The interelectronic-interaction effect on the transition probabilities in high-Z He-like ions is investigated within a systematic quantum electrodynamic approach. The calculation formulas for the interelectronic-interaction corrections of first order in 1/Z are derived using the two-time Green function method. These formulas are employed for numerical evaluations of the magnetic transition probabilities in heliumlike ions. The results of the calculations are compared with experimental values and previous calculations.
The nuclear recoil effect on the ground-state $g$ factor of highly charged boronlike ions is considered within the relativistic framework. The interelectronic-interaction contribution is evaluated within the Breit approximation employing two independent approaches: the second-order perturbation theory and the configuration-interaction Dirac-Fock-Sturm method. The uncertainty of the nuclear recoil $g$-factor contributions is significantly reduced, especially for low- and middle-$Z$ ions.
Based on a rigorous QED approach a theoretical analysis is performed for the two-photon transitions in heavy He-like ions. Special attention is paid to the interelectronic-interaction corrections to the decay rates that are taken into account within the two-time Green-function method. Detailed calculations are carried out for the two-photon transitions 2^1S_0 -> 1^1S_0 and 2^3S_1 -> 1^1S_0 in He-like ions within the range of nuclear numbers Z=28-92. The total decay rates together with the spectral distributions are given. The obtained results are compared with experimental values and previous …
Relativistic calculations of the second- and third-order contributions in magnetic field to the Zeeman splitting in boronlike ions are presented for the wide range of nuclear charge numbers $Z=6$--$92$. The interelectronic-interaction correction of the first order in $1/Z$ is evaluated to all orders in $αZ$. The higher-order corrections in $1/Z$ are taken into account approximately by means of effective screening potentials. The obtained results are important for interpretation of experimental data on the Zeeman splitting in boronlike ions, in particular, for the ARTEMIS experiment presently i…
The ground-state hyperfine splitting values of high-Z boronlike ions are calculated. Calculation of the interelectronic-interaction contribution is based on a combination of the 1/Z perturbation theory and the large-scale configuration-interaction Dirac-Fock-Sturm method. The screened QED corrections are evaluated utilizing an effective screening potential approach. Total hyperfine splitting energies are presented for several B-like ions of particular interest: {}^{45}Sc{}^{16+}, {}^{57}Fe{}^{21+}, {}^{207}Pb{}^{77+}, and {}^{209}Bi{}^{78+}. For lead and bismuth the experimental values of the …
Theoretical calculations of the interelectronic-interaction and QED corrections to the $g$ factor of the ground state of boronlike ions are presented. The first-order interelectronic-interaction and the self-energy corrections are evaluated within the rigorous QED approach in the effective screening potential. The second-order interelectronic interaction is considered within the Breit approximation. The nuclear recoil effect is also taken into account. The results for the ground-state $g$ factor of boronlike ions in the range $Z$=10--20 are presented and compared to the previous calculations.
The fully relativistic theory of the g factor of Li-like ions with nonzero nuclear spin is considered for the (1s)^2 2s state. The magnetic-dipole hyperfine-interaction correction to the atomic g factor is calculated including the one-electron contributions as well as the interelectronic-interaction effects of order 1/Z. This correction is combined with the interelectronic-interaction, QED, nuclear recoil, and nuclear size corrections to obtain high-precision theoretical values for the g factor of Li-like ions with nonzero nuclear spin. The results can be used for a precise determination of nu…
The rigorous QED evaluation of the one- and two-photon exchange corrections to the ground-state hyperfine splitting in Li-like ions is presented for the wide range of nuclear charge number $Z= 7 - 82$. The calculations are carried out in the framework of the extended Furry picture, i.e., with inclusion of the effective local screening potential in the zeroth-order approximation. The interelectronic-interaction contributions of the third and higher orders are taken into account in the framework of the Breit approximation employing the recursive perturbation theory. In comparison to the previous…
Calculations of various corrections to the g factor of Li-like ions are presented, which result in a significant improvement of the theoretical accuracy in the region Z = 6-92. The configuration-interaction Dirac-Fock method is employed for the evaluation of the interelectronic-interaction correction of order 1/Z^2 and higher. This correction is combined with the 1/Z interelectronic-interaction term derived within a rigorous QED approach. The one-electron QED corrections of first in αare calculated to all orders in the parameter αZ. The screening of QED corrections is taken into account to the…
