In this paper we reconsider the Mass Action Law (MAL) for the anomalous reversible reaction $A\rightleftarrows B$ with diffusion. We provide a mesoscopic description of this reaction when the transitions between two states $A$ and $B$ are governed by anomalous (heavy-tailed) waiting-time distributions. We derive the set of mesoscopic integro-differential equations for the mean densities of reacting and diffusing particles in both states. We show that the effective reaction rate memory kernels in these equations and the uniform asymptotic states depend on transport characteristics such as jumping rates. This is in contradiction with the classical picture of MAL. We find that transport can even induce an extinction of the particles such that the density of particles $A$ or $B$ tends asymptotically to zero. We verify analytical results by Monte Carlo simulations and show that the mesoscopic densities exhibit a transient growth before decay.
We address the two-dimensional bimolecular annihilation reaction $A + A \to \emptyset$ in the presence of random impurities. Impurities with sufficiently long-ranged interaction energies are known to lead to anomalous diffusion, $<r^2(t)> \sim t^{1-δ}$, in the absence of reaction. Applying renormalization group theory to a field theoretic description of this reaction, we find that this disorder also leads to anomalous kinetics in the long time limit: $c(t) \sim t^{δ-1}$. This kinetics results because the disorder forces the system into the (sub)diffusion controlled regime, in which the kinetic…
Reaction-diffusion equations deliver a versatile tool for the description of reactions in inhomogeneous systems under the assumption that the characteristic reaction scales and the scales of the inhomogeneities in the reactant concentrations separate. In the present work we discuss the possibilities of a generalization of reaction-diffusion equations to the case of anomalous diffusion described by continuous-time random walks with decoupled step length and waiting time probability densities, the first being Gaussian or Levy, the second one being an exponential or a power-law lacking the first …
We address via numerical simulation the two-dimensional bimolecular annihilation reaction $A + A \to \emptyset$ in the presence of quenched, random impurities. Renormalization group calculations have suggested that this reaction displays anomalous kinetics at long times, $c_{A}(t) \sim at^{δ-1}$, for certain types of topological or charged reactants and impurities. Both the exponent and the prefactor depend on the strength of disorder. The decay exponents determined from our simulations agree well with the values predicted by theory. The observed renormalization of the prefactor also agrees we…
We briefly review some aspects of the anomalous diffusion, and its relevance in reactive systems. In particular we consider {\it strong anomalous} diffusion characterized by the moment behaviour $\langle x(t)^q \rangle \sim t^{q ν(q)}$, where $ν(q)$ is a non constant function, and we discuss its consequences. Even in the apparently simple case $ν(2)=1/2$, strong anomalous diffusion may correspond to non trivial features, such as non Gaussian probability distribution and peculiar scaling of large order moments. When a reactive term is added to a normal diffusion process, one has a propagating f…
We study the dynamics of a radioactive species flowing through a porous material, within the Continuous-Time Random Walk (CTRW) approach to the modelling of stochastic transport processes. Emphasis is given to the case where radioactive decay is coupled to anomalous diffusion in locally heterogeneous media, such as porous sediments or fractured rocks. In this framework, we derive the distribution of the number of jumps each particle can perform before a decay event. On the basis of the obtained results, we compute the moments of the cumulative particle distribution, which can be then used to q…
We study a two-species reaction-diffusion system with the reactions $A+A\to (0, A)$ and $A+B\to A$, with general diffusion constants $D_A$ and $D_B$. Previous studies showed that for dimensions $d\leq 2$ the $B$ particle density decays with a nontrivial, universal exponent that includes an anomalous dimension resulting from field renormalization. We demonstrate via renormalization group methods that the $B$ particle correlation function has a distinct anomalous dimension resulting in the asymptotic scaling $C_{BB}(r,t) \sim t^ϕf(r/\sqrt{t})$, where the exponent $ϕ$ results from the renormaliza…
We investigate the kinetics of $A+B \to 0$ reaction with the local attractive interaction between opposite species in one spatial dimension. The attractive interaction leads to isotropic diffusions inside segregated single species domains, and accelerates the reactions of opposite species at the domain boundaries. At equal initial densities of $A$ and $B$, we analytically and numerically show that the density of particles ($ρ$), the size of domains ($\ell$), the distance between the closest neighbor of same species ($\ell_{AA}$), and the distance between adjacent opposite species ($\ell_{AB}$)…
We use random matrix theory to study the statistics of wave transport in one-dimensional random media with Levy disorder, in which waves perform Levy flights.
