We present a stability analysis of the classical ideal gas in a new theory of nonextensive statistics and use the theory to understand the phenomena of negative specific heat in some self-gravitating systems. The stability analysis is made on the basis of the second variation of Tsallis entropy. It is shown that the system is thermodynamically unstable if the nonextensive parameter is q>5/3, which is exactly equivalent to the condition of appearance of the negative specific heat.
Based on the prescription termed the optimal Lagrange multipliers formalism for extremizing the Tsallis entropy indexed by q, it is shown that key aspects of the treatment of the ideal gas problem are identical in both the nonextensive and extensive cases.
The concepts of quantity of heat and work are deduced in the non-extensive statistical mechanics context, following steps in parallel to those employed in the extensive statistical mechanics.
Macroscopic nonextensive thermodynamics is studied without recourse to microscopic statistical mechanics. It is shown that if entropy is nonextensive, the concept of physical temperature introduced through the generalized zeroth law of thermodynamics necessarily leads to modifications of the first law of thermodynamics and some of thermodynamic relations including Clausius definition of thermodynamic entropy. It is also shown, by applying this generalized Clausius entropy to a composite nonextensive system, how the nonextensive entropy and the quantity of heat consistently behave in an arbitra…
We obtain the specific heat in the third constraint scenario for a canonical ensemble of a nonextensive extreme relativistic ideal gas in a closed form. The canonical ensemble of N particles in D dimensions is well-defined for the choice of the deformation parameter in the range 0 < q < 1 + 1 / DN. For a relativistic ideal gas with particles of arbitrary mass a perturbative scheme in the nonextensivity parameter (1 - q) is developed by employing an infinite product expansion of the q-exponential, and a direct transformation of the internal energy from the second to the third constraint picture…
The underlying connection between the degrees of freedom of a system and its nonextensive thermodynamic behavior is addressed. The problem is handled by starting from a thermodynamical system with fractal structure and its analytical reduction to a finite ideal gas. In the limit where the thermofractal has no internal structure, it is found that it reproduces the basic properties of a nonextensive ideal gas with a finite number of particles as recently discussed (Lima \& Deppman, Phys. Rev. E 101, 040102(R) 2020). In particular, the entropic $q$-index is calculated in terms of the number of pa…
We have used the generalized two-atom ideal gas model in Tsallis statistics for the statistical description of a real gas. By comparing the heat capacity with the experimental results for the two-atom molecule gases such as N2, O2 and CO, we find that these gases appear extensive at normal temperature, but they may be nonextensive at the lower temperature. Furthermore, we study the heat capacity of the generalized many-atom gas model. We conclude that, for the many-atom gas with a high degree of freedom, a weak nonextensivity of 1-q<0 can lead to the instability.
We investigate perturbative thermodynamic geometry of nonextensive ideal Classical, Bose and Fermi gases.We show that the intrinsic statistical interaction of nonextensive Bose (Fermi) gas is attractive (repulsive) similar to the extensive case but the value of thermodynamic curvature is changed by nonextensive parameter. In contrary to the extensive ideal classical gas, the nonextensive one may be divided to two different regimes. According to deviation parameter of the system to the nonextensive case, one can find a special value of fugacity, $z^{*}$, where the sign of thermodynamic curvatur…
We have studied finite $N$-body $D$-dimensional nonextensive ideal gases and harmonic oscillators, by using the maximum-entropy methods with the $q$- and normal averages ($q$: the entropic index). The validity range, specific heat and Tsallis entropy obtained by the two average methods are compared. Validity ranges of the $q$- and normal averages are $0 < q < q_U$ and $q > q_L$, respectively, where $q_U=1+(ηDN)^{-1}$, $q_L=1-(ηDN+1)^{-1}$ and $η=1/2$ ($η=1$) for ideal gases (harmonic oscillators). The energy and specific heat in the $q$- and normal averages coincide with those in the Boltzmann…
In a recent paper [Int. J. Mod. Phys. B {\bf 14}, 405 (2000)] we discussed the Bose-Einstein condensation (BEC) in the framework of Tsallis's nonextensive statistical mechanics. In particular, we studied an ideal gas of bosons in a confining harmonic potential. In this memoir we generalize our previous analysis by investigating an ideal Bose gas in a generic power-law external potential. We derive analytical formulas for the energy of the system, the BEC transition temperature and the condensed fraction.
