Hyperuniform point patterns are characterized by vanishing infinite wavelength density fluctuations and encompass all crystal structures, certain quasi-periodic systems, and special disordered point patterns. This article generalizes the notion of hyperuniformity to include also two-phase random heterogeneous media. Hyperuniform random media do not possess infinite-wavelength volume fraction fluctuations, implying that the variance in the local volume fraction in an observation window decays faster than the reciprocal window volume as the window size increases. For microstructures of impenetrable and penetrable spheres, we derive an upper bound on the asymptotic coefficient governing local volume fraction fluctuations in terms of the corresponding quantity describing the variance in the local number density (i.e., number variance). Extensive calculations of the asymptotic number variance coefficients are performed for a number of disordered (e.g., quasiperiodic tilings, classical stealth disordered ground states, and certain determinantal point processes), quasicrystal, and ordered (e.g., Bravais and non-Bravais periodic systems) hyperuniform structures in various Euclidean space dimensions, and our results are consistent with a quantitative order metric characterizing the degree of hyperuniformity. We also present corresponding estimates for the asymptotic local volume fraction coefficients for several lattice families. Our results have interesting implications for a certain problem in number theory.
The hyperuniformity concept provides a unified means to classify all perfect crystals, perfect quasicrystals, and exotic amorphous states of matter according to their capacity to suppress large-scale density fluctuations. While the classification of hyperuniform point configurations has received considerable attention, much less is known about the classification of hyperuniform heterogeneous two-phase media, which include composites, porous media, foams, cellular solids, colloidal suspensions and polymer blends. The purpose of this article is to begin such a program for certain two-dimensional…
Hyperuniformity, quasi-long-range correlations, and void-space constraints in maximally random jammed particle packings. II. Anisotropy in particle shape
We analyse the long-lasting effects of initial conditions on fluctuations in one-dimensional diffusive systems. We consider both the fluctuations of current for non-interacting diffusive particles starting from a step-like initial density profile, and the mean-square displacement of tracers in homogeneous systems with single-file diffusion. For these two cases, we show analytically (via the propagator and Macroscopic Fluctuation Theory, respectively) that the long-term memory of initial conditions is mediated by a single static quantity: a generalized compressibility that quantifies the densit…
The recently developed concept of spreadability, $\mathcal{S}(t)$, provides a direct link between time-dependent diffusive transport and the microstructure of two-phase media across length scales. We explicitly compute $\mathcal{S}(t)$ for well-known two-dimensional and three-dimensional model structures, including nonhyperuniform fully penetrable spheres and equilibrium hard spheres, as well as hyperuniform sphere packings derived from perfect glasses, uniformly randomized lattices (URL), disordered stealthy point processes and Bravais lattices. We further confirm that the small-, intermediat…
We investigate a diffusion process in heterogeneous media where particles stochastically reset to their initial positions at a constant rate. The heterogeneous media is modeled using a spatial-dependent diffusion coefficient with a power-law dependence on particles' positions. We use the Green function approach to obtain exact solutions for the probability distribution of particles' positions and the mean square displacement. These results are further compared and agree with numerical simulations of a Langevin equation. We also study the first-passage time problem associated with this diffusio…
