Here we made an analysis of the principles of a semiconductor NMR quantum computer and its developments. The known variant of an individual-access computer (B. Kane) and alternative solid-state bulk-ensemble approach versions allowing to avoid some difficulties in implementing the first variant are considered.
A quantum information processing device, based on bulk solid state NMR of the quasi-one dimensional material hydroxyapatite, is proposed following the magnetic resonance force microscopy work of Yamamoto et al (quant-ph/0009122). In a macroscopic sample of hydroxyapatite, our solid state NMR model yields a limit of 10^8 qubits imposed by physics, while development of current technological considerations should allow an upper bound in the range of hundreds to thousands of qubits.
A dipolar recoupling technique is introduced as a new approach to quantum gate operation in solid-state NMR under magic angle spinning. The default-off property of inter-qubit interaction provides a simple way to controlled operation without requiring elaborate qubit-decoupling pulses.
A connection of the Wigner-Yanase skew information and multiple quantum (MQ) NMR coherences is considered at different temperatures and evolution times of nuclear spins with dipole-dipole interactions in MQ NMR experiments in solids. It is shown that the Wigner-Yanase skew information at temperature $T$ is equal to the double second moment of the MQ NMR spectrum at the double temperature for any evolution times. A comparison of the many-spin entanglement obtained with the Wigner-Yanase information and the Fisher information is conducted.
We demonstrate the implementation of a quantum algorithm for estimating the number of matching items in a search operation using a two qubit nuclear magnetic resonance (NMR) quantum computer.
We construct a local realistic hidden-variable model that describes the states and dynamics of bulk-ensemble NMR information processing up to about 12 nuclear spins. The existence of such a model rules out violation of any Bell inequality, temporal or otherwise, in present high-temperature, liquid-state NMR experiments. The model does not provide an efficient description in that the number of hidden variables grows exponentially with the number of nuclear spins.
We present a classical model for bulk-ensemble NMR quantum computation: the quantum state of the NMR sample is described by a probability distribution over the orientations of classical tops, and quantum gates are described by classical transition probabilities. All NMR quantum computing experiments performed so far with three quantum bits can be accounted for in this classical model. After a few entangling gates, the classical model suffers an exponential decrease of the measured signal, whereas there is no corresponding decrease in the quantum description. We suggest that for small numbers o…
We show that differently constructed ensembles having the same density matrix may be physically distinguished by observing fluctuations of some observables. An explicit expression for fluctuations of an observable in an ensemble is given. This result challenges Peres's fundamental postulate and seems to be contrary to the widely-spread belief that ensembles with the same density matrix are physically identical. This leads us to suggest that the current liquid NMR quantum computing is truly quantum-mechanical in nature.
A scheme for decoupling and selectively recoupling large networks of dipolar-coupled spins is proposed. The scheme relies on a combination of broadband, decoupling pulse sequences applied to all the nuclear spins with a band-selective pulse sequence for single spin rotations or recoupling. The evolution-time overhead required for selective coupling is independent of the number of spins, subject to time-scale constraints, for which we discuss the feasibility. This scheme may improve the scalability of solid-state-NMR quantum computing architectures.
Problems in realization of silicon-based solid-state NMR quantum computer with ensemble addressing to qubits are considered. It is presented the extension of Kane's scheme to ensemble approach version with strip gates. For the initialization of nuclear quantum states it is proposed to use the solid-state effect in ENDOR technique whereby the nuclear spins can be practically fully polarized or, that is the same, indirect cooled to the spin temperature less than ~ 1 mK. It is suggested the possible planar silicon topology of such ensemble quantum computer and shown that the measurement with stan…
A three-qubit 13C solid-state nuclear magnetic resonance (NMR) system for quantum information processing, based on the malonic acid molecule, is used to demonstrate high-fidelity universal quantum control via strongly-modulating radio-frequency pulses. This control is achieved in the strong-coupling regime, in which the timescales of selective qubit addressing and of two-qubit interactions are comparable.
