We present a complete analytical solution of a system of Potts spins on a random k-regular graph in both the canonical and microcanonical ensembles, using the Large Deviation Cavity Method (LDCM). The solution is shown to be composed of three different branches, resulting in an non-concave entropy function.The analytical solution is confirmed with numerical Metropolis and Creutz simulations and our results clearly demonstrate the presence of a region with negative specific heat and, consequently, ensemble inequivalence between the canonical and microcanonical ensembles.
Systems with long range interactions in general are not additive, which can lead to an inequivalence of the microcanonical and canonical ensembles. The microcanonical ensemble may show richer behavior than the canonical one, including negative specific heats and other non-common behaviors. We propose a classification of microcanonical phase transitions, of their link to canonical ones, and of the possible situations of ensemble inequivalence. We discuss previously observed phase transitions and inequivalence in self-gravitating, two-dimensional fluid dynamics and non-neutral plasmas. We note a…
We consider a system of globally coupled rotors, described by a set of Langevin equations, and examine stability of the incoherent phase. The corresponding Fokker-Planck equation, providing a unified description of microcanonical and canonical ensembles, bears a few solutions, depending upon the ensemble. It is found that the stability of each solution varies differently with the temperature, revealing the inequivalence between the two ensembles. This also suggests a physical explanation of the quasi-stationarity observed in recent numerical results.
We investigate the relation between various statistical ensembles of finite systems. If ensembles differ at the level of fluctuations of the order parameter, we show that the equations of states can present major differences. A sufficient condition for this inequivalence to survive at the thermodynamical limit is worked out. If energy consists in a kinetic and a potential part, the microcanonical ensemble does not converge towards the canonical ensemble when the partial heat capacities per particle fulfill the relation $c_{k}^{-1}+c_{p}^{-1}<0$.
Ensemble inequivalence has been observed in several systems. In particular it has been recently shown that negative specific heat can arise in the microcanonical ensemble in the thermodynamic limit for systems with long-range interactions. We display a connection between such behaviour and a mean-field like structure of the partition function. Since short-range models cannot display this kind of behaviour, this strongly suggests that such systems are necessarily non-mean field in the sense indicated here. We further show that a broad class of systems with non-integrable interactions are indeed…
We explore ensemble inequivalence in long-range interacting systems by studying an XY model of classical spins with ferromagnetic and nematic coupling. We demonstrate the inequivalence by mapping the microcanonical phase diagram onto the canonical one, and also by doing the inverse mapping. We show that the equilibrium phase diagrams within the two ensembles strongly disagree within the regions of first-order transitions, exhibiting interesting features like temperature jumps. In particular, we discuss the coexistence and forbidden regions of different macroscopic states in both the phase diag…
Ensemble inequivalence has been observed in several systems. In particular it has been recently shown that negative specific heat can arise in the microcanonical ensemble in the thermodynamic limit for systems with long-range interactions. We display a connection between such behaviour and a mean-field like structure of the partition function. Since short-range models cannot display this kind of behaviour, this strongly suggests that such systems are necessarily non-mean field in the sense indicated here. We illustrate our results showing an application to the Blume-Emery-Griffiths model. We f…
It is well known that systems with long-range interactions may exhibit different phase diagrams when studied within two different ensembles. In many of the previously studied examples of ensemble inequivalence, the phase diagrams differ only when the transition in one of the ensembles is first order. By contrast, in a recent study of a generalized ABC model, the canonical and grand-canonical ensembles of the model were shown to differ even when they both exhibit a continuous transition. Here we show that the order of the transition where ensemble inequivalence may occur is related to the symme…
The classical wave-particle Hamiltonian is considered in its generalized version, where two modes are assumed to interact with the co-evolving charged particles. The equilibrium statistical mechanics solution of the model is worked out analytically, both in the canonical and the microcanonical ensembles. The competition between the two modes is shown to yield ensemble inequivalence, at variance with the standard scenario where just one wave is allowed to develop. As a consequence, both temperature jumps and negative specific heat can show up in the microcanonical ensemble. The relevance of the…
