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arXiv 0807.3378cond-mat.mes-hallcond-mat.mtrl-sci
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Controlling transistor threshold voltages using molecular dipoles

Smitha Vasudevan, Neeti Kapur, Tao He, Matthew Neurock, James M. Tour, Avik W. Ghosh

英文摘要:

We develop a theoretical model for how organic molecules can control the electronic and transport properties of an underlying transistor channel to whose surface they are chemically bonded. The influence arises from a combination of long-ranged dipolar electrostatics due to the molecular head-groups, as well as short-ranged charge transfer and interfacial dipole driven by equilibrium band-alignment between the molecular backbone and the reconstructed semiconductor surface atoms.

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