A number of results for reactions involving subdiffusive species all with the same anomalous exponent gamma have recently appeared in the literature and can often be understood in terms of a subordination principle whereby time t in ordinary diffusion is replaced by t^gamma. However, very few results are known for reactions involving different species characterized by different anomalous diffusion exponents. Here we study the reaction dynamics of a (sub)diffusive particle surrounded by a sea of (sub)diffusive traps in one dimension. We find rigorous results for the asymptotic survival probabil…
Levy flights and subdiffusive processes and their properties are discussed. We derive the space- and time-fractional transport equations, and consider their solutions in external potentials. An extensive list of references is included.
Anomalous transport in tilted periodic potentials is investigated within the framework of the fractional Fokker-Planck dynamics and the underlying continuous time random walk. The analytical solution for the stationary, anomalous current is obtained in closed form. We derive a universal scaling law for anomalous diffusion occurring in tilted periodic potentials. This scaling relation is corroborated with precise numerical studies covering wide parameter regimes and different shapes for the periodic potential, being either symmetric or ratchet-like ones.
We consider the coagulation dynamics A+A -> A and A+A <-> A and the annihilation dynamics A+A -> 0 for particles moving subdiffusively in one dimension. This scenario combines the "anomalous kinetics" and "anomalous diffusion" problems, each of which leads to interesting dynamics separately and to even more interesting dynamics in combination. Our analysis is based on the fractional diffusion equation.
We generalize the reaction-diffusion model A + B -> 0 in order to study the impact of an excess of A (or B) at the reaction front. We provide an exact solution of the model, which shows that linear response breaks down: the average displacement of the reaction front grows as the square-root of the imbalance. We argue that this model provides a highly simplified but generic framework to understand the square-root impact of large orders in financial markets.
In this paper we investigate the behavior of particles crossing a neat interface between two media. A Monte Carlo and analytical model, based on fractional derivatives, are presented and discussed in detail, together with a comparison. Anomalous and normal diffusion are consdered.
Deriving evolution equations accounting for both anomalous diffusion and reactions is notoriously difficult, even in the simplest cases. In contrast to normal diffusion, reaction kinetics cannot be incorporated into evolution equations modeling subdiffusion by merely adding reaction terms to the equations describing spatial movement. A series of previous works derived fractional reaction-diffusion equations for the spatiotemporal evolution of particles undergoing subdiffusion in one space dimension with linear reactions between a finite number of discrete states. In this paper, we first give a…
The expansion velocity profile in central heavy-ion reactions in the Fermi energy domain is examined. The radial expansion is non-hubblean and in the surface region it scales proportional to a higher exponent ($α> 1$) of the radius. The anomalous expansion velocity profile is accompanied by a power law nucleon density profile in the surface region. Both these features of central heavy-ion reactions disappear at higher energies, and the system follows a uniform Hubble expansion ($α\simeq 1$).
A recently developed non-linear fluctuating hydrodynamics theory has been quite successful in describing various features of anomalous energy transport. However the diffusion and the noise terms present in this theory are not derived from microscopic descriptions but rather added phenomenologically. We here derive these hydrodynamic equations with explicit calculation of the diffusion and noise terms in a one-dimensional model. We show that in this model the energy current scales anomalously with system size $L$ as $\sim L^{-2/3}$ in the leading order with a diffusive correction of order $\sim…
We computationally study the effects of binding kinetics to the channel wall, leading to transient immobility, on the diffusive transport of particles within narrow channels, that exhibit single-file diffusion (SFD). We find that slow binding kinetics leads to an anomalously slow diffusive transport. Remarkably, the scaled diffusivity $\hat{D}$ characterizing transport exhibits scaling collapse with respect to the occupation fraction $p$ of sites along the channel. We present a simple "cage-physics" picture that captures the characteristic occupation fraction $p_{scale}$ and the asymptotic $1/…
Many approaches to modelling reaction-diffusion systems with anomalous transport rely on deterministic equations and ignore fluctuations arising due to finite particle numbers. Starting from an individual-based model we use a generating-functional approach to derive a Gaussian approximation for this intrinsic noise in subdiffusive systems. This results in corrections to the deterministic fractional reaction-diffusion equations. Using this analytical approach, we study the onset of noise-driven quasi-patterns in reaction-subdiffusion systems. We find that subdiffusion can be conducive to the fo…
We analyze the dynamics of the ion-dipole pairing reaction in the two-dimensional Coulomb gas in the presence of disorder. Sufficiently singular disorder forces the critical temperature of the Kosterlitz-Thouless-Berezinskii fixed point to be non-universal. This disorder leads to anomalous ion pairing kinetics with a continuously variable decay exponent. Sufficiently strong disorder eliminates the transition altogether. For ions that are chemically reactive, anomalous kinetics with a continuously variable decay exponent also occurs in the high-temperature regime. The Coulomb interaction inhibi…
