towards the C-rich AGB star IRC+10216. We have mapped the emission of several lines of SiS, H13CN, SiO, and SiC2 in the ground and first excited vibrational states with a high angular resolution of 0.25 arcsec. These observations have allowed us to partially resolve the emission of the envelope at distances from the star <50 stellar radii (R*), where the stellar wind is mainly accelerated. The structure of the molecular emission …
The transition from the asymptotic giant branch (AGB) to the final white dwarf (WD) stage is arguably the least understood phase in the evolution of single low- and intermediate-mass stars ($0.8 \lesssim M_{\rm ZAMS}/M_\odot\lesssim 8...10$). Here we briefly review the progress in the last 50 years of the modeling of stars during the post-AGB phase. We show that although the main features, like the extreme mass dependency of post-AGB timescales were already present in the earliest post-AGB models, the quantitative values of the computed post-AGB timescales changed every time new physics was in…
Aims. The carbon-rich asymptotic giant branch (AGB) star TX Piscium (TX Psc) has been observed multiple times during multiple epochs and at different wavelengths and resolutions, showing a complex molecular CO line profile and a ring-like structure in thermal dust emission. We investigate the molecular counterpart in high resolution, aiming to resolve the ring-like structure and identify its origin. Methods. Atacama Large Millimeter/submillimeter Array (ALMA) observations have been carried out to map the circumstellar envelope (CSE) of TX Psc in CO(2-1) emission and investigate the counterpart…
We present a near-infrared spectro-interferometric observation of the non-Mira-type, semiregular asymptotic giant branch star SW Vir. Our aim is to probe the physical properties of the outer atmosphere with spatially resolved data in individual molecular and atomic lines. We observed SW Vir in the spectral window between 2.28 and 2.31 micron with the near-infrared interferometric instrument AMBER at ESO's Very Large Telescope Interferometer (VLTI). Thanks to AMBER's high spatial resolution and high spectral resolution of 12000, the atmosphere of SW Vir has been spatially resolved not only in s…
We present 2 to 2.4 micron integral field spectroscopy of a sample of hot post-AGB stars with early-B spectral types, using the NIFS instrument on Gemini North. These stars are just beginning to ionize their immediate environments and turn into planetary nebulae (PNe).We use molecular hydrogen emission lines together with hydrogen and helium recombination lines to explore the distribution of molecular and atomic gas and the extent of the developing ionized region. We see a range of evolutionary stages: IRAS 18062+2410 and IRAS 18379-1707 have recently developed compact and unresolved regions o…
Over two decades ago, a prominent, mysterious emission band peaking at ~20.1 micrometer was serendipitously detected in four preplanetary nebulae (PPNe; also known as "protoplanetary nebulae"). So far, this spectral feature, designated as the "21 micrometer" feature, has been seen in 18 carbon-rich PPNe. The nature of the carriers of this feature remains unknown although many candidate materials have been proposed. The 21 micrometer sources also exhibit an equally mysterious, unidentified emission feature peaking at 30 micrometer. While the 21 micrometer feature is exclusively seen in PPNe, a …
This chapter reviews some of the expected contributions of the ngVLA to the understanding of the late evolutionary stages of low-to-intermediate mass stars, including asymptotic giant branch (AGB) stars, post-AGB stars, and pre-planetary nebulae. Such objects represent the ultimate fate of stars like the Sun, and the stellar matter they lose to their immediate vicinity contributes significantly to the chemical enrichment of galaxies. Topics addressed in this chapter include continuum imaging of radio photospheres, studies of circumstellar envelopes in both thermal and nonthermal lines, and the…
W Aql is an asymptotic giant branch (AGB) star with an atmospheric elemental abundance ratio C/O$\approx$0.98 and reported circumstellar molecular abundances intermediate between those of M-type (C/O$<$1) and C-type (C/O$>$1) AGB stars. This intermediate status is considered typical for S-type stars, although our understanding of the chemical content of their circumstellar envelopes (CSEs) is currently rather limited. We performed observations in the frequency range 159-268 GHz with the APEX telescope and make abundance estimates through comparison to available spectra towards some well-studie…
