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arXiv 0903.3069quant-ph
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长程电子转移反应:一个解析可解模型

Long Range Electron Transfer Reactions: An Analytically Solvable Model

Aniruddha Chakraborty

摘要:

我们提出了一种分析方法来理解在溶液中的远程电子转移反应的问题,建模的粒子进行扩散运动的影响下,许多潜在的参与(供体桥受体)的过程中。这些势之间的耦合被假定为由狄拉克δ函数表示。本文中的扩散运动用Smoluchowski方程表示。我们的解决方案需要知识的拉普拉斯变换的格林函数的运动在所有的非耦合的潜力。

英文摘要:

We propose an analytical method for understanding the problem of long range electron transfer reaction in solution, modeled by a particle undergoing diffusive motion under the influence of many potentials which are involved (donor - bridge - acceptor) in the process. The coupling between these potentials are assumed to be represented by Dirac Delta functions. The diffusive motion in this paper is represented by the Smoluchowski equation. Our solution requires the knowledge of the Laplace transform of the Green's function for the motion in all the uncoupled potentials.

机构、总结、中文摘要均由AI分析而来,可能存在错误,请以论文正文为准。

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