We investigate the dephasing of ultra cold ^{85}Rb atoms trapped in an optical dipole trap and prepared in a coherent superposition of their two hyperfine ground states by interaction with a microwave pulse. We demonstrate that the dephasing, measured as the Ramsey fringe contrast, can be reversed by stimulating a coherence echo with a pi-pulse between the two pi/2 pulses, in analogy to the photon echo. We also demonstrate that the failure of the echo for certain trap parameters is due to dynamics in the trap, and thereby that ''echo spectroscopy'' can be used to study the quantum dynamics in the trap even when more than 10^6 states are thermally populated, and to study the crossover from quantum (where dynamical decoherence is supressed) to classical dynamics.
We discuss a recently demonstrated type of microwave spectroscopy of trapped ultra-cold atoms known as "echo spectroscopy" [M.F. Andersen et. al., Phys. Rev. Lett., in press (2002)]. Echo spectroscopy can serve as an extremely sensitive experimental tool for investigating quantum dynamics of trapped atoms even when a large number of states are thermally populated. We show numerical results for the stability of eigenstates of an atom-optics billiard of the Bunimovich type, and discuss its behavior under different types of perturbations. Finally, we propose to use special geometrical constructio…
We experimentally demonstrate and systematically study the stimulated revival (echo) of motional wave packet oscillations. For this purpose, we prepare wave packets in an optical lattice by non-adiabatically shifting the potential and stimulate their reoccurence by a second shift after a variable time delay. This technique, analogous to spin echoes, enables one even in the presence of strong dephasing to determine the coherence time of the wave packets. We find that for strongly bound atoms it is comparable to the cooling time and much longer than the inverse of the photon scattering rate.
The rotational echo response of molecules is found to strongly depend on the delay between the two ultrashort laser pulses, as opposed to two-level systems. We study this dependence experimentally and theoretically and show that by judicious control of the 2nd pulse intensity, 'rotational echo spectroscopy' in a multi-level molecular system becomes possible.
We report on the collapse and revival of Ramsey fringe visibility when a spatially dependent phase is imprinted in the coherences of a trapped ensemble of two-level atoms. The phase is imprinted via the light shift from a Gaussian laser beam which couples the dynamics of internal and external degrees of freedom for the atoms in an echo spectroscopy sequence. The observed revivals are directly linked to the oscillatory motion of atoms in the trap. An understanding of the effect is important for quantum state engineering of trapped atoms.
Motivated by atom optics experiments, we investigate a new class of fidelity functions describing the reconstruction of quantum states by time-reversal operations as $M_{\mathrm{Da}}(t) = | <ψ| e^{i H_2 t / 2} e^{i H_1 t / 2} e^{-i H_2 t / 2} e^{-i H_1 t / 2} | ψ>|^2$. We show that the decay of $M_{\mathrm{Da}}$ is quartic in time at short times, and that it freezes well above the ergodic value at long times, when $H_2-H_1$ is not too large. The long-time saturation value of $M_{\mathrm{Da}}$ contains easily extractable information on the strength of decoherence in these systems.