The relation between thermodynamic phase transitions in classical systems and topology changes in their state space is discussed for systems in which equivalence of statistical ensembles does not hold. As an example, the spherical model with mean field-type interactions is considered. Exact results for microcanonical and canonical quantities are compared with topological properties of a certain family of submanifolds of the state space. Due to the observed ensemble inequivalence, a close relation is expected to exist only between the topological approach and one of the statistical ensembles. I…
The thermodynamics of the discrete nonlinear Schrödinger equation in the vicinity of infinite temperature is explicitly solved in the microcanonical ensemble by means of large-deviation techniques. A first-order phase transition between a thermalized phase and a condensed (localized) one occurs at the infinite-temperature line. Inequivalence between statistical ensembles characterizes the condensed phase, where the grand-canonical representation does not apply. The control over finite size corrections of the microcanonical partition function allows to design an experimental test of delocalized…
We present a theoretical description for the equilibrium states of a large class of models of two-dimensional and geophysical flows, in arbitrary domains. We account for the existence of ensemble inequivalence and negative specific heat in those models, for the first time using explicit computations. We give exact theoretical computation of a criteria to determine phase transition location and type. Strikingly, this criteria does not depend on the model, but only on the domain geometry. We report the first example of bicritical points and second order azeotropy in the context of systems with l…
For studying the thermodynamic properties of systems using statistical mechanics we propose an ensemble that lies in between the familiar canonical and microcanonical ensembles. From a comparative study of these ensembles we conclude that all these ensembles may not yield the same results even in the thermodynamic limit except at high temperatures. An investigation of the coupling between systems suggest that the state of thermodynamic equilibrium is a special case of statistical equilibrium. As a byproduct of this analysis we have obtained a general form for probability density function in an…
We consider a paradigmatic model describing the one-dimensional motion of $N$ rotators coupled through a mean-field interaction, and subject to the perturbation of an external magnetic field. The latter is shown to significantly alter the system behaviour, driving the emergence of ensemble inequivalence in the out-of-equilibrium phase, as signalled by a negative (microcanonical) magnetic susceptibility. The thermodynamic of the system is analytically discussed, building on a maximum entropy scheme justified from first principles. Simulations confirm the adequacy of the theoretical picture. Ens…
Ensemble Inequivalence in Long-Range Quantum Spin Systems
ETH Zürich（苏黎世联邦理工学院）；Weizmann Institute of Science（魏茨曼科学研究所）；Istituto dei Sistemi Complessi, Consiglio Nazionale delle Ricerche（意大利国家研究委员会复杂系统研究所）；INFN Sezione di Firenze（佛罗伦萨国家核物理研究所）；SISSA（的里雅斯特国际高等研究院）
Equilibrium Statistical Mechanics is undoubtedly a cornerstone for the description of many particle systems. The common interpretation is based on ensemble theory as put forward by Gibbs, alongside the basic assumptions that different ensembles are equivalent, i.~e.\ the properties of the system can equally be obtained in any ensemble with the same results. However, the simplicity of the argument that provides such equivalence, mathematically grounded by the existence of Legendre transformation between the ensembles and the existence of its inverse, may break down for physical systems with lon…
We study the global phase diagram of the infinite range Blume-Emery-Griffiths model both in the canonical and in the microcanonical ensembles. The canonical phase diagram is known to exhibit first order and continuous transition lines separated by a tricritical point. We find that below the tricritical point, when the canonical transition is first order, the phase diagrams of the two ensembles disagree. In this region the microcanonical ensemble exhibits energy ranges with negative specific heat and temperature jumps at transition energies. These results can be extended to weakly decaying noni…
We study stochastic processes in which the trajectories are constrained so that the process realises a large deviation of the unconstrained process. In particular we consider stochastic bridges and the question of inequivalence of path ensembles between the microcanonical ensemble, in which the end points of the trajectory are constrained, and the canonical or s ensemble in which a bias or tilt is introduced into the process. We show how ensemble inequivalence can be manifested by the phenomenon of temporal condensation in which the large deviation is realised in a vanishing fraction of the du…
