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arXiv 0705.3080cond-mat.str-elcond-mat.mtrl-sci
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Mo掺杂对铁磁锰氧化物La0 .7Ca0.3MnO3中Mn位的影响

Effect of Mo doping for the Mn site in the ferromagnetic manganite La0.7Ca0.3MnO3

G. Narsinga Rao, J. W. Chen

摘要:

研究了Mo掺杂的钙钛矿结构La_(0.7)Ca_(0.3)Mn_(1-x)Mo_xO_3(x < 0.1)的结构、电子和磁性。观察到与Mo掺杂的电阻率和晶格参数的显着增加。居里温度Tc和相关的金属-绝缘体转变Tp的边际下降进行了观察。磁化强度数据显示,长程铁磁有序持续在所有研究的样品和饱和力矩线性下降,x的增加。在Tc附近的最佳掺杂值x = 0.05的钼掺杂的化合物中的磁电阻的增强被观察到。实验结果表明,Mn ~(2+)离子与Mo ~(6+)离子在Mo掺杂体系中相互诱导,Mn ~(4+)/2+-O-Mn ~(3+)离子间存在较强的FM耦合。

英文摘要:

The structure, electronic, and magnetic properties of the Mo-doped perovskite La0.7Ca0.3Mn1-xMoxO3 (x < 0.1) have been studied. A significant increase in resistivity and lattice parameters were observed with Mo doping. A marginal decrease in the Curie temperature Tc and the associated metal-insulator transition Tp were observed. Magnetization data reveal that long-range ferromagnetic ordering persists in all samples studied and the saturation moment decreases linearly as x increases. Enhancement in magnetoresistance at near Tc in the Mo-doped compounds with an optimum doping value x = 0.05 was observed. The overall experimental results can be explained by considering the induced Mn2+ ions with Mo6+ in the Mo-doped systems, with the strong FM coupling between Mn4+/2+- O - Mn3+.

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