Time flow has been embodied in time-dependent Schroedinger equation representing one of the foundations of quantum mechanics. Pauli's criticism (1933) has, however, indicated that the assumptions concerning representation Hilbert space have led to some contradictions. Many authors have tried to solve this discrepancy practically without any actual success. The reason may be seen in that two different problems have been mixed: the problem of Pauli (being more general and more important) and non-unitarity of exponential phase operator of linear harmonic oscillator introduced by Dirac, as demonstrated in 1964. The problem will be discussed in a broad historical context and a solution based on extension of representation Hilbert space will be shown.
An axiomatic formalism for a minimal irreversible quantum mechanics is introduced. It is shown that a quantum equilibrium and the decoherence phenomenon are consequences of the axioms and that Lyapunov variables, exponential survival probabilities, and a classisal conditional never-decreasing entropy can be defined.
The new formulation of the theory of multichannel scattering on the example of collinear model is proposed. It is shown, that in the closed three-body scattering system the principle of quantum determinism in general case breaks down and we have a micro- irreversible quantum mechanics.
It is demonstrated that, making minimal changes in ordinary quantum mechanics, a reasonable irreversible quantum mechanics can be obtained. This theory has a more general spectral decompositions, with eigenvectors corresponding to unstable states that vanish when $t \to \infty .$ These ''Gamov vectors'' have zero norm, in such a way that the norm and the energy of the physical states remain constant. The evolution operator has no inverse, showing that we are really dealing with a time-asymmetric theory. Using Friedrichs model reasonable physical results are obtained, e. g. : the remaining of a…
Brownian motion is modelled by a harmonic oscillator (Brownian particle) interacting with a continuous set of uncoupled harmonic oscillators. The interaction is linear in the coordinates and the momenta. The model has an analytical solution that is used to study the time evolution of the reduced density operator. It is derived in a closed form, in the one-particle sector of the model. The irreversible behavior of the Brownian particle is described by a reduced density matrix.
Based on the modelling of quantum systems with the aid of (classical) non-equilibrium thermodynamics, both the emergence and the collapse of the superposition principle are understood within one and the same framework. Both are shown to depend in crucial ways on whether or not an average orthogonality is maintained between reversible Schroedinger dynamics and irreversible processes of diffusion. Moreover, said orthogonality is already in full operation when dealing with a single free Gaussian wave packet. In an application, the quantum mechanical "decay of the wave packet" is shown to simply r…
We present an explicit correspondence between quantum mechanics and the classical theory of irreversible thermodynamics as developed by Onsager, Prigogine et al. Our correspondence maps irreversible Gaussian Markov processes into the semiclassical approximation of quantum mechanics. Quantum-mechanical propagators are mapped into thermodynamical probability distributions. The Feynman path integral also arises naturally in this setup. The fact that quantum mechanics can be translated into thermodynamical language provides additional support for the conjecture that quantum mechanics is not a fund…
We elaborate on the existing notion that quantum mechanics is an emergent phenomenon, by presenting a thermodynamical theory that is dual to quantum mechanics. This dual theory is that of classical irreversible thermodynamics. The linear regime of irreversibility considered here corresponds to the semiclassical approximation in quantum mechanics. An important issue we address is how the irreversibility of time evolution in thermodynamics is mapped onto the quantum-mechanical side of the correspondence.