Ensemble inequivalence has been previously displayed only for long-range interacting systems with non-extensive energy. In order to perform the thermodynamic limit, such systems require an unphysical, so-called, Kac rescaling of the coupling constant. We here study models defined on long-range random networks, which avoid such a rescaling. The proposed models have an extensive energy, which is however non-additive. For such long-range random networks, pairs of sites are coupled with a probability decaying with the distance $r$ as $1/r^δ$. In one dimension and with $0 \leq δ<1$, surface energy …
The canonical phase diagram of the Blume-Emery-Griffiths (BEG) model with infinite-range interactions is known to exhibit a fourth order critical point at some negative value of the bi-quadratic interaction $K<0$. Here we study the microcanonical phase diagram of this model for $K<0$, extending previous studies which were restricted to positive $K$. A fourth order critical point is found to exist at coupling parameters which are different from those of the canonical ensemble. The microcanonical phase diagram of the model close to the fourth order critical point is studied in detail revealing s…
We study inequivalence of canonical and microcanonical ensembles in the mean-field Blume-Emery-Griffiths model. This generalizes previous results obtained for the Blume-Capel model. The phase diagram strongly depends on the value of the biquadratic exchange interaction K, the additional feature present in the Blume-Emery-Griffiths model. At small values of K, as for the Blume-Capel model, lines of first and second order phase transitions between a ferromagnetic and a paramagnetic phase are present, separated by a tricritical point whose location is different in the two ensembles. At higher val…
Mean-field models, while they can be cast into an {\it extensive} thermodynamic formalism, are inherently {\it non additive}. This is the basic feature which leads to {\it ensemble inequivalence} in these models. In this paper we study the global phase diagram of the infinite range Blume-Emery-Griffiths model both in the {\it canonical} and in the {\it microcanonical} ensembles. The microcanonical solution is obtained both by direct state counting and by the application of large deviation theory. The canonical phase diagram has first order and continuous transition lines separated by a tricrit…
A generalization of the ABC model, a one-dimensional model of a driven system of three particle species with local dynamics, is introduced, in which the model evolves under either (i) density-conserving or (ii) nonconserving dynamics. For equal average densities of the three species, both dynamical models are demonstrated to exhibit detailed balance with respect to a Hamiltonian with long-range interactions. The model is found to exhibit two distinct phase diagrams, corresponding to the canonical (density-conserving) and grand canonical (density nonconserving) ensembles, as expected in long-ra…
It is demonstrated that in many thermodynamic textbooks the equivalence of the different ensembles is achieved in the thermodynamic limit. In this present work we remark the inequivalence of microcannonical and canonical ensembles in a finite ultracold system at low energies. We calculate the microcanonical momentum distribution function (MDF) in a system of identical fermions (bosons). We find that, the microcanonical MDF deviates from the canonical one, which is the Fermi-Dirac (Bose-Einstein) function, in a finite system at low energies where the single-particle density of states and its in…
We present a detailed account of a first-order localization transition in the Discrete Nonlinear Schrödinger Equation, where the localized phase is associated to the high energy region in parameter space. We show that, due to ensemble inequivalence, this phase is thermodynamically stable only in the microcanonical ensemble. In particular, we obtain an explicit expression of the microcanonical entropy close to the transition line, located at infinite temperature. This task is accomplished making use of large-deviation techniques, that allow us to compute, in the limit of large system size, also…
We investigate the ensemble inequivalence of the spherical spin glass model with nonlinear interactions of polynomial order $p$. This model is solved exactly for arbitrary $p$ and is shown to have first-order phase transitions between the paramagnetic and spin glass or ferromagnetic phases for $p \geq 5$. In the parameter region around the first-order transitions, the solutions give different results depending on the ensemble used for the analysis. In particular, we observe that the microcanonical specific heat can be negative and the phase may not be uniquely determined by the temperature.