The quantum nature of bulk ensemble NMR quantum computing --the center of recent heated debate, is addressed. Concepts of the mixed state and entanglement are examined, and the data in a 2 qubit liquid NMR quantum computation are analyzed. It is pointed out that the key problem in the current debate is the understanding of entanglement in a mixed state system. The following points are concluded in this Letter: 1)Density matrix describes the "state" of an average particle in an ensemble. It can not describe the state of an individual particle in an ensemble in detail; 2) Entanglement is a prope…
A phenomenological theory of spin-lattice relaxation of multiple-quantum coherences in systems of two dipolar coupled spins at low temperatures is developed. Intensities of multiple-quantum NMR coherences depending on the spin-lattice relaxation time are obtained. It is shown that the theory is also applicable to finite spin chains when the approximation of nearest neighbour interaction is used. An application of this theory to an estimation of the influence of decoherence processes on quantum entanglement and its fluctuations is briefly discussed.
Searching a marked item or several marked items from an unsorted database is a very difficult mathematical problem. Using classical computer, it requires $O(N=2^n)$ steps to find the target. Using a quantum computer, Grover's algorithm uses $O(\sqrt{N=2^n})$ steps. In NMR ensemble computing, Brushweiler's algorithm uses $\log N$ steps. In this Letter, we propose an algorithm that fetches marked items in an unsorted database directly. It requires only a single query. It can find a single marked item or multiple number of items.
As an ensemble scheme of solid-state NMR quantum computers the extension of Kane's many-qubits silicon scheme based on the array of 31 P donor atoms are spaced lengthwise of the strip gates is considered. The possible planar topology of such ensemble quantum computer is suggested. The estimation of the output NMR signal was performed and it was shown that for the number N>=10^5 of ensemble elements involving L~10^3 qubits each, the standard NMR methods are usable. As main mechanisms of decoherence for low temperature (<0.1K), the adiabatic processes of random modulation of qubit resonance freq…
Quantum ensembles form easily accessible architectures for studying various phenomena in quantum physics, quantum information science, and spectroscopy. Here we review some recent protocols for measurements in quantum ensembles by utilizing ancillary systems. We also illustrate these protocols experimentally via nuclear magnetic resonance techniques. In particular, we shall review noninvasive measurements, extracting expectation values of various operators, characterizations of quantum states, and quantum processes, and finally quantum noise engineering.
Experimental NMR implementations of the Deutsch-Josza quantum algorithm based on pesudo-pure spin states exhibit an exponential sensitivity scaling with the number of qubits. By employing truly mixed spin states in spin Liouville space, where molecules with different nuclear spin configurations represent different input states, the Deutsch-Josza problem can be solved by single function evaluation without sensitivity loss concomitant with increase of the number of bits.
The efficiency of dipole-dipole coupling driven coherence transfer experiments in solid-state NMR spectroscopy of powder samples is limited by dispersion of the orientation of the internuclear vectors relative to the external magnetic field. Here we introduce general design principles and resulting pulse sequences that approach full polarization transfer efficiency for all crystallite orientations in a powder in magic-angle-spinning experiments. The methods compensate for the defocusing of coherence due to orientation dependent dipolar coupling interactions and inhomogeneous radio-frequency fi…
It is discussed the decoherence problems in ensemble large-scale solid state NMR quantum computer based on the array of P donor atoms having nuclear spin I = 1/2. It is considered here, as main mechanisms of decoherence for low temperature (< 0.1 K), the adiabatic processes of random modulation of qubit resonance frequency determined by secular part of nuclear spin interaction with electron spin of the basic atoms, with impurity paramagnetic atoms and also with nuclear spins of impurity diamagnetic atoms. It was made estimations of allowed concentrations of magnetic impurities and of spin temp…
The one-dimensional homonuclear periodic array of nuclear spins I = 1/2, owing to hyperfine interaction of nuclear spins with electronic magnetic moments in antiferromagnetic structure, is considered. The neighbor nuclear spins in such array are opposite oriented and have resonant frequencies determined by hyperfine interaction constant, applied magnetic field value and interaction with the left and right nuclear neighbor spins. The resonant frequencies difference of nuclear spins, when the neighbor spins have different and the same states, is used to control the spin dynamics by means of sele…
