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arXiv 0807.1203cond-mat.supr-concond-mat.str-el
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块体MgB2超导体的物理性质表征

Physical Property Characterization of Bulk MgB2 Superconductor

V. P. S. Awana, Arpita Vajpaye, Monika Mudgel, H. Kishan, V. Ganesan, A. M. Awasthi, G. L. Bhalla

摘要:

我们报告的合成,结构/微结构,电阻率下磁场[R(T)H],拉曼光谱,热电功率S(T),热导率K(T),和磁化的环境压力氩气退火的MgB 2多晶块状样品,在相同的条件下处理。该化合物为六方晶系,空间群为P6/mmm。透射电子显微镜(TEM)揭示了电子显微照片,其显示了各种类型的缺陷特征以及3- 4 nm厚的非晶层的存在,所述非晶层形成否则结晶MgB 2的晶界。室温下的拉曼光谱在600 cm-1处显示出特征声子峰。通过测量磁化率C(T)、电阻率R(T)、热电势S(T)和热导率K(T),在37.2K下观察到超导性。R(T)的幂律拟合导致德拜温度在1400 K,这与S(T)的理论拟合一致,表现出1410 K的θ D和3.81 × 1028/m3的载流子密度。热导率K(T)在38 K处显示出跳跃,即,在TC,这是在一些早期的报告失踪。在1- 2 T(Tesla)磁场中,在高达10 K的温度(T)下,从磁化测量中看到高达105 A/cm 2的临界电流密度(Jc)。在4、10和20 K下,不可逆场(定义为与M(H)环合并有关的场)分别为78、68和42 kOe。纳米SiC和纳米金刚石的加入显著提高了所研究的MgB_2的超导性能参数,即不可逆场(Hirr)和临界电流密度J_c(H)。多晶MgB 2测量的物理性能参数与以前的报告和各种物理性能的综合见解进行了比较。

英文摘要:

We report synthesis, structure/micro-structure, resistivity under magnetic field [R(T)H], Raman spectra, thermoelectric power S(T), thermal conductivity K(T), and magnetization of ambient pressure argon annealed polycrystalline bulk samples of MgB2, processed under identical conditions. The compound crystallizes in hexagonal structure with space group P6/mmm. Transmission electron microscopy (TEM) reveals electron micrographs showing various types of defect features along with the presence of 3-4nm thick amorphous layers forming the grain boundaries of otherwise crystalline MgB2. Raman spectra of the compound at room temperature exhibited characteristic phonon peak at 600 cm-1. Superconductivity is observed at 37.2K by magnetic susceptibility C(T), resistivity R(T), thermoelectric power S(T), and thermal conductivity K(T) measurements. The power law fitting of R(T) give rise to Debye temperature at 1400K which is found consistent with the theoretical fitting of S(T), exhibiting ThetaD of 1410K and carrier density of 3.81x 1028/m3. Thermal conductivity K(T) shows a jump at 38K, i.e., at Tc, which was missing in some earlier reports. Critical current density (Jc) of up to 105 A/cm2 in 1-2T (Tesla) fields at temperatures (T) of up to 10K is seen from magnetization measurements. The irreversibility field, defined as the field related to merging of M(H) loops is found to be 78, 68 and 42 kOe at 4, 10 and 20K respectively. The superconducting performance parameters viz. irreversibility field (Hirr) and critical current density Jc(H) of the studied MgB2 are improved profoundly with addition of nano-SiC and nano-Diamond. The physical property parameters measured for polycrystalline MgB2 are compared with earlier reports and a consolidated insight of various physical properties is presented.

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