This work discusses theoretically the interplay between the superconducting and ferromagnetic proximity effects, in a diffusive normal metal strip in contact with a superconductor and a non-uniformly magnetized ferromagnetic insulator. The quasiparticle density of states of the normal metal shows clear qualitative signatures of triplet correlations with spin one (TCS1). When one goes away from the superconduting contact, TCS1 focus at zero energy under the form of a peak surrounded by dips, which show a typical spatial scaling behavior. This behavior can coexist with a focusing of singlet correlations and triplet correlations with spin zero at finite but subgap energies. The simultaneous observation of both effects would enable an unambigous characterization of TCS1.
We present an overview of the contributions made by Konstantin B. Efetov and the authors to the field of triplet odd-frequency superconductivity in hybrid ferromagnet-superconductor structures and the repercussions they had on experimental and theoretical research. Konstantin B. Efetov passed away in August 2021. We hope the present short review gives a faithful testimony of an important part of his scientific legacy.
It has been commonly accepted that magnetic field suppresses superconductivity by inducing the ordered motion of Cooper pairs. We demonstrate that magnetic field can instead provide a generation of superconducting correlations by inducing the motion of superconducting condensate. This effect arises in superconductor/ferromagnet heterostructures in the presence of Rashba spin-orbital coupling. We predict the odd-frequency spin-triplet superconducting correlations called the Berezinskii order to be switched on at large distances from the superconductor/ferromagnet interface by the application of…
We have investigated the proximity effect in superconductor/ferromagnet junctions in a systematic manner to discuss the relationship between the zero-energy peak (ZEP) of the local density of states (LDOS) and spin-triplet odd-frequency pairing. By exactly solving the nonlinear Usadel equations, we have found that the ZEP is realized in a wide range of geometrical and material parameters in the case of the noncollinear magnetization. This strongly suggests the robustness of the ZEP induced by spin-triplet odd-frequency pairing in such systems. We also found that the crossover from singlet pair…
Using the quasiclassical Green's function formalism, we study the influence of the odd-frequency spin-triplet superconductivity on the local density of states (LDOS) in a diffusive ferromagnet (DF) attached to a superconductor. Various possible symmetry classes in a superconductor are considered which are consistent with the Pauli's principle: even-frequency spin-singlet even-parity (ESE) state, even-frequency spin-triplet odd-parity (ETO) state, odd-frequency spin-triplet even-parity (OTE) state and odd-frequency spin-singlet odd-parity (OSO) state. For each of these states, the pairing state…
We consider a multidomain superconductor/ferromagnet (SF) structure with an in-plane magnetization, assuming that the neighboring domains are separated by the Neel domain walls. We show that an odd triplet long-range component arises in the domain walls and spreads into domains over a long distance of the order ξ_T = \sqrt{D/2πT} (in the dirty limit). The density of states variation in the domains due to this component changes over distances of the order ξ_T and turns to zero in the middle of domains if the magnetization rotates in the same direction in all domain walls.
We study proximity effect in diffusive ferromagnet/normal-metal/superconductor junction with precessing magnetization of the ferromagnet. We find that the odd-frequency pairing induced in the normal metal is modified by spin pumping from the ferromagnet and hence can be tuned by changing the precessional frequency. At the frequency corresponding to twice the superconducting gap, the odd-frequency pairing is strongly enhanced. We find a crossover from the even- to the odd-frequency superconductivity in the normal metal by tuning the precessional frequency. This gives a clearcut signature of the…
We study the Josephson effect and pairing correlations in SFFS junctions that consist of conventional superconductors (S) connected through two metallic monodomain ferromagnets (F) with transparent and spin inactive interfaces. We solve the Eilenberger equations for arbitrary relative orientation of magnetizations of the two F layers in the clean limit and for moderate disorder in ferromagnets. Spatial variation of pair amplitudes, singlet $f_s$, and odd in frequency triplet $f_{t0}$ and $f_{t1}$, with 0 and $\pm1$ spin projections, as well as the Josephson current-phase relations are calculat…