We investigate a model of globally coupled conservative oscillators. Two different algebraic potentials are considered that display in the canonical ensemble either a second ($ϕ^{4}$) or both a second and a first order phase transition separated by tricritical points ($ϕ^{6}$). The stability of highly clustered states appearing in the low temperature/energy region is studied both analytically and numerically for the $ϕ^{4}$-model. Moreover, long-lived out-of-equilibrium states appear close to the second order phase transition when starting with "water-bag" initial conditions, in analogy with w…
In systems with long-range interactions, since energy is a non-additive quantity, ensemble inequivalence can arise: it is possible that different statistical ensembles lead to different equilibrium descriptions, even in the thermodynamic limit. The microcanonical ensemble should be considered the physically correct equilibrium distribution as long as the system is isolated. The canonical ensemble, on the other hand, can always be defined mathematically, but it is quite natural to wonder to which physical situations it does correspond. We show numerically and, in some cases, analytically, that …
In bulk systems the calculation of the main thermodynamic quantities leads to the same expectation values in the thermodynamic limit, regardless of the choice of the statistical ensemble. Single linear molecules can be still regarded as statistical systems, where the thermodynamic limit is represented by infinitely long chains. The question of equivalence between different ensembles is not at all obvious and has been addressed in the literature, with sometimes contradicting conclusions. We address this problem by studying the scaling properties of the ensemble difference for two different chai…
We consider the one-dimensional driven ABC model under particle-conserving and particle-non-conserving processes. Two limiting cases are studied: (a) the rates of the non-conserving processes are vanishingly slow compared with the conserving processes in the thermodynamic limit and (b) the two rates are comparable. For case (a) we provide a detailed analysis of the phase diagram and the large deviations function of the overall density, G(r). The phase diagram of the non-conserving model, derived from G(r), is found to be different from the conserving one. This difference, which stems from the …
We study the role of fluctuations in single molecule experimental measurements of force-extension curves. We use the Worm Like Chain (WLC) model to bring out the connection between the Helmholtz ensemble characterized by the Free Energy and the Gibbs ensemble characterized by the Free Energy . We consider the rigid rod limit of the WLC model as an instructive special case to bring out the issue of ensemble inequivalence. We point out the need for taking into account the free energy of transition when one goes from one ensemble to another. We also comment on the ``phase transition'' noticed in …
Single particle tracking has become a standard tool to investigate diffusive properties, especially in small systems such as biological cells. Usually the resulting time series are analyzed in terms of time averages over individual trajectories. Here we study confined normal as well as anomalous diffusion modeled by fractional Brownian motion and the fractional Langevin equation, and show that even for such ergodic systems time-averaged quantities behave differently from their ensemble averaged counterparts, irrespective of how long the measurement time becomes. Knowledge of the exact behavior…
We study the effect that randomness has on long-range interacting systems by using the ferromagnetic Ising model with $p$-body interactions in random fields. The case with p=2 yields a phase diagram similar to that of previously studied models and shows known features that inequivalence of the canonical and microcanonical ensembles brings with it, for example negative specific heat in a narrow region of the phase diagram. When p>2, however, the canonical phase diagram is completely different from the microcanonical one. The temperature does not necessarily determine the microcanonical phases u…
We use large-scale exact diagonalization to study the quantum Ising chain in a transverse field with long-range power-law interactions decaying with exponent $α$. We numerically study various probes for quantum chaos and eigenstate thermalization {on} the level of eigenvalues and eigenstates. The level-spacing statistics yields a clear sign towards a Wigner-Dyson distribution and therefore towards quantum chaos across all values of $α>0$. Yet, for $α<1$ we find that the microcanonical entropy is nonconvex. This is due to the fact that the spectrum is organized in energetically separated multip…
The equivalence of thermodynamic results in the canonical and the microcanonical ensembles has been questioned in some calculations for spin models with long-range interactions. We show that these claims of inequivalence are related to an inadequate definition of the independent (density) variables in the microcanonical ensemble. We illustrate this point with the example of a simple spin-1 ideal paramagnet, and then revisit the original calculations of Barré, Mukamel, and Ruffo, for a mean-field spin-1 Blume-Capel model. If the microcanonical ensemble is defined in terms of adequate density va…
