Polar molecules, with their rich internal structure, offer immense potential for fundamental physics, quantum technology, and controlled chemistry. However, their utilization is currently limited because of slow and imperfect state detection and weak dipolar interaction, limiting fast and large-scale entanglement generation. We propose and analyze a scheme for quantum logic control and measurement-based state preparation in a hybrid platform of polar molecules and neutral atoms. The method leverages fast, high-fidelity atom-molecule gates and high-fidelity atomic ancilla measurements to overcome the common challenges in molecule-only platforms, while preserving their diverse structural advantages. The proposed atom-molecule controlled-phase gate is based on resonant dipole-dipole exchange between a molecular rotational transition and an atomic Rydberg transition, rendering it three orders of magnitude faster than any direct molecule-molecule entangling gate. We further study several applications of our scheme including the preparation of molecular GHZ states for quantum enhanced precision measurements, the preparation of exotic molecular qudit states with topological order, and measurement-altered criticality. Our scheme is applicable to any polar molecule. It expands the paradigm of quantum logic control and paves the way to large-scale molecular entangled states. More generally, it highlights a concrete hybrid quantum system in which each qubit is utilized in an optimal way and where the measurement-based approach can yield a significant advantage in near-term devices.
Due to their intrinsic electric dipole moments and rich internal structure, ultracold polar molecules are promising candidate qubits for quantum computing and for a wide range of quantum simulations. Their long-lived molecular rotational states form robust qubits while the long-range dipolar interaction between molecules provides quantum entanglement. Using a molecular optical tweezer array, single molecules can be moved and separately addressed for qubit operations using optical and microwave fields, creating a scalable quantum platform. Here, we demonstrate long-range dipolar spin-exchange i…
In this work we show how constructing Wigner functions of heterogeneous quantum systems leads to new capability in the visualization of quantum states of atoms and molecules. This method allows us to display quantum correlations (entanglement) between spin and spatial degrees of freedom (spin-orbit coupling) and between spin degrees of freedom, as well as more complex combinations of spin and spatial entanglement for the first time. This is important as there is growing recognition that such properties affect the physical characteristics, and chemistry, of atoms and molecules. Our visualizatio…
Logic-qubit entanglement has attracted much attention in both quantum communication and quantum computation. Here, we present an efficient protocol to distill the logic-qubit entanglement with the help of cross-Kerr nonlinearity. This protocol not only can purify the logic bit-flip error and logic phase-flip error, but also can correct the physical bit-flip error completely. We use cross-Kerr nonlinearity to construct quantum nondemolition detectors. Our distillation protocol for logic-qubit entanglement may be useful for the practical applications in quantum information, especially in long-di…
Recently, the theoretical work of Fröwis and W. Dür (Phys. Rev. Lett. \textbf{106}, 110402 (2011)) and the experiment of Lu \emph{et al.} (Nat. Photon. \textbf{8}, 364 (2014)) both showed that the logic-qubit entanglement has its potential application in future quantum communication and quantum network. However, the entanglement will suffer from the noise and decoherence. In this paper, we will investigate the entanglement purification for logic-qubit entanglement. We show that both the bit-flip error and phase-flip error in logic-qubit entanglement can be well purified. Moreover, the bit-flip…
Decoherence is one of the main obstacles in long-distance quantum communication. Recently, the theoretical work of Fröwis and W. Dür (Phys. Rev. Lett. \textbf{106}, 110402 (2011)) and the experiment of Lu \emph{et al.} (Nat. Photon. \textbf{8}, 364 (2014)) both showed that the logic qubits entanglement say the concatenated Greenberger-Horne-Zeilinger (C-GHZ) state is more robust under decoherence. In this paper, we describe a protocol for Bell-state analysis for this logic qubits entanglement. This protocol can also be extended to the multipartite C-GHZ state analysis. Also, we discuss its app…
In this paper we investigate some entanglement properties for the Hydrogen molecule considered as a two interacting spin 1/2 (qubit) model. The entanglement related to the $H_{2}$ molecule is evaluated both using the von Neumann entropy and the Concurrence and it is compared with the corresponding quantities for the two interacting spin system. Many aspects of these functions are examinated employing in part analytical and, essentially, numerical techniques. We have compared analogous results obtained by Huang and Kais a few years ago. In this respect, some possible controversial situations ar…
Conventional information processors freely convert information between different physical carriers to process, store, or transmit information. It seems plausible that quantum information will also be held by different physical carriers in applications such as tests of fundamental physics, quantum-enhanced sensors, and quantum information processing. Quantum-controlled molecules in particular could transduce quantum information across a wide range of quantum-bit (qubit) frequencies, from a few kHz for transitions within the same rotational manifold, a few GHz for hyperfine transitions, up to a …
Logic-qubit entanglement is a promising resource in quantum information processing, especially in future large-scale quantum networks. In the paper, we put forward an efficient entanglement purification protocol (EPP) for nonlocal mixed logic entangled states with the bit-flip error in the logic qubits of the logic Bell state, resorting to the photon-atom interaction in low-quality (Q) cavity and atomic state measurement. Different from existing EPPs, this protocol can also purify the logic phase-flip error, and the bit-flip error and the phase-flip error in physic qubit. During the protocol, …
We propose an alternative scenario for the generation of entanglement between rotational quantum states of two polar molecules. This entanglement arises from dipole-dipole interaction, and is controlled by a sequence of laser pulses simultaneously exciting both molecules. We study the efficiency of the process, and discuss possible experimental implementations with cold molecules trapped in optical lattices or in solid matrices. Finally, various entanglement detection procedures are presented, and their suitability for these two physical situations is analyzed.