The formation of silicates in circumstellar envelopes of stars evolving through the AGB is still debated given the uncertainties affecting stellar evolution modelling, the description of the dust formation process, and the capability of silicate grains to accelerate stellar outflows via radiation pressure. We study the formation of dust in the winds of intermediate mass (M $\geq 4 M_{\odot}$) stars of solar metallicity while evolving through the AGB phase. We tested the different treatments of the mass-loss mechanism by this class of stars, with the aim of assessing their contribution to the g…
We aim to determine the distributions of molecular SiS and CS in the circumstellar envelopes of oxygen-rich asymptotic giant branch stars and how these distributions differ between stars that lose mass at different rates. In this study we analyse ALMA observations of SiS and CS emission lines for three oxygen-rich galactic AGB stars: IK Tau, with a moderately high mass-loss rate of $5\times10^{-6}$M$_\odot$ yr$^{-1}$, and W Hya and R Dor with low mass loss rates of $\sim1\times10^{-7}$M$_\odot$ yr$^{-1}$. These molecules are usually more abundant in carbon stars but the high sensitivity of ALM…
Detections of SiO masers from the Bulge Asymmetries and Dynamical Evolution (BAaDE) survey more tightly define the region where Oxygen-rich (O) Asymptotic Giant Branch (AGB) stars reside in multiple infrared (IR) color-color diagrams. Using MSX and 2MASS data along with radio spectra from the BAaDE survey we find that three main populations were observed in the BAaDE survey: O-rich AGB stars of which about $73\%$ host SiO masers, Carbon-rich (C) AGB stars which do not host these masers, and a small contaminating set of possible Young Stellar Objects (YSOs). The distinction between YSOs and AGB…
The circumstellar environment of the AGB star L$_{\rm 2}$ Puppis was observed with ALMA in cycle 3, with a resolution of $15 \times 18 \rm\ mas$. The molecular emission shows a differentially rotating disk, inclined to a nearly edge-on position. In the first paper in this series (paper I) the molecular emission was analysed to accurately deduce the motion of the gas in the equatorial regions of the disk. In this work we model the optically thick $^{\rm 12}$CO $J=$3$-$2 and the optically thin $^{\rm 13}$CO $J=$3$-$2 rotational transition to constrain the physical conditions in the disk. To real…
Circumstellar envelopes (CEs) around evolved stars are an active site for the production of molecules. After evolving through the Asymptotic Giant Branch (AGB), proto-planetary nebula (PPN), to planetary nebula (PN) phases, CEs ultimately merge with the interstellar medium (ISM). The study of molecules in PNe, therefore, is essential to understanding the transition from stellar to interstellar materials. So far, over 20 molecular species have been discovered in PNe. The molecular composition of PNe is rather different from those of AGB and PPNe, suggesting that the molecules synthesized in PN …
Chemical modelling of AGB outflows is typically focused on either non-thermodynamic equilibrium chemistry in the inner region or photon-driven chemistry in the outer region. We include, for the first time, a comprehensive dust-gas chemistry in our AGB outflow chemical kinetics model, including both dust-gas interactions and grain-surface chemistry. The dust is assumed to have formed in the inner region, and follows an interstellar-like dust-size distribution. Using radiative transfer modelling, we obtain dust temperature profiles for different dust types in an O-rich and a C-rich outflow. We c…
OH 231.8+4.2, a bipolar outflow around a Mira-type variable star, displays a unique molecular richness amongst circumstellar envelopes (CSEs) around O-rich AGB and post-AGB stars. We report line observations of the HCO+ and H13CO+ molecular ions and the first detection of SO+, N2H+, and (tentatively) H3O+ in this source. SO+ and H3O+ have not been detected before in CSEs around evolved stars. These data have been obtained as part of a full mm-wave and far-IR spectral line survey carried out with the IRAM 30 m radio telescope and with Herschel/HIFI. Except for H3O+, all the molecular ions detec…
The evolution of low- and intermediate-mass stars on the asymptotic giant branch (AGB) is mainly controlled by the rate at which these stars lose mass in a stellar wind. Understanding the driving mechanism and strength of the stellar winds of AGB stars and the processes enriching their surfaces with products of nucleosynthesis are paramount to constraining AGB evolution and predicting the chemical evolution of galaxies. In a previous paper we have constrained the structure of the outflowing envelope of W Hya using spectral lines of the $^{12}$CO molecule. Here we broaden this study by modellin…
Circumstellar molecular composition of the oxygen-rich AGB star IK~Tau: II. In-depth non-LTE chemical abundance analysis
K.U.Leuven（荷语鲁汶大学）；University of Amsterdam（阿姆斯特丹大学）；Harvard-Smithsonian Center for Astrophysics（哈佛-史密森天体物理中心）；Universität zu Köln（科隆大学）；Max-Planck Institut für Radioastronomie（马克斯·普朗克射电天文研究所）；MPI für Gravitationsphysik（引力物理学马普研究所）；Jet Propulsion Laboratory, California Institute of Technology（加州理工学院喷气推进实验室）