We theoretically predict proximity-induced odd-frequency (odd-$ω$) pairing on the surface of a Weyl nodal loop semimetal, characterized by a nodal loop Fermi surface and drumhead-like surface states (DSSs), attached to conventional spin-singlet $s$-wave superconducting leads. Due to the complete spin polarization of the DSS, odd-$ω$ equal-spin triplet pairing is present, and we show that it gives rise to a finite Josephson current. Placing an additional ferromagnet in the junction can also generate odd-$ω$ mixed-spin triplet pairing, but the pairing and current is not affected if the magnetiza…
We consider a SFS Josephson junction made of two superconductors S and a multidomain ferromagnet F with an in-plane magnetization. We assume that the neighboring domains of the ferromagnet are separated by Neel domain walls. An odd-frequency triplet long-range component of superconducting correlations arises in the domain walls and spreads into the domains over a long distance of the order $ξ_T = \sqrt{D / 2 πT}$, where $D$ is the diffusion coefficient (dirty limit is implied). We calculate the contribution of this component to the Josephson current in the situation when conventional short-ran…
Superconducting correlations which are long-ranged in magnetic systems have attracted much attention due to their spin-polarization properties and potential use in spintronic devices. Whereas experiments have demonstrated the slow decay of such correlations, it has proven more difficult to obtain a smoking gun signature of their odd-frequency character which is responsible, e.g. for their gapless behavior. We here demonstrate that the magnetic susceptibility response of a normal metal in contact with a superconducting spin-valve provides precisely this signature, namely in form of an anomalous…
We consider some properties of odd frequency triplet superconducting condensates. In order to describe fluctuations we construct a supermatrix sigma-model for the superconductor/ferromagnet or superconductor/normal-metal structures. We show that an odd frequency triplet superconductor, when in isolation or coupled to a normal metal, generally displays behaviour comparable to a superconductor with the usual singlet pairings. However, for spin dependent systems such as the superconductor/ferromagnet the two types of superconductor have quite different behaviour. We discuss this difference by con…
We demonstrate that in multilayered superconductor-ferromagnet structures a non-collinear alignment of the magnetizations of different ferromagnetic layers generates a triplet superconducting condensate which is odd in frequency. This triplet condensate coexists in the superconductors with the conventional singlet one but decays very slowly in the ferromagnet, which should lead to a large Josephson effect between the superconductors separated by the ferromagnet. Depending on the mutual direction of the ferromagnetic moments the Josephson coupling can be both of 0 and $π$ type.
We show that mixed-parity superconductors may exhibit equal-spin pair correlations that are odd-in-time and can be tuned by means of an applied field. The direction and the amplitude of the pair correlator in the spin space turn out to be strongly dependent on the symmetry of the order parameter, and thus provide a tool to identify different types of singlet-triplet mixed configurations. We find that odd-in-time spin-polarized pair correlations can be generated without magnetic inhomogeneities in superconducting/ferromagnetic hybrids when parity mixing is induced at the interface.
Contacting a bilayer ferromagnet with a singlet even-frequency superconductor allows for the realization of an effective triplet odd-frequency superconductor. In this work, we investigate the Josephson effect between superconductors with different symmetries (e.g. odd- versus even-frequency). In particular, we study the supercurrent flowing between two triplet odd-frequency superconducting leads through a weak singlet even-frequency superconductor. We show that the peculiar temperature dependence of the critical current below the superconducting transition of the weak superconductor is a signa…
The superconducting critical temperature $T_C$ of a superconductor/ferromagnet (S/F) bilayer with spin-flip scatterings at the interface is calculated as a function of the ferromagnet thickness $d_F$ in the dirty limit employing the Usadel equation. The appropriate boundary conditions from the spin-flip scatterings at the S/F interface are derived for the Usadel equation which includes the spin triplet pairing components as well as the spin singlet one. The spin-flip processes induce the spin triplet pairing components with s-wave in momentum and odd symmetry in frequency from the s-wave singl…
We predict the occurrence of odd frequency equal-spin-triplet correlations at a normal metal-superconductor junction. This result is significant because equal-spin-triplet correlations are associated with the presence of dissipation-less pure spin current. Inserting a spin-flipper at the interface of a normal metal-superconductor junction excites equal-spin-triplet correlations. The existence of odd frequency equal-spin-triplet correlations in absence of odd frequency mixed spin-triplet correlations is the main take-home message of this work. It tallies well with the measured local magnetizati…