Crosstalk between target and neighboring spectator qubits due to spillover of control signals represents a major error source limiting the fidelity of two-qubit entangling gates in quantum computers. We show that in our laser-driven trapped-ion system coherent crosstalk error can be modelled as residual $X\hatσ_ϕ$ interaction and can be actively cancelled by single-qubit echoing pulses. We propose and demonstrate a crosstalk suppression scheme that eliminates all first-order crosstalk, yet only requires local control by driving rotations solely on the target qubits. We report a two-qubit Bell …
We perform spectroscopy on the hyperfine splitting of $^{85}$Rb atoms trapped in far-off-resonance optical traps. The existence of a spatially dependent shift in the energy levels is shown to induce an inherent dephasing effect, which causes a broadening of the spectroscopic line and hence an inhomogeneous loss of atomic coherence at a much faster rate than the homogeneous one caused by spontaneous photon scattering. We present here a number of approaches for reducing this inhomogeneous broadening, based on trap geometry, additional laser fields, and novel microwave pulse sequences. We then sh…
Central spin decoherence is useful for detecting many-body physics in environments and moreover, the spin echo control can remove the effects of static thermal fluctuations so that the quantum fluctuations are revealed. The central spin decoherence approach, however, is feasible only in some special configurations and often requires uniform coupling between the central spin and individual spins in the baths, which are very challenging in experiments. Here, by making analogue between central spin decoherence and depolarization of photons, we propose a scheme of Faraday rotation echo spectroscop…
We theoretically study an impulsively excited quantum bouncer (QB) - a particle bouncing off a surface in the presence of gravity. A pair of time-delayed pulsed excitations is shown to induce a wave-packet echo effect - a partial rephasing of the QB wave function appearing at twice the delay between pulses. In addition, an appropriately chosen observable [here, the population of the ground gravitational quantum state (GQS)] recorded as a function of the delay is shown to contain the transition frequencies between the GQSs, their populations, and partial phase information about the wave packet …
In the strong coupling regime with J-coupling much larger than chemical shift differences, J-coupling spectroscopy enables spectral identification of molecules even when conventional NMR fails. While this classically required the presence of a heteronucleus, we recently showed that J-coupling spectra can be acquired in many homonuclear systems using spin-lock induced crossing (SLIC). Here, we present an alternative method using a spin echo train in lieu of a spin-locking SLIC pulse, which has a number of advantages. In particular, spin echo acquisition within the pulse train enables simultaneo…
Transverse spin diffusion in a polarized, interacting Fermi gas leads to the Leggett-Rice effect, where the spin current precesses around the local magnetization. With a spin-echo sequence both the transverse diffusivity and the spin-rotation parameter $γ$ are obtained; the sign of $γ$ reveals the repulsive or attractive character of the effective interaction. In a trapped Fermi gas the spin diffusion equations become nonlinear, and their numerical solution exhibits an inhomogeneous spin state even at the spin echo time. While the microscopic diffusivity and $γ$ increase at weak coupling, thei…
Ultra-cold atoms trapped in an optical dipole trap and prepared in a coherent superposition of their hyperfine ground states, decohere as they interact with their environment. We demonstrate than the loss in coherence in an "echo" experiment, which is caused by mechanisms such as Rayleigh scattering, can be suppressed by the use of a new pulse sequence. We also show that the coherence time is then limited by mixing to other vibrational levels in the trap and by the finite lifetime of the internal quantum states of the atoms.
We present precision spectroscopy on electrically trapped formaldehyde (H$_2$CO), demonstrating key attributes which will enable molecular spectroscopy with unprecedented precision. Our method makes use of a microstructured electric trap with homogeneous fields in the trap center and rotational transitions with minimal Stark broadening at a 'magic' offset electric field. Using molecules cooled to the low millikelvin temperature regime via optoelectrical Sisyphus cooling, we reduce Stark broadening on the $J=5\leftarrow4$ ($K=3$) transition at 364 GHz to well below 1 kHz, observe Doppler-limite…
We present a detailed experimental study of the Uhrig Dynamical Decoupling (UDD) sequence in a variety of noise environments. Our qubit system consists of a crystalline array of $^{9}$Be$^{+}$ ions confined in a Penning trap. We use an electron-spin-flip transition as our qubit manifold and drive qubit rotations using a 124 GHz microwave system. We study the effect of the UDD sequence in mitigating phase errors and compare against the well known CPMG-style multipulse spin echo as a function of pulse number, rotation axis, noise spectrum, and noise strength. Our results agree well with theoreti…