Methods to control errors will be essential for quantum information processing. It is widely believed that fault-tolerant quantum error correction is the leading contender to achieve this goal. Although the theory of fault-tolerant quantum error correction is very well understood, experimental implementation has been lagging. We study the feasibility of implementing repeated rounds of quantum error correction with refreshed ancillas in solid state nuclear magnetic resonance (NMR). In particular we study the procedure proposed for extracting entropy that consists of two stages; an error correct…
We have characterized spin-squeezed states produced at a temperature of $26^\circ{\mathrm C}$ on a Nuclear Magnetic Resonance (NMR) quadrupolar system. The implementation is carried out in an ensemble of $^{133}$Cs nuclei with spin $I=7/2$ of a lyotropic liquid crystal sample. We identify the source of spin squeezing due to the interaction between the quadrupole moment of the nuclei and the electric field gradients internally present in the molecules. We use the spin angular momentum representation to describe formally the nonlinear operators that produce the spin squeezing. The quantitative a…
In this work we experimentally study the efficiency of various dynamical decoupling sequences for suppressing decoherence of single as well as multiple quantum coherences on large spin-clusters. The system involves crystallites of a powdered sample containing a large number of molecular protons interacting via long-range dipole-dipole interaction. The multiple quantum coherences are prepared by progressively creating correlations in the spin lattice using standard pulse sequences implementing two-quantum average Hamiltonian. The spin system is then subjected to various dynamical decoupling seq…
A bipartite quantum system in a mixed state can exhibit nonclassical correlations, which can go beyond quantum entanglement. While quantum discord is the standard measure of quantifying such general quantum correlations, the nonclassicality can be determined by simpler means via the measurement of witness operators. We experimentally construct a positive map to witness nonclassicality of two qubits in an NMR system. The map can be decomposed so that a single run of an experiment on an ensemble of spins suffices to detect the nonclassicality in the state, if present. We let the state evolve in …
The quantum search problem is an important problem due to the fact that a general NP problem can be solved efficiently by an unsorted quantum search algorithm. Here it has been shown that the quantum search problem could be solved in polynomial time on an NMR quantum computer. The NMR ensemble quantum computation is based on the quantum mechanical unitary dynamics that both a closed quantum system and its ensemble obey the same quantum mechanical unitary dynamics instead of on the pseudopure state or the effective pure state of the classical NMR quantum computation. Based on the new principle …
We consider two new quantum gate mechanisms based on nuclear spins in hyperpolarized solid $^{129}Xe$ and HCl mixtures and inorganic semiconductors. We propose two schemes for implementing a controlled NOT (CNOT) gate based on nuclear magnetic resonance (NMR) spectroscopy and magnetic resonance imaging (MRI) from hyperpolarized solid $^{129}Xe$ and HCl mixtures and optically pumped NMR in semiconductors. Such gates might be built up with particular spins addressable based on MRI techniques and optical pumping and optical detection techniques. The schemes could be useful for implementing actual…
We present a framework that uses a continuous frequency space to describe and design solid-state NMR experiments. The approach is similar to the well established Floquet treatment for NMR, but is not restricted to periodic Hamiltonians and allows the design of experiments in a reverse fashion. The framework is based on perturbation theory on a continuous Fourier space, which leads to effective, i.e., time-independent, Hamiltonians. It allows the back calculation of the pulse scheme from the desired effective Hamiltonian as a function of spin-system parameters. We show as an example how to back…
We demonstrate a synchronized readout (SR) technique for spectrally selective detection of oscillating magnetic fields with sub-millihertz resolution, using coherent manipulation of solid state spins. The SR technique is implemented in a sensitive magnetometer (~50 picotesla/Hz^(1/2)) based on nitrogen vacancy (NV) centers in diamond, and used to detect nuclear magnetic resonance (NMR) signals from liquid-state samples. We obtain NMR spectral resolution ~3 Hz, which is nearly two orders of magnitude narrower than previously demonstrated with NV based techniques, using a sample volume of ~1 pic…
We report an observation of extremely long-lived spin states in systems of dipolar-coupled nuclear spins in solids. The 'suspended echo' experiment uses a simple stimulated echo pulse sequence and creates non-equilibrium states which live many orders of magnitude longer than the characteristic time of spin-spin dynamics T2. Large amounts of information can be encoded in such long-lived states, stored in a form of multi-spin correlations, and subsequently retrieved by an application of a single 'reading' pulse.
