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arXiv 0708.4256cond-mat.supr-con
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取向Na_{x}(H_{3} O)_{z} CoO_{2} \cdot O超导体的上临界场

Upper critical field of aligned Na_{x}(H_{3}O)_{z}CoO_{2}\cdot yH_{2}O superconductor by magnetization measurement

Zhi Ren, Chunmu Feng, Zhu'an Xu, Minghu Fang, Guanghan Cao

摘要:

我们测量了磁场平行于CoOPDMATHABMS层的定向Na $_{x}$(HPDMATHABMO O)$_{z}$ CoO $_{2}\cdot y$ HPDMATHABMR O超导体的上临界场$H_{c2}$的磁化强度。正常态磁化强度$M(H,T)$的温度依赖部分可以用布里渊函数很好地标度,表明杂质矩的存在。通过减去杂质磁矩的贡献,一个定义良好的超导抗磁性的开始允许在现场超导转变温度$T_{c}$($H$)准确地确定。在8特斯拉的外加磁场下,没有观察到超导转变到1.9 K。结果表明,$H^{\|ab}_{c2}(0)$值正好在泡利顺磁极限之内,支持水合钴超导体的自旋单重态超导性。此外,在$H^{\|ab}_{c2}-T$相图中$T_{c}$附近的向上弯曲被证实是固有的。讨论了异常的可能来源。

英文摘要:

We present magnetization measurements for the upper critical field $H_{c2}$ on aligned Na$_{x}$(H$_{3}$O)$_{z}$CoO$_{2}\cdot y$H$_{2}$O superconductors with magnetic field parallel to CoO$_2$ layers. The temperature-dependent part of the normal-state magnetization $M(H,T)$ can be well scaled with Brillouin function, suggesting the existence of impurity moments. By subtracting the contribution of the magnetic impurity moments, a well defined onset of superconducting diamagnetism allows the in-field superconducting transition temperature $T_{c}$($H$) accurately determined. No superconducting transition was observed down to 1.9 K under an applied field of 8 Tesla. The result suggests that the $H^{\|ab}_{c2}(0)$ value is just within the Pauli paramagnetic limit, supporting spin-singlet superconductivity in the cobalt oxyhydrate superconductor. Additionally, the upward curvature near $T_{c}$ in the $H^{\|ab}_{c2}-T$ phase diagram was confirmed to be intrinsic. Possible origin of the anomaly was discussed.

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