We investigate the entanglement properties of multiparticle systems, concentrating on the case where the entanglement is robust against disposal of particles. Two qubits -belonging to a multipartite system- are entangled in this sense iff their reduced density matrix is entangled. We introduce a family of multiqubit states, for which one can choose for any pair of qubits independently whether they should be entangled or not as well as the relative strength of the entanglement, thus providing the possibility to construct all kinds of ''Entanglement molecules''. For some particular configuration…
We, based on the photoassociation of fermion atoms into bosonic molecules, propose a scheme to create the steady entanglement between the atom state and the molecule state inside an optical lattice. The stability of entanglement state is guaranteed by sweeping the frequency of Ramman laser beam through resonance according to the second Demkov-Kunike (DK2) nonadiabatic transition model\cite{DK,models}. The probability amplitude of each components can be precisely controlled by adjusting the sweeping parameter.
A Rydberg molecule is composed of an outer electron that collides on the residual ionic core. Typical states of Rydberg molecules display entanglement between the outer electron and the core. In this work we quantify the average entanglement of molecular eigenstates and further investigate the time evolution of entanglement production from initially unentangled states. The results are contrasted with the underlying classical dynamics, obtained from the semiclassical limit of the core-electron collision. Our findings indicate that entanglement is not simply correlated with the degree of classic…
High-fidelity entanglement of polar molecules by dynamic geometric control
Harvard University（哈佛大学）；Harvard-MIT Center for Ultracold Atoms（哈佛-麻省理工学院超冷原子中心）；Massachusetts Institute of Technology（麻省理工学院）；Tsinghua University（清华大学）；Imperial College London（伦敦帝国理工学院）；Korea University（韩国大学）；University of Southern California（南加州大学）
We propose a scheme for concentrating nonmaximally pure and mixed polarization-entangled state of individual photon pairs. The scheme uses only simple linear optical elements and may be feasible within current optical technology.
We theoretically investigate the quantum correlations (in terms of concurrence of indistinguishable electrons) in a prototype molecular system (hydrogen molecule). With the assistance of the standard approximations of the linear combination of atomic orbitals and the configuration interaction methods we describe the electronic wavefunction of the ground state of the H2 molecule. Moreover, we managed to find a rather simple analytic expression for the concurrence (the most used measure of quantum entanglement) of the two electrons when the molecule is in its lowest energy. We have found that co…
Entanglement generated from polar molecules of two-dimensional rotation is investigated in a static electric field. The electric field modulates the rotational properties of molecules, leading to distinctive entanglement. The concurrence is used to estimate the degree of entanglement. When the electric field is applied parallel or perpendicular to the intermolecular direction, the concurrences reveal two overlapping features. Such a pronounced signature corresponds to the coexistence of all Bell-like states. The characteristics of Bell-like states and overlapping concurrences are kept independ…
We present a systematic approach to implementation of basic quantum logic gates operating on polar molecules in pendular states as qubits for a quantum computer. A static electric field prevents quenching of the dipole moments by rotation, thereby creating the pendular states; also, the field gradient enables distinguishing among qubit sites. Multi-Target Optimal Control Theory (MTOCT) is used as a means of optimizing the initial-to-target transition probability via a laser field. We give detailed calculations for the SrO molecule, a favorite candidate for proposed quantum computers. Our simul…
We introduce and study the concept of a reversible transfer of the quantum state of two internally-translationally entangled fragments, formed by molecular dissociation, to a photon pair. The transfer is based on intracavity stimulated Raman adiabatic passage and it requires a combination of processes whose principles are well established.