It is presented a microscopic interpretation for the temperature within Tsallis thermostatistics, generalizing the classical derivation based on the Boltzmann-Gibbs statistics. It is shown that with this definition the zeroth law and the equipartition theorem are valid in their classical form. Moreover, it is observed that the equation of state for an ideal gas within generalized thermostatistics preserves the classical Boyle's law form $PV=NkT$.
The generalized zeroth law of thermodynamics indicates that the physical temperature in nonextensive statistical mechanics is different from the inverse of the Lagrange multiplier, beta. This leads to modifications of some of thermodynamic relations for nonextensive systems. Here, taking the first law of thermodynamics and the Legendre transform structure as the basic premises, it is found that Clausius definition of the thermodynamic entropy has to be appropriately modified, and accordingly the thermodynamic relations proposed by Tsallis, Mendes and Plastino [Physica A 261 (1998) 534] are als…
We study the diffusion and thermal conductivity of charged particles in the weakly ionized plasma with the power-law q-distributions in nonextensive statistics and without the magnetic field. Electrons and ions have different q-parameters and temperature. We derive new expressions of the diffusion, thermal diffusion, thermal conductivity and thermoelectric coefficients of electrons and ions respectively in the plasma. It is shown that these transport coefficients depend significantly on the q-parameters in the power-law q-distributed plasma and thus they have different properties from those de…
We discuss the Bose-Einstein condensation (BEC) for an ideal gas of bosons in the framework of Tsallis's nonextensive statistical mechanics. We study the corrections to the standard BEC formulas due to a weak nonextensivity of the system. In particular, we consider three cases in the D-dimensional space: the homogeneous gas, the gas in a harmonic trap and the relativistic homogenous gas. The results show that small deviations from the extensive Bose statistics produce remarkably large changes in the BEC transition temperature.
We have constructed a nonextensive thermodynamic formalism consisting of two sets of parallel Legendre transformation structures in previous papers. One is the physical set and the other is the Lagrange set. In this paper we study the thermodynamic stability criterion with a dual interpretation of the thermodynamic relations and quantities. By recourse to the assumption that volume in nonextenstive system is nonadditive, we conclude that it is the physical pressure that is responsible for the mechanical balance between any two parts in a given nonextensive system. It is verified that in the ph…
The incomplete nonextensive statistics in the canonical and microcanonical ensembles is explored in the general case and in a particular case for the ideal gas. By exact analytical results for the ideal gas it is shown that taking the thermodynamic limit, with $z=q/(1-q)$ being an extensive variable of state, the incomplete nonextensive statistics satisfies the requirements of equilibrium thermodynamics. The thermodynamical potential of the statistical ensemble is a homogeneous function of the first degree of the extensive variables of state. In this case, the incomplete nonextensive statistic…
Thermodynamics of power means applies to an ideal quantum gas which may be nonextensive. Transition to an ideal classical gas occurs when the empirical temperature exponents of the internal energy and absolute temperature coalesce. Limiting processes are pure heat conduction and pure deformations. Largest and smallest mean final volumes occur for isothermal and adiabatic processes, respectively. The increment in the heat admits two integrating factors which yield conserved quantities for adiabatic processes. Energy-conserving equilibrations yield the largest final means possible, while the sec…
By using the generalized Boltzmann equation of transport in nonextensive statistics, we study transport properties of the diffusion flux and the heat flux of charged particles in the weakly ionized plasma with the power-law q-distributions under the magnetic field. We derive the tensor expressions of diffusion coefficient, thermal diffusion coefficient, mobility and thermal conductivity of electrons and ions in the q-distributed plasma under magnetic field. We show that the tensors of the diffusion coefficient, the thermal diffusion coefficient and the thermal conductivity are strongly depend …
