arXivDaily arXiv每日学术速递 周一至周五更新
arXiv 1104.3928cond-mat.stat-mechnlin.CD
收藏

自由能变化、涨落和路径概率

Free Energy Changes, Fluctuations, and Path Probabilities

William G. Hoover, Carol G. Hoover

摘要:

我们举例说明了科恩、克鲁克斯、埃文斯、贾津斯基、柯克伍德、莫里斯、塞尔和茨旺齐格发现的一些静态和动态关系。这些关系将非平衡过程与平衡等温自由能变化和动力学路径概率联系起来。我们包括Dellago,Geissler,Oberhofer和Schoell-Paschinger提出的想法。我们的处理是为了教学,用于我们的书的更新版本:时间可逆性,计算机模拟和混沌。非常欢迎评论。

英文摘要:

We illustrate some of the static and dynamic relations discovered by Cohen, Crooks, Evans, Jarzynski, Kirkwood, Morriss, Searles, and Zwanzig. These relations link nonequilibrium processes to equilibrium isothermal free energy changes and to dynamical path probabilities. We include ideas suggested by Dellago, Geissler, Oberhofer, and Schoell-Paschinger. Our treatment is intended to be pedagogical, for use in an updated version of our book: Time Reversibility, Computer Simulation, and Chaos. Comments are very welcome.

机构、总结、中文摘要均由AI分析而来,可能存在错误,请以论文正文为准。

↑