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arXiv 1105.3233physics.atom-phphysics.opticsquant-ph
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光频计量中黑体辐射位移的精确计算

Precision calculation of blackbody radiation shifts for optical frequency metrology

M. S. Safronova, M. G. Kozlov, Charles W. Clark

摘要:

我们发现三种IIIB族二价离子B+、Al+和In+在ns^2 1 S 0- nsnp 3 P0时钟跃迁中具有非常小的黑体辐射(BBR)位移。在相同温度下,这些离子的BBR分数位移至少比任何其他现有或拟议的光频标准的BBR分数位移小10倍,并且小于Sr时钟位移的0.3%。我们已经开发了一种混合配置相互作用+耦合集群方法,提供了准确的治疗,在这样的离子相关校正,认为所有相关的国家在相同的系统的方式,并产生严格的上限的最终结果的不确定性。在T= 300 K时,我们将BBR对Al+时钟的分数频率不确定度的贡献减少到4 \times 10^{-19}。我们还将室温下B+和In+的不确定度降低到10^{-18}水平,以促进这些系统在计量和量子传感方面的进一步发展。这些不确定性接近目前提出的光学原子钟的可行精度的最新估计。

英文摘要:

We show that three group IIIB divalent ions, B+, Al+, and In+, have anomalously small blackbody radiation (BBR) shifts of the ns^2 1S0 - nsnp 3P0 clock transitions. The fractional BBR shifts for these ions are at least 10 times smaller than those of any other present or proposed optical frequency standards at the same temperature, and are less than 0.3% of the Sr clock shift. We have developed a hybrid configuration interaction + coupled-cluster method that provides accurate treatment of correlation corrections in such ions, considers all relevant states in the same systematic way, and yields a rigorous upper bound on the uncertainty of the final results. We reduce the BBR contribution to the fractional frequency uncertainty of the Al+ clock to 4 \times 10^{-19} at T=300K. We also reduce the uncertainties due to this effect at room temperature to 10^{-18} level for B+ and In+ to facilitate further development of these systems for metrology and quantum sensing. These uncertainties approach recent estimates of the feasible precision of currently proposed optical atomic clocks.

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