M. R. Tarbutt, J. J. Hudson, B. E. Sauer, E. A. Hinds
This paper is a chapter from an upcoming book on cold molecule physics. In it we describe techniques for the preparation and manipulation of cold molecules. We further describe techniques for applying said cold molecules to tests of fundamental physics.
机构、总结、中文摘要均由AI分析而来，可能存在错误，请以论文正文为准。
继续探索
Site-selective preparation and multi-state readout of molecules in optical tweezers
本文通过高保真Cs原子探测、位点选择性转动量子比特初始化及顺序解离成像，显著提升了光镊阵列中单个分子的态制备与测量能力。
We present experiments in which an ultra-cold sample of ammonia molecules is released from an electrostatic trap and recaptured after a variable time. It is shown that, by performing adiabatic cooling before releasing the molecules and adiabatic re-compression after they are recaptured, we are able to observe molecules even after more than 10 ms of free expansion. A coherent measurement performed during this time will have a statistical uncertainty that decreases approximately as the inverse of the square root of the expansion time. This offers interesting prospects for high-resolution spectro…
A strongly confined light field necessarily exhibits a local polarization that varies on a subwavelength scale. We demonstrate that a single optical mode of such kind can be used to selectively and simultaneously manipulate atomic ensembles that are less than a micron away from each other and equally coupled to the light field. The technique is implemented with an optical nanofiber that provides an evanescent field interface between a strongly guided optical mode and two diametric linear arrays of cesium atoms. Using this single optical mode, the two atomic ensembles can simultaneously be opti…
We study the growth dynamics of ordered structures of strongly interacting polar molecules in optical lattices. Using dipole blockade of microwave excitations, we map the system onto an interacting spin-1/2 model possessing ground states with crystalline order, and describe a way to prepare these states by non-adiabatically driving the transitions between molecular rotational levels. The proposed technique bypasses the need to cross a phase transition and allows for the creation of ordered domains of considerably larger size compared to approaches relying on adiabatic preparation.
We report on the preparation of a quantum degenerate mixture of $^{23}$Na$^{40}$K molecules and $^{40}$K atoms. A deeply degenerate atomic mixture of $^{23}$Na and $^{40}$K atoms with a large number ratio ($N_F/N_B\approx 6$) is prepared by the mode-matching loading of atoms from a cloverleaf-type magnetic trap into a large-volume horizontal optical dipole trap and evaporative cooling in a large-volume three-beam optical dipole trap. About $3.0\times10^4$ $^{23}$Na$^{40}$K ground-state molecules are created through magneto-association followed by stimulated adiabatic Raman passage. The 2D dens…
We report bunching, slowing, and acceleration of a supersonically cooled beam of diatomic hydroxyl radicals (OH). \textit{In situ} observation of laser-induced fluorescence along the beam propagation path allows for detailed characterization of longitudinal phase-space manipulation of OH molecules through the Stark effect by precisely sequenced inhomogeneous electric fields.
Preparing molecules at rest and in a highly pure quantum state is a long standing dream in chemistry and physics, so far achieved only for a select set of molecules in dedicated experimental setups. Here, a quantum-limited combination of mass spectrometry and Raman spectroscopy is proposed that should be applicable to a wide range of molecular ions. Excitation of electrons in the molecule followed by uncontrolled decay and branching into several lower energy states is avoided. Instead, the molecule is always connected to rotational states within the electronic and vibrational ground-state mani…
We show how to prepare a single molecular ion in a specific internal quantum state in a situation where the molecule is trapped and sympathetically cooled by an atomic ion and where its internal degrees of freedom are initially in thermal equilibrium with the surroundings. The scheme is based on conditional creation of correlation between the internal state of the molecule and the translational state of the collective motion of the two ions, followed by a projection measurement of this collective mode by atomic ion shelving techniques. State preparation in a large number of internal states is …
The atom-to-molecule conversion by the technique of optical Feshbach resonance in a magnetic lattice is studied in the mean-field approximation. For the case of shallow lattice, we give the dependence of the atom-to-molecule conversion efficiency on the tunnelling strength and the atomic interaction by taking a double-well as an example. We find that one can obtain a high atom-to-molecule conversion by tuning the tunnelling and interaction strengths of the system. For the case of deep lattice, we show that the existence of lattice can improve the atom-to-molecule conversion for certain initial…
Ultrafast preparation and strong-field ionization of an atomic Bell-like state
提出在飞秒尺度下从单个氧分子制备价电子磁量子数纠缠的类贝尔原子态的方案，并利用非绝热隧穿电离探测单双电离概率相关性，实验结果验证了该纠缠态。
We experimentally observe the action of multiple light pulses on the transverse motion of a continuous beam of fullerenes. The light potential is generated by non-resonant ultra-short laser pulses in perpendicular spatial overlap with the molecule beam. We observe a small but clear enhancement of the number of molecules in the center fraction of the molecular beam. Relatively low light intensity and short laser pulse duration prevent the molecule from fragmentation and ionization. Experimental results are confirmed by Monte Carlo trajectory simulations.