We show that the Turing patterns in reaction systems with subdiffusion can be replicated in an effective system with Markovian cross-diffusion. The effective system has the same Turing instability as the original system, and the same patterns. If particles are short-lived, the transient dynamics are captured as well. We use the cross-diffusive system to define effective diffusion coefficients for the system with anomalous transport, and we show how they can be used to efficiently describe the Turing instability. We also demonstrate that the mean squared displacement of a suitably defined ensem…
There is a high degree of compartmentalization in the living cell where various compartments sustain different chemical reactions and transport reactants among themselves. It is exactly such situation that is investigated. The main motivation behind this study is to understand interplay between reactions and transport in a geometries that are not compact. Typical examples of compact geometries are box, sphere, etc. On the other hand, a network made of containers C1,C2,...,CN and tubes is a typical example of space that is structured, and such non compact space is main focus on this study. The …
We here numerically investigate the heat transport behavior in a one-dimensional lattice with a soft-type (ST) anharmonic interparticle interaction. It is found that with the increase of system's temperature, while the introduction of ST anharmonicity softens phonons and decreases their velocities, this type of nonlinearity like its counterpart of hard type (HT), can still not be able to fully damp the longest wave phonons. Therefore, an anomalous temperature dependent heat transport with certain scaling properties similarly to those in the Fermi-Pasta-Ulam like systems with HT interactions ca…
We investigate the dynamics of a single tracer exploring a course of fixed obstacles in the vicinity of the percolation transition for particles confined to the infinite cluster. The mean-square displacement displays anomalous transport, which extends to infinite times precisely at the critical obstacle density. The slowing down of the diffusion coefficient exhibits power-law behavior for densities close to the critical point and we show that the mean-square displacement fulfills a scaling hypothesis. Furthermore, we calculate the dynamic conductivity as response to an alternating electric fie…
Anomalous diffusion has recently turned out to be almost ubiquitous in transport problems. When the physical properties of the medium where the transport process takes place are stationary and constant at each spatial location, anomalous transport has been successfully analyzed within the Continuous Time Random Walk (CTRW) model. In this paper, within a Monte Carlo approach to CTRW, we focus on the particle transport through two regions characterized by different physical properties, in presence of an external driving action constituted by an additional advective field, modeled within both the…
We introduce a fractional Klein-Kramers equation which describes sub-ballistic superdiffusion in phase space in the presence of a space-dependent external force field. This equation defines the differential L{é}vy walk model whose solution is shown to be non-negative. In the velocity coordinate, the probability density relaxes in Mittag-Leffler fashion towards the Maxwell distribution whereas in the space coordinate, no stationary solution exists and the temporal evolution of moments exhibits a competition between Brownian and anomalous contributions.
Anomalous (or non-Fickian) diffusion has been widely found in fluid reactive transport and the traditional advection diffusion reaction equation based on Fickian diffusion is proved to be inadequate to predict this anomalous transport of the reactive particle in flows. To capture the complex couple effect among advection, diffusion and reaction, and the energy-dependent characteristics of fluid reactive anomalous transport, in the present paper we analyze $A\rightarrow B$ reaction under anomalous diffusion with waiting time depending on the preceding jump length in linear flows, and derive the…
The single-species annihilation reaction $A + A \rightarrow\varnothing$ is studied in the presence of a random velocity field generated by the stochastic Navier-Stokes equation. The renormalization group is used to analyze the combined influence of the density and velocity fluctuations on the long-time behavior of the system. The direct effect of velocity fluctuations on the reaction constant appears only from the two- loop order, therefore all stable fixed points of the renormalization group and their regions of stability are calculated in the two-loop approximation in the two-parameter $(ε, …
Chiral active fluids are known to have anomalous transport properties such as the so-called odd viscosity. In this paper, we provide a microscopic mechanism for how such anomalous transport coefficients can emerge. We construct an Irving-Kirkwood-type stress tensor for chiral liquids and express the transport coefficients in terms of orientation-averaged intermolecular forces and distortions of the pair correlation function induced by a flow field. We then show how anomalous transport properties can be expected naturally due to the presence of a transverse component in the orientation-averaged…