We propose a versatile Loschmidt echo protocol to detect and quantify multiparticle entanglement. It allows us to extract the quantum Fisher information for arbitrary pure states, and finds direct application in quantum metrology. In particular, the protocol applies to states that are generally difficult to characterize, as non-Gaussian states, and states that are not symmetric under particle exchange. We focus on atomic systems, including trapped ions, polar molecules, and Rydberg atoms, where entanglement is generated dynamically via long-range interaction, and show that the protocol is stab…
Sympathetic cooling of trapped ions has been established as a powerful technique for manipulation of non-laser-coolable ions (Raizen1992,Waki1992,Bowe1999,Barrett2003). For molecular ions, it promises vastly enhanced spectroscopic resolution and accuracy. However, this potential remains untapped so far, with the best resolution achieved being not better than $5\times10^{-8}$ fractionally, due to residual Doppler broadening being present in ion clusters even at the lowest achievable translational temperatures (Bressel2012). Here we introduce a general and accessible approach that enables Dopple…
When ground state atoms are excited to a Rydberg state, van der Waals interactions among them can lead to a strong suppression of the excitation. Despite the strong interactions the evolution can still be reversed by a simple phase shift in the excitation laser field. We experimentally prove the coherence of the excitation in the strong blockade regime by applying an `optical rotary echo' technique to a sample of magnetically trapped ultracold atoms, analogous to a method known from nuclear magnetic resonance. We additionally measured the dephasing time due to the interaction between the Rydbe…
We present an experimental scheme to perform spectroscopy of the $^2$S$_{1/2}-^2$P$_{1/2}$ and $^2$D$_{3/2}-^2$P$_{1/2}$ transitions in \Ca. By rapidly switching lasers between both transitions, we circumvent the complications of both dark resonances and Doppler heating. We apply this method to directly observe the micromotion modulated fluorescence spectra of both transitions and measure the dependence of the micromotion modulation index on the trap frequency. With a measurement time of 10 minutes, we can detect the center frequencies of both dipole transitions with a precision on the order o…
Trapped atoms and ions are among the best controlled quantum systems which find widespread applications in quantum information, sensing and metrology. For molecules, however, a similar degree of control is currently lacking owing to their complex energy-level structure. Quantum-logic protocols in which atomic ions serve as probes for molecular ions are a promising route for achieving this level of control, especially with homonuclear molecules that decouple from black-body radiation. Here, a quantum-non-demolition protocol on single trapped N$_2^+$ molecules is demonstrated. The spin-rovibroni…
Coherent nonlinear multi-pulse processes, nonlinear waves and echo effects in resonant media are the topical problems of modern optics and important tools of coherent spectroscopy and quantum information science. We generalize the McCall-Hahn area theorem to the formation of an arbitrary photon echo generated during the multi-pulse excitation of the optically dense resonant media. The derived theorem made it possible to reveal the nonlinear mechanism of generation and evolution of the photon echo signals inside the media after a two-pulse excitation. We find that a series of self-reviving echo…
We summarize efforts at NIST to implement quantum computation using trapped ions, based on a scheme proposed by J.I. Cirac and P. Zoller (Innsbruck University). The use of quantum logic to create entangled states, which can maximize the quantum-limited signal-to-noise ratio in spectroscopy, is discussed.
We demonstrate a general method for state detection of trapped ions that can be applied to a large class of atomic and molecular species. We couple a "spectroscopy" ion (Al+) to a "control" ion (Mg+) in the same trap and perform state detection through off-resonant laser excitation of the spectroscopy ion that induces coherent motion. The motional amplitude, dependent on the spectroscopy ion state, is measured either by time-resolved photon counting, or by resolved sideband excitations on the control ion. The first method provides a simplified way to distinguish "clock" states in Al+, which av…
Rapid progress in cooling and trapping of molecules has enabled first experiments on high resolution spectroscopy of trapped diatomic molecules, promising unprecedented precision. Extending this work to polyatomic molecules provides unique opportunities due to more complex geometries and additional internal degrees of freedom. Here, this is achieved by combining a homogeneous-field microstructured electric trap, rotational transitions with minimal Stark broadening at a 'magic' offset electric field, and optoelectrical Sisyphus cooling of molecules to the low millikelvin temperature regime. We …
