As the only icy satellite with a thick atmosphere and liquids on its surface, Titan represents a unique end-member to study the impact cratering process. Unlike craters on other Saturnian satellites, Titan's craters are preferentially located in high-elevation regions near the equator. This led to the hypothesis that the presence of liquid methane in Titan's lowlands affects crater morphology, making them difficult to identify. This is because surfaces covered by weak fluid-saturated sediment limit the topographic expression of impact craters, as sediment moves into the crater cavity shortly after formation. Here we simulate crater-forming impacts on Titan's surface, exploring how a methane-saturated layer overlying a methane-clathrate layer affects crater formation. Our numerical results show that impacts form smaller craters in a methane-clathrate basement than a water-ice basement, due to the differences in strength. We find that the addition of a methane-saturated layer atop this basement reduces crater depths and influences crater morphology. The morphology of impact craters formed in a thin methane-saturated layer are similar to those in a "dry" target, but a thick saturated layer produces an impact structure with little to no topography. A thick methane-saturated layer (thicker than 40% of the impactor diameter) could explain the dearth of craters in the low-elevation regions on Titan.
Impact crater counts on the Saturnian satellites are a key element for estimating their surface ages and placing constraints on their impactor population. The Cassini mission radar observations allowed crater counts to be made on the surface of Titan, revealing an unexpected scarcity of impact craters that show high levels of degradation. Following previous studies on impact cratering rates on the Saturnian satellites, we modeled the cratering process on Titan to constrain its surface chronology and to assess the role of centaur objects as its main impactors. A theoretical model previously dev…
The origin of Titan's atmospheric methane is a key issue for understanding the origin of the Saturnian satellite system. It has been proposed that serpentinization reactions in Titan's interior could lead to the formation of the observed methane. Meanwhile, alternative scenarios suggest that methane was incorporated in Titan's planetesimals before its formation. Here, we point out that serpentinization reactions in Titan's interior are not able to reproduce the deuterium over hydrogen (D/H) ratio observed at present in methane in its atmosphere, and would require a maximum D/H ratio in Titan's…
Saturn's moon Titan is the only extraterrestrial body known to host stable lakes and a hydrological cycle. Titan's lakes predominantly contain liquid methane, ethane, and nitrogen, with methane evaporation driving its hydrological cycle. Molecular interactions between these three species lead to non-ideal behavior that causes Titan's lakes to behave differently than Earth's lakes. Here, we numerically investigate how methane evaporation and non-ideal interactions affect the physical properties, structure, dynamics, and evolution of shallow lakes on Titan. We find that, under certain temperatur…
The strength of Titan's methane cycle, as measured by precipitation and evaporation, is key to interpreting fluvial erosion and other indicators of the surface-atmosphere exchange of liquids. But the mechanisms behind the occurrence of large cloud outbursts and precipitation on Titan have been disputed. A gobal- and annual-mean estimate of surface fluxes indicated only 1% of the insolation, or $\sim$0.04 W/m$^2$, is exchanged as sensible and/or latent fluxes. Since these fluxes are responsible for driving atmospheric convection, it has been argued that moist convection should be quite rare and…
Titan's equatorial regions are covered by eastward propagating linear dunes. This direction is opposite to mean surface winds simulated by Global Climate Models (GCMs), which are oriented westward at these latitudes, similar to trade winds on Earth. Different hypotheses have been proposed to address this apparent contradiction, involving Saturn's gravitational tides, large scale topography or wind statistics, but none of them can explain a global eastward dune propagation in the equatorial band. Here we analyse the impact of equinoctial tropical methane storms developing in the superrotating a…
We retrieve vertical and meridional variations of methane mole fraction in Titan's lower troposphere by re-analyzing near-infrared ground-based observations from 17 July 2014 UT (Adamkovics et al., 2016). We generate synthetic spectra using atmospheric methane profiles that do not contain supersaturation or discontinuities to fit the observations, and thereby retrieve minimum saturation altitudes and corresponding specific humidities in the boundary layer. We relate these in turn to surface-level relative humidities using independent surface temperature measurements. We also compare our result…