We propose a two-qubit gate based on dipolar exchange interactions between individually addressable ultracold polar molecules in an array of optical dipole traps. Our proposal treats the full Hamiltonian of the $^1Σ^+$ molecule NaCs, utilizing a pair of nuclear spin states as storage qubits. A third rotationally excited state with rotation-hyperfine coupling enables switchable dipolar exchange interactions between two molecules to generate an iSWAP gate. All three states are insensitive to external magnetic and electric fields. Impacts on gate fidelity due to coupling to other molecular states…
We present a logical type of proof of contextuality for a two-qubit state. We formulate a paradox that cannot be verified by a two-qubit system with local measurements while it is possible by using entanglement measurements. With our scheme we achieve $p_{\rm Hardy} \approx 0.167$, which is the highest probability obtained for a system of similar dimension. Our approach uses graph theory and the global exclusivity principle to give an interpretation of logical type of proofs of quantum correlations. We review the Hardy paradox and find connection to the KCBS inequality. We apply the same metho…
As it is well known, quantum entanglement is one of the most important features of quantum computing, as it leads to massive quantum parallelism, hence to exponential computational speed-up. In a sense, quantum entanglement is considered as an implicit property of quantum computation itself. But...can it be made explicit? In other words, is it possible to find the connective "entanglement" in a logical sequent calculus for the machine language? And also, is it possible to "teach" the quantum computer to "mimic" the EPR "paradox"? The answer is in the affirmative, if the logical sequent calculu…
Entangled states of two coupled polar molecules controlled by laser pulses are studied theoretically. Schmidt decomposition is used to measure the degree of entanglement. By varying the pulse shape of the applied laser, transition from regular to chaotic behavior may occur. This quantum feature is due to the inference of different phases. Moreover, the entanglement is also found to be enhanced by increasing the strength of the laser pulses.
Quantum trajectories are used to investigate the EPR-Bohr debate in a modern sense by examining entanglement and nonlocality. We synthesize a single "entanglement molecule" from the two scattered particles of the EPR experiment. We explicitly investigate the behavior of the entanglement molecule rather than the behaviors of the two scattered particles to gain insight into the EPR-Bohr debate. We develop the entanglement molecule's wave function in polar form and its reduced action, both of which manifest entanglement. We next apply Jacobi's theorem to the reduced action to generate the equatio…
Several emerging quantum technologies, including quantum networks, modular and fusion-based quantum computing, rely crucially on the ability to perform photonic Bell state measurements. Therefore, photon losses and the 50\% success probablity upper bound of Bell state measurements pose a critical limitation to photonic quantum technologies. Here, we develop protocols that overcome these two key challenges through logical encoding of photonic qubits. Our approach uses a tree graph state logical encoding, which can be produced deterministically with a few quantum emitters, and achieves near-dete…
We demonstrate that entanglement can persistently recur in an oscillating two-spin molecule that is coupled to a hot and noisy environment, in which no static entanglement can survive. The system represents a non-equilibrium quantum system which, driven through the oscillatory motion, is prevented from reaching its (separable) thermal equilibrium state. Environmental noise, together with the driven motion, plays a constructive role by periodically resetting the system, even though it will destroy entanglement as usual. As a building block, the present simple mechanism supports the perspective …
This work provides a complete description of entanglement properties between electrons inside coupled quantum molecules, nanoestructures which consist of two quantum dots. Each electron can tunnel between the two quantum dots inside the molecule, being also coupled by Coulomb interaction. First, it is shown that Bell states act as a natural basis for the description of this physical system, defining the characteristics of the energy spectrum and the eigenstates. Then, the entanglement properties of the eigenstates are discussed, shedding light on the roles of each physical parameters on experi…
Over the past two decades, several molecules have been explored as possible building blocks of a quantum computer, a device that would provide exponential speedups for a number of problems, including the simulation of large, strongly correlated chemical systems. Achieving strong interactions and entanglement between molecular qubits remains an outstanding challenge. Here, we show that the TbPc$_2$ single-molecule magnet has the potential to overcome this obstacle due to its sensitivity to electric fields stemming from the hyperfine Stark effect. We show how this feature can be leveraged to ach…