Canonical ensembles consisting of $M$-unit $Hubbard$ $dimers$ have been studies within the nonextensive statistics (NES). The temperature dependences of the energy, entropy, specific heat and susceptibility have been calculated for the number of dimers, $M = 1, 2, 3$ and $\infty$. We have assumed the relation between the entropic index $q$ and the cluster size $N$ given by $q=1+2/N$ ($N = 2\:M$ for $M$ dimers), which was previously derived by several methods. For relating the physical temperature $T$ to the Lagrange multiplier $β$, two methods have been adopted: $T=1/k_B β$ in the method A [Ts…
The homogeneous entropy for continuous systems in nonextensive statistics reads $S^{H}_{q}=k_B\,{(1 - (K \int dΓρ^{1/q}(Γ))^{q})}/({1-q})$, where $Γ$ is the phase space variable. Optimization of $S^{H}_{q}$ combined with normalization and energy constraints gives an implicit expression of the distribution function $ρ(Γ)$ which can be computed explicitly for the ideal gas. From this result, we compute properties such as the energy fluctuations and the specific heat. Similar results are also presented using the formulation based on the Tsallis entropy. From the analysis, we discuss the validity …
We obtain an analytic expression for the specific heat of a system of N rigid rotators exactly in the high temperature limit, and via a pertubative approach in the low temperature limit. We then evaluate the specific heat of a diatomic gas with both translational and rotational degrees of freedom, and conclude that there is a mixing between the translational and rotational degrees of freedom in nonextensive statistics.
We show that Tsallis ensemble of power-law distributions provides a mechanical model of nonextensive equilibrium thermodynamics for small interacting Hamiltonian systems, i.e., using Boltzmann's original nomenclature, we prove that it is an exact orthode. This means that the heat differential admits the inverse average kinetic energy as an integrating factor. One immediate consequence is that the logarithm of the normalization function can be identified with the entropy, instead of the q-deformed logarithm. It has been noted that such entropy coincides with Renyi entropy rather than Tsallis en…
Generalized Bose-Einstein (BE) and Fermi-Dirac (FD) distributions in nonextensive quantum statistics have been discussed by the maximum-entropy method (MEM) with the optimum Lagrange multiplier based on the exact integral representation [Rajagopal, Mendes, and Lenzi, Phys. Rev. Lett. {\bf 80}, 3907 (1998)]. It has been shown that the $(q-1)$ expansion in the exact approach agrees with the result obtained by the asymptotic approach valid for $O(q-1)$. Model calculations have been made with a uniform density of states for electrons and with the Debye model for phonons. Based on the result of the…
We perform a molecular dynamical study of the isolated $d=1$ classical Hamiltonian ${\cal H} = {1/2} \sum_{i=1}^N L_i^2 + \sum_{i \ne j} \frac{1-cos(θ_i-θ_j)}{r_{ij}^α} ;(α\ge 0)$, known to exhibit a second order phase transition, being disordered for $u \equiv U/N{\tilde N} \ge u_c(α,d)$ and ordered otherwise ($U\equiv$ total energy and ${\tilde N} \equiv \frac{N^{1-α/d}-α/d}{1-α/d}$). We focus on the nonextensive case $α/d \le 1$ and observe that, for $u<u_c$, a basin of attraction exists for the initial conditions for which the system quickly relaxes onto a longstanding metastable state (wh…
The property that power means are monotonically increasing functions of their order is shown to be the basis of the second laws not only for processes involving heat conduction but also for processes involving deformations. In an $L$-potentail equilibration the final state will be one of maximum entropy, while in an entropy equilibrium the final state will be one of minimum $L$. A metric space is connected with the power means, and the distance between means of different order is related to the Carnot efficiency. In the ideal classical gas limit, the average change in the entropy is shown to b…
Schmidt et al (Phys Rev Lett 86, 1191 (2001)) observe and analyze a negative specific heat in Na clusters. The analysis is done within the framework of Boltzmann-Gibbs equilibrium statistical mechanics. We argue that this is not the only physical possibility to be taken into account. A possible connection with nonextensive statistical mechanics is considered as well.
