The origin of Titan's atmospheric methane is a key issue for understanding the origin of the Saturnian satellite system. It has been proposed that serpentinization reactions in Titan's interior could lead to the formation of the observed methane. Meanwhile, alternative scenarios suggest that methane was incorporated in Titan's planetesimals before its formation. Here, we point out that serpentinization reactions in Titan's interior are not able to reproduce the deuterium over hydrogen (D/H) ratio observed at present in methane in its atmosphere, and would require a maximum D/H ratio in Titan's water ice 30% lower than the value likely acquired by the satellite during its formation, based on Cassini observations at Enceladus. Alternatively, production of methane in Titan's interior via radiolytic reactions with water can be envisaged but the associated production rates remain uncertain. On the other hand, a mechanism that easily explains the presence of large amounts of methane trapped in Titan in a way consistent with its measured atmospheric D/H ratio is its direct capture in the satellite's planetesimals at the time of their formation in the solar nebula. In this case, the mass of methane trapped in Titan's interior can be up to 1,300 times the current mass of atmospheric methane.
Saturn's moon Titan is the only extraterrestrial body known to host stable lakes and a hydrological cycle. Titan's lakes predominantly contain liquid methane, ethane, and nitrogen, with methane evaporation driving its hydrological cycle. Molecular interactions between these three species lead to non-ideal behavior that causes Titan's lakes to behave differently than Earth's lakes. Here, we numerically investigate how methane evaporation and non-ideal interactions affect the physical properties, structure, dynamics, and evolution of shallow lakes on Titan. We find that, under certain temperatur…
The strength of Titan's methane cycle, as measured by precipitation and evaporation, is key to interpreting fluvial erosion and other indicators of the surface-atmosphere exchange of liquids. But the mechanisms behind the occurrence of large cloud outbursts and precipitation on Titan have been disputed. A gobal- and annual-mean estimate of surface fluxes indicated only 1% of the insolation, or $\sim$0.04 W/m$^2$, is exchanged as sensible and/or latent fluxes. Since these fluxes are responsible for driving atmospheric convection, it has been argued that moist convection should be quite rare and…
The details of the Solar system's formation are still heavily debated. Questions remain about the formation locations of the giant planets, and the degree to which volatile material was mixed throughout the proto-planetary system. One diagnostic which offers great promise in helping to unravel the history of planet formation is the study of the level of deuteration in various Solar system bodies. For example, the D/H ratio of methane in the atmosphere of Titan can be used as a diagnostic of the initial conditions of the solar nebula within the region of giant planet formation, and can help us …
Titan's equatorial regions are covered by eastward propagating linear dunes. This direction is opposite to mean surface winds simulated by Global Climate Models (GCMs), which are oriented westward at these latitudes, similar to trade winds on Earth. Different hypotheses have been proposed to address this apparent contradiction, involving Saturn's gravitational tides, large scale topography or wind statistics, but none of them can explain a global eastward dune propagation in the equatorial band. Here we analyse the impact of equinoctial tropical methane storms developing in the superrotating a…
We retrieve vertical and meridional variations of methane mole fraction in Titan's lower troposphere by re-analyzing near-infrared ground-based observations from 17 July 2014 UT (Adamkovics et al., 2016). We generate synthetic spectra using atmospheric methane profiles that do not contain supersaturation or discontinuities to fit the observations, and thereby retrieve minimum saturation altitudes and corresponding specific humidities in the boundary layer. We relate these in turn to surface-level relative humidities using independent surface temperature measurements. We also compare our result…
Lainey et al. (2012), by re-analyzing long-baseline astrometry of Saturn's moons, have found that the moons' tidal evolution is much faster than previously thought, implying an order of magnitude stronger tidal dissipation within Saturn. This result is controversial and implies recent formation of at least some of the mid-sized icy moons of Saturn. Here we show that this more intensive tidal dissipation is in full agreement with the evolved state of the Titan-Hyperion resonance. This resonance was previously thought to be non-tidal in origin, as the amount of tidal evolution required for its a…