In non relativistic quantum mechanics time enters as a parameter in the Schroedinger equation. However, there are various situations where the need arises to view time as a dynamical variable. In this paper we consider the dynamical role of time through the construction of a Lyapunov variable - i.e., a self-adjoint quantum observable whose expectation value varies monotonically as time increases. It is shown, in a constructive way, that a certain class of models admit a Lyapunov variable and that the existence of a Lyapunov variable implies the existence of a transformation mapping the origina…
The neutral Kaon system is used to test the quantum theory of resonance scattering and decay phenomena. The two dimensional Lee-Oehme-Yang theory with complex Hamiltonian is obtained by truncating the complex basis vector expansion of the exact theory in Rigged Hilbert space. This can be done for K_1 and K_2 as well as for K_S and K_L, depending upon whether one chooses the (self-adjoint, semi-bounded) Hamiltonian as commuting or non-commuting with CP. As an unexpected curiosity one can show that the exact theory (without truncation) predicts long-time 2 pion decays of the neutral Kaon system …
We report an approach to quantum open system dynamics that leads to novel nonlinear constant relations governing information flow among the participants. Our treatment is for mixed state systems entangled in a pure state fashion with an unspecified party that was involved in preparing the system for an experimental test, but no longer interacts after $t=0$. Evolution due to subsequent interaction with another party is treated as an amplitude flow channel and uses Schmidt-type bipartite decomposition of the evolving state. We illustrate this with three examples, including both reversible and ir…
The discussion on time-reversal in quantum mechanics exists at least since Wigner's ``Uber die Operation der Zeitumkehr in der Quantenmechanik'' paper in 1932. If and how the dynamics of the quantum world is time-reversible has been the subject of many controversies. Some have seen quantum mechanics as fundamentally time-irreversible, see for example von Neumann, and some have seen in that the ultimate cause of time's arrow and second law behavior. In his best-selling book ``The Emperor's New Mind'', Roger Penrose argues similarly and concludes that ``our sought-for quantum gravity must be a t…
I prove that, if a change happens in a closed quantum system so that its state is perfectly distinguishable from all past or future states, the Hamiltonian is $\widehat{H}=-i\hbar\frac{\partial\ }{\partialτ}$. A time operator $\widehatτ$ can be defined as its canonical conjugate. This Hamiltonian is usually rejected because it has no ground state, but I show that even a weaker form of irreversibility is inconsistent with a ground state. What is the right choice, that the world's Hamiltonian is $-i\hbar\frac{\partial\ }{\partialτ}$, or that changes are reversible?
It is well known that a state with complex energy cannot be the eigenstate of a self-adjoint operator, like the Hamiltonian. Resonances, i.e. states with exponentially decaying observables, are not vectors belonging to the conventional Hilbert space. One can describe these resonances in an unusual mathematical formalism, based on the so-called Rigged Hilbert Space (RHS). In the RHS, the states with complex energy are denoted as Gamow Vectors (GV), and they model decay processes. We study GV of the Reversed Harmonic Oscillator (RHO), and we analytically and numerically investigate the unstable …
We discuss the systematic expansion of the solution of the Fokker-Planck equation with the help of the eigenfunctions of the time-dependent Fokker-Planck operator. The expansion parameter is the time derivative of the external parameter which controls the form of an external potential. Our expansion corresponds to the perturbative calculation of the adiabatic motion in quantum mechanics. With this method, we derive a new formula to calculate the irreversible work order by order, which is expressed as the expectation value with a pseudo density matrix. Applying this method to the case of the ha…
We discuss the structure and main features of the nonlinear evolution equation proposed by this author as the fundamental dynamical law within the framework of Quantum Thermodynamics. The nonlinear equation generates a dynamical group providing a unique deterministic description of irreversible, conservative relaxation towards equilibrium from any non-equilibrium state, and satisfies a very restrictive stability requirement equivalent to Hatsopoulos-Keenan statement of the second law of thermodynamics. Here, we emphasize its mathematical structure and its applicability also within other contex…
The article is dedicated to discussion of irreversibility and foundation of statistical mechanics "from the first principles". Taking into account infinitesimal and, as it seems, neglectful for classical mechanics fluctuations of the physical vacuum, makes a deterministic motion of unstable dynamic systems is broken ("spontaneous determinism breaking", "spontaneous stochastization"). Vacuum fluctuations play part of the trigger, starting the powerful mechanism of exponent instability. The motion of the dynamic systems becomes irreversible and stochastic. Classical mechanics turns out to be app…
The auxiliary rules of quantum mechanics can be written without the Born rule by using what are called the nRules. The nRules are understood in part by making certain modifications in the Hamiltonian. In this paper, those modifications are written directly into the nRules, reducing their number from four to three. It is shown that the nRules in either form provide for a definite direction in time, guaranteeing that a statistically irreversible interaction is absolutely irreversible.