Laser cooling and trapping of atoms and atomic ions has led to numerous advances including the observation of exotic phases of matter, development of exquisite sensors and state-of-the-art atomic clocks. The same level of control in molecules could also lead to profound developments such as controlled chemical reactions and sensitive probes of fundamental theories, but the vibrational and rotational degrees of freedom in molecules pose a formidable challenge for controlling their quantum mechanical states. Here, we use quantum-logic spectroscopy (QLS) for preparation and nondestructive detecti…
In this paper, we present an electrode geometry for the manipulation of ultracold rovibrational ground state NaK molecules. The electrode system allows to induce a dipole moment in trapped diatomic NaK molecules with a magnitude up to $68 \%$ of their internal dipole moment along any direction in a given two-dimensional plane. The strength, the sign and the direction of the induced dipole moment is therefore fully tunable. Furthermore, the possibility to create strong electric field gradients provides the opportunity to address molecules in single layers of an optical lattice. The maximal rela…
The use of tapered optical fibers, i.e., optical nanofibers, for spectroscopy and the detection of small numbers of particles, such as neutral atoms or molecules, has been gaining ground in recent years. In this review, we briefly introduce the optical nanofiber, its fabrication and optical mode propagation within. We discuss recent progress on the integration of optical nanofibers into laser-cooled atom and vapor systems, paying particular attention to spectroscopy, cold atom cloud characterization and optical trapping schemes. Next, a natural extension on this work to molecules will be intro…
Chiral molecule candidates for trapped ion spectroscopy by ab initio calculations: from state preparation to parity violation
本文通过从头计算筛选出CHDBrI⁺和CHCaBrI⁺等适合囚禁离子光谱实验的手性分子离子候选体系，并计算其振动跃迁的宇称不守恒值，为首次测量手性分子PNC奠定基础。
Quantum logic control and entanglement in hybrid atom-molecule arrays
该研究提出了一种混合原子-分子平台中实现量子逻辑控制和测量基于状态制备的方案，通过快速高保真的原子-分子门和测量，克服分子-only平台的挑战，实现快速大规模纠缠生成。
Quantum state manipulation and cooling of ultracold molecules
本文综述了将超冷原子缔合为分子量子气体和直接激光冷却两种技术，它们使分子进入量子领域，实现了对分子内、外态的量子操控，为冷分子科学探索开辟了新空间。
Quantum particles can penetrate potential barriers by tunneling (1). If that barrier is rotating, the tunneling process is modified (2,3). This is typical for electrons in atoms, molecules or solids exposed to strong circularly polarized laser pulses (4,5). Here we measure how the transmission probability through a rotating tunnel depends on the sign of the magnetic quantum number m of the electron and thus on the initial sense of rotation of its quantum phase. We further show that the electron keeps part of that rotary motion on its way through the tunnel by measuring m-dependent modification…
The goal of the present article is to review the major developments that have led to the current understanding of molecule-field interactions and experimental methods for manipulating molecules with electromagnetic fields. Molecule-field interactions are at the core of several, seemingly distinct, areas of molecular physics. This is reflected in the organization of this article, which includes sections on Field control of molecular beams, External field traps for cold molecules, Control of molecular orientation and molecular alignment, Manipulation of molecules by non-conservative forces, Ultr…
Low-entropy arrays of microwave-shielded molecules prepared by interaction blockade
通过相互作用阻塞技术，实现微波屏蔽分子在运动基态的高保真度单分子制备，为大规模极性分子阵列在量子计算和精密测量中应用奠定基础。
Ultracold molecules offer entirely new possibilities for the control of quantum processes due to their rich internal structure. Recently, near quantum degenerate gases of molecules have been prepared in their rovibronic ground state. For future experiments, it is crucial to also control their hyperfine state. Here, we report the preparation of a rovibronic ground state molecular quantum gas in a single hyperfine state and in particular in the absolute lowest quantum state. The demonstrated and presented scheme is general for bialkali polar molecules and allows the preparation of molecules in a…