The effects of spin independent hybridization potential and spin orbit coupling on two band superconductor with equal time s-wave inter band pairing order parameter is investigated theoretically. To study symmetry classes in two band superconductors the Gorkov equations are solved analytically. By defining spin singlet and spin triplet s wave order parameter due to two band degree of freedom the symmetry classes of Cooper pair are studied. For spin singlet case it is shown that spin independent hybridization generates Cooper pair belongs to even frequency spin singlet even momentum even band p…
We study triplet pairing correlations in clean Ferromagnet (F)/Superconductor (S) nanojunctions, via fully self consistent solution of the Bogoliubov-de Gennes equations. We consider FSF trilayers, with S being an s-wave superconductor, and an arbitrary angle $α$ between the magnetizations of the two F layers. We find that contrary to some previous expectations, triplet correlations, odd in time, are induced in both the S and F layers in the clean limit. We investigate their behavior as a function of time, position, and $α$. The triplet amplitudes are largest at times on the order of the inver…
We study the interplay of spin and charge coherence in a single-level quantum dot. A tunnel coupling to a superconducting lead induces superconducting correlations in the dot. With full spin symmetry retained, only even-singlet superconducting correlations are generated. An applied magnetic field or attached ferromagnetic leads partially or fully reduce the spin symmetry, and odd-triplet superconducting correlations are generated as well. For single-level quantum dots, no other superconducting correlations are possible. We analyze, with the help of a diagrammatic real-time technique, the inter…
We analyze a superconductor-ferromagnet (S/F) system with a spiral magnetic structure in the ferromagnet F for a weak and strong exchange field. The long-range triplet component (LRTC) penetrating into the ferromagnet over a long distance is calculated for both cases. In the dirty limit (or weak ferromagnetism) we study the LRTC for conical ferromagnets. Its spatial dependence undergoes a qualitative change as a function of the cone angle θ. At small angles the LRTC decays in the ferromagnet exponentially in a monotonic way. If the angle θexceeds a certain value, the exponential decay of the L…
We study the interplay between proximity-induced superconductivity and ferromagnetism in graphene by self-consistently solving the Bogoliubov-de Gennes equations on the honeycomb lattice. We find that a strong triplet proximity effect is generated in graphene, leading to odd-frequency pairing correlations. These odd-frequency correlations are clearly manifested in the local density of states of the graphene sheet, which can be probed via STM-measurements. Motivated by recent experiments on S$\mid$N$\mid$S graphene Josephson junctions, we also study the spectrum of Andreev-bound states formed i…
We study the proximity effect in superconductor-ferromagnet (SF) structure with a narrow domain wall (DW) at the SF interface. The width of the domain wall is assumed to be larger than the Fermi wave length, but smaller than other characteristic lengths (for example, the ''magnetic'' length). The transmission coefficient is supposed to be small so that we deal with a weak proximity effect. Solving the linearized Eilenberger equation, we find analytical expressions for quasiclassical Green's functions. These functions describe the short-range (SR) condensate components, singlet and triplet with…
We consider novel unusual effects in superconductor-ferromagnet (S/F) structures. In particular we analyze the triplet component (TC) of the condensate generated in those systems.This component is odd in frequency and even in the momentum, which makes it insensitive to non-magnetic impurities. If the exchange field is not homogeneous in the system the triplet component is not destroyed even by a strong exchange field and can penetrate the ferromagnet over long distances. Some other effects considered here and caused by the proximity effect are: enhancement of the Josephson current due to the p…
We propose a route to achieve odd-parity spin-triplet superconductivity in metallic collinear antiferromagnets with inversion symmetry. Owing to the existence of hidden antiunitary symmetry, which we call the effective time-reversal symmetry (eTRS), the Fermi surfaces of ordinary antiferromagnetic metals are generally spin-degenerate, and spin-singlet pairing is favored. However, by introducing a local inversion symmetry breaking perturbation that also breaks the eTRS, we can lift the degeneracy to obtain spin-polarized Fermi surfaces. In the weak-coupling limit, the spin-polarized Fermi surfa…