While Saturn's moon Titan appears to support an active methane hydrological cycle, no direct evidence for surface-atmosphere exchange has yet appeared. It is possible that the identified lake-features could be filled with ethane, an involatile long term residue of atmospheric photolysis; the apparent stream and channel features could be ancient from a previous climate; and the tropospheric methane clouds, while frequent, could cause no rain to reach the surface. We report here the detection of fog at the south pole of Titan during late summer using observations from the VIMS instrument on boar…
Is life a common outcome of physical and chemical processes in the universe? Within our own solar system, a successful search for even primitive life, were it to have an origin independent from life on Earth, would dramatically advance a positive answer. The most stringent test for a second independent origin of life on Earth would come from examination of either the most physically remote from Earth, or the most exotic type, of planetary environments in which one might plausibly imagine a form of life could exist. In this paper I argue that Saturn's moon Titan is the best such target in our s…
Aims: It has recently been shown that the fast migration of Titan could be responsible for the current 26.7°-tilt of Saturn's spin axis. We aim to quantify the level of generality of this result and to measure the most likely sets of parameters. We also aim to determine the obliquity that Saturn will reach in the future. Methods: We explore a broad range of parameters and propagate numerically the orientation of Saturn's spin axis both backward and forward in time. Results: In the adiabatic regime, the likelihood of reproducing Saturn's current spin-axis orientation is maximised for primordial…
The obliquity of a planet is the tilt between its equator and its orbital plane. Giant planets are expected to form with near-zero obliquities. After its formation, some dynamical mechanism must therefore have tilted Saturn up to its current obliquity of 26.7°. This event is traditionally thought to have happened more than 4 Gyrs ago during the late planetary migration because of the crossing of a resonance between the spin-axis precession of Saturn and the nodal orbital precession mode of Neptune. Here, we show that the fast tidal migration of Titan measured by Lainey et al. (2020) is incompa…
We search for meridional variation in the abundance of CH$_3$D relative to CH$_4$ on Titan using near-IR spectra obtained with NIRSPAO at Keck, which have a photon-limited signal-to-noise ratio of $\sim$50. Our observations can rule out a larger than 10% variation in the column of CH$_3$D below 50 km. The preferential condensation of the heavy isotopologues will fractionate methane by reducing CH$_3$D in the remaining vapor, and therefore these observations place limits on the amount of condensation that occurs in the troposphere. While previous estimates of CH$_3$D fractionation on Titan have…
We present evidence for condensed phase methane precipitation near Xanadu using nine nights of observations from the SINFONI integral-field spectrograph at the Very Large Telescope and imaging analysis with empirical surface subtraction. Radiative transfer models are used to support the imaging technique by simulating the spectrometer datacubes and testing for variations in both the surface reflectivity spectrum and atmospheric opacity. We use the models and observations together to argue against artifacts that may arise in the image analysis. High phase angle observations from Cassini/VIMS ar…
Ethane is expected to be the dominant photochemical product on Titan's surface and, in the absence of a process that sequesters it from exposed surface reservoirs, a major constituent of its lakes and seas. Absorption of Cassini's 2.2 cm radar by Ligeia Mare however suggests that this north polar sea is dominated by methane. In order to explain this apparent ethane deficiency, we explore the possibility that Ligeia Mare is the visible part of an alkanofer that interacted with an underlying clathrate layer and investigate the influence of this interaction on an assumed initial ethane-methane mi…
Context: As a result of Titan's migration and Saturn's probable capture in secular spin-orbit resonance, recent works show that Saturn's obliquity could be steadily increasing today and may reach large values in the next billions of years. Satellites around high-obliquity planets are known to be unstable near their Laplace radius, but the approximations used so far are invalidated in this regime. Aims: We aim to investigate the behaviour of a planet and its satellite when the satellite crosses its Laplace radius while the planet is locked in secular spin-orbit resonance. Methods: We expand on …