Motivated by our observation of fast echo decay and a surprising coherence freeze, we have developed a pump-probe spectroscopy technique for vibrational states of ultracold $^{85}$Rb atoms in an optical lattice to gain information about the memory dynamics of the system. We use pump-probe spectroscopy to monitor the time-dependent changes of frequencies experienced by atoms and to characterize the probability distribution of these frequency trajectories. We show that the inferred distribution, unlike a naive microscopic model of the lattice, correctly predicts the main features of the observed…
$^{133}\text{Ba}^+$ has been identified as an attractive ion for quantum information processing due to the unique combination of its spin-1/2 nucleus and visible wavelength electronic transitions. Using a microgram source of radioactive material, we trap and laser-cool the synthetic $A$ = 133 radioisotope of barium II in a radio-frequency ion trap. Using the same, single trapped atom, we measure the isotope shifts and hyperfine structure of the $6^2 \text{P}_{1/2}$ $\leftrightarrow$ $6^2 \text{S}_{1/2}$ and $6^2 \text{P}_{1/2}$ $\leftrightarrow$ $5^2 \text{D}_{3/2}$ electronic transitions that…
We demonstrate the initialisation, read-out and high-speed manipulation of a qubit stored in a single 87 Rb atom trapped in a submicron-size optical tweezer. Single qubit rotations are performed on a sub-100 ns time scale using two-photon Raman transitions. Using the ``spin-echo'' technique, we measure an irreversible dephasing time of 34 ms. The read-out of the single atom qubit is at the quantum projection noise limit when averaging up to 1000 individual events.
Molecules are the most demanding quantum systems to be simulated by quantum computers because of their complexity and the emergent role of quantum nature. The recent theoretical proposal of Huh et al. (Nature Photon., 9, 615 (2015)) showed that a multi-photon network with a Gaussian input state can simulate a molecular spectroscopic process. Here, we report the first experimental demonstration of molecular vibrational spectroscopy of SO$_{2}$ with a trapped-ion system. In our realization, the molecular scattering operation is decomposed to a series of elementary quantum optical operations, whi…
We present a quantum logic scheme to detect atomic and molecular ions in different states of angular momentum based on their magnetic $g$-factors. The state-dependent magnetic $g$-factors mean that electronic, rotational or hyperfine states may be distinguished by their Zeeman splittings in a given magnetic field. Driving motional sidebands of a chosen Zeeman splitting enables reading out the corresponding state of angular momentum with an auxillary logic ion. As a proof-of-principle demonstration, we show that we can detect the ground electronic state of a ${^{174}}$Yb$^+$ ion using ${^{171}}…
We demonstrate spectroscopy and thermometry of individual motional modes in a mesoscopic 2D ion array using entanglement-induced decoherence as a method of transduction. Our system is a $\sim$400 $μ$m-diameter planar crystal of several hundred $^9$Be$^+$ ions exhibiting complex drumhead modes in the confining potential of a Penning trap. Exploiting precise control over the $^9$Be$^+$ valence electron spins, we apply a homogeneous spin-dependent optical dipole force to excite arbitrary transverse modes with an effective wavelength approaching the interparticle spacing ($\sim$20 \nolinebreak$μ$m…
We perform echo spectroscopy on ultra cold atoms in atom optics billiards, to study their quantum dynamics. The detuning of the trapping laser is used to change the ``perturbation'', which causes a decay in the echo coherence. Two different regimes are observed: First, a perturbative regime in which the decay of echo coherence is non-monotonic and partial revivals of coherence are observed. These revivals are more pronounced in traps with mixed dynamics as compared to traps where the dynamics is fully chaotic. Next, for stronger perturbations, the decay becomes monotonic and independent of the…
We experimentally study the ground state coherence properties of cesium atoms in a nanofiber-based two-color dipole trap, localized 200 nm away from the fiber surface. Using microwave radiation to coherently drive the clock transition, we record Ramsey fringes as well as spin echo signals and infer a reversible dephasing time $T_2^\ast=0.6$ ms and an irreversible dephasing time $T_2^\prime=3.7$ ms. By theoretically modelling the signals, we find that, for our experimental parameters, $T_2^\ast$ and $T_2^\prime$ are limited by the finite initial temperature of the atomic ensemble and the heatin…
We study a system of periodic Bose condensed atoms coupled to cavity photons using the input-output formalism. We show that the cavity will either act as a through pass Lorentzian filter when the superfluid fraction of the condensate is minimum or completely reflect the input field when the superfluid fraction is maximum. We show that by monitoring the ratio between the transmitted field and the reflected field, one can estimate the superfluid fraction.