The magnetic-dipole transition probabilities between the fine-structure levels (1s^2 2s^2 2p) ^2P_1/2 - ^2P_3/2 for B-like ions and (1s^2 2s 2p) ^3P_1 - ^3P_2 for Be-like ions are calculated. The configuration-interaction method in the Dirac-Fock-Sturm basis is employed for the evaluation of the interelectronic-interaction correction with negative-continuum spectrum being taken into account. The 1/Z interelectronic-interaction contribution is derived within a rigorous QED approach employing the two-time Green function method. The one-electron QED correction is evaluated within framework of the…
The nuclear recoil effect on the $g$ factor of the ground state of highly charged B-like ions is studied to first order in the electron-to-nucleus mass ratio $m/M$. The leading one-electron and two-electron recoil contributions are calculated nonperturbatively in the parameter $αZ$ within the rigorous QED formalism. The interelectronic-interaction correction to the nuclear recoil effect is evaluated in the Breit approximation by means of perturbation theory to the first order in $1/Z$. The higher-order interelectronic-interaction corrections are taken into account partially by performing the c…
The relativistic nuclear recoil, higher-order interelectronic-interaction, and screened QED corrections to the transition energies in Li-like ions are evaluated. The calculation of the relativistic recoil effect is performed to all orders in 1/Z. The interelectronic-interaction correction to the transition energies beyond the two-photon exchange level is evaluated to all orders in 1/Z within the Breit approximation. The evaluation is carried out employing the large-scale configuration-interaction Dirac-Fock-Sturm method. The rigorous calculation of the complete gauge invariant sets of the scre…
The fully relativistic theory of the Zeeman splitting of the $(1s)^2 2s$ hyperfine-structure levels in lithiumlike ions with $Z=6 - 32$ is considered for the magnetic field magnitude in the range from 1 to 10 T. The second-order corrections to the Breit -- Rabi formula are calculated and discussed including the one-electron contributions as well as the interelectronic-interaction effects of order 1/Z. The 1/Z corrections are evaluated within a rigorous QED approach. These corrections are combined with other interelectronic-interaction, QED, nuclear recoil, and nuclear size corrections to obtai…
The nuclear recoil correction to the g factor of boronlike ions is evaluated within the lowest-order relativistic (Breit) approximation. The interelectronic-interaction effects are taken into account to the first order of the perturbation theory in 1/Z. Higher orders in 1/Z are partly accounted for by means of the effective screening potential. The most accurate up-to-date values of this contribution are presented for the ions in the range Z=10-20.
QED corrections to the $g$ factor of Li-like and B-like ions in a wide range of nuclear charges are presented. Many-electron contributions as well as radiative effects on the one-loop level are calculated. Contributions resulting from the interelectronic interaction, the self-energy effect, and most of the terms of the vacuum-polarization effect are evaluated to all orders in the nuclear coupling strength $Zα$. Uncertainties resulting from nuclear size effects, numerical computations, and uncalculated effects are discussed.
The nuclear magnetic shielding is considered within the fully relativistic approach for the ground state of H-, Li-, and B-like ions in the range Z=32-92. The interelectronic interaction is evaluated to the first order of the perturbation theory in Li- and B-like ions. The calculations are based on the finite-field method. The numerical solution of the Dirac equation with the magnetic-field and hyperfine interactions included within the dual-kinetic-balance method is employed. The nuclear magnetic shielding constant is an important ingredient for accurate determination of the nuclear magnetic …
A rigorous evaluation of the complete gauge-invariant set of the screened one-loop QED corrections to the hyperfine structure and g factor in lithiumlike heavy ions is presented. The calculations are performed in both Feynman and Coulomb gauges for the virtual photon mediating the interelectronic interaction. As a result, the most accurate theoretical predictions for the specific difference between the hyperfine splitting values of H- and Li-like Bi ions as well as for the g factor of Li-like Pb ion are obtained.
The hyperfine splitting of the ground state of selected B-like ions within the range of nuclear charge numbers $Z=49-83$ is investigated in detail. The rigorous QED approach together with the large-scale configuration-interaction Dirac-Fock-Sturm method are employed for the evaluation of the interelectronic-interaction contributions of first and higher orders in $1/Z$. The screened QED corrections are evaluated to all orders in $αZ$ by using an effective potential. The influence of nuclear magnetization distribution is taken into account within the single-particle nuclear model.
