We propose a high efficiency high fidelity measurement of the ground state spin of a single NV center in diamond, using the effects of cavity quantum electrodynamics. The scheme we propose is based in the one dimensional atom or Purcell regime, removing the need for high Q cavities that are challenging to fabricate. The ground state of the NV center consists of three spin levels $^{3}A_{(m=0)}$ and $^{3}A_{(m=\pm1)}$ (the $\pm1$ states are near degenerate in zero field). These two states can undergo transitions to the excited ($^{3}E$) state, with an energy difference of $\approx7-10$ $μ$eV between the two. By choosing the correct Q factor, this small detuning between the two transitions results in a dramatic change in the intensity of reflected light. We show the change in reflected intensity can allow us to read out the ground state spin using a low intensity laser with an error rate of $\approx5.5\times10^{-3}$, when realistic cavity and experimental parameters are considered. Since very low levels of light are used to probe the state of the spin we limit the number of florescence cycles, thereby limiting the non spin preserving transitions through the intermediate singlet state $^{1}A$.
The negatively charged nitrogen-vacancy (NV-) centre in diamond has many exciting applications in quantum nano-metrology, including magnetometry, electrometry, thermometry and piezometry. Indeed, it is possible for a single NV- centre to measure the complete three-dimensional vector of the local electric field or the position of a single fundamental charge in ambient conditions. However, in order to achieve such vector measurements, near complete knowledge of the orientation of the centre's defect structure is required. Here, we demonstrate an optically detected magnetic resonance (ODMR) techn…
We propose a high-sensitivity magnetometry scheme based on a diamond Raman laser with visible pump absorption by an ensemble of coherently microwave driven negatively charged nitrogen-vacancy centres (NV) in the same diamond crystal. The NV centres' absorption and emission are spin-dependent. We show how the varying absorption of the NV centres changes the Raman laser output. A shift in the diamond Raman laser threshold and output occurs with the external magnetic-field and microwave driving. We develop a theoretical framework including steady-state solutions to describe the effects of coheren…
The efficiency of collecting photons from optically active defect centres in bulk diamond is greatly reduced by refraction and reflection at the diamond-air interface. We report on the fabrication and measurement of a geometrical solution to the problem; integrated solid immersion lenses (SILs) etched directly into the surface of diamond. An increase of a factor of 10 was observed in the saturated count-rate from a single negatively charged nitrogen-vacancy (NV-) within a 5um diameter SIL compared with NV-s under a planar surface in the same crystal. A factor of 3 reduction in background emiss…
Nitrogen-vacancy (NV) centres in diamond hold promise in quantum sensing applications. A major interest in them is an enhancement of their sensitivity by the extension of the coherence time ($T_2$). In this report, we experimentally generated more than four dressed states in a single NV centre in diamond based on Autler-Townes splitting (ATS). We also observed the extension of the coherence time to $T_2 \sim$ 1.5 ms which is more than two orders of magnitude longer than that of the undressed states. As an example of a quantum application using these results we propose a protocol of quantum sen…
Circuit-QED has demonstrated very strong coupling between individual microwave photons trapped in a superconducting coplanar resonator and nearby superconducting qubits. In this work we show how, by designing a novel interconnect, one can strongly connect the superconducting resonator, via a magnetic interaction, to a small number (perhaps single), of electronic spins. By choosing the electronic spin to be within a Nitrogen Vacancy centre in diamond one can perform optical readout, polarization and control of this electron spin using microwave and radio frequency irradiation. More importantly,…
We address a problem of generating a robust entangling gate between electronic and nuclear spins in the system of a single nitrogen-vacany centre coupled to a nearest Carbon-13 atom in diamond against certain types of systematic errors such as pulse-length and off-resonance errors. We analyse the robustness of various control schemes: sequential pulses, composite pulses and numerically-optimised pulses. We find that numerically-optimised pulses, produced by the gradient ascent pulse engineering algorithm (GRAPE), are more robust than the composite pulses and the sequential pulses. The optimise…