We use the planar circular restricted three-body problem in order to numerically investigate the orbital dynamics of orbits of a spacecraft, or a comet, or an asteroid in the Saturn-Titan system in a scattering region around the Titan. The orbits can escape through the necks around the Lagrangian points $L_1$ and $L_2$ or collide with the surface of the Titan. We explore all the four possible Hill's regions depending on the value of the Jacobi constant. We conduct a thorough numerical analysis on the phase space mixing by classifying initial conditions of orbits and distinguishing between thre…
Tidal effects in planetary systems are the main driver in the orbital migration of natural satellites. They result from physical processes occurring deep inside celestial bodies, whose effects are rarely observable from surface imaging. For giant planet systems, the tidal migration rate is determined by poorly understood dissipative processes in the planet, and standard theories suggest an orbital expansion rate inversely proportional to the power 11/2 in distance, implying little migration for outer moons such as Saturn's largest moon, Titan. Here, we use two independent measurements obtained…
Natural satellite systems present a large variety of orbital configurations in the solar system. While some are clearly the result of known processes, others still have largely unexplained eccentricity and inclination values. Iapetus has a still unexplained 3% orbital eccentricity and its orbital plane is tilted with respect to its local Laplace plane. On the other hand, astrometric measurements of saturnian moons have revealed high tidal migration rates, corresponding to a quality factor Q of Saturn of around 1600 for the mid-sized icy moons. We show how a past crossing of the 5:1 mean motion…
The spatial distribution of the tropospheric methane on Titan was measured using near-infrared spectroscopy. Ground-based observations at 1.5$μ{\rm m}$ (H-band) were performed during the same night using instruments with adaptive optics at both the W. M. Keck Observatory and at the Paranal Observatory on 17 July 2014 UT. The integral field observations with SINFONI on the VLT covered the entire H-band at moderate resolving power, $R=λ/Δλ\approx1,500$, while the Keck observations were performed with NIRSPAO near 1.55254$μ{\rm m}$ at higher resolution, $R\approx25,000$. The moderate resolution o…
We investigate the effects of varying Saturn's orbit on the atmospheric circulation and surface methane distribution of Titan. Using a new general circulation model of Titan's atmosphere, we simulate its climate under four characteristic configurations of orbital parameters that correspond to snapshots over the past 42 kyr, capturing the amplitude range of long-period cyclic variations in eccentricity and longitude of perihelion. The model, which covers pressures from the surface to 0.5 mbar, reproduces the present-day temperature profile and tropospheric superrotation. In all four simulations…
We have obtained spatially resolved spectra of Titan in the near-infrared J, H and K bands at a resolving power of ~5000 using the near-infrared integral field spectrometer (NIFS) on the Gemini North 8m telescope. Using recent data from the Cassini/Huygens mission on the atmospheric composition and surface and aerosol properties, we develop a multiple-scattering radiative transfer model for the Titan atmosphere. The Titan spectrum at these wavelengths is dominated by absorption due to methane with a series of strong absorption band systems separated by window regions where the surface of Titan…
The abundance of deuterium in giant planet atmospheres provides constraints on the reservoirs of ices incorporated into these worlds during their formation and evolution. Motivated by discrepancies in the measured deuterium-hydrogen ratio (D/H) on Jupiter and Saturn, we present a new measurement of the D/H ratio in methane for Saturn from ground-based measurements. We analysed a spectral cube (covering 1151-1160 cm$^{-1}$ from 6 February 2013) from the Texas Echelon Cross Echelle Spectrograph (TEXES) on NASA's Infrared Telescope Facility (IRTF) where emission lines from both methane and deuter…
On Titan, methane (CH4) and ethane (C2H6) are the dominant species found in the lakes and seas. In this study, we have combined laboratory work and modeling to refine the methane-ethane binary phase diagram at low temperatures and probe how the molecules interact at these conditions. We used visual inspection for the liquidus and Raman spectroscopy for the solidus. Through these methods we determined a eutectic point of 71.15$\pm$0.5 K at a composition of 0.644$\pm$0.018 methane - 0.356$\pm$0.018 ethane mole fraction from the liquidus data. Using the solidus data, we found a eutectic isotherm …
