Many studies of especially dust nucleation in winds of carbon-rich AGB stars consider primarily carbon as dust forming material. But dust grains formed in such circumstellar envelopes are rather a mixture of several chemical elements such as titanium or silicon in addition to the main component carbon as verified by many investigations of pre-solar grains enclosed in meteorites, for example. In this contribution we focus on the study of the nucleation of titanium carbide particles from the gas phase. Therefore, the necessary properties of molecular titanium carbide clusters have been estimated within density functional approaches and first implications on the homogeneous nucleation of TiC are studied for conditions being representative for circumstellar dust shells around carbon-rich AGB stars.
Unravelling the composition and characteristics of gas and dust lost by asymptotic giant branch (AGB) stars is important as these stars play a vital role in the chemical life cycle of galaxies. The general hypothesis of their mass loss mechanism is a combination of stellar pulsations and radiative pressure on dust grains. However, current models simplify dust formation, which starts as a microscopic phase transition called nucleation. Various nucleation theories exist, yet all assume chemical equilibrium, growth restricted by monomers, and commonly use macroscopic properties for a microscopic …
Chemical equilibrium has proven extremely useful to predict the chemical composition of AGB atmospheres. Here we use a recently developed code and an updated thermochemical database, including gaseous and condensed species involving 34 elements, to compute the chemical equilibrium composition of AGB atmospheres of M-, S-, and C-type stars. We include for the first time TixCy clusters, with x = 1-4 and y = 1-4, and selected larger clusters ranging up to Ti13C22, for which thermochemical data is obtained from quantum chemical calculations. We find that in general chemical equilibrium reproduces …
TIC 295741342: A Triply-Eclipsing Triple Star System with a Giant Tertiary
NASA Goddard Space Flight Center（NASA戈达德太空飞行中心）；SETI Institute（地外文明研究所）；Department of Physics, Kavli Institute for Astrophysics and Space Research, M.I.T.（麻省理工学院物理系、卡弗里天体物理学与空间研究研究所）；Baja Astronomical Observatory of University of Szeged（塞格德大学巴亚天文台）；HUN-REN – SZTE Stellar Astrophysics Research Group（匈牙利研究与教育网络-塞格德大学恒星天体物理学研究组）；Konkoly Observatory, Research Centre for Astronomy and Earth Sciences（孔科利天文台，地球科学研究中心）
Silicon carbide (SiC) grains are a major dust component in carbon-rich AGB stars. The formation pathways of these grains are, however, not fully understood.\ We calculate ground states and energetically low-lying structures of (SiC)$_n$, $n=1,16$ clusters by means of simulated annealing (SA) and Monte Carlo simulations of seed structures and subsequent quantum-mechanical calculations on the density functional level of theory. We derive the infrared (IR) spectra of these clusters and compare the IR signatures to observational and laboratory data.\ According to energetic considerations, we evalu…
The formation of silicate dust in oxygen-rich envelopes of evolved stars is thought to be initiated by formation of seed particles that can withstand the high temperatures close to the stellar photosphere and act as condensation cores farther away from the star. Candidate species considered as first condensates are TiO and TiO$_2$. We aim to identify and characterize the circumstellar gas-phase chemistry of titanium that leads to the formation of solid titanium compounds in the envelope of $o$ Cet, the prototypical Mira, and seek an observational verification of whether titanium oxides play a …
Clustering of the abundant SiO molecules has been discussed as a possible mechanism of seed particle formation for silicate dust in stellar outflows with an oxygen rich element mixture. Previous results indicated that condensation temperatures based on this mechanism are significant lower than what is really observed. This negative result strongly rests on experimental data on vapour pressure of SiO. New determinations show the older data to be seriously in error. Here we aim to check with improved data the possibility that SiO nucleation triggers the cosmic silicate dust formation. First we p…
We model the synthesis of molecules and dust in the inner wind of the oxygen-rich Mira-type star IK Tau, by considering the effects of periodic shocks induced by the stellar pulsation on the gas, and by following the non-equilibrium chemistry in the shocked gas layers between 1 and 10 Rstar. We consider a complete set of molecules and dust clusters, and combine the nucleation phase of dust formation with the condensation of these clusters into dust grains. Our derived molecular abundances and dust properties are compared to the most recent observational data. The chemistry is described by usin…