Thermodynamical properties of canonical and grand-canonical ensembles of the half-filled two-site Hubbard model have been discussed within the framework of the nonextensive statistics (NES). For relating the physical temperature $T$ to the Lagrange multiplier $β$, two methods have been adopted: $T=1/k_B β$ in the method A [Tsallis {\it et al.} Physica A {\bf 261} (1998) 534], and $T=c_q/k_B β$ in the method B [Abe {\it et al.} Phys. Lett. A {\bf 281} (2001) 126], where $k_B$ denotes the Boltzman constant, $c_q= \sum_i p_i^q$, $p_i$ the probability distribution of the $i$th state, and $q$ the e…
We consider both Otto and Diesel heat engine cycles running upon the working substances modeled by the van der Waals fluid as a simple non-ideal gas model. We extensively perform the efficiency study in these model engines. Then we find that this "real" engine model can go beyond its ideal-gas counterpart in efficiency, whereas as well-known, the maximum Carnot efficiency is the same for both ideal and non-ideal gas engines. In fact, the higher the density of non-ideality is, the higher efficiency tends to be found, especially in the low-temperature regime, but with more shrinkage in the range…
There is a long-standing question as to whether and to what extent it is possible to describe nonequilibrium systems in stationary states in terms of global thermodynamic functions. The positive answers have been obtained only for isothermal systems or systems with small temperature differences. We formulate thermodynamics of the stationary states of the ideal gas subjected to heat flow in the form of the zeroth, first, and second law. Surprisingly, the formal structure of steady state thermodynamics is the same as in equilibrium thermodynamics. We rigorously show that $U$ satisfies the follow…
We calculate the specific heat of the ideal gas obeying the generalized exclusion statistics (GES) in the continuum model and the tight binding model numerically. In the continuum model of 3-d space, the specific heat increases with statistical parameter at low temperature whereas it decreases with statistical parameter at high temperature. We find that the critical temperature normalized by $μ_f$ (Fermi energy) is 0.290. The specific heat of 2-d space was known to be independent of $g$ in the continuum model, but it varies with $g$ drastically in the tight-binding model. From its unique behav…
Ideal heat engine cycles at maximal efficiency -- the ideal gas and beyond
University of Maryland, College Park（马里兰大学帕克分校）；University of Maryland, Baltimore County（马里兰大学巴尔的摩郡分校）；Quantum Science Institute, University of Maryland, Baltimore County（马里兰大学巴尔的摩郡分校量子科学研究所）；National Quantum Laboratory（国家量子实验室）
Realistic phenomena can be described more appropriately using generalized canonical ensemble, with proper parameter sets involved. We have generalized the Einstein's theory for specific heat of solid in Tsallis statistics, where the temperature fluctuation is introduced into the theory via the fluctuation parameter $q$. At low temperature the Einstein's curve of the specific heat in the nonextensive Tsallis scenario exactly lies on the experimental data points. Consequently this $q$-modified Einstein's curve is found to be overlapping with the one predicted by Debye. Considering only the tempe…
Considering ideal paramagnetic medium, in this paper we deduced an expression for the thermal efficiency of Carnot heat engine with a paramagnetic gas as working substance. We found that the efficiency depends on the limits of maximum and minimal temperature imposed on the Carnot cycle, as in the ideal gas, photon gas and variable Chaplygin gas.