In order to analyze varying plasma conditions upstream of Titan, we have combined a physical model of Saturn's plasmadisk with a geometrical model of the oscillating current sheet. During modeled oscillation phases where Titan is furthest from the current sheet, the main sources of plasma pressure in the near-Titan space are the magnetic pressure and, for disturbed conditions, the hot plasma pressure. When Titan is at the center of the sheet, the main source is the dynamic pressure associated with Saturn's cold, subcorotating plasma. Total pressure at Titan (dynamic plus thermal plus magnetic)…
The building blocks of Titan and Enceladus are believed to have formed in a late-stage circumplanetary disk around Saturn. Evaluating the evolution of the abundances of volatile species in this disk as a function of the migration, growth, and evaporation of icy grains is then of primary importance to assess the origin of the material that eventually formed these two moons. Here we use a simple prescription of Saturn's circumplanetary disk in which the location of the centrifugal radius is varied, to investigate the time evolution of the icelines of water ice, ammonia hydrate, methane clathrate…
It is widely accepted that Titan and the mid-sized regular satellites around Saturn were formed in the circum-Saturn disk. Thus, if these mid-sized satellites were simply accreted by collisions of similar ice-rock satellitesimals in the disk, the observed wide diversity in density (i.e., the rock fraction) of the Saturnian mid-sized satellites is enigmatic. A recent circumplanetary disk model suggests satellite growth in an actively supplied circumplanetary disk, in which Titan-sized satellites migrate inward by interaction with the gas and are eventually lost to the gas planet. Here we report…
Titan has an abundance of lakes and seas, as confirmed by Cassini. Major components of these liquid bodies include methane ($CH_4$) and ethane ($C_2H_6$); however, evidence indicates that minor components such as ethylene ($C_2H_4$) may also exist in the lakes. As the lake levels drop, 5 $μm$-bright deposits, resembling evaporite deposits on earth, are left behind. Here, we provide saturation values, evaporation rates, and constraints on ethylene evaporite formation by using a Titan simulation chamber capable of reproducing Titan surface conditions (89-94 K, 1.5 bar $N_2$). Experimental sample…
The atmosphere of Saturn's largest moon Titan is driven by photochemistry, charged particle precipitation from Saturn's upstream magnetosphere, and presumably by the diffusion of the magnetospheric field into the outer ionosphere, amongst other processes. Ion pickup, controlled by the upstream convection electric field, plays a role in the loss of this atmosphere. The interaction of Titan with Saturn's magnetosphere results in the formation of a flow-induced magnetosphere. The upstream magnetoplasma environment of Titan is a complex and highly variable system and significant quasi-periodic mod…
The Cassini-Huygens mission measured the chemical abundances of the major components of Titan's atmosphere, and analyses of the data revealed several as-yet unexplained anomalies in the methane and hydrogen profiles. We model the deceleration and ablation of meteors in Titan's atmosphere to examine whether meteor energy deposition could explain, in part, two of these anomalies. Our simulations vary meteor entry mass, trajectory angle, and velocity, and follow changes in all three as our meteors descend into a realistic Titan atmosphere. For the smallest particles, which deliver the most mass a…
In order to examine how the terrestrial life emerged, a number of laboratory experiments have been conducted since the 1950s. Methane has been one of the key molecules in these studies. In earlier studies, strongly reducing gas mixtures containing methane and ammonia were mainly used to simulate possible reactions in primitive Earth atmosphere, and amino acids and other organic compounds were detected. Since the primitive Earth atmosphere was estimated to be less reducing, contribution of extraterrestrial organics to the origin of life is considered quite important. Extraterrestrial organic ch…
We explore the past evolution of Saturn's moons using direct numerical integrations. We find that the past Tethys-Dione 3:2 orbital resonance predicted in standard models likely did not occur, implying that the system is less evolved than previously thought. On the other hand, the orbital inclinations of Tethys, Dione and Rhea suggest that the system did cross the Dione-Rhea 5:3 resonance, which is closely followed by a Tethys-Dione secular resonance. A clear implication is that either the moons are significantly younger than the planet, or that their tidal evolution must be extremely slow (Q …
The analyses of Titan's gravity field obtained by Cassini space mission suggest the presence of an internal ocean beneath its icy surface. The characterization of the geophysical parameters of the icy shell and the ocean is important to constrain the evolution models of Titan. The knowledge of the librations, that are periodic oscillations around a uniform rotational motion, can bring piece of information on the interior parameters. The objective of this paper is to study the librational response in longitude from an analytical approach for Titan composed of a deep atmosphere, an elastic icy s…