We study a reaction diffusion system where we consider a non-gaussian process instead of a standard diffusion. If the process increments follow a probability distribution with tails approaching to zero faster than a power law, the usual qualitative behaviours of the standard reaction diffusion system, i.e., exponential tails for the reacting field and a constant front speed, are recovered. On the contrary if the process has power law tails, also the reacting field shows power law tail and the front speed increases exponentially with time. The comparison with other reaction-transport systems wh…
A numerical study of the role of anomalous diffusion in front propagation in reaction-diffusion systems is presented. Three models of anomalous diffusion are considered: fractional diffusion, tempered fractional diffusion, and a model that combines fractional diffusion and regular diffusion. The reaction kinetics corresponds to a Fisher-Kolmogorov nonlinearity. The numerical method is based on a finite-difference operator splitting algorithm with an explicit Euler step for the time advance of the reaction kinetics, and a Crank-Nicholson semi-implicit time step for the transport operator. The a…
We present a \textit{mesoscopic}description of the anomalous transport and reactions of particles in spiny dendrites. As a starting point we use two-state Markovian model with the transition probabilities depending on residence time variable. The main assumption is that the longer a particle survives inside spine, the smaller becomes the transition probability from spine to dendrite. We extend a linear model presented in [PRL, \textbf{101}, 218102 (2008)] and derive the nonlinear Master equations for the average densities of particles inside spines and parent dendrite by eliminating residence …
We study a two-species reaction-diffusion model where A+A->0, A+B->0 and B+B->0, with annihilation rates lambda0, delta0 > lambda0 and lambda0, respectively. The initial particle configuration is taken to be randomly mixed with mean densities nA(0) > nB(0), and with the two species A and B diffusing with the same diffusion constant. A field-theoretic renormalization group analysis suggests that, contrary to expectation, the large-time density of the minority species decays at the same rate as the majority when d<=2. Monte Carlo data supports the field theory prediction in d=1, while in d=2 the…
Reaction dynamics involving subdiffusive species is an interesting topic with only few known results, especially when the motion of different species is characterized by different anomalous diffusion exponents. Here we study the reaction dynamics of a (sub)diffusive particle surrounded by a sea of (sub)diffusive traps in one dimension. Under some reasonable assumptions we find rigorous results for the asymptotic survival probability of the particle in most cases, but have not succeeded in doing so for a particle that diffuses normally while the anomalous diffusion exponent of the traps is smal…
We consider viscous two-dimensional steady flows of incompressible fluids past doubly periodic arrays of solid obstacles. In a class of such flows, the autocorrelations for the Lagrangian observables decay in accordance with the power law, and the Fourier spectrum is neither discrete nor absolutely continuous. We demonstrate that spreading of the droplet of tracers in such flows is anomalously fast. Since the flow is equivalent to the integrable Hamiltonian system with 1 degree of freedom, this provides an example of integrable dynamics with long-range correlations, fractal power spectrum, and…
Continuous time random walk (CTRW) subdiffusion along with the associated fractional Fokker-Planck equation (FFPE) is traditionally based on the premise of random clock with divergent mean period. This work considers an alternative CTRW and FFPE description which is featured by finite mean residence times (MRTs) in any spatial domain of finite size. Transient subdiffusive transport can occur on a very large time scale $τ_c$ which can greatly exceed mean residence time in any trap, $τ_c\gg <τ>$, and even not being related to it. Asymptotically, on a macroscale transport becomes normal for $t\gg…
We present a theory for the coagulation reaction A+A -> A for particles moving subdiffusively in one dimension. Our theory is tested against numerical simulations of the concentration of $A$ particles as a function of time (``anomalous kinetics'') and of the interparticle distribution function as a function of interparticle distance and time. We find that the theory captures the correct behavior asymptotically and also at early times, and that it does so whether the particles are nearly diffusive or very subdiffusive. We find that, as in the normal diffusion problem, an interparticle gap respo…
In this review paper we aim at illustrating recent achievements in anomalous heat diffusion, while highlighting open problems and research perspectives. We briefly recall the main features of the phenomenon for low-dimensional classical anharmonic chains and outline some recent developments on perturbed integrable systems, and on the effect of long-range forces and magnetic fields. Some selected applications to heat transfer in material science at the nanoscale are described. In the second part, we discuss of the role of anomalous conduction on coupled transport and describe how systems with a…
This Chapter contains an overview of the effects of nonlinear interactions in selected problems of non-equilibrium statistical mechanics. Most of the emphasis is put on open setups, where energy is exchanged with the environment. With reference to a few models of classical coupled anharmonic oscillators, we review anomalous but general properties such as extremely slow relaxation processes, or non-Fourier heat transport.