A youthful Titan implied by improved impact simulations
Massachusetts Institute of Technology（麻省理工学院）；Purdue University（普渡大学）；The Planetary Science Institute（行星科学研究所）；The University of Western Ontario（韦仕敦大学）
While Saturn's moon Titan appears to support an active methane hydrological cycle, no direct evidence for surface-atmosphere exchange has yet appeared. It is possible that the identified lake-features could be filled with ethane, an involatile long term residue of atmospheric photolysis; the apparent stream and channel features could be ancient from a previous climate; and the tropospheric methane clouds, while frequent, could cause no rain to reach the surface. We report here the detection of fog at the south pole of Titan during late summer using observations from the VIMS instrument on boar…
The details of the Solar system's formation are still heavily debated. Questions remain about the formation locations of the giant planets, and the degree to which volatile material was mixed throughout the proto-planetary system. One diagnostic which offers great promise in helping to unravel the history of planet formation is the study of the level of deuteration in various Solar system bodies. For example, the D/H ratio of methane in the atmosphere of Titan can be used as a diagnostic of the initial conditions of the solar nebula within the region of giant planet formation, and can help us …
We search for meridional variation in the abundance of CH$_3$D relative to CH$_4$ on Titan using near-IR spectra obtained with NIRSPAO at Keck, which have a photon-limited signal-to-noise ratio of $\sim$50. Our observations can rule out a larger than 10% variation in the column of CH$_3$D below 50 km. The preferential condensation of the heavy isotopologues will fractionate methane by reducing CH$_3$D in the remaining vapor, and therefore these observations place limits on the amount of condensation that occurs in the troposphere. While previous estimates of CH$_3$D fractionation on Titan have…
We present evidence for condensed phase methane precipitation near Xanadu using nine nights of observations from the SINFONI integral-field spectrograph at the Very Large Telescope and imaging analysis with empirical surface subtraction. Radiative transfer models are used to support the imaging technique by simulating the spectrometer datacubes and testing for variations in both the surface reflectivity spectrum and atmospheric opacity. We use the models and observations together to argue against artifacts that may arise in the image analysis. High phase angle observations from Cassini/VIMS ar…
Ethane is expected to be the dominant photochemical product on Titan's surface and, in the absence of a process that sequesters it from exposed surface reservoirs, a major constituent of its lakes and seas. Absorption of Cassini's 2.2 cm radar by Ligeia Mare however suggests that this north polar sea is dominated by methane. In order to explain this apparent ethane deficiency, we explore the possibility that Ligeia Mare is the visible part of an alkanofer that interacted with an underlying clathrate layer and investigate the influence of this interaction on an assumed initial ethane-methane mi…
Currently, Mars is the celestial object with the biggest quantity of devices made by mankind. This fact explain the astronomical quantity of data available about this planet, which allows several studies in several lines of research. Here we present the result of a monograph in Space Geophysics, in a graduation in Geophysics, the data used were collected by the device PFS (Planetary Fourier Spectrometer) in the mission MEX (Mars Express) launched in 2006. The main aim was the verification of the existence of methane (CH 4 ) in a specific region in the atmosphere of the Red Planet. The target r…
The spatial distribution of the tropospheric methane on Titan was measured using near-infrared spectroscopy. Ground-based observations at 1.5$μ{\rm m}$ (H-band) were performed during the same night using instruments with adaptive optics at both the W. M. Keck Observatory and at the Paranal Observatory on 17 July 2014 UT. The integral field observations with SINFONI on the VLT covered the entire H-band at moderate resolving power, $R=λ/Δλ\approx1,500$, while the Keck observations were performed with NIRSPAO near 1.55254$μ{\rm m}$ at higher resolution, $R\approx25,000$. The moderate resolution o…