We theoretically investigate thermalization and spin diffusion driven by a quantum spin bath for a realistic solid-state NMR experiment. We consider polycrystalline L-alanine, and investigate how the spin polarization spreads among several $^{13}$C nuclear spins, which interact via dipole-dipole coupling with the bath of strongly dipolar-coupled $^1$H nuclear (proton) spins. We do this by using direct numerical simulation of the many-spin time-dependent Schrödinger equation. We find that, although the proton spins located near the carbon sites interact most strongly with the $^{13}$C spins, th…
In this paper, we present an ensemble algorithm for selection problem to find the k-th smallest element in the unsorted database. We will search the k-th smallest element by using "divide-and-conquer" strategy. We first divide D, the domain of the database, into two parts, determine which of the two parts the object element sought belongs to, and then concentrate on that part. We repeat divide that part until object element is found. The determination of which part depends on the output of ensemble counting scheme, which outputs the number of assignments satisfying the value of the oracle quer…
The free-induction decay (FID) of the transverse magnetization in a dipolar-coupled rigid lattice is a fundamental problem in magnetic resonance and in the theory of many-body systems. As it was shown earlier the FID shapes for the systems of classical magnetic moments and for quantum nuclear spins ones coincide if there are many quite equivalent nearest neighbors V in a solid lattice. In this paper, we reduce a multispin density matrix of above system to a two-spin matrix. Then we obtain analytic expressions for the mutual information and the quantum and classical parts of correlations at the…
The response of a quadrupolar nucleus (nuclear spin with I>1/2) to an oscillating radio-frequency (RF) pulse/field is delicately dependent on the ratio of the quadrupolar coupling constant to the amplitude of the pulse in addition to its duration and oscillating frequency. Consequently, analytic description of the excitation process in the density operator formalism has remained less transparent within existing theoretical frameworks. As an alternative, the utility of the "concept of effective Floquet Hamiltonians" is explored in the present study to explicate the nuances of the excitation pro…
The nitrogen-vacancy (NV) center has enabled widespread study of nanoscale nuclear magnetic resonance (NMR) spectroscopy at low magnetic fields. NMR spectroscopy at high magnetic fields significantly improves the technique's spectral resolution, enabling clear identification of closely related chemical species. However, NV-detected NMR is typically performed using AC sensing through electron spin echo envelope modulation (ESEEM), a hyperfine spectroscopic technique that is not feasible at high magnetic fields. Within this paper, we have explored an NV-detected NMR technique for applications of…
A proposal for a scalable, solid-state implementation of a quantum computer is presented. Qubits are fluorine nuclear spins in a solid crystal of fluorapatite [Ca_5 F(PO_4)_3] with resonant frequencies separated by a large field gradient. Quantum logic is accomplished using nuclear-nuclear dipolar couplings with decoupling and selective recoupling RF pulse sequences. Magnetic resonance force microscopy is used for readout. As many as 300 qubits can be implemented in the laboratory extremes of T=10 mK and B_0=20 T with the existing sensitivity of force microscopy.
An efficient quantum algorithm is proposed to solve in polynomial time the parity problem, one of the hardest problems both in conventional quantum computation and in classical computation, on NMR quantum computers. It is based on the quantum parallelism principle in a quantum ensemble, the selective decoherence manipulation, and the NMR phase-sensitive measurement. The quantum circuit for the quantum algorithm is designed explicitly.