We consider normal-superconductor (NS) and superconductor-normal-superconductor (SNS) junctions based on one-dimensional nanowires with Rashba spin-orbit coupling and proximity-induced $s$-wave spin-singlet superconductivity and analytically demonstrate how both even- and odd-frequency and spin-singlet and -triplet superconducting pair correlations are always present. In particular, by using a fully quantum mechanical scattering approach, we show that Andreev reflection induces mixing of spatial parities at interfaces, thus being the unique process which generates odd-frequency pairing; on the…
We construct a quasiclassical framework for topological superconductors with the strong spin-orbit coupling such as CuxBi2Se3. In the manner of the quasiclassical treatment, decomposing the slowly varying component from the total quasi-particle wave function, the original massive Dirac Bogoliubov-de Gennes (BdG) Hamiltonian derived from the tight-binding model represented by 8 x 8 matrix is reduced to 4 x 4 one. The resultant equations are equivalent to Andreev-type equations of singlet or triplet superconductors, in which the apparent spin-orbit coupling vanishes. Using this formalism, we fin…
In this work, we systematically study two phases, called Andreev $π$-phase and orbital-phase, and their influence on the Josephson effect. When the system is time-reversal invariant and centrosymmetric, these two phases only appear in the odd-parity pairings. The Andreev $π$-phase has nothing to do with the specific form of the odd-parity pairings and means an intrinsic $π$-phase between the spin-triplet Cooper pairs entering and leaving CTSCs in the Andreev reflections. The orbital-phase corresponds to the phase difference between the spin-triplet Cooper pairs with opposite spin polarization …
Strongly correlated systems exhibit a rich phenomenology due to the antagonism of a diversity of ordered phases. The aftermath of this interplay can lead to a coexistence which takes place at a microscopic level, or, a phase separation in which non-overlapping single-order domains extend throughout the material. In most cases it appears experimentally challenging to disentangle the two scenarios, unless, there exist robust and measurable properties particular to only one of the two types of coexistence. This is for instance the case when the type of coexistence decides on the appearance of top…
Searching for unconventional Cooper pairing states has been at the heart of superconductivity research since the discovery of BCS superconductors. In particular, spin-triplet odd-parity pairing states were recently revisited due to the possibility of tuning towards topological superconductors. In this context, it is interesting to note a recent proposal that such a spin-triplet pairing instability occurs when the band filling is near van Hove singularities (vHS) associated with momenta away from time-reversal invariant momenta named type-II vHS. However, this result was obtained within a weak …
After more than a decade, direct observation of the odd frequency triplet pairing state in super- conducting hybrid structures remains elusive. We propose an experimentally feasible setup that can unambiguously reveal the zero energy peak due to proximity-induced equal spin superconducting triplet correlations. We theoretically investigate a two dimensional Josephson junction in the diffu- sive regime. The nanostructure consists of a normal metal sandwiched between two ferromagnetic layers with spiral magnetization patterns. By applying an external magnetic field perpendicular to the junction …
We demonstrate that, quite generally, the spin-singlet even-parity (spin-triplet odd-parity) pair potential in a superconductor induces the odd-frequency pairing component with spin-singlet odd-parity (spin-triplet even-parity) near interfaces. The magnitude of the induced odd-frequency component is enhanced in the presence of the midgap Andreev resonant state due to the sign change of the anisotropic pair potential at the interface. The Josephson effect should therefore occur between odd- and even-frequency superconductors, contrary to the standard wisdom. A method to probe the odd-frequency …
We propose a novel experiment to identify the symmetry of superconductivity on the basis of theoretical results for differential conductance of a normal metal connected to a superconductor. The proximity effect from the superconductor modifies the conductance of the remote current depending remarkably on the pairing symmetry: spin-singlet or spin-triplet. The clear-cut difference in the conductance is explained by symmetry of Cooper pairs in a normal metal with respect to frequency. In the spin-triplet case, the anomalous transport is realized due to an odd-frequency symmetry of Cooper pairs.