The two-body potential of systems with long-range interactions decays at large distances as $V(r)\sim 1/r^α$, with $α\leq d$, where $d$ is the space dimension. Examples are: gravitational systems, two-dimensional hydrodynamics, two-dimensional elasticity, charged and dipolar systems. Although such systems can be made extensive, they are intrinsically non additive. Moreover, the space of accessible macroscopic thermodynamic parameters might be non convex. The violation of these two basic properties is at the origin of ensemble inequivalence, which implies that specific heat can be negative in t…
In a pioneer work, John Nagle has shown that an Ising chain with competing short and long-range interactions displays second and first-order phase transitions separated by a tricritical point. More recently, it has been claimed that Nagle's model provides an example of the inequivalence between canonical and microcanonical calculations. We then revisit Nagle's original solution, as well as the usual formulation of the problem in a canonical ensemble, which lead to the same results. Also, in contrast to recent claims, we show that an alternative formulation in the microcanonical ensemble, with …
The so-called $χ^{2}$-superstatistics of Beck and Cohen (BC) is employed to investigate the infinite-range Blume-Capel model, a well-known representative system displaying inequivalence of canonical and microcanonical phase diagrams. While not being restricted to any of those particular thermodynamic limits, our analytical result can smoothly recover both canonical and microcanonical ensemble solutions as its nonextensive parameter $q$ is properly tuned. Additionally, we compare our findings to ones previously obtained from a generalized canonical framework named Extended Gaussian ensemble (EG…
We study the problem of ensemble equivalence in spin systems with short-range interactions under the existence of a first-order phase transition. The spherical model with nonlinear nearest-neighbour interactions is solved exactly both for canonical and microcanonical ensembles. The result reveals apparent ensemble inequivalence at the first-order transition point in the sense that the microcanonical entropy is non-concave as a function of the energy and consequently the specific heat is negative. In order to resolve the paradox, we show that an unconventional saddle point should be chosen in t…
We investigate the p-spin model with Gaussian-distributed random interactions in the microcanonical ensemble using the replica theory. For p=2, there are only second-order phase transitions and we recover the results of Sherrington and Kirkpatrick obtained in the canonical ensemble. For p > 2, the transition between the ferromagnetic and paramagnetic phases is of first order, and the microcanonical and canonical ensembles give different results. We also discuss the ensemble inequivalence of the random energy model, corresponding to the limit p => infinity. This is the first systematic treatmen…
Logarithmic Aging Diffusion from a Multiplicative Event Clock: Rare Event Statistics, Ultraslow Transport, and Ensemble-Time Inequivalence
Center for Advanced Quantum Studies, School of Physics and Astronomy, Beijing Normal University（北京师范大学物理与天文学部先进量子研究中心）；Key Laboratory of Multiscale Spin Physics, Ministry of Education（教育部多尺度自旋物理重点实验室）；School of Science, Tianjin University of Technology and Education（天津职业技术师范大学理学院）；Interdisciplinary Center for Theoretical Physics and Information Sciences, Fudan University（复旦大学理论物理与信息科学交叉中心）；International Center for Quantum Materials, School of Physics, Peking University（北京大学物理学院量子材料国际中心）；Hefei National Laboratory（合肥国家实验室）
It is pointed out that there exists a short-range interacting system, i.e. the elastic spin model, which is extensive but nonadditive. It is numerically shown that, depending on the statistical ensemble, the specific heat or the susceptibility becomes negative in a certain parameter region, which shows ensemble inequivalence in this model. Further, we numerically estimate the effective Hamiltonian for spin variables, and it is clarified that the effective interaction among spin variables is long-ranged. Remarkably, the so called Kac's prescription, which is usually regarded as a mathematical o…
In his pioneering work on negative specific heat, Walter Thirring in\-tro\-duced a model that is solvable in the microcanonical ensemble. Here, we give a complete description of the phase-diagram of this model in both the microcanonical and the canonical ensemble, highlighting the main features of ensemble inequivalence. In both ensembles, we find a line of first-order phase transitions which ends in a critical point. However, neither the line nor the point have the same location in the phase-diagram of the two ensembles. We also show that the microcanonical and canonical critical points can b…
For the repulsive Blume-Emery-Griffiths model the phase diagram in the space of three fields, temperature (T), crystal field ($Δ$), and magnetic field (H), is computed on a complete graph, in the canonical and microcanonical ensembles. For weak strength of the biquadratic interaction (K), there exists a tricritical point in the phase diagram where three critical lines meet. As K decreases below a threshold value(which is ensemble dependent), new multicritical points like the critical end point and bicritical end point arise in the (T,$Δ$) plane. For K>-1, we observe that the two critical lines…
