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arXiv 0903.0775astro-ph.GA
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气相冷凝实验中多环芳烃和含碳固体的形成

Formation of PAHs and Carbonaceous Solids in Gas-Phase Condensation Experiments

C. Jäger, H. Mutschke, I. Llamas Jansa, Th. Henning, F. Huisken

摘要:

碳质颗粒是宇宙尘埃的主要成分。为了了解它们的形成途径,它们已经在实验室中通过气相缩合反应如激光热解和激光烧蚀制备。我们的研究表明,在冷凝区的温度决定了碳颗粒的形成途径。在低于1700 K的温度下,冷凝副产物主要是多环芳烃(PAH),这也是冷凝烟尘颗粒的前体或构件。低温冷凝物中含有多环芳烃混合物,主要由挥发性3-5环体系组成。在高于3500 K的冷凝温度下,形成类富勒烯碳颗粒和富勒烯化合物。富勒烯片段或完整的富勒烯装备成核颗粒。富勒烯可被鉴定为可溶性组分。因此,在冷和热的天体物理环境,如冷和热的AGB星或沃尔夫拉叶星的冷凝产品应该是不同的,应该有不同的光谱特性。

英文摘要:

Carbonaceous grains represent a major component of cosmic dust. In order to understand their formation pathways, they have been prepared in the laboratory by gas-phase condensation reactions such as laser pyrolysis and laser ablation. Our studies demonstrate that the temperature in the condensation zone determines the formation pathway of carbonaceous particles. At temperatures lower than 1700 K, the condensation by-products are mainly polycyclic aromatic hydrocarbons (PAHs), that are also the precursors or building blocks for the condensing soot grains. The low-temperature condensates contain PAH mixtures that are mainly composed of volatile 3-5 ring systems. At condensation temperatures higher than 3500 K, fullerene-like carbon grains and fullerene compounds are formed. Fullerene fragments or complete fullerenes equip the nucleating particles. Fullerenes can be identified as soluble components. Consequently, condensation products in cool and hot astrophysical environments such as cool and hot AGB stars or Wolf Rayet stars should be different and should have distinct spectral properties.

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