Important models of nonequilibrium statistical physics (NESP) are limited by a commonly used, but often unrecognized, near-equilibrium approximation. Fokker-Planck and Langevin equations, the Einstein and random-flight diffusion models, and the Schnakenberg model of biochemical networks suppose that fluctuations are due to an ideal equilibrium bath. But far from equilibrium, this perfect bath concept does not hold. A more principled approach should derive the rate fluctuations from an underlying dynamical model, rather than assuming a particular form. Here, using Maximum Caliber as the underly…
We present analytical formulae for the first and second derivatives of the Helmholtz free energy of non-relativistic ideal Fermi-gas. Important thermodynamic quantities such as heat capacity, sound velocity, heat capacity ratio and others can be easily expressed through the derivatives. We demonstrate correct ideal Boltzmann gas and low--temperature Fermi-gas asymptotes and derive corrections to thermodynamic functions for these limiting cases. Numerical computations of thermodynamic properties of ideal Fermi-gas can be accurately performed using the developed freely available Python module if…
We study the thermodynamic properties of an ideal gas of fermions in a harmonic oscillator confining potential. The analogy between this problem and the de Haas-van Alphen effect is discussed and used to obtain analytical results for the chemical potential and specific heat in the case of both isotropic and anisotropic potentials. Step-like behaviour in the chemical potential, first noted in numerical studies, is obtained analytically and shown to result in an oscillatory behaviour of the specific heat when the particle number is varied. The origin of these oscillations is that part of the the…
The sympathetic cooling of an initially degenerate Fermi gas by either an ideal Bose gas below $T_c$ or an ideal Boltzmann gas is investigated. It is shown that the efficiency of cooling by a Bose gas below $T_c$ is by no means reduced when its heat capacity becomes much less than that of the Fermi gas, where efficiency is measured by the decrease in the temperature of the Fermi gas per number of particles evaporated from the coolant. This contradicts the intuitive idea that an efficient coolant must have a large heat capacity. In contrast, for a Boltzmann gas a minimal value of the ratio of t…
We provide firm convincing evidence that the energy transport in a one-dimensional gas of elastically colliding free particles of unequal masses is anomalous, i.e. the Fourier Law does not hold. Our conclusions are based on the analysis of the dependence of the heat current on the number of particles, of the internal temperature profile and on the Green-Kubo formalism.
The equations of state for an ideal generalized gas, like an ideal quantum gas, are expressed in terms of power laws of the temperature. The reduction of an ideal generalized gas to an ideal classical case occurs when the characteristic empirical temperature exponents in the thermal equation of state and in the absolute temperature coincide in contrast to the merger of an ideal quantum gas with an ideal classical gas in the high temperature limit. A corollary to Carnot's theorem is proved asserting that the ratio of the work done over a cycle to the heat absorbed to increase the temperature at…
We revisit the paradigm of an ideal gas under isothermal conditions. A moving piston performs work on an ideal gas in a container that is strongly coupled to a heat reservoir. The thermal coupling is modelled by stochastic scattering at the boundaries. In contrast to recent studies of an adiabatic ideal gas with a piston [R.C. Lua and A.Y. Grosberg, \textit{J. Phys. Chem. B} 109, 6805 (2005); I. Bena et al., \textit{Europhys. Lett.} 71, 879 (2005)], container and piston stay in contact with the heat bath during the work process. Under this condition the heat reservoir as well as the system dep…
Heat transfer properties in non-reciprocal systems are discussed. An ideal experiment employing microwave or optical isolators is considered in order to investigate the possibility for a spontaneous transfer of energy between two black bodies at common temperatures. Under the validity of the adopted assumptions on the examined physical system, the effect appears to be weak but feasible.
The ideal uniform two-dimensional (2D) Fermi and Bose gases are considered both in the thermodynamic limit and the finite case. We derive May's Theorem, viz. the correspondence between the internal energies of the Fermi and Bose gases in the thermodynamic limit. This results in both gases having the same heat capacity. However, as we shall show, the thermodynamic limit is never truly reached in two dimensions and so it is essential to consider finite-size effects. We show in an elementary manner that for the finite 2D Bose gas, a pseudo-Bose-Einstein condensate forms at low temperatures, incom…
We study the behaviour of an ideal non-relativistic Bose gas in a three-dimensional space where one of the dimensions is compactified to form a circle. In this case there is no phase transition like that for the case of an infinite volume, nevertheless Bose-Einstein condensation signified by a sudden buildup of particles in the ground state can occur. We use the grand canonical ensemble to study this problem. In particular, the specific heat is evaluated numerically, as well as analytically in certain limits. We show analytically how the familiar result for the specific heat is recovered as we…
I discuss in parallel two universal phenomena: the independence of statistics of the heat capacity and entropy of ideal gases of the same, constant, density of states, on one hand, and the independence of statistics of the heat and entropy transport through one-dimensional channels, on the other hand. I show that there is a close similarity between the microscopic explanations of each of these phenomena.