Despite its simplicity, it seems to my best of knowledge that the possibly simplest approach towards deriving equations governing irreversible thermodynamics from gas-kinetic considerations within the framework of classical mechanics has never been pursued. In this paper we address this omission and derive the equations describing the irreversible thermodynamics of a gas in a piston and associated thermodynamic cycles performed in finite time. What we find is a thermodynamic action principle: The irreversible work we require for performing a thermodynamic cycle in finite time times the time we…
Irreversible processes are frequently adopted to account for the entropy increase in classical thermodynamics. However, the corresponding physical origins are not always clear, e.g. in a free expansion process, a typical model in textbooks. In this letter, we study the entropy change during free expansion for a particle with the thermal de Broglie wavelength ($λ_{T}$) in a one-dimensional square trap with size $L$. By solely including quantum dephasing as an irreversible process, we recover classical result of entropy increase in the classical region ($L\ggλ_{T}$), while predict prominent disc…
Time of arrival in quantum mechanics is discussed in two versions: the classical axiomatic "time of arrival operator" introduced by J. Kijowski and the EEQT method. It is suggested that for free particles the two methods may lead to the same result. On the other hand the EEQT method can be easily geometrized within the framework of Galilei-Newton general relativistic quantum mechanics developed by M. Modugno and collaborators, and it can be applied to non-free evolutions. The way of geometrization of irreversible quantum dynamics based on dissipative Liouville equation is suggested.
By making use of a recently proposed framework for the inference of thermodynamic irreversibility in bosonic quantum systems, we experimentally measure and characterize the entropy production rates in the non-equilibrium steady state of two different physical systems -- a micro-mechanical resonator and a Bose-Einstein condensate -- each coupled to a high finesse cavity and hence also subject to optical loss. Key features of our setups, such as cooling of the mechanical resonator and signatures of a structural quantum phase transition in the condensate are reflected in the entropy production ra…
Non-unitary quantum mechanics has been used in the past to study irreversibility, dissipation and decay in a variety of physical systems. In this letter, we propose a general scheme to deal with systems governed by non-Hermitian Hamiltonians. We argue that the Schwinger-Keldysh formalism gives a natural description for those problems. To elucidate the method, we study a simple model inspired by mesoscopic physics --an asymmetric junction. The system is governed by a non-Hermitian Hamiltonian which captures essential aspects of irreversibility.
The irreversible work during a driving protocol constitutes one of the most widely studied measures in non-equilibrium thermodynamics, as it constitutes a proxy for entropy production. In quantum systems, it has been shown that the irreversible work has an additional, genuinely quantum mechanical contribution, due to coherence produced by the driving protocol. The goal of this paper is to explore this contribution in systems that undergo a quantum phase transition. Substantial effort has been dedicated in recent years to understand the role of quantum criticality in work protocols. However, pr…
The quantum measurement problem considered for measuring system (MS) model which consist of measured state S (particle), detector D and information processing device O. For spin chains and other O models the state evolution for MS observables measurements studied. It's shown that specific O states structure forbids the measurement of MS interference terms which discriminate pure and mixed S states. It results in the reduction MS Hilbert space to O representation in which MS evolution is irreversible, which in operational formalism corresponds to S state collapse. In radiation decoherence O mod…
A new formulation of the theory of quantum mechanical multichannel scattering for three-body collinear systems is proposed. It is shown, that in this simple case the principle of quantum determinism in the general case breaks down and we have a micro-irreversible quantum mechanics. The first principle calculations of the quantum chaos (wave chaos) were pursued on the example of an elementary chemical reaction Li+(FH)->(LiFH)*->(LiF)+H.
We show that the quantization of a simple damped system leads to a self-adjoint Hamiltonian with a family of complex generalized eigenvalues. It turns out that they correspond to the poles of energy eigenvectors when continued to the complex energy plane. Therefore, the corresponding generalized eigenvectors may be interpreted as resonant states. We show that resonant states are responsible for the irreversible quantum dynamics of our simple model.