We demonstrate a cavity-enhanced room-temperature magnetic field sensor based on nitrogen-vacancy centers in diamond. Magnetic resonance is detected using absorption of light resonant with the 1042 nm spin-singlet transition. The diamond is placed in an external optical cavity to enhance the absorption, and significant absorption is observed even at room temperature. We demonstrate a magnetic field sensitivity of 2.5 nT/sqrt(Hz), and project a photon shot-noise-limited sensitivity of 70 pT/sqrt(Hz) for a few mW of infrared light, and a quantum projection-noise-limited sensitivity of 250 fT/sqr…
We introduce a process for the fabrication of high quality, spatially isolated nano-diamonds on iridium via microwave plasma assisted CVD-growth. We perform spectroscopy of single silicon-vacancy (SiV)-centres produced during the growth of the nano-diamonds. The colour centres exhibit extraordinary narrow zero-phonon-lines down to 0.7 nm at room temperature. Single photon count rates up to 4.8 Mcps at saturation make these SiV-centres the brightest diamond based single photon sources to date. We measure for the first time the fine structure of a single SiV-centre thus confirming the atomic com…
We demonstrate the tunable enhancement of the zero phonon line of a single nitrogen-vacancy color center in diamond at cryogenic temperature. An open cavity fabricated using focused ion beam milling provides mode volumes as small as 1.24 $μ$m$^3$. In-situ tuning of the cavity resonance is achieved with piezoelectric actuators. At optimal coupling of the full open cavity the signal from individual zero phonon line transitions is enhanced by about a factor of 10 and the overall emission rate of the NV$^-$ center is increased by 40% compared with that measured from the same center in the absence …
Recently, the negatively charged silicon vacancy centre (SiV) in diamond has emerged as a novel promising system for quantum information processing (QIP) due to its superior spectral properties and advantageous electronic structure: The SiV offers an optically accessible Λ-type level structure with a large orbital level splitting even without the need of an external magnetic field and previous studies determined the ground state coherence time of the centre to be on the order of 35-45ns. While these studies already indicate the feasibility of an ultrafast all-optical coherent control of the Si…
The novel aspect of the centre (NV-) in diamond is the high degree of spin polarisation achieved through optical illumination. In this paper it is shown that the spin polarisation occurs as a consequence of an electron-vibration interaction combined with spin-orbit interaction, and an electronic model involving these interactions is developed to account for the observed polarisation.
The protocols for the control and readout of Nitrogen Vacancy (NV) centres electron spins in diamond offer an advanced platform for quantum computation, metrology and sensing. These protocols are based on the optical readout of photons emitted from NV centres, which process is limited by the yield of photons collection. Here we report on a novel principle for the detection of NV centres magnetic resonance in diamond by directly monitoring spin-preserving electron transitions through measurement of NV centre related photocurrent. The demonstrated direct detection technique offers a sensitive wa…
We propose an efficient scheme for a coherent quantum interface between microwave and optical photons using nitrogen-vacancy (NV) centers in diamond. In this setup, an NV center ensemble is simultaneously coupled to an optical and a microwave cavity. We show that, by using the collective spin excitation modes as an intermediary, quantum states can be transferred between the microwave cavity and the optical cavity through either a double-swap scheme or a dark-state protocol. This hybrid quantum interface may provide interesting applications in single microwave photon detections or quantum infor…
An unexplored diamond defect centre which is found to emit stable single photons at a measured rate of 1.6 MHz at room temperature is reported. The novel centre, identified in chemical vapour deposition grown diamond crystals, exhibits a sharp zero phonon line at 734 nm with a full width at half maximum of ~ 4 nm. The photon statistics confirm the center is a single emitter and provides direct evidence of the first true two-level single quantum system in diamond.
We demonstrate electrical control of the single photon emission spectrum from chromium-based colour centres implanted in monolithic diamond. Under an external electric field the tunability range is typically three orders of magnitude larger than the radiative linewidth and at least one order of magnitude larger than the observed linewidth. The electric and magnetic field dependence of luminescence gives indications on the inherent symmetry and we propose Cr-X or X-Cr-Y type noncentrosymmetric atomic configurations as most probable candidates for these centres.