AGB stars are, together with supernovae, the main contributors of stellar dust to the interstellar medium (ISM). Dust grains formed by AGB stars are thought to be large. However, as dust nucleation and growth within their outflows are still not understood, the dust-grain size distribution (GSD) is unknown. This is an important uncertainty regarding our knowledge of the chemical and physical history of interstellar dust, as AGB dust forms $\sim$ 70% of the starting point of its evolution. We expand on our chemical kinetics model, which uniquely includes a comprehensive dust-gas chemistry. The G…
Long-period variables (LPVs) and Miras are highly evolved stars at the upper region of the asymptotic giant branch. They exhibit a pronounced variability of their luminosity with a more or less well defined period and suffer large mass loss in the form of stellar winds. Due to this extensive mass loss, LPVs and Miras are surrounded by extended circumstellar dust shells (CDSs). The dynamics of these envelopes is the result of a complex interplay via an external excitation by the pulsating central star, dust formation and radiative transfer. Our study is aimed at an understanding of the dynamics…
Using ALMA, we observed the stellar wind of two oxygen-rich Asymptotic Giant Branch (AGB) stars, IK Tau and R Dor, between 335 and 362 GHz. One aim was to detect metal oxides and metal hydroxides (AlO, AlOH, FeO, MgO, MgOH), some of which are thought to be direct precursors of dust nucleation and growth. We report on the potential first detection of FeO (v=0, Omega=4, J=11-10) in RDor (mass-loss rate, Mdot, ~1e-7 Msun/yr). The presence of FeO in IK Tau (Mdot~5e-6 Msun/yr) cannot be confirmed due to a blend with 29SiS, a molecule that is absent in R Dor. The detection of AlO in R Dor and of AlO…
Aims. We present the implementation of the treatment of particle ejection and dust nucleation in the smoothed particle hydrodynamics (SPH) code phantom. These developments represent the first step toward a more complete modeling of dust-driven winds emanating from AGB stars. Methods. The AGB outflow is modeled by injecting the SPH particles from a spherical inner boundary. This boundary is a series of concentric shells, with the AGB star at its center, and the particles are positioned on these shells on the vertices of an isocahedron geodesic surface. The outermost shell is ejected with a pred…
Clouds form in atmospheres of brown dwarfs and planets. The cloud particle formation processes are similar to the dust formation process studied in circumstellar shells of AGB stars and in Supernovae. Cloud formation modelling in substellar objects requires gravitational settling and element replenishment in addition to element depletion. All processes depend on the local conditions, and a simultaneous treatment is required. We apply new material data in order to assess our cloud formation model results regarding the treatment of the formation of condensation seeds. We re-address the question …
Stellar dust grains are predominantly composed of mineralic, anorganic material forming in the circumstellar envelopes of oxygen-rich AGB stars. However, the initial stage of the dust synthesis, or its nucleation, is not well understood. In particular, the chemical nature of the nucleating species, represented by molecular clusters, is uncertain. We investigated the vertical and adiabatic ionization energies of four different metal-oxide clusters by means of density functional theory. They included clusters of magnesia (MgO)$_n$, silicon monoxide (SiO)$_n$, alumina (Al$_2$O$_3$)$_n$, and titan…
We investigate the formation of silicon carbide (SiC) grains in the framework of dust-driven wind around pulsating carbon-rich Asymptotic Giant Branch (C-rich AGB) stars in order to reveal not only the amount but also the size distribution. Two cases are considered for the nucleation process; one is the LTE case where the vibration temperature of SiC clusters $T_{\rm v}$ is equal to the gas temperature as usual, and another is the non-LTE case in which $T_{\rm v}$ is assumed to be the same as the temperature of small SiC grains. The results of hydrodynamical calculations for a model with stell…
Presolar silicon carbide (SiC) grains in meteoritic samples can help constrain circumstellar condensation processes and conditions in C-rich stars and core-collapse supernovae. This study presents our findings on eight presolar SiC grains from AGB stars (four mainstream and one Y grain) and core-collapse supernovae (three X grains), chosen on the basis of μ-Raman spectral features that were indicative of their having unusual non-3C polytypes and/or high degrees of crystal disorder. Analytical transmission electron microscopy (TEM), which provides elemental compositional and structural informat…
