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arXiv 0908.0226cond-mat.str-el
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可果美体系YBaCo4O7和YBaCo3MO7(M=Al,Fe)的电磁性质

Electronic and magnetic properties of the kagome systems YBaCo4O7 and YBaCo3MO7 (M=Al, Fe)

N. Hollmann, Z. Hu, M. Valldor, A. Maignan, A. Tanaka, H. H. Hsieh, H. -J. Lin, C. T. Chen, L. H. Tjeng

摘要:

我们提出了一种结合实验和理论的X射线吸收光谱(XAS)研究的新类别的钴酸盐YBaCo 4 O 7和YBaCo 3 MO 7(M= Al,Fe)。重点是在这些几何挫折戈薇化合物的过渡金属离子的局部电子和磁性。对于混合价钴酸盐YBaCo_4 O_7,Co ~(2+)和Co ~(3+)都处于高自旋态。这些高自旋态的稳定性在四面体协调与那些在八面体协调的情况下更深入的研究。对于新化合物YBaCo_3FeO_7,我们发现只有Co ~(2+)和Fe ~(3+)作为电荷态。

英文摘要:

We present a combined experimental and theoretical x-ray absorption spectroscopy (XAS) study of the new class of cobaltates YBaCo4O7 and YBaCo3MO7 (M= Al, Fe). The focus is on the local electronic and magnetic properties of the transition metal ions in these geometrically frustrated kagome compounds. For the mixed valence cobaltate YBaCo4O7, both the Co2+ and Co3+ are found to be in the high spin state. The stability of these high spin states in tetrahedral coordination is compared with those in the more studied case of octahedral coordination. For the new compound YBaCo3FeO7, we find exclusively Co2+ and Fe3+ as charge states.

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