We explore coherent multi-photon processes in $^{87}$Rb$^{133}$Cs molecules using 3-level lambda and ladder configurations of rotational and hyperfine states, and discuss their relevance to future applications in quantum computation and quantum simulation. In the lambda configuration, we demonstrate the driving of population between two hyperfine levels of the rotational ground state via a two-photon Raman transition. Such pairs of states may be used in the future as a quantum memory, and we measure a Ramsey coherence time for a superposition of these states of 58(9) ms. In the ladder configur…
Ultracold molecules have experienced increasing attention in recent years. Compared to ultracold atoms, they possess several unique properties that make them perfect candidates for the implementation of new quantum-technological applications in several fields, from quantum simulation to quantum sensing and metrology. In particular, ultracold molecules of two-electron atoms (such as strontium or ytterbium) also inherit the peculiar properties of these atomic species, above all the possibility to access metastable electronic states via direct excitation on optical clock transitions with ultimate…
We demonstrate the measurement and manipulation of the temperature of cold CO molecules in a microchip environment. Through the use of time-resolved spatial imaging, we are able to observe the phase-space distribution of the molecules, and hence deduce the corresponding temperature. We do this both by observing the expansion of the molecular ensemble in time and through the use of numerical trajectory simulations. Furthermore, we demonstrate the adiabatic cooling of the trapped molecular sample and discuss this process.
The extraordinary success in laser cooling, trapping, and coherent manipulation of atoms has energized the efforts in extending this exquisite control to molecules. Not only are molecules ubiquitous in nature, but the control of their quantum states offers unparalleled access to fundamental constants and possible physics beyond the Standard Model. Quantum state manipulation of molecules can enable high-precision measurements including tests of fundamental symmetries and searches for new particles and fields. At the same time, their complex internal structure presents experimental challenges to…
We analyze a method for preparing low-entropy many-body states in isolated quantum optical systems of atoms, ions and molecules. Our approach is based upon shifting entropy between different regions of a system by spatially modulating the magnitude of the effective Hamiltonian. We conduct two case studies, on a topological spin chain and the spinful fermionic Hubbard model, focusing on the key question: can a "conformal cooling quench" remove sufficient entropy within experimentally accessible timescales? Finite temperature, time-dependent matrix product state calculations reveal that even mod…
Prospect for precision quantum logic spectroscopy of vibrational overtone transitions in molecular oxygen ions
本文提出分子氧离子的完整量子逻辑光谱学方案，利用协同囚禁的原子离子实现态制备与探测，并给出可用于检验质子-电子质量比变化的振动泛频跃迁耦合率。
Electric deflection measurements on liquid helium nanodroplets doped with individual polar molecules demonstrate that the cold superfluid matrix enables full orientation of the molecular dipole along the external field. This translates into a deflection force which is increased enormously by comparison with typical deflection experiments, and it becomes possible to measurably deflect neutral doped droplets with masses of tens to hundreds of thousands of Daltons. This approach permits preparation and study of continuous fluxes of fully oriented polar molecules and is broadly and generally appli…
Preparation of molecular quantum gas promises novel applications including quantum control of chemical reactions, precision measurements, quantum simulation and quantum information processing. Experimental preparation of colder and denser molecular samples, however, is frequently hindered by fast inelastic collisions that heat and deplete the population. Here we report the formation of two-dimensional Bose-Einstein condensates (BECs) of spinning $g-$wave molecules by inducing pairing interactions in an atomic condensate. The trap geometry and the low temperature of the molecules help reducing …
扫码添加微信好友，提出您的宝贵建议 👇
💡 备注请填写：网站反馈
发表机构由 AI 从论文文本抽取，如发现错误，欢迎反馈修正建议。