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arXiv 0704.1241cond-mat.mtrl-sci
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Ni $_{50}$ Mn $_{34}$ In $_{16}$磁性记忆合金的绝热磁化冷却和加热

Cooling and heating by adiabatic magnetization in the Ni$_{50}$Mn$_{34}$In$_{16}$ magnetic shape memory alloy

Xavier Moya, Lluis Manosa, Antoni Planes, Seda Aksoy, Mehmet Acet, Eberhard F. Wassermann, Thorsten Krenke

摘要:

本文报道了逆磁热Ni $_{50}$ Mn $_{34}$ In $_{16}$合金的绝热温度变化的测量结果。结果表明,这种合金加热与应用程序的磁场周围的居里点,由于传统的磁热效应。相反,与马氏体相变相关的逆磁热效应导致绝热磁化引起的温度异常降低。我们还提供了磁化和比热数据,使测量的温度变化的热力学关系间接计算的值进行比较。在二阶顺磁-铁磁相变中的常规效应得到了很好的一致性。然而,在一级结构转变,在高场的测量值低于计算值。不可逆的热力学参数表明,这种差异是由于一级马氏体相变的不可逆性。

英文摘要:

We report on measurements of the adiabatic temperature change in the inverse magnetocaloric Ni$_{50}$Mn$_{34}$In$_{16}$ alloy. It is shown that this alloy heats up with the application of a magnetic field around the Curie point due to the conventional magnetocaloric effect. In contrast, the inverse magnetocaloric effect associated with the martensitic transition results in the unusual decrease of temperature by adiabatic magnetization. We also provide magnetization and specific heat data which enable to compare the measured temperature changes to the values indirectly computed from thermodynamic relationships. Good agreement is obtained for the conventional effect at the second-order paramagnetic-ferromagnetic phase transition. However, at the first order structural transition the measured values at high fields are lower than the computed ones. Irreversible thermodynamics arguments are given to show that such a discrepancy is due to the irreversibility of the first-order martensitic transition.

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