We investigate the effects of varying Saturn's orbit on the atmospheric circulation and surface methane distribution of Titan. Using a new general circulation model of Titan's atmosphere, we simulate its climate under four characteristic configurations of orbital parameters that correspond to snapshots over the past 42 kyr, capturing the amplitude range of long-period cyclic variations in eccentricity and longitude of perihelion. The model, which covers pressures from the surface to 0.5 mbar, reproduces the present-day temperature profile and tropospheric superrotation. In all four simulations…
We have obtained spatially resolved spectra of Titan in the near-infrared J, H and K bands at a resolving power of ~5000 using the near-infrared integral field spectrometer (NIFS) on the Gemini North 8m telescope. Using recent data from the Cassini/Huygens mission on the atmospheric composition and surface and aerosol properties, we develop a multiple-scattering radiative transfer model for the Titan atmosphere. The Titan spectrum at these wavelengths is dominated by absorption due to methane with a series of strong absorption band systems separated by window regions where the surface of Titan…
On Titan, methane (CH4) and ethane (C2H6) are the dominant species found in the lakes and seas. In this study, we have combined laboratory work and modeling to refine the methane-ethane binary phase diagram at low temperatures and probe how the molecules interact at these conditions. We used visual inspection for the liquidus and Raman spectroscopy for the solidus. Through these methods we determined a eutectic point of 71.15$\pm$0.5 K at a composition of 0.644$\pm$0.018 methane - 0.356$\pm$0.018 ethane mole fraction from the liquidus data. Using the solidus data, we found a eutectic isotherm …
Titan has an abundance of lakes and seas, as confirmed by Cassini. Major components of these liquid bodies include methane ($CH_4$) and ethane ($C_2H_6$); however, evidence indicates that minor components such as ethylene ($C_2H_4$) may also exist in the lakes. As the lake levels drop, 5 $μm$-bright deposits, resembling evaporite deposits on earth, are left behind. Here, we provide saturation values, evaporation rates, and constraints on ethylene evaporite formation by using a Titan simulation chamber capable of reproducing Titan surface conditions (89-94 K, 1.5 bar $N_2$). Experimental sample…
The Cassini-Huygens mission measured the chemical abundances of the major components of Titan's atmosphere, and analyses of the data revealed several as-yet unexplained anomalies in the methane and hydrogen profiles. We model the deceleration and ablation of meteors in Titan's atmosphere to examine whether meteor energy deposition could explain, in part, two of these anomalies. Our simulations vary meteor entry mass, trajectory angle, and velocity, and follow changes in all three as our meteors descend into a realistic Titan atmosphere. For the smallest particles, which deliver the most mass a…
We have studied the pressure and temperature dependence of solubility of nitrogen in methane and ethane using vapor-liquid equilibrium simulations of binary mixtures of nitrogen in methane and ethane for a range of pressures between 1.5 atm and 3.5 atm and temperatures between 90 K and 110 K, thermodynamic conditions that may exist on the Saturn's moon, Titan. We find that the solubility of nitrogen in methane increases linearly with pressure while the solubility of nitrogen in ethane increases exponentially with pressure at temperature 90 K. Solubility of nitrogen in both methane and ethane e…
The Descent Imager/Spectral Radiometer aboard the Huygens probe successfully acquired images and spectra of the surface of Titan. To counter the effects of haze and atmospheric methane absorption it carried a Surface Science Lamp to illuminate the surface just before landing. We reconstruct the reflectance spectrum of the landing site in the 500-1500 nm range from Downward Looking Visual and Infrared Spectrometer data that show evidence of lamp light. Our reconstruction is a followup to the analysis by Tomasko et al. (2005), who scaled their result to the ratio of the up- and down flux measure…
From orbit, the visibility of Titan's surface is limited to a handful of narrow spectral windows in the near-infrared (near-IR), primarily from the absorption of methane gas. This has limited the ability to identify specific compounds on the surface -- to date Titan's bulk surface composition remains unknown. Further, understanding of the surface composition would provide insight into geologic processes, photochemical production and evolution, and the biological potential of Titan's surface. One approach to obtain wider spectral coverage with which to study Titan's surface is by decreasing the…