We investigate a heat engine with a finite-length Kitaev chain in an ideal Otto cycle. It is found that the critical point of the topological phase transition coincides with the maxima of the efficiency and work output of the total Otto engine. Finite-size effects are taken into account using the method of Hill's nanothermodynamics, as well as using the method of temperature-dependent energy levels. We identify the bulk and boundary thermal cycles of the Kitaev chain engine and find that they are non-ideal Otto cycles. The physics of deviation from ideal Otto cycle is identified as a finite si…
We compare two approaches to the generalization of the ordinary Fermi-statistics based on the nonadditive Tsallis $q$-exponential used in the Gibbs factor instead of the conventional exponential function. Both numerical and analytical calculations are made for the chemical potential, fugacity, energy, and the specific heat of the ideal gas obeying such generalized types of statistics. In the approach based on the Gibbs factor containing the chemical potential, high temperature behavior of the specific heat significantly deviates from the expected classical limit, while at low temperatures it r…
International Centre for Theoretical Sciences, Tata Institute of Fundamental Research（国际理论科学中心，塔塔基础研究所）；Racah Institute of Physics, Hebrew University of Jerusalem（拉卡物理研究所，耶路撒冷希伯来大学）
Even though irreversibility is one of the major hallmarks of any real life process, an actual understanding of irreversible processes remains still mostly semiempirical. In this paper we formulate a thermodynamic uncertainty principle for irreversible heat engines operating with an ideal gas as a working medium. In particular, we show that the time needed to run through such an irreversible cycle multiplied by the irreversible work lost in the cycle, is bounded from below by an irreducible and process-dependent constant that has the dimension of an action. The constant in question depends on a…
Physical properties of ideal Bose gas with the fractal dimensionality between D=2 and D=3 are theoretically investigated. Calculation shows that the characteristic features of the specific heat and the superfluid density of ideal Bose gas in fractal dimensions are strikingly similar to those of superfluid Helium-4 in porous media. This result indicates that the geometrical factor is dominant over mutual interactions in determining physical properties of Helium-4 in porous media.
Specific heat per particle ($c_v$) of an ideal gas, in many occasions, is interpreted as energy fluctuation per particle ($\triangleε^2$) of the ideal gas through the relation: $\triangleε^2=kT^2c_v$, where $k$ is the Boltzmann constant and $T$ is the temperature. This relationship is true only in the classical limit, and deviates significantly in the quantum degenerate regime. We have analytically explored quantum to classical crossover of this relationship, in particular, for 3-D free Bose and Fermi gases. We also have explored the same for harmonically trapped cases. We have obtained a hump…
We analyze the dynamics of a Brownian gas in contact with a heat bath in which large temperature fluctuations occur. There are two distinct time scales present, one describes the decay of the fluctuations in the temperature and the other one is associated with the establishment of local equilibrium. Although the gas has reached local equilibrium, there exist large fluctuations in an intensive parameter (temperature) which break the thermodynamic equilibrium with the heat bath. Thus the decay of the fluctuations in the intensive parameter is larger than the characteristic time for the establish…
The ideal gas laws are derived from the democritian concept of corpuscles moving in vacuum plus a principle of simplicity, namely that these laws are independent of the laws of motion aside from the law of energy conservation. A single corpuscle in contact with a heat bath and submitted to a $z$ and $t$-invariant force $-w$ is considered, in which case corpuscle distinguishability is irrelevant. The non-relativistic approximation is made only in examples. Some of the end results are known but the method appears to be novel. The mathematics being elementary the present paper should facilitate t…