We study the dc Josephson effect in a diffusive multilayered SF'FF'S structure, where S is a superconductor and F,F' are different ferromagnets. We assume that the exchange energies in the F' and F layers are different ($% h $ and $H$, respectively) and the middle F layer consists of two layers with parallel or antiparallel magnetization vectors $M$. The $M$ vectors in the left and right F' layers are generally not collinear to those in the F layer. In the limit of a weak proximity effect we use a linearized Usadel equation. Solving this equation, we calculate the Josephson critical current fo…
Conventional electron-phonon coupling induces either odd (triplet) or even (singlet) pairing states in a time reversal and inversion invariant Dirac semi - metal. In certain range of the chemical potential $μ$ and parameters characterizing the pairing attraction (effective electron-electron coupling constant $λ$ and the Debye energy $T_{D}$) the energy of the singlet although always lower, prevails by a very slim margin over the triplet. This means that interactions that are small but discriminate between the spin singlet and the spin triplet determine the nature of the superconducting order t…
We study the critical temperature T_c of FSF trilayers (F is a ferromagnet, S is a singlet superconductor), where the triplet superconducting component is generated at noncollinear magnetizations of the F layers. An exact numerical method is employed to calculate T_c as a function of the trilayer parameters, in particular, mutual orientation of magnetizations. Analytically, we consider limiting cases. Our results determine conditions which are necessary for existence of recently investigated odd triplet superconductivity in SF multilayers.
We theoretically study the magnetization inside a normal metal induced in an s-wave superconductor/ferromagnetic metal/normal metal/ferromagnetic metal/s-wave superconductor (S/F1/N/F2/S) Josephson junction. Using quasiclassical Green's function method, we show that the magnetization becomes finite inside N. The origin of this magnetization is due to odd-frequency spin-triplet Cooper pairs formed by electrons of equal and opposite spins, which are induced by proximity effect in the S/F1/N/F2/S junction. We find that the magnetization M(d,q) in N can be decomposed into two parts, M(d,q)=MI(d)+M…
The unique Fermi surfaces and their nesting properties of Sr2RuO4 are considered. The existence of unconventional superconductivity is shown microscopically, for the first time, from the magnetic interactions (due to nesting) and the phonon-mediated interactions. The odd-parity superconductivity is favored in the $α$ and $β$ sheets of the Fermi surface, and the various superconductivities are possible in the $γ$ sheet. There are a number of possible odd-parity gaps, which include the gaps with nodes, the breaking of time-reversal symmetry and $\vec{d}\parallel \hat{z}$.
We explore the role of proximity-induced odd-frequency pairing in the thermoelectricity of a ferromagnet when coupled to a conventional $s$-wave spin-singlet superconductor through a spin-active interface. By varying both the polarization and its direction in the ferromagnet and the interfacial spin-orbit interaction strength, we analyze the behavior of all proximity-induced pair amplitudes in the ferromagnet and their contributions to the thermoelectric coefficients. Based on our results for the Seebeck coefficient, we predict that odd-frequency spin-triplet Cooper pairs are much efficient th…
We establish that Majorana fermions on the boundary of topological superconductors have only spin-triplet superconducting correlations independent of whether the bulk superconducting gap is spin singlet or triplet. This is universal for time-reversal broken (respected) topological superconductors (TSCs) with an odd number of (pairs of) Majorana fermions on the boundary. Consequently, resonant Andreev reflection induced by Majorana fermions only occurs in spin-triplet channels and always injects spin-triplet Cooper pairs into the leads. This spin-triplet condensate results in a spin-orbit coupl…
We argue that odd-frequency triplet superconductivity can be conveniently realized in hybrid superconductor-ferromagnet (SF) structures with a ferromagnetic vortex. We demonstrate that due to proximity-induced long-range triplet pairing such SFS junctions can sustain appreciable supercurrent which can be directly measured in experiments.