We design extremely flexible ultrahigh-Q diamond-based double-heterostructure photonic crystal slab cavities by modifying the refractive index of the diamond. The refractive index changes needed for ultrahigh-Q cavities with $Q ~ 10^7$, are well within what can be achieved ($Δn \sim 0.02$). The cavity modes have relatively small volumes $V<2 (λ/n)^3$, making them ideal for cavity quantum electro-dynamic applications. Importantly for realistic fabrication, our design is flexible because the range of parameters, cavity length and the index changes, that enables an ultrahigh-Q is quite broad. Fur…
We study single silicon vacancy (SiV) centres in chemical vapour deposition (CVD) nanodiamonds on iridium as well as an ensemble of SiV centres in a high quality, low stress CVD diamond film by using temperature dependent luminescence spectroscopy in the temperature range 5-295 K. We investigate in detail the temperature dependent fine structure of the zero-phonon-line (ZPL) of the SiV centres. The ZPL transition is affected by inhomogeneous as well as temperature dependent homogeneous broadening and blue shifts by about 20 cm-1 upon cooling from room temperature to 5 K. We employ excitation p…
We demonstrate coupling of the zero-phonon line of individual nitrogen-vacancy centers and the modes of microring resonators fabricated in single-crystal diamond. A zero-phonon line enhancement exceeding ten-fold is estimated from lifetime measurements at cryogenic temperatures. The devices are fabricated using standard semiconductor techniques and off-the-shelf materials, thus enabling integrated diamond photonics.
We investigate spin-dependent decay and intersystem crossing in the optical cycle of single negatively-charged nitrogen-vacancy (NV) centres in diamond. We use spin control and pulsed optical excitation to extract both the spin-resolved lifetimes of the excited states and the degree of optically-induced spin polarization. By optically exciting the centre with a series of picosecond pulses, we determine the spin-flip probabilities per optical cycle, as well as the spin-dependent probability for intersystem crossing. This information, together with the indepedently measured decay rate of singlet…
We report on the coherence properties of single photons from chromium-based colour centres in diamond. We use field-correlation and spectral lineshape measurements to reveal the interplay between slow spectral wandering and fast dephasing mechanisms as a function of temperature. We show that the zero-phonon transition frequency and its linewidth follow a power-law dependence on temperature indicating that the dominant fast dephasing mechanisms for these centres are direct electron-phonon coupling and phonon-modulated Coulomb coupling to nearby impurities. Further, the observed reduction in the…
The nitrogen-vacancy colour centre in diamond is emerging as one of the most important solid-state quantum systems. It has applications to fields including high-precision sensing, quantum computing, single photon communication, metrology, nanoscale magnetic imaging and biosensing. For all of these applications, a high quantum yield of emitted photons is desirable. However, diamond samples engineered to have high densities of nitrogen-vacancy centres show levels of brightness varying significantly within single batches, or even within the same sample. Here we show that nearby nitrogen impuritie…
Modelling and experimental verification of photoelectrical response of NV diamond spin centres
Hasselt University（哈瑟尔特大学）；Czech Technical University in Prague（布拉格捷克理工大学）；IMEC（imec研究所）；Institute of Organic Chemistry and Biochemistry of the CAS（捷克科学院有机化学与生物化学研究所）
Optically active point defects in crystals have gained widespread attention as photonic systems that can find use in quantum information technologies. However challenges remain in the placing of individual defects at desired locations, an essential element of device fabrication. Here we report the controlled generation of single nitrogen-vacancy (NV) centres in diamond using laser writing. The use of aberration correction in the writing optics allows precise positioning of vacancies within the diamond crystal, and subsequent annealing produces single NV centres with up to 45% success probabili…
We report strong coupling between an ensemble of N impurity (P1) centres in diamond and microwave photons using a unique double post re-entrant cavity. The cavity is designed so that the magnetic component of the cavity field is spatially separated from the electric component and focused into the small volume in which the diamond sample is mounted. The novelty of the structure simultaneously allows high magnetic filling factor (38.4\%) and low frequencies necessary to interact, at low magnetic field, with transitions in diamond such as those in NV$^{-}$ and P1 centres. Coupling strength (or no…
Deterministic coupling of single solid-state emitters to nanocavities is the key for integrated quantum information devices. We here fabricate a photonic crystal cavity around a preselected single silicon-vacancy color center in diamond and demonstrate modification of the emitters internal population dynamics and radiative quantum efficiency. The controlled, room-temperature cavity coupling gives rise to a resonant Purcell enhancement of the zero-phonon transition by a factor of 19, coming along with a 2.5-fold reduction of the emitter's lifetime.