Quantum gates and entanglement based on dipole-dipole interactions of neutral Rydberg atoms are relevant to both fundamental physics and quantum information science. The precision and robustness of the Rydberg-mediated entanglement protocols are the key factors limiting their applicability in experiments and near-future industry. There are various methods for generating entangling gates by exploring the Rydberg interactions of neutral atoms, each equipped with its own strengths and weaknesses. The basics and tricks in these protocols are reviewed, with specific attention paid to the achievable…
We investigate the generation of entanglement through a quantum dot molecule under the influence of vibrational phonon modes in a bias voltage junction. The molecular quantum dot system is realized by coupled quantum dots inside a suspended carbon nanotube. We consider the dynamical entanglement as a function of bias voltage and temperature by taking into account the electron-phonon interaction. In order to generate the robust entanglement between quantum dots and preserve it to reach the maximal achievable amount steadily, we introduce an asymmetric coupling protocol and apply the easy tunabl…
Quantum entanglement is a concept commonly used with reference to the existence of certain correlations in quantum systems that have no classical interpretation. It is a useful resource to enhance the mutual information of memory channels or to accelerate some quantum processes as, for example, the factorization in Shor's Algorithm. Moreover, entanglement is a physical observable directly measured by the von Neumann entropy of the system. We have used this concept in order to give a physical meaning to the electron correlation energy in systems of interacting electrons. The electronic correlat…
We investigate theoretically the dissociative ionization of a H2+ molecule using two ultrashort laser (pump-probe) pulses. The pump pulse prepares a dissociating nuclear wave packet on an ungerade surface of H2+. Next, an UV (or XUV) probe pulse ionizes this dissociating state at large (R = 20 - 100 bohr) internuclear distance. We calculate the momenta distributions of protons and photoelectrons which show a (two-slit-like) interference structure. A general, simple interference formula is obtained which depends on the electron and protons momenta, as well as on the pump-probe delay on the puls…
An array of ultracold polar molecules trapped in an external electric field is regarded as a promising carrier of quantum information. Under the action of this field, molecules are compelled to undergo pendular oscillations by the Stark effect. Particular attention has been paid to the influence of intrinsic decoherence on the model of linear polar molecular pendular states, thereby we evaluate the tripartite entanglement with negativity, as well as fidelity of bipartite quantum systems for input and output signals using electric dipole moments of polar molecules as qubits. According to this s…
We solve the Jaynes-Cummings Hamiltonian with time-dependent coupling parameters under dipole and rotating-wave approximation for a three-dimensional (3D) photonic crystal (PC) single mode cavity with a sufficiently high quality (Q) factor. We then exploit the results to show how to create a maximally entangled state of two atoms, and how to implement several quantum logic gates: a dual-rail Hadamard gate, a dual-rail NOT gate, and a SWAP gate. The atoms in all of these operations are syncronized, which is not the case in previous studies [1,2] in PCs. Our method has the potential for extensio…
We report on the usage of a linear optics phase gate for distinguishing all four Bell states simultaneously in a quantum teleportation and entanglement swapping protocol. This is demonstrated by full state tomography of the one and two qubit output states of the two protocols, yielding average state fidelities of about 0.83 and 0.77, respectively. In addition, the performance of the teleportation channel is characterised by quantum process tomography. The non classical properties of the entanglement swapping output states are further confirmed by the violation of a CHSH-type Bell inequality of…
We expose the information flow capabilities of pure bipartite entanglement as a theorem -- which embodies the exact statement on the `seemingly acausal flow of information' in protocols such as teleportation. We use this theorem to re-design and analyze known protocols (e.g. logic gate teleportation and entanglement swapping) and show how to produce some new ones (e.g. parallel composition of logic gates). We also show how our results extend to the multipartite case and how they indicate that entanglement can be measured in terms of `information flow capabilities'. Ultimately, we propose a sch…