We show that all the singlet even-frequency, singlet odd-frequency, triplet even-frequency and triplet odd-frequency pairings, and together with the corresponding order parameters (gaps) can be realized in InSb (110) spin-orbit-coupled quantum well in proximity to s-wave superconductor in Fulde-Ferrell-Larkin-Ovchinnikov phase or with a supercurrent. It is revealed that with the singlet even-frequency order parameter induced by the proximity effect, triplet even-frequency pairing is induced due to the broken spin-rotational symmetry by the spin-orbit coupling. Since the translational symmetry …
We explore possible superconducting states in $t_{2g}$ multi-orbital correlated electron systems with strong spin-orbit coupling (SOC). In order to study such systems in a controlled manner, we employ large-scale dynamical mean-field theory (DMFT) simulations with the hybridization expansion continuous-time Quantum Monte Carlo (CTQMC) impurity solver. To determine the pairing symmetry, we go beyond the local DMFT formalism using parquet equations to introduce the momentum dependence in the two-particle vertex and correlation functions. In the strong SOC limit, a singlet, $d$-wave pairing state…
Motivated by recent thermal conductivity measurements in the superconductor CeCoIn5, we theoretically examine a possible staggered spin-triplet superconducting order to be induced by the coupled spin-density-wave (SDW) and d-wave superconducting (SC) orders in the high field and low temperature (HFLT) SC phase peculiar to this material with strong paramagnetic pair-breaking (PPB). It is shown that one type of the $π$-triplet order is consistent with the thermal conductivity data and can naturally be incorporated in the picture that the Q-phase is a consequence of the strong PPB effect inducing…
It has been predicted theoretically that an unconventional odd-frequency spin-triplet component of superconducting order parameter can be induced in multilayered ferromagnetic structures with non-collinear magnetization. In this work we study experimentally nano-scale devices, in which a ferromagnetic spin valve is embedded into a Josephson junction. We demonstrate two ways of in-situ analysis of such Josephson spin valves: via magnetoresistance measurements and via in-situ magnetometry based on flux quantization in the junction. We observe that supercurrent through the device depends on the r…
We theoretically study the effects of spin-orbit interactions on symmetry of a Cooper pair in a spin-singlet d-wave superconductor in two-dimension. The pairing symmetry is analyzed in terms of the anomalous Green's function which is obtained by solving the Gor'kov equation analytically. A spin-orbit interaction induces a spin-triplet p-wave pairing correlation in a uniform superconductor. An odd-frequency spin-triplet s-wave pairing correlation appears at a surface of such superconductor as a result of breaking inversion symmetry locally. We also discuss a close relationship among the odd-fre…
The Josephson effect in superconductor / diffusive ferromagnet / superconductor (SFS) junctions is studied using the recursive Green function method in the regime of large exchange energy in a ferromagnet. Motivated by recent experiment [R. S. Keizer, et. al., Nature 439, 825 (2006)] we also address the case of superconductor / diffusive half metal / superconductor junctions. The pairing function in spin-singlet and triplet channels, the Josephson current and their mesoscopic fluctuations are calculated. We show that the spin-flip scattering at the junction interfaces opens the Josephson chann…
The proximity effect from a spin-triplet $p_x$-wave superconductor to a dirty normal-metal has been shown to result in various unusual electromagnetic properties, reflecting a cooperative relation between topologically protected zero-energy quasiparticles and odd-frequency Cooper pairs. However, because of a lack of candidate materials for spin-triplet $p_x$-wave superconductors, observing this effect has been difficult. In this paper, we demonstrate that the anomalous proximity effect, which is essentially equivalent to that of a spin-triplet $p_x$-wave superconductor, can occur in a semicond…
Motivated by the proposed topological state in Cu$_x$Bi$_2$Se$_3$, we study the possibility of phonon-mediated odd-parity superconductivity in spin-orbit coupled systems with time-reversal and inversion symmetry. For such systems, we show that, in general, pure electron-phonon coupling can never lead to a triplet state with a higher critical temperature than the leading singlet state. The Coulomb pseudopotential, which is the repulsive part of the electron-electron interaction and is typically small in weakly correlated systems, is therefore critical to stabilizing the triplet state. We introd…
The spin transport inside an odd-frequency spin-triplet superconductor differs from that of a conventional superconductor due to its distinct symmetry properties. We study spin transport inside an emergent odd-frequency superconductor by replacing the spin-singlet gap matrix in the Usadel equation with a matrix representing spin-triplet pairing that is odd under inversion of energy. We show that the peculiar nature of the density of states allows for an even larger spin injection than in the normal-state. Moreover, when the odd-frequency pairing inherits its temperature dependence from a conve…
We show that odd-parity superconductivity occurs in multilayer Rashba systems without requiring spin-triplet Cooper pairs. A pairing interaction in the spin-singlet channel stabilizes the odd-parity pair-density-wave (PDW) state in the magnetic field parallel to the two-dimensional conducting plane. It is shown that the layer-dependent Rashba spin-orbit coupling and the orbital effect play essential roles for the PDW state in binary and tricolor heterostructures. We demonstrate that the odd-parity PDW state is a symmetry-protected topological superconducting state characterized by the one-dime…