Nuclear Magnetic Resonance (NMR) has provided a valuable experimental testbed for quantum information processing (QIP). Here, we briefly review the use of nuclear spins as qubits, and discuss the current status of NMR-QIP. Advances in the techniques available for control are described along with the various implementations of quantum algorithms and quantum simulations that have been performed using NMR. The recent application of NMR control techniques to other quantum computing systems are reviewed before concluding with a description of the efforts currently underway to transition to solid st…
We demonstrate that Fokker-Planck equations in which spatial coordinates are treated on the same conceptual level as spin coordinates yield a convenient formalism for treating magic angle spinning NMR experiments. In particular, time dependence disappears from the background Hamiltonian (sample spinning is treated as an interaction), spherical quadrature grids are avoided completely (coordinate distributions are a part of the formalism) and relaxation theory with any linear diffusion operator is easily adopted from the Stochastic Liouville Equation theory. The proposed formalism contains Floqu…
We experimentally demonstrate quantum machine learning using NMR based on a framework of quantum reservoir computing. Reservoir computing is for exploiting natural nonlinear dynamics with large degrees of freedom, which is called a reservoir, for a machine learning purpose. Here we propose a concrete physical implementation of a quantum reservoir using controllable dynamics of a nuclear spin ensemble in a molecular solid. In this implementation, we demonstrate learning of nonlinear functions with binary or continuous variable inputs with low mean squared errors. Our implementation and demonstr…
The ability to post-select the outcomes of an experiment is a useful theoretical concept and experimental tool. In the context of weak measurements post-selection can lead to surprising results such as complex weak values outside the range of eigenvalues. Usually post-selection is realized by a projective measurement, which is hard to implement in ensemble systems such as NMR. We demonstrate the first experiment of a weak measurement with post-selection on an NMR quantum information processor. Our setup is used for measuring complex weak values and weak values outside the range of eigenvalues.…
An ensemble of nuclear spin-pairs under certain conditions is known to exhibit singlet state life-times much longer than other non-equilibrium states. This property of singlet state can be exploited in quantum information processing for efficient initialization of quantum registers. Here we describe a general method of initialization and experimentally demonstrate it with two-, three-, and four-qubit nuclear spin registers.
We propose a scheme for generating squeezed states in solid state circuits consisting of a nanomechanical resonator (NMR), a superconducting Cooper-pair box (CPB) and a superconducting transmission line resonator (STLR). The nonlinear interaction between the NMR and the STLR can be implemented by setting the external biased flux of the CPB at certain values. The interaction Hamiltonian between the NMR and the STLR is derived by performing Fr$\rm\ddot o$hlich transformation on the total Hamiltonian of the combined system. Just by adiabatically keeping the CPB at the ground state, we get the sta…
We implement an ensemble quantum counting algorithm on three NMR spectrometers with 1H resonance frequencies of 500, 600 and 750 MHz. At higher frequencies, the results deviate markedly from naive theoretical predictions. These systematic errors can be attributed almost entirely to off-resonance effects, which can be substantially corrected for using fully-compensating composite rotation pulse sequences originally developed by Tycko. We also derive an analytic expression for generating such sequences with arbitrary rotation angles.
In conventional NMR experiments, the Zeeman energy gaps of the nuclear spin ensembles are much lower than their thermal energies, and accordingly exhibit tiny polarizations. Generally such low-purity quantum states are devoid of quantum entanglement. However, there exist certain nonclassical correlations which can be observed even in such systems. In this chapter, we discuss three such quantum correlations, namely, quantum contextuality, Leggett-Garg temporal correlations, and quantum discord. In each case, we provide a brief theoretical background and then describe some results from NMR exper…
We report here the experimental realization of multi-step cooling of a quantum system via heat-bath algorithmic cooling. The experiment was carried out using nuclear magnetic resonance (NMR) of a solid-state ensemble three-qubit system.
In a lattice ${\cal L}$ of nuclear spins with ABCABCABC... type periodic structure embedded in a single-crystal solid, each ABC-unit can be used to store quantum information and the information can be moved around via some cellular shifting mechanism. Impurity doping marks a special site D$\not\in{\cal L}$ which together with the local spin lattice constitute a quantum automaton where the D site serves as the input/output port and universal quantum logic is done through two-body interactions between two spins at D and a nearby site. The novel NMR quantum computer can be easily scaled up and ma…
Nuclear spins are promising candidates for quantum information processing because their good isolation from the environment precludes the rapid loss of quantum coherence. Many strategies have been developed to further extend their decoherence times. Some of them make use of decoupling techniques based on the Carr-Purcell and Carr-Purcell-Meiboom-Gill pulse sequences. In many cases, when applied to inhomogeneous samples, they yield a magnetization decay much slower than the Hahn echo. However, we have proved that these decays cannot be associated with longer decoherence times as coherences rema…