We present the first radio/submillimeter detection of monodeuterated methane (CH$_3$D) in Titan's atmosphere, using archival data from of the Atacama Large Millimeter/submillimeter Array (ALMA). The $J_K=2_1-1_1$ and $J_K=2_0-1_0$ transitions at 465.235 and 465.250 GHz ($\sim0.644$ mm) were measured at significance levels of $4.6σ$ and $5.7σ$, respectively. These two lines were modeled using the Non-linear optimal Estimator for MultivariatE spectral analySIS (NEMESIS) radiative transfer code to determine the disk-averaged CH$_3$D volume mixing ratio = $6.157\times10^{-6}$ in Titan's stratosphe…
The Curiosity rover recently detected a background of 0.7 ppb and spikes of 7 ppb of methane on Mars. This in situ measurement reorients our understanding of the Martian environment and its potential for life, as the current theories do not entail any geological source or sink of methane that varies sub-annually. In particular, the 10-fold elevation during the southern winter indicates episodic sources of methane that are yet to be discovered. Here we suggest a near-surface reservoir could explain this variability. Using the temperature and humidity measurements from the rover, we find that pe…
Clouds on Titan result from the condensation of methane and ethane and, as on other planets, are primarily structured by circulation of the atmosphere. At present, cloud activity mainly occurs in the southern (summer) hemisphere, arising near the pole and at mid-latitudes from cumulus updrafts triggered by surface heating and/or local methane sources, and at the north (winter) pole, resulting from the subsidence and condensation of ethane-rich air into the colder troposphere. General circulation models predict that this distribution should change with the seasons on a 15-year timescale, and th…
Several clues indicate that Titan's atmosphere has been depleted in methane during some period of its history, possibly as recently as 0.5-1 billion years ago. It could also happen in the future. Under these conditions, the atmosphere becomes only composed of nitrogen with a range of temperature and pressure allowing liquid or solid nitrogen to condense. Here, we explore these exotic climates throughout Titan's history with a 3D Global Climate Model (GCM) including the nitrogen cycle and the radiative effect of nitrogen clouds. We show that for the last billion years, only small polar nitrogen…
In Titan's nitrogen-methane atmosphere, photochemistry leads to the production of complex organic particles, forming Titan's thick haze layers. Laboratory-produced aerosol analogs, or "tholins", are produced in a number of laboratories; however, most previous studies have investigated analogs produced by only one laboratory rather than a systematic, comparative analysis. In this study, we performed a comparative study of an important material property, the surface energy, of seven tholin samples produced in three independent laboratories under a broad range of experimental conditions, and expl…
Simulations of Titan's atmospheric transmission and surface reflectivity have been developed in order to estimate how Titan's atmosphere and surface properties could affect performances of the Cassini radar experiment. In this paper we present a selection of models for Titan's haze, vertical rain distribution, and surface composition implemented in our simulations. We collected dielectric constant values for the Cassini radar wavelength ($\sim 2.2$ cm) for materials of interest for Titan: liquid methane, liquid mixture of methane-ethane, water ice and light hydrocarbon ices. Due to the lack of…
This paper refines model predictions for the production of methane from UV-irradiated interplanetary dust particles (IDPs) now that the Rover Environmental Monitoring Station (REMS) instrument onboard the Mars Science Laboratory (MSL) Rover has made the first measurements of the UV environment on the surface of Mars, at Gale Crater. Once these measurements are included in a UV radiative transfer model, we find that modelled UV sol-integrated energies across the planet are lower than pre-measurement estimates by 35% on average, considering all latitudes and seasons. This reduction, in turn, red…
Saturn's largest moon, Titan, has an Earth-like volatile cycle, but with methane playing the role of water and surface liquid reservoirs geographically isolated at high latitudes. We recreate Titan's characteristic dry hydroclimate at the equator of an Earth-like climate model without seasons and with water as the condensable by varying a small set of planetary parameters. We use three observationally motivated criteria for Titan-like conditions at the equator: 1) the peak in surface specific humidity is not at the equator, despite it having the warmest annual-mean temperatures; 2) the vertica…
High Resolution Optical Methane Linelist from observations of Titan for Cross-Correlation studies
