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arXiv 0803.1291cond-mat.stat-mechcond-mat.soft
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硬球气体的碰撞统计

Collisional statistics of the hard-sphere gas

P. Visco, F. van Wijland, E. Trizac

摘要:

本文研究了处于平衡状态的硬球气体中自由飞行时间和碰撞次数的概率分布函数。与天真的期望不同,后者的数量不遵循泊松统计,即使在稀释限制,这是本分析的重点。相应的偏差都解决了数值和分析。在编写碰撞次数累积量的生成函数的方程时,我们遇到了我们的问题与先前引入的模型之间的完美映射:概率弹道湮灭过程[Coppex等人,E 69 11303(2004)]。我们利用这个类比来构建一个Monte-Carlo算法,能够在合理的计算时间内研究碰撞统计的渐近大时间行为。此外,我们的预测与分子动力学模拟和直接模拟蒙特卡罗技术的结果进行了对比。报告了一个极好的协议。

英文摘要:

We investigate the probability distribution function of the free flight time and of the number of collisions in a hard sphere gas at equilibrium. At variance with naive expectation, the latter quantity does not follow Poissonian statistics, even in the dilute limit which is the focus of the present analysis. The corresponding deviations are addressed both numerically and analytically. In writing an equation for the generating function of the cumulants of the number of collisions, we came across a perfect mapping between our problem and a previously introduced model: the probabilistic ballistic annihilation process [Coppex et al., Phys. Rev. E 69 11303 (2004)]. We exploit this analogy to construct a Monte-Carlo like algorithm able to investigate the asymptotically large time behavior of the collisional statistics within a reasonable computational time. In addition, our predictions are confronted against the results of Molecular Dynamics simulations and Direct Simulation Monte Carlo technique. An excellent agreement is reported.

机构、总结、中文摘要均由AI分析而来,可能存在错误,请以论文正文为准。

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