We have studied the pressure and temperature dependence of solubility of nitrogen in methane and ethane using vapor-liquid equilibrium simulations of binary mixtures of nitrogen in methane and ethane for a range of pressures between 1.5 atm and 3.5 atm and temperatures between 90 K and 110 K, thermodynamic conditions that may exist on the Saturn's moon, Titan. We find that the solubility of nitrogen in methane increases linearly with pressure while the solubility of nitrogen in ethane increases exponentially with pressure at temperature 90 K. Solubility of nitrogen in both methane and ethane e…
Recently it was found from Cassini data that the mean recession speed of Titan from Saturn is $v=11.3\pm 2.0$ cm/yr which corresponds to a tidal quality factor of Saturn $Q\cong 100$ while the standard estimate yields $Q\ge 6\cdot 10^4$. It was assumed that such a large speed $v$ is due to a resonance locking mechanism of five inner mid-sized moons of Saturn. In this paper, we show that an essential part of $v$ may come from a local Hubble expansion, where the Hubble-Lema\^ıtre constant $H_0$ recalculated to the Saturn-Titan distance $D$ is 8.15 cm/(yr $D$). Our hypothesis is based on many oth…
Context: Saturn's massive gravity is expected to causes a tide in Titan's atmosphere, producing a surface pressure variation through the orbit of Titan and tidal winds in the troposphere. The future Dragonfly mission could analyse this exotic meteorological phenomenon. Aims: We analyse the effect of Saturn's tides on Titan's atmosphere and interior to determine how pressure measurements by Dragonfly could constrain Titan's interior. Methods: We model atmospheric tides with analytical calculations and with a 3D Global Climate Model (the IPSL-Titan GCM), including the tidal response of the inter…
The Descent Imager/Spectral Radiometer aboard the Huygens probe successfully acquired images and spectra of the surface of Titan. To counter the effects of haze and atmospheric methane absorption it carried a Surface Science Lamp to illuminate the surface just before landing. We reconstruct the reflectance spectrum of the landing site in the 500-1500 nm range from Downward Looking Visual and Infrared Spectrometer data that show evidence of lamp light. Our reconstruction is a followup to the analysis by Tomasko et al. (2005), who scaled their result to the ratio of the up- and down flux measure…
We present the first radio/submillimeter detection of monodeuterated methane (CH$_3$D) in Titan's atmosphere, using archival data from of the Atacama Large Millimeter/submillimeter Array (ALMA). The $J_K=2_1-1_1$ and $J_K=2_0-1_0$ transitions at 465.235 and 465.250 GHz ($\sim0.644$ mm) were measured at significance levels of $4.6σ$ and $5.7σ$, respectively. These two lines were modeled using the Non-linear optimal Estimator for MultivariatE spectral analySIS (NEMESIS) radiative transfer code to determine the disk-averaged CH$_3$D volume mixing ratio = $6.157\times10^{-6}$ in Titan's stratosphe…
In Titan's nitrogen-methane atmosphere, photochemistry leads to the production of complex organic particles, forming Titan's thick haze layers. Laboratory-produced aerosol analogs, or "tholins", are produced in a number of laboratories; however, most previous studies have investigated analogs produced by only one laboratory rather than a systematic, comparative analysis. In this study, we performed a comparative study of an important material property, the surface energy, of seven tholin samples produced in three independent laboratories under a broad range of experimental conditions, and expl…
Clouds on Titan result from the condensation of methane and ethane and, as on other planets, are primarily structured by circulation of the atmosphere. At present, cloud activity mainly occurs in the southern (summer) hemisphere, arising near the pole and at mid-latitudes from cumulus updrafts triggered by surface heating and/or local methane sources, and at the north (winter) pole, resulting from the subsidence and condensation of ethane-rich air into the colder troposphere. General circulation models predict that this distribution should change with the seasons on a 15-year timescale, and th…
Simulations of Titan's atmospheric transmission and surface reflectivity have been developed in order to estimate how Titan's atmosphere and surface properties could affect performances of the Cassini radar experiment. In this paper we present a selection of models for Titan's haze, vertical rain distribution, and surface composition implemented in our simulations. We collected dielectric constant values for the Cassini radar wavelength ($\sim 2.2$ cm) for materials of interest for Titan: liquid methane, liquid mixture of methane-ethane, water ice and light hydrocarbon ices. Due to the lack of…