A robust laser cavity platform for NV-diamond singlet infrared absorption magnetometry
RMIT University（皇家墨尔本理工大学）；The University of Melbourne（墨尔本大学）；Fraunhofer Institute for Applied Solid State Physics IAF（弗劳恩霍夫应用固体物理研究所）；National Institutes for Quantum Science and Technology: QST（量子科学技术研究院）；Tohoku University（东北大学）；Adelaide University（阿德莱德大学）；MOGLabs
Colour centres in diamond have emerged as versatile tools for solid-state quantum technologies ranging from quantum information to metrology, where the nitrogen-vacancy centre is the most studied to-date. Recently, this toolbox has expanded to include different materials for their nanofabrication opportunities, and novel colour centres to realize more efficient spin-photon quantum interfaces. Of these, the silicon-vacancy centre stands out with ultrabright single photon emission predominantly into the desirable zero-phonon line. The challenge for utilizing this centre is to realise the hithert…
We present a rigorous theoretical model for the optical interaction between a nitrogen-vacancy (NV) centre in diamond and a plasmonic metal nanoparticle (MNP), accompanied by a computationally efficient procedure to solve the evolution. The proposed model enables us to successfully explain existing optical emission measurements of NV centres both in the presence and absence of a metal nanoparticle. We show that the NV-plasmon interaction provides a versatile new avenue to enhance and control the optical emission of an NV centre. Changes to the MNP type and size, NV-MNP centre separation, subme…
A central goal in quantum information science is to efficiently interface photons with single optical modes for quantum networking and distributed quantum computing. Here, we introduce and experimentally demonstrate a compact and efficient method for the low-loss coupling of a solid-state qubit, the nitrogen vacancy (NV) centre in diamond, with a single-mode optical fibre. In this approach, single-mode tapered diamond waveguides containing exactly one high quality NV memory are selected and integrated on tapered silica fibres. Numerical optimization of an adiabatic coupler indicates that near-…
Levitated diamond nanocrystals with nitrogen-vacancy (NV) centres in high vacuum have been proposed as a unique system for experiments in fundamental quantum mechanics, including the generation of large quantum superposition states and tests of quantum gravity. This system promises extreme isolation from its environment while providing quantum control and sensing through the NV centre spin. While optical trapping has been the most explored method of levitation, recent results indicate that excessive optical heating of the nanodiamonds under vacuum may make the method impractical with currently…
High-cooperativity coupling and spin-resolved extinction of tin-vacancy centers in a diamond-like microcavity
Karlsruhe Institute of Technology (KIT)（卡尔斯鲁厄理工学院）；University of Kassel（卡塞尔大学）；University of Stuttgart（斯图加特大学）；Ulm University（乌尔姆大学）；University of Leipzig（莱比锡大学）；Ferdinand-Braun-Institut (FBH)（费迪南德·布劳恩研究所）；Humboldt-Universität zu Berlin（柏林洪堡大学）；Fraunhofer Institute for Applied Solid State Physics（弗劳恩霍夫应用固态物理研究所）
Negatively charged nitrogen-vacancy centres in diamond are promising quantum magnetic field sensors. Laser threshold magnetometry has been a theoretical approach for the improvement of NV-centre ensemble sensitivity via increased signal strength and magnetic field contrast. In this work we experimentally demonstrate laser threshold magnetometry. We use a macroscopic high-finesse laser cavity containing a highly NV-doped and low absorbing diamond gain medium that is pumped at 532nm and resonantly seeded at 710nm. This enables amplification of the signal power by stimulated emission of 64%. We s…