University College London（伦敦大学学院）；Instituto de Astrofísica e Ciências do Espaço, Universidade de Lisboa（里斯本大学空间科学与天体物理研究所）；Departamento de Física, Faculdade de Ciências, Universidade de Lisboa（里斯本大学理学院物理系）；Bard College（巴德学院）；NMES Faculty, King’s College London（伦敦国王学院非医学教育系）
Titan's polar surface is dotted with hundreds of lacustrine depressions. Based on the hypothesis that they are karstic in origin, we aim at determining the efficiency of surface dissolution as a landshaping process on Titan, in a comparative planetology perspective with the Earth as reference. Our approach is based on the calculation of solutional denudation rates and allow inference of formation timescales for topographic depressions developed by chemical erosion on both planetary bodies. The model depends on the solubility of solids in liquids, the density of solids and liquids, and the aver…
Organic aerosols accumulated in Titan's orange haze start forming in its ionosphere. This upper part of the atmosphere is highly reactive and complex ion chemistry takes place at altitudes from 1200 to 900 km. The ionosphere is a nitrogen plasma with a few percent of methane and hydrogen. Carbon from methane enables the formation of macromolecules with long organic chains, finally leading to the organic aerosols. On the other hand, we suspect that hydrogen and the protonated ions have a different erosive effect on the aerosols. Here we experimentally studied the effect of hydrogen and protonat…
Titan is the only moon with a substantial atmosphere, the only other thick N$_{2}$ atmosphere besides Earth's, the site of extraordinarily complex atmospheric chemistry that far surpasses any other solar system atmosphere, and the only other solar system body with stable liquid currently on its surface. The connection between Titan's surface and atmosphere is also unique in our Solar system; atmospheric chemistry produces materials that are deposited on the surface and subsequently altered by surface-atmosphere interactions such as aeolian and fluvial processes resulting in the formation of ex…
Titan is one of the primary scientific objectives of the NASA ESA ASI Cassini Huygens mission. Scattering by haze particles in Titan's atmosphere and numerous methane absorptions dramatically veil Titan's surface in the visible range, though it can be studied more easily in some narrow infrared windows. The Visual and Infrared Mapping Spectrometer (VIMS) instrument onboard the Cassini spacecraft successfully imaged its surface in the atmospheric windows, taking hyperspectral images in the range 0.4 5.2 ?m. On 26 October (TA flyby) and 13 December 2004 (TB flyby), the Cassini Huygens mission fl…
A candidate explanation for Early Mars rivers is atmospheric warming due to surface release of H$_2$ or CH$_4$ gas. However, it remains unknown how much gas could be released in a single event. We model the CH$_4$ release by one mechanism for rapid release of CH$_4$ from clathrate. By modeling how CH$_4$-clathrate release is affected by changes in Mars' obliquity and atmospheric composition, we find that a large fraction of total outgassing from CH$_4$ clathrate occurs following Mars' first prolonged atmospheric collapse. This atmosphere-collapse-initiated CH$_4$-release mechanism has three st…
Titan's thick atmosphere is primarily composed of nitrogen and methane. Complex chemistry happening in Titan's atmosphere produces optically thick organic hazes. These hazes play significant roles in Titan's atmosphere and on its surface, and their optical properties are crucial for understanding many processes happening on Titan. Due to the lack of such information, the optical constants of laboratory prepared Titan haze analogues are essential inputs for atmospheric modeling and data analysis of remote sensing observations of Titan. Here, we perform laboratory simulations in a Titan relevant…
We have analyzed the complete Visual and Infrared Mapping Spectrometer (VIMS) data archive of Titan. Our objective is to build global surface cartographic products, by combining all the data gathered during the 127 targeted flybys of Titan into synthetic global maps interpolated on a grid at 32 pixels per degree (~1.4 km/pixel at the equator), in seven infrared spectral atmospheric windows. Multispectral summary images have been computed for each single VIMS cube in order to rapidly identify their scientific content and assess their quality. These summary images are made available to the commu…
Titan's abundant lakes and seas exchange methane vapor and energy with the atmosphere via a process generally known as air-sea interaction. This turbulent exchange process is investigated with an atmospheric mesoscale model coupled to a slab model representation of an underlying lake. The impact of lake size, effective lake mixed layer depth, background wind speed, air-lake temperature differential, and atmospheric humidity on air-sea interaction processes is studied through dozens of two-dimensional simulations. The general, quasi-steady solution is a non-linear superposition of a very weak b…