Jet Propulsion Laboratory, California Institute of Technology（加州理工学院喷气推进实验室）；The Pennsylvania State University（宾夕法尼亚州立大学）；The University of Chicago（芝加哥大学）；Arizona State University（亚利桑那州立大学）；Johns Hopkins University（约翰斯·霍普金斯大学）；Carnegie Institution for Science（卡内基科学机构）
The dynamical features of the irregular satellites of the giant planets argue against an in-situ formation and are strongly suggestive of a capture origin. Since the last detailed investigations of their dynamics, the total number of satellites have doubled, increasing from 50 to 109, and almost tripled in the case of Saturn system. We have performed a new dynamical exploration of Saturn system to test whether the larger sample of bodies could improve our understanding of which dynamical features are primordial and which are the outcome of the secular evolution of the system. We have performed…
We investigate the atmospheric composition of the long period ($P_{\rm orb}=$ 10 days), eccentric exo-Saturn WASP-117b. WASP-117b could be in atmospheric temperature and chemistry similar to WASP-107b. In mass and radius WASP-117b is similar to WASP-39b, which allows a comparative study of these planets. We analyze a near-infrared transmission spectrum of WASP-117b taken with Hubble Space Telescope/WFC3 G141, which was reduced with two independent pipelines. High resolution measurements were taken with VLT/ESPRESSO in the optical. We report the robust ($3σ$) detection of a water spectral featu…
Titan, Saturn's largest moon, is the only extraterrestrial body known to support stable liquid on its surface, in the form of seas and lakes that dot the polar regions. Many indications suggest that the liquid should be composed of a mixture of N2, CH4 and C2H6. Recent RADAR observations of Titan's large sea, called ``Ligeia Mare'', have shown unexplained and ephemeral bright features, possibly due to rising bubbles. Here we report that our numerical model, when combined with experimental data found in the literature, shows that Ligeia Mare's bed is a favourable place for nitrogen exsolution. …
In the Grand Tack (GT) scenario for the young solar system, Jupiter formed beyond 3.5 AU from the Sun and migrated as close as 1.5 AU until it encountered an orbital resonance with Saturn. Both planets then supposedly migrated outward for several $10^5$ yr, with Jupiter ending up at ~5 AU. The initial conditions of the GT and the timing between Jupiter's migration and the formation of the Galilean satellites remain unexplored. We study the formation of Ganymede and Callisto, both of which consist of ~50% H$_2$O and rock, in the GT scenario. We examine why they lack dense atmospheres, while Tit…
In this paper we will summarize some of the most important results of the Cassini mission concerning the satellites of Saturn. Given the long duration of the mission, the complexity of the payload onboard the Cassini Orbiter and the amount of data gathered on the satellites of Saturn, it would be impossible to describe all the new discoveries made, therefore we will describe only some selected, paramount examples showing how Cassini's data confirmed and extended ground-based observations. In particular we will describe the achievements obtained for the satellites Phoebe, Enceladus and Titan. W…
The crystalline state of water ice in the Solar System depends on the temperature history of the ice and the influence of energetic particles to which it has been exposed. We measured the infrared absorption spectra of amorphous and crystalline water ice in the 10-50 K and 10-140 K temperature range, respectively, and conducted a systematic experimental study to investigate the amorphization of crystalline water ice via ionizing radiation irradiation at doses of up to 160 \pm 30 eV per molecule. We found that crystalline water ice can be converted only partially to amorphous ice by electron ir…
Saturn has a dynamically rich satellite system, which includes at least three orbital resonances between three pairs of moons: Mimas-Tethys 4:2, Enceladus-Dione 2:1, and Titan-Hyperion 4:3 mean-motion resonances. Studies of the orbital history of Saturn's moons usually assume that their past dynamics was also dominated solely by two-body resonances. Using direct numerical integrations, we find that three-body resonances among Saturnian satellites were quite common in the past, and could result in a relatively long-term, but finite capture time (10 Myr or longer). We find that these three-body …
Dynamically favorable hosts for submoons around Jupiter and Saturn
Centro Interdipartimentale di Ricerca Industriale Aerospaziale, Alma Mater Studiorum, Università di Bologna（博洛尼亚大学航空航天工业跨部门研究中心）；LTE, Observatoire de Paris, Université PSL, Sorbonne Université, Université de Lille, LNE,CNRS（巴黎天文台）