We realize a potential platform for an efficient spin-photon interface, namely negatively-charged silicon-vacancy centers in a diamond membrane coupled to the mode of a fully-tunable, fiber-based, optical resonator. We demonstrate that introducing the thin ($\sim 200 \, \text{nm}$), single crystal diamond membrane into the mode of the resonator does not change the cavity properties, which is one of the crucial points for an efficient spin-photon interface. In particular, we observe constantly high Finesse values of up to $3000$ and a linear dispersion in the presence of the membrane. We observ…
Coherent interfaces between optical photons and long-lived matter qubits form a key resource for a broad range of quantum technologies. Cavity quantum electrodynamics (cQED) offers a route to achieve such an interface by enhancing interactions between cavity-confined photons and individual emitters. Over the last two decades, a promising new class of emitters based on defect centers in diamond have emerged, combining long spin coherence times with atom-like optical transitions. More recently, advances in optical resonator technologies have made it feasible to realize cQED in diamond. This arti…
Amplification by stimulated emission of nitrogen vacancy centres in a diamond-loaded fibre cavity
Macquarie University（麦考瑞大学）；Fraunhofer Institut für Angewandte Festkörperphysik (IAF)（弗劳恩霍夫应用固体物理研究所）；National Institutes for Quantum and Radiological Science and Technology（量子科学技术研究机构）；University of Tokyo（东京大学）；RMIT University（皇家墨尔本理工大学）
Diamond photonics provides an attractive architecture to explore room temperature cavity quantum electrodynamics and to realize scalable multi-qubit computing. Here we review the present state of diamond photonic technology. The design, fabrication and characterization of a novel triangular cross section nanobeam cavity produced in a single crystal diamond is demonstrated. The present cavity design, based on a triangular cross section allows vertical confinement and better signal collection efficiency than that of slab-based nanocavities, and eliminates the need for a pre-existing membrane. Th…
Due to interest in both solid state based quantum computing architectures and the application of quantum mechanical systems to nanomagnetometry, there has been considerable recent attention focused on understanding the microscopic dynamics of solid state spin baths and their effects on the coherence of a controllable, coupled central electronic spin. Many analytic approaches are based on simplified phenomenological models in which it is difficult to capture much of the complex physics associated with this system. Conversely, numerical approaches reproduce this complex behaviour, but are limite…
The nitrogen-vacancy center in diamond has been explored extensively as a light-matter interface for quantum information applications, however it is limited by low coherent photon emission and spectral instability. Here, we present a promising interface based on an alternate defect with superior optical properties (the germanium-vacancy) coupled to a finesse $\approx11{,}000$ fiber cavity, resulting in a $31^{+11}_{-15}$-fold increase in the spectral density of emission. This work sets the stage for cryogenic experiments, where we predict a measurable increase in the spontaneous emission rate.