The photochemical haze produced in the upper atmosphere of Titan plays a key role in various atmospheric and surface processes on Titan. The surface energy, one important physical properties of the haze, is crucial for understanding the growth of the haze particles and can be used to predict their wetting behavior with solid and liquid species on Titan. We produced Titan analog haze materials, so-called "tholin", with different energy sources and measured their surface energies through contact angle and direct force measurements. From the contact angle measurement, we found that the tholins pr…
Titan's atmosphere is optically thick and hides the surface and the lower layers from the view at almost all wavelengths. However, because gaseous absorptions are spectrally selective, some narrow spectral intervals are relatively transparent and allow to probe the surface. To use these intervals (called windows) a good knowledge of atmospheric absorption is necessary. Once gas spectroscopic linelists are well established, the absorption inside windows depends on the way the far wings of the methane absorption lines are cut-off. We know that the intensity in all the windows can be explained wi…
Titan's stratosphere has been observed in a superrotation state, where the atmosphere rotates many times faster than the surface does. Another characteristics of Titan's atmosphere is the presence of thick haze layer. In this paper, we performed numerical experiments using a General Circulation Model (GCM), to explore the effects of the haze layer on the stratospheric superrotation. We employed a semi-gray radiation model of Titan's atmosphere following McKay et al. (1999), which takes account of the sunlight absorption by haze particles. The phase change of methane or the seasonal changes wer…
We present a geomorphologic map of Titan's polar terrains. The map was generated from a combination of Cassini Synthetic Aperture Radar (SAR) and Imaging Science Subsystem imaging products, as well as altimetry, SARTopo and radargrammetry topographic datasets. In combining imagery with topographic data, our geomorphologic map reveals a stratigraphic sequence from which we infer process interactions between units. In mapping both polar regions with the same geomorphologic units, we conclude that processes that formed the terrains of the north polar region also acted to form the landscape we obs…
Titan's surface was revealed by Cassini's instruments, showing the presence of liquid hydrocarbons in lakes, and features like dry riverbed. In order to study the sediment transport in Titan's channels and to map distribution of the water-ice signature in these terrains, we use a radiative transfer model to retrieve the surface albedo, after we estimated VIMS error via an original method. We also establish a criteria related to the intensity of the water ice signature. The tuning of the radiative transfer model shows that the fractal dimension of Titan's aerosols is higher than previously thou…
A Cross-Laboratory Comparison Study of Titan Haze Analogs: Surface Energy II
University of Texas at San Antonio（圣安东尼奥大学）；Johns Hopkins University（约翰斯·霍普金斯大学）；NASA Ames Research Center（美国国家航空航天局艾姆斯研究中心）；University of Northern Iowa（北爱荷华大学）；University of California Santa Cruz（加州大学圣克鲁兹分校）
Surface-bound exospheres facilitate volatile migration across the surfaces of nearly airless bodies. However, such transport requires that the body can both form and retain an exosphere. To form a sublimation exosphere requires the surface of a body to be sufficiently warm for surface volatiles to sublime; to retain an exosphere, the ballistic escape and photodestruction rates and other loss mechanisms must be sufficiently low. Here we construct a simple free molecular model of exospheres formed by volatile desorption/sublimation. We consider the conditions for forming and retaining exospheres…
The vast, deep, volatile-ice-filled basin informally named Sputnik Planum is central to Pluto's geological activity[1,2]. Composed of molecular nitrogen, methane, and carbon monoxide ices[3], but dominated by N2-ice, this ice layer is organized into cells or polygons, typically ~10-40 km across, that resemble the surface manifestation of solid state convection[1,2]. Here we report, based on available rheological measurements[4], that solid layers of N2 ice approximately greater than 1 km thick should convect for estimated present-day heat flow conditions on Pluto. More importantly, we show num…