We study the quantum-mechanical problem of scattering caused by a localized obstacle that breaks spatial and temporal reversibility. Accordingly, we follow Maxwell's prescription to achieve a violation of the second law of thermodynamics by means of a momentum-dependent interaction in the Hamiltonian, resulting in what is known as Maxwell's demon. We obtain the energy-dependent Green's function analytically, as well as its meromorphic structure. The poles lead directly to the solution of the evolution problem, in the spirit of M. Moshinsky's work in the 1950s. Symmetric initial conditions are …
We show that the quantum Jarzynski equality generalizes to $\mathcal{PT}$-symmetric quantum mechanics with unbroken $\mathcal{PT}$-symmetry. In the regime of broken $\mathcal{PT}$-symmetry the Jarzynski equality does not hold as also the $\mathcal{CPT}$-norm is not preserved during the dynamics. These findings are illustrated for an experimentally relevant system -- two coupled optical waveguides. It turns out that for these systems the phase transition between the regimes of unbroken and broken $\mathcal{PT}$-symmetry is thermodynamically inhibited as the irreversible work diverges at the cri…
Schlosshauer has advanced a theory of minimal no-collapse quantum mechanics for a decoherence-based subjective resolution of the measurement problem. The basic premise being that superposition states are maintained beyond the retinal apparatus, becoming correlated with neuronal arrays located in the occipital lobe of the brain. Decoherence for these neurons in a superposition of firing and resting, leads to an irreversible dynamical decoupling of the two branches, resulting in the emergence of a single subjective perception. Based upon prior retinal research, it is shown that his theory is unt…
According to thermodynamics, the inevitable increase of entropy allows the past to be distinguished from the future. From this perspective, any clock must incorporate an irreversible process that allows this flow of entropy to be tracked. In addition, an integral part of a clock is a clockwork, that is, a system whose purpose is to temporally concentrate the irreversible events that drive this entropic flow, thereby increasing the accuracy of the resulting clock ticks compared to counting purely random equilibration events. In this article, we formalise the task of autonomous temporal probabil…
Within the general formalism of quantum theory irreversibility and the arrow of time in the evolution of various physical systems are studied. Irreversible behavior often manifests itself in the guise of entropy production. This motivates me to begin this paper with a brief review of quantum-mechanical entropy, a subject that Elliott Lieb has made outstanding contributions to, followed by an enumeration of examples of irreversible behavior and of an arrow of time analyzed in later sections. Subsequently, a derivation of the laws of thermodynamics from (quantum) statistical mechanics, and, in p…
Quantum mechanics describes the unitary time evolution of isolated systems. In reality, every quantum system interacts with its environment, leading to an irreversible loss of the phase relation. Path integral based methods provide a rigorous description of the process of decoherence. We provide an overview over recent numerical methods suited to describe the non-perturbative regime of system bath interaction. -- Quantenmechanik beschreibt die unitäre Zeitentwicklung isolierter Systeme. In der Realität interagiert jedes Quantensystem mit seiner Umwelt, was zu einem irreversiblen Verlust von Ph…
The derivation of macroscopic irreversible dynamics of nonequilibrium systems from microscopic equations was recently revisited from the point of view of infinitely extended quantum systems. Here we have briefly reviewed the $C^*$ algebra and its application to equilibrium systems as well as introduced some recent results on NESS. In addition, we have demonstrated the derivation of Landauer formula rigorously for quadratic systems but using a more physical presentation.
We present a map of standard quantum mechanics onto a dual theory, that of the classical thermodynamics of irreversible processes. While no gravity is present in our construction, our map exhibits features that are reminiscent of the holographic principle of quantum gravity.
It has been argued that gravity acts dissipatively on quantum-mechanical systems, inducing thermal fluctuations that become indistinguishable from quantum fluctuations. This has led some authors to demand that some form of time irreversibility be incorporated into the formalism of quantum mechanics. As a tool towards this goal we propose a thermodynamical approach to quantum mechanics, based on Onsager's classical theory of irreversible processes and on Prigogine's nonunitary transformation theory. An entropy operator replaces the Hamiltonian as the generator of evolution. The canonically conj…