Nuclear magnetic resonance (NMR) and nuclear quadrupole resonance (NQR) spectroscopy of bulk quantum materials have provided insight into phenomena such as quantum phase criticality, magnetism, and superconductivity. With the emergence of nanoscale 2-D materials with magnetic phenomena, inductively-detected NMR and NQR spectroscopy are not sensitive enough to detect the smaller number of spins in nanomaterials. The nitrogen-vacancy (NV) center in diamond has shown promise in bringing the analytic power of NMR and NQR spectroscopy to the nanoscale. However, due to depth-dependent formation effi…
We propose a new approach to the measurement of a single spin state, based on nuclear magnetic resonance (NMR) techniques and inspired by the coherent control over many-body systems envisaged by Quantum Information Processing (QIP). A single target spin is coupled via the natural magnetic dipolar interaction to a large ensemble of spins. Applying external radio frequency (rf) pulses, we can control the evolution of the system so that the spin ensemble reaches one of two orthogonal states whose collective properties differ depending on the state of the target spin and are easily measured. We fi…
We give a general method of construting quantum circuit for random \QTR{it}{satisfiability} (SAT) problems with the basic logic gates such as multi-qubit controlled-NOT and NOT gates. The sizes of these circuits are almost the same as the sizes of the SAT formulas. Further, a parallelization scheme is described to solve random SAT problems efficiently through these quantum circuits in \QTR{it}{nuclear magnetic resonance} (NMR) ensemble quantum computing. This scheme exploits truly mixed states as input states rather than pseudo-pure states, and combines with the topological nanture of the NMR …
First-principles calculations of high-temperature spin dynamics in solids in the context of nuclear magnetic resonance (NMR) is a long-standing problem, whose conclusive solution can significantly advance the applications of NMR as a diagnostic tool for material properties. In this work, we propose a new hybrid quantum-classical method for computing NMR free induction decay(FID) for spin $1/2$ lattices. The method is based on the simulations of a finite cluster of spins $1/2$ coupled to an environment of interacting classical spins via a correlation-preserving scheme. Such simulations are show…
Magic-angle spinning (MAS) solid state nuclear magnetic resonance (NMR) spectroscopy is shown to be a promising technique for implementing quantum computing. The theory underlying the principles of quantum computing with nuclear spin systems undergoing MAS is formulated in the framework of formalized quantum Floquet theory. The procedures for realizing state labeling, state transformation and coherence selection in Floquet space are given. It suggests that by this method, the largest number of qubits can easily surpass that achievable with other techniques. Unlike other modalities proposed for…
Nuclear magnetic resonance (NMR) schemes can be applied to micron-, and nanometer-sized samples by the aid of quantum sensors such as nitrogen-vacancy (NV) color centers in diamond. These minute devices allow for magnetometry of nuclear spin ensembles with high spatial and frequency resolution at ambient conditions, thus having a clear impact in different areas such as chemistry, biology, medicine, and material sciences. In practice, NV quantum sensors are driven by microwave (MW) control fields with a twofold objective: On the one hand, MW fields bridge the energy gap between NV and nearby nu…
Nuclear magnetic resonance (NMR) provides an experimental setting to explore physical implementations of quantum information processing (QIP). Here we introduce the basic background for understanding applications of NMR to QIP and explain their current successes, limitations and potential. NMR spectroscopy is well known for its wealth of diverse coherent manipulations of spin dynamics. Ideas and instrumentation from liquid state NMR spectroscopy have been used to experiment with QIP. This approach has carried the field to a complexity of about 10 qubits, a small number for quantum computation …
We present experimental NMR demonstration of a scheme of reversible projective measurement, which allows extracting information on outcomes and probabilities of a projective measurement in a non-destructive way, with a minimal net effect on the quantum state of an ensemble. The scheme uses reversible dynamics and weak measurement of the intermediate state. The experimental system is an ensemble of 133Cs (S = 7/2) nuclei in a liquid-crystalline matrix.
We propose a method of controlling a quantum logic gate in a solid-state NMR quantum computer. A switchable inter-qubit coupling can be generated by using the longitudinal component of the Suhl-Nakamura interaction induced by a local singlet-triplet excitation in a 1-D antiferromagnet with a spin gap.
Refocalization sequences in Nuclear Magnetic Resonance (NMR) can in principle reverse the coherent evolution under the secular dipolar Hamiltonian of a closed system. We use this experimental strategy to study the effect of irreversible decoherence on the signal amplitude attenuation in a single crystal hydrated salt where the nuclear spin system consists in the set of hydration water proton spins having a strong coupling within each pair and a much weaker coupling with other pairs. We study the experimental response of attenuation times with temperature, crystal orientation with respect to th…