We show that the generalized diffusion coefficient of a subdiffusive intermittent map is a fractal function of control parameters. A modified continuous time random walk theory yields its coarse functional form and correctly describes a dynamical phase transition from normal to anomalous diffusion marked by strong suppression of diffusion. Similarly, the probability density of moving particles is governed by a time-fractional diffusion equation on coarse scales while exhibiting a specific fine structure. Approximations beyond stochastic theory are derived from a generalized Taylor-Green-Kubo f…
We present results for the entire set of anomalous charge and heat transport coefficients for metallic systems in the presence of a finite-temperature heat bath. In realistic physical systems this necessitates the inclusion of inelastic dissipation mechanisms; relatively little is known theoretically about their effects on anomalous transport. Here we demonstrate how these dissipative processes are strongly intertwined with Berry-curvature physics. Our calculations are made possible by the introduction of a Caldeira-Leggett reservoir which allows us to avoid the sometimes-problematic device of…
We consider the coagulation dynamics A+A -> A and the annihilation dynamics A+A -> 0 for particles moving subdiffusively in one dimension, both on a lattice and in a continuum. The analysis combines the "anomalous kinetics" and "anomalous diffusion" problems, each of which leads to interesting dynamics separately and to even more interesting dynamics in combination. We calculate both short-time and long-time concentrations, and compare and contrast the continuous and discrete cases. Our analysis is based on the fractional diffusion equation and its discrete analog.
A classical wave-particle entity in the form of a millimetric walking droplet can emerge on the free surface of a vertically vibrating liquid bath. Such wave-particle entities have been shown to exhibit hydrodynamic analogs of quantum systems. Using an idealized theoretical model of this wave-particle entity in a tilted potential, we explore its transport behavior. The integro-differential equation of motion governing the dynamics of the wave-particle entity transforms to a Lorenz-like system of ordinary differential equations (ODEs) that drives the particle's velocity. Several anomalous trans…
Many experimentally relevant quantum spin chains are approximately integrable, and support long-lived quasiparticle excitations. A canonical example of integrable model of quantum magnetism is the XXZ spin chain, for which energy spreads ballistically, but, surprisingly, high-temperature spin transport can be diffusive or superdiffusive. We review the transport properties of this model using an intuitive quasiparticle picture that relies on the recently introduced framework of generalized hydrodynamics. We discuss how anomalous linear response properties emerge from hierarchies of quasiparticl…
Molecular dynamics simulations and nonequilibrium importance sampling are used to study the heat transport of low dimensional carbon lattices. For both carbon nanotubes and graphene sheets heat transport is found to be anomalous, violating Fourier's law of conduction with a system size dependent thermal conductivity and concomitant nonlinear temperature profiles. For carbon nanotubes, the thermal conductivity is found to increase as the square root of the length of the nanotube, while for graphene sheets the thermal conductivity is found to increase as the logarithm of the length of the sheet.…
Daily, are reported systems in nature that present anomalous diffusion phenomena due to irregularities of medium, traps or reactions process. In this scenario, the diffusion with traps or localised--reactions emerge through various investigations that include numerical, analytical and experimental techniques. In this work, we construct a model which involves a coupling of two diffusion equations to approach the random walkers in a medium with localised reaction point (or controlled diffusion). We present the exact analytical solutions to the model. In the following, we obtain the survival prob…
Absolute negative mobility is one of the most paradoxical forms of anomalous transport behaviour. At the first glance it contradicts the superposition principle and the second law of thermodynamics, however, its fascinating nature bridges nonlinearity and nonequlibrium in which these fundamental rules are no longer valid. We consider a paradigmatic model of the nonlinear Brownian motion in a driven periodic system which exhibits the absolute negative mobility. So far research on this anomalous transport feature has been limited mostly to the single case studies due to the fact that this model …
This review summarizes recent advances in our understanding of anomalous transport in spin chains, viewed through the lens of integrability. Numerical advances, based on tensor-network methods, have shown that transport in many canonical integrable spin chains -- most famously the Heisenberg model -- is anomalous. Concurrently, the framework of generalized hydrodynamics has been extended to explain some of the mechanisms underlying anomalous transport. We present what is currently understood about these mechanisms, and discuss how they resemble (and differ from) the mechanisms for anomalous tr…
Anomalous transport in one dimensional translation invariant Hamiltonian systems with short range interactions, is shown to belong in general to the KPZ universality class. Exact asymptotic forms for density-density and current-current time correlation functions and their Fourier transforms are given in terms of the Prähofer-Spohn scaling functions, obtained from their exact solution for the Polynuclear growth model. The exponents of corrections to scaling are found as well, but not so the coefficients. Mode coupling theories developed previously are found to be adequate for weakly nonlinear c…