We use Rabi spectroscopy to explore the low-energy excitation spectrum of a finite-temperature Bose gas of rubidium atoms across the phase transition to a Bose-Einstein condensate (BEC). To record this spectrum, we coherently drive the atomic population between two spin states. A small relative displacement of the spin-specific trapping potentials enables sideband transitions between different motional states. The intrinsic non-linearity of the motional spectrum, mainly originating from two-body interactions, makes it possible to resolve and address individual excitation lines. Together with s…
The quantum coherence of a Bose-Einstein condensate is studied using the concept of quantum fidelity (Loschmidt echo). The condensate is confined in an elongated anharmonic trap and subjected to a small random potential such as that created by a laser speckle. Numerical experiments show that the quantum fidelity stays constant until a critical time, after which it drops abruptly over a single trap oscillation period. The critical time depends logarithmically on the number of condensed atoms and on the perturbation amplitude. This behavior may be observable by measuring the interference fringes…
Due to the experimental time constraints of state of the art quantum simulations with trapped ions, the direct preparation of the ground state by adiabatically ramping the field of a transverse field Ising model becomes more and more difficult as the number of particles increase. We propose a spectroscopy protocol that intentionally creates excitations through diabatic ramping of the transverse field and measures a low-noise observable as a function of time for a constant field to reveal the structure of the coherent dynamics of the resulting many-body states. To simulate the experimental data…
We study the impact of inter-pulse phase fluctuation in free-electron X-ray laser on the signal in the photon echo spectroscopy, which is one of the simplest non-linear spectroscopic methods. A two-pulse echo model is considered with two-level atoms as the sample. The effect of both fluctuation amplitude and correlation strength of the random phase fluctuation is studied both numerically and analytically. We show that the random phase effect only affects the amplitude of the photon echo, yet not change the recovering time. Such random phase induces the fluctuation of recovering amplitude in th…
We devise a phase-coherent three-pulse protocol to probe the polariton dynamics in a trapped-ion quantum simulation. In contrast to conventional nonlinear signals, the presented scheme does not change the number of excitations in the system, allowing for the investigation of the dynamics within an $N$-excitation manifold. In the particular case of a filling factor one ($N$ excitations in an $N$-ion chain), the proposed interaction induces coherent transitions between a delocalized phonon superfluid and a localized atomic insulator phase. Numerical simulations of a two-ion chain demonstrate tha…
The static and dynamic properties of many-body quantum systems are often well described by collective excitations, known as quasiparticles. Engineered quantum systems offer the opportunity to study such emergent phenomena in a precisely controlled and otherwise inaccessible way. We present a spectroscopic technique to study artificial quantum matter and use it for characterizing quasiparticles in a many-body system of trapped atomic ions. Our approach is to excite combinations of the system's fundamental quasiparticle eigenmodes, given by delocalised spin waves. By observing the dynamical resp…
We experimentally demonstrate optical spectroscopy of magnetically trapped atoms on an atom chip. High resolution optical spectra of individual trapped clouds are recorded within a few hundred milliseconds. Detection sensitivities close to the single atom level are obtained by photoionization of the excited atoms and subsequent ion detection with a channel electron multiplier. Temperature and decay rates of the trapped atomic cloud can be monitored in real time for several seconds with only little detection losses. The spectrometer can be used for investigations of ultracold atomic mixtures an…
A mixed-species geometric phase gate has been proposed for implementing quantum logic spectroscopy on trapped ions that combines probe and information transfer from the spectroscopy to the logic ion in a single pulse. We experimentally realize this method, show how it can be applied as a technique for identifying transitions in currently intractable atoms or molecules, demonstrate its reduced temperature sensitivity, and observe quantum-enhanced frequency sensitivity when it is applied to multi-ion chains. Potential applications include improved readout of trapped-ion clocks and simplified err…