Proposals for quantum computing using rotational states of polar molecules as qubits have previously considered only diatomic molecules. For these the Stark effect is second-order, so a sizable external electric field is required to produce the requisite dipole moments in the laboratory frame. Here we consider use of polar symmetric top molecules. These offer advantages resulting from a first-order Stark effect, which renders the effective dipole moments nearly independent of the field strength. That permits use of much lower external field strengths for addressing sites. Moreover, for a parti…
Genuine Multipartite Entanglement between Logical Qubits via Cross-Code Lattice Surgery
Universität Innsbruck（因斯布鲁克大学）；Technische Universität Wien（维也纳工业大学）；Institute for Theoretical Physics, University of Innsbruck（因斯布鲁克大学理论物理研究所）；neQxt GmbH（neQxt有限公司）；Alpine Quantum Technologies GmbH（阿尔卑斯量子技术有限公司）
Implementing a scalable quantum information processor using polar molecules in optical lattices requires precise control over the long-range dipole-dipole interaction between molecules in selected lattice sites. We present here a scheme using trapped open-shell $^2Σ$ polar molecules that allows dipolar exchange processes between nearest and next-nearest neighbors to be controlled to construct a generalized transverse Ising spin Hamiltonian with tunable $XX$, $YY$ and $XY$ couplings in the rotating frame of the driving lasers. The scheme requires a moderately strong bias magnetic field with nea…
The occupancies and entropic entanglement measures for the ground state of two particles in a two-dimensional harmonic anisotropic trap are studied. We implement a method to study the large interaction strength limit for different short- and long-range interaction potentials that allows to obtain the exact entanglement spectrum and several entropies. We show that for long-range interactions, the von Neumann, min-entropy and the family of Rényi entropies remain finite for the anisotropic traps and diverge logarithmically for the isotropic traps. In the short-range interaction case the entanglem…
We describe how to implement quantum logic operations in a silicon-based quantum computer with phosphorus atoms serving as qubits. The information is stored in the states of nuclear spins and the conditional logic operations are implemented through the electron spins using nuclear-electron hyperfine and electron-electron exchange interactions. The electrons in our computer should stay coherent only during implementation of one Control-Not gate. The exchange interaction is constant and selective excitations are provided by a magnetic field gradient. The quantum logic operations are implemented …
Lattice surgery for near-term experimental logical qubit entanglement creation in planar architectures
Institute for Theoretical Nanoelectronics (PGI-2), Forschungszentrum Jülich（于利希研究中心理论纳米电子学研究所）；Institute for Quantum Information, RWTH Aachen University（亚琛工业大学量子信息研究所）；Department of Physics, ETH Zurich（苏黎世联邦理工学院物理系）；ETH Zurich - PSI Quantum Computing Hub, Paul Scherrer Institute（保罗谢勒研究所苏黎世联邦理工学院-PSI量子计算中心）；Quantum Center, ETH Zurich（苏黎世联邦理工学院量子中心）
We investigate the influence of vibrational phonon modes on the entanglement through a quantum dot molecule under the bias voltage-driven field. The molecular quantum dot system can be realized by coupled quantum dots in the middle of the suspended carbon nanotube. This system would be described by the Anderson-Holstein model and also can be analyzed by the polaron master equation in Markovian regime. In the presence of electron-phonon interaction, we study the entanglement as a function of bias voltage and temperature. Despite entanglement degradation because of phonon decoherence, we employ …
We investigate the dynamics of entanglement in the excitation transfer through a chain of interacting molecules. In the case of two-molecule coupled to noisy environments we show that entanglement can be further enhanced if the distance between the molecules is oscillating. Our results demonstrate that motional effect plays a constructive role on quantum entanglement in the dynamics of excitation transfer. This mechanism might provide useful guideline for designing artificial systems to battle against decoherence.
We present a scheme to achieve maximally entangled states, controlled phase-shift gate, and SWAP gate for two superconducting-quantum-interference-device (SQUID) qubits, by placing SQUIDs in a microwave cavity. We also show how to transfer quantum information from one SQUID qubit to another. In this scheme, no transfer of quantum information between the SQUIDs and the cavity is required, the cavity field is only virtually excited and thus the requirement on the quality factor of the cavity is greatly relaxed.
We study entanglement and fidelity of a two-qubit system when a noisy holonomic, non-Abelian, transformation is applied to one of them. The source of noise we investigate is of two types: one due to a stochastic error representing an imprecise control of the fields driving the evolution; the other due to an interaction between the two near qubits. The peculiar level structure underlying the holonomic operator leads us to introduce the reduced logical entanglement which is the fraction of entanglement in the logical space. The comparison between entanglement and fidelity shows how they are diff…