The recently discovered negatively charged tin-vacancy centre in diamond is a promising candidate for applications in quantum information processing (QIP). We here present a detailed spectroscopic study encompassing single photon emission and polarisation properties, the temperature dependence of emission spectra as well as a detailed analysis of the phonon sideband and Debye-Waller factor. Using photoluminescence excitation spectroscopy (PLE) we probe an energetically higher lying excited state and prove fully lifetime limited linewidths of single emitters at cryogenic temperatures. For these…
Single-crystal diamond cavity optomechanical devices are a promising example of a hybrid quantum system: by coupling mechanical resonances to both light and electron spins, they can enable new ways for photons to control solid state qubits. However, realizing cavity optomechanical devices from high quality diamond chips has been an outstanding challenge. Here we demonstrate single-crystal diamond cavity optomechanical devices that can enable photon-phonon-spin coupling. Cavity optomechanical coupling to $2\,\text{GHz}$ frequency ($f_\text{m}$) mechanical resonances is observed. In room tempera…
Nitrogen-vacancy (NV) centres in diamond are appealing nano-scale quantum sensors for temperature, strain, electric fields and, most notably, for magnetic fields. However, the cryogenic temperatures required for low-noise single-shot readout that have enabled the most sensitive NV-magnetometry reported to date, are impractical for key applications, e.g. biological sensing. Overcoming the noisy readout at room-temperature has until now demanded repeated collection of fluorescent photons, which increases the time-cost of the procedure thus reducing its sensitivity. Here we show how machine learn…
We present the design of two-dimensional photonic crystal microcavities in thin diamond membranes well suited for coupling of color centers in diamond. By comparing simulated and ideal field distributions in Fourier and real space and by according modification of air hole positions and size, we optimize the cavity structure yielding high quality factors up to Q = 320000 with a modal volume of V = 0.35 (lambda/n)^3. Using the very same approach we also improve previous designs of a small modal volume microcavity in silicon, gaining a factor of 3 in cavity Q. In view of practical realization of …
On-demand, high repetition rate sources of indistinguishable, polarised single photons are the key component for future photonic quantum technologies. Colour centres in diamond offer a promising solution, and the narrow line-width of the recently identified nickel-based NE8 centre makes it particularly appealing for realising the transform-limited sources necessary for quantum interference. Here we report the characterisation of dipole orientation and coherence properties of a single NE8 colour centre in a diamond nanocrystal at room-temperature. We observe a single photon coherence time of 0.…
The application of magnetic resonance (MR) spectroscopy at progressively smaller length scales may eventually permit "chemical imaging" of spins at the surfaces of materials and biological complexes. In particular, the negatively charged nitrogen-vacancy (NV-) centre in diamond has been exploited as an optical transducer for nanoscale nuclear magnetic resonance. However, the spectra of detected spins are generally broadened by their interaction with proximate paramagnetic NV- centres through coherent and incoherent mechanisms. Here we demonstrate a detection technique that can resolve the spec…
The ability to measure weak signals such as pressure, force, electric field, and temperature with nanoscale devices and high spatial resolution offers a wide range of applications in fundamental and applied sciences. Here we present a proposal for a hybrid device composed of thin film layers of diamond with color centers implanted and piezo-active elements for the transduction and measurement of a wide variety of physical signals. The magnetic response of a piezomagnetic layer to an external stress or a stress induced by the change of electric field and temperature is shown to affect significa…
We investigate phonon induced electronic dynamics in the ground and excited states of the negatively charged silicon-vacancy ($\mathrm{SiV}^-$) centre in diamond. Optical transition line widths, transition wavelength and excited state lifetimes are measured for the temperature range 4-350 K. The ground state orbital relaxation rates are measured using time-resolved fluorescence techniques. A microscopic model of the thermal broadening in the excited and ground states of the $\mathrm{SiV}^-$ centre is developed. A vibronic process involving single-phonon transitions is found to determine orbita…
We describe how an ensemble of four-level atoms in the diamond-type configuration can be applied to create a fully controllable effective coupling between two cavity modes. The diamond-type configuration allows one to use a bimodal cavity that supports modes of different frequencies or different circular polarisations, because each mode is coupled only to its own transition. This system can be used for mapping a quantum state of one cavity mode onto the other mode on demand. Additionally, it can serve as a fast opening high-Q cavity system that can be easily and coherently controlled with lase…
New magnetometry techniques based on Nitrogen-Vacancy (NV) defects in diamond allow for the imaging of static (DC) and oscillatory (AC) nanoscopic magnetic systems. However, these techniques require accurate knowledge and control of the sample dynamics, and are thus limited in their ability to image fields arising from rapidly fluctuating (FC) environments. We show here that FC fields place restrictions on the DC field sensitivity of an NV qubit magnetometer, and that by probing the dephasing rate of the qubit in a magnetic FC environment, we are able to measure fluctuation rates and RMS field…