We study experimentally and theoretically discrete solitons in crystalline structures consisting of several tens of laser-cooled ions confined in a radiofrequency trap. Resonantly exciting localized, spectrally gapped vibrational modes of the soliton, a nonlinear mechanism leads to a nonequilibrium steady state of the continuously cooled crystal. We find that the propagation and the escape of the soliton out of its a quasi-one-dimensional channel can be described as a thermal activation mechanism. We control the effective temperature of the soliton's collective coordinate by the amplitude of t…
Nonlinear spectroscopy employs a series of laser pulses to interrogate dynamics in large interacting many-body systems, and has become a highly successful method for experiments in chemical physics. Current quantum optical experiments approach system sizes and levels of complexity which require the development of efficient techniques to assess spectral and dynamical features with scalable experimental overhead. However, established methods from optical spectroscopy of macroscopic ensembles cannot be applied straightforwardly to few-atom systems. Based on the ideas proposed in [M. Gessner et al…
We consider quantum gates for trapped ions using state-selective displacement of the ions. We generalize earlier work in order to treat arbitrary separations between the traps. This requires the impact of anharmonicity arising from the Coulomb interaction to be estimated. We show that its effects are always small enough to allow high fidelity. In particular, the method can be applied to two ions in the same trap. We also show that gates between non-neighbour ions, and hence a Toffoli (three-qubit controlled-NOT) gate, can be achieved. We discuss how the gate can be applied to logical qubits en…
Spectroscopic labels for a few particles with spin that are harmonically trapped in one-dimension with effectively zero-range interactions are provided by quantum numbers that characterize the symmetries of the Hamiltonian: permutations of identical particles, parity inversion, and the separability of the center-of-mass. The exact solutions for the non-interacting and infinitely repulsive cases are reduced with respect to these symmetries. This reduction explains how states of single-component and multi-component fermions and bosons transform under adiabatic evolution from non-interacting to s…
We investigate the crossover of the impurity-induced dynamics, in trapped one-dimensional Bose polarons subject to radio frequency (rf) pulses of varying intensity, from an adiabatic to a diabatic regime. Utilizing adiabatic pulses for either weak repulsive or attractive impurity-medium interactions, a multitude of polaronic excitations or mode-couplings of the impurity-bath interaction with the collective breathing motion of the bosonic medium are spectrally resolved. We find that for strongly repulsive impurity-bath interactions, a temporal orthogonality catastrophe manifests in resonances i…
Developing the isolation and control of ultracold atomic systems to the level of single quanta has led to significant advances in quantum sensing, yet demonstrating a quantum advantage in real world applications by harnessing entanglement remains a core task. Here, we realize a many-body quantum-enhanced sensor to detect weak displacements and electric fields using a large crystal of $\sim 150$ trapped ions. The center of mass vibrational mode of the crystal serves as high-Q mechanical oscillator and the collective electronic spin as the measurement device. By entangling the oscillator and the…
This review presents the Laser-Induced Fluorescence Spectroscopy (LIFS) of trapped gas-phase molecular ions. A brief description of the theory and experimental approaches involved in fluorescence spectroscopy, together with state-of-the-art LIFS experiments employing ion traps, is presented. Quadrupole ion traps are commonly used for spatial confinement of ions. One of the main challenges involved in such experiments is poor Signal-to-Noise Ratio (SNR) arising due to weak gas-phase fluorescence emission, high background noise, and small solid angle for the fluorescence collection optics. The e…
Revealing Noise in Axial Motion Through Quantum Noise Spectroscopy on a Trapped Ion Processor
Johns Hopkins University Applied Physics Laboratory（约翰斯·霍普金斯大学应用物理实验室）；HRL Laboratories, LLC（HRL实验室有限责任公司）；Sandia National Laboratories（桑迪亚国家实验室）；Department of Physics and Astronomy, University of New Mexico（新墨西哥大学物理与天文系）；Center for Quantum Information and Control, CQuIC, University of New Mexico（新墨西哥大学量子信息与控制中心）；Quantinuum；Johns Hopkins University（约翰斯·霍普金斯大学）