We study the thermodynamics of the Hamiltonian Mean Field (HMF) model with an external potential playing the role of a "magnetic field". If we consider only fully stable states, this system does not present any phase transition. However, if we take into account metastable states (for a restricted class of perturbations), we find a very rich phenomenology. In particular, the system displays a region of negative specific heats in the microcanonical ensemble in which the temperature decreases as the energy increases. This leads to ensembles inequivalence and to zeroth order phase transitions simi…
We derive the thermodynamic entropy of the mean field $ϕ^{6}$ spin model in the framework of the micro-canonical ensemble as a function of the energy and magnetization. Using the theory of large deviations and Rugh's micro-canonical formalism we obtain the entropy and its derivatives and study the thermodynamic properties of $ϕ^{6}$ spin model. The interesting point we found is that like $ϕ^{4}$ model the entropy is a concave function of the energy for all values of the magnetization, but is non-concave as a function of the magnetization for some values of the energy. This means that the magne…
The random matrix ensembles (RME) of quantum statistical Hamiltonian operators, e.g. Gaussian random matrix ensembles (GRME) and Ginibre random matrix ensembles (Ginibre RME), are applied to following quantum statistical systems: nuclear systems, molecular systems, and two-dimensional electron systems (Wigner-Dyson electrostatic analogy). Measures of quantum chaos and quantum integrability with respect to eigenergies of quantum systems are defined and calculated. Quantum statistical information functional is defined as negentropy (opposite of entropy or minus entropy). The distribution functio…
Random matrix ensembles (RME) of quantal statistical Hamiltonian operators, e.g. Gaussian random matrix ensembles (GRME) and Ginibre random matrix ensembles (Ginibre RME), had been applied in literature in study of following quantal statistical systems: molecular systems, nuclear systems, disordered materials, random Ising spin systems, quantal chaotic systems, and two-dimensional electron systems (Wigner-Dyson electrostatic analogy). Measures of quantum chaos and quantum integrability with respect to eigenergies of quantal systems are defined and calculated. Information functional is defined …
A new class of Random Matrix Ensembles is introduced. The Gaussian orthogonal, unitary, and symplectic ensembles GOE, GUE, and GSE, of random matrices are analogous to the classical Gibbs ensemble governed by Boltzmann's distribution in the coordinate space. The proposed new class of Random Matrix ensembles is an extension of the above Gaussian ensembles and it is analogous to the canonical Gibbs ensemble governed by Maxwell-Boltzmann's distribution in phase space. The thermodynamical magnitudes of partition function, intrinsic energy, free energy of Helmholtz, free energy of Gibbs, enthalpy, …
It is shown that the families of generalized matrix ensembles recently considered which give rise to an orthogonal invariant stable Lévy ensemble can be generated by the simple procedure of dividing Gaussian matrices by a random variable. The nonergodicity of this kind of disordered ensembles is investigated. It is shown that the same procedure applied to random graphs gives rise to a family that interpolates between the Erdös-Renyi and the scale free models.
The random matrix ensembles (RME), especially Gaussian random matrix ensembles GRME and Ginibre random matrix ensembles, are applied to following quantum systems: nuclear systems, molecular systems, and two-dimensional electron systems (Wigner-Dyson electrostatic analogy). Measures of quantum chaos and quantum integrability with respect to eigenergies of quantum systems are defined and calculated. The distribution function for the random matrix ensembles is derived from the maximum entropy principle. Information functional is defined as negentropy (opposite of entropy or minus entropy).
A system of globally coupled rotors is studied in a unified framework of microcanonical and canonical ensembles. We consider the Fokker-Planck equation governing the time evolution of the system, and examine various stationary as well as non-stationary solutions. The canonical distribution, describing equilibrium, provides a stationary solution also in the microcanonical ensemble, which leads to order in a system with ferromagnetic coupling at low temperatures. On the other hand, the microcanonical ensemble admits additional stationary and non-stationary solutions; the latter allows dynamical …
The random matrix ensembles (RME) of quantum statistical Hamiltonians, e.g. Gaussian random matrix ensembles (GRME) and Ginibre random matrix ensembles (Ginibre RME), are applied in literature to following quantum statistical systems: molecular systems, nuclear systems, disordered materials, random Ising spin systems, and two-dimensional electron systems (Wigner-Dyson electrostatic analogy). Measures of quantum chaos and quantum integrability with respect to eigenergies of quantum systems are defined and calculated. Quantum statistical information functional is defined as negentropy (opposite …
Random matrix ensembles (RME) of quantum statistical Hamiltonian operators, {\em e.g.} Gaussian random matrix ensembles (GRME) and Ginibre random matrix ensembles (Ginibre RME), found applications in literature in study of following quantum statistical systems: molecular systems, nuclear systems, disordered materials, random Ising spin systems, quantum chaotic systems, and two-dimensional electron systems (Wigner-Dyson electrostatic analogy). Measures of quantum chaos and quantum integrability with respect to eigenergies of quantum systems are defined and calculated. Quantum statistical inform…