The influence of hypothetical new interactions beyond the Standard Model on atomic spectra has attracted recent interest. In the present work, interelectronic photon-exchange corrections and radiative quantum electrodynamic corrections to the hypothetical contribution to the energy levels of few-electron ions from a new interaction are calculated. The $1s$, $2s$ and $2p_{1/2}$ ground states of H-like, Li-like and B-like ions are considered, as motivated by proposals to use isotope shift spectroscopy of few-electron ions in order to set stringent constraints on hypothetical new interactions. It…
Fully relativistic approach to evaluate the correlation effects in highly charged ions is presented. The interelectronic-interaction contributions of first and second orders in $1/Z$ are treated rigorously within the framework of bound-state quantum electrodynamics, whereas the calculations of the third- and higher-order contributions are based on the Dirac-Coulomb-Breit Hamiltonian. The developed approach allows one to deal with single as well as degenerate or quasi-degenerate states. We apply this approach to the calculations of the correlation contributions to the $n=1$ and $n=2$ energy lev…
The hyperfine splitting of the ground state of H-, Li-, and B-like ions is investigated in details within the range of nuclear numbers Z = 7-28. The rigorous QED approach together with the large-scale configuration-interaction Dirac-Fock-Sturm method are employed for the evaluation of the interelectronic-interaction contributions of first and higher orders in 1/Z. The screened QED corrections are evaluated to all orders in (αZ) utilizing an effective potential approach. The influence of nuclear magnetization distribution is taken into account within the single-particle nuclear model. The speci…
The ground state hyperfine splitting values and the transition probabilities between the hyperfine structure components of high Z lithiumlike ions are calculated in the range $Z=49-83$. The relativistic, nuclear, QED and interelectronic interaction corrections are taken into account. It is found that the Bohr-Weisskopf effect can be eliminated in a combination of the hyperfine splitting values of the hydrogenlike and lithiumlike ions of an isotope. This gives a possibility for testing the QED effects in a combination of the strong electric and magnetic fields of the heavy nucleus. Using the ex…
Dirac equation for an electron bound by a nucleus in the presence of external axially symmetric field can be solved numerically by using the dual-kinetic-balance conditions imposed on the finite basis set (A-DKB method [Rozenbaum et al, Phys. Rev. A 89, 012514 (2014)]). We present the application of this method to describe helium-like ions exposed to homogeneous external magnetic field. The second-order Zeeman shift and the nuclear magnetic shielding constant are evaluated for the ground state, including the leading contribution of the interelectronic interaction. The A-DKB values are compared…
$g$ factor of the $2p_j$ excited states in lithium-like ions
St. Petersburg State University（圣彼得堡国立大学）；ITMO University（伊托莫大学）；Petersburg Nuclear Physics Institute named by B. P. Konstantinov of National Research Centre “Kurchatov Institute”（库尔恰托夫国家研究中心鲍·波·康斯坦丁诺夫彼得堡核物理研究所）
The nuclear recoil effect on the $^2 P_{3/2}$-state $g$ factor of B-like ions is calculated to first order in the electron-to-nucleus mass ratio $m/M$ in the range $Z=18$--$92$. The calculations are performed by means of the $1/Z$ perturbation theory. Within the independent-electron approximation, the one- and two-electron recoil contributions are evaluated to all orders in the parameter $αZ$ by employing a fully relativistic approach. The interelectronic-interaction correction of first order in $1/Z$ is treated within the Breit approximation. Higher orders in $1/Z$ are partially taken into ac…
The magnetic dipole (M1) line strength between the fine-structure levels of the ground configurations in B-, F-, Al- and Cl-like ions are calculated for the four elements argon, iron, molybdenum and tungsten. Systematically enlarged multiconfiguration Dirac-Hartree-Fock~(MCDHF) wave functions are employed to account for the interelectronic interaction with the Breit interaction included in first-order perturbation theory. The QED corrections are evaluated to all orders in $αZ$ utilizing an effective potential approach. The calculated line strengths are compared with the results of other theori…
A method is proposed to determine the $M1$ nuclear transition amplitude and hence the lifetime of the "nuclear clock transition" between the low-lying ($\sim 8$ eV) first isomeric state and the ground state of $^{229}$Th from a measurement of the ground-state $g$ factor of few-electron $^{229}$Th ions. As a tool, the effect of nuclear hyperfine mixing (NHM) in highly charged $^{229}$Th-ions such as $^{229}$Th$^{89+}$ or $^{229}$Th$^{87+}$ is utilized. The ground-state-only $g$-factor measurement would also provide first experimental evidence of NHM in atomic ions. Combining the measurements fo…
Axion-Exchange Contribution to the Energy of Lithium-Like Ions
ITMO University（ITMO大学）；Saint Petersburg State University（圣彼得堡国立大学）；Petersburg Nuclear Physics Institute named after B.P. Konstantinov, National Research Centre “Kurchatov Institute”（以B.P.康斯坦丁诺夫命名的圣彼得堡核物理研究所，国家研究中心“库尔恰托夫研究所”）；St. Petersburg Electrotechnical University “LETI”（圣彼得堡电气工程学院“LETI”）
The nuclear recoil effect to the g factor of boron-like ions is investigated. The one-photon-exchange correction to the nuclear recoil effect is calculated in the non-relativistic approximation for the nuclear recoil operator and in the Breit approximation for the interelectronic-interaction operator. The screening potential is employed to estimate the higher-order contributions. The updated g-factor values are presented for the ground 2P_1/2 and first excited 2P_3/2 states of B-like argon 40^Ar^13+, which are presently being measured by the ARTEMIS group at GSI.
The two-time Green function method in quantum electrodynamics of high-Z few-electron atoms is described in detail. This method provides a simple procedure for deriving formulas for the energy shift of a single level and for the energies and wave functions of degenerate and quasi-degenerate states. It also allows one to derive formulas for the transition and scattering amplitudes. Application of the method to resonance scattering processes yields a systematic theory for the spectral line shape. The practical ability of the method is demonstrated by deriving formulas for the QED and interelectro…
In sudden perturbation approximation, the probability of the shake-up process accompanying inner-shell ionization is calculated for the isoelectronic sequences of Li-, Na- and K-like ions in the ground and excited $n$p and $n$d states. Numerical solutions of Hartree-Fock equations and hydrogen-like radial orbitals are used. Very large differences between the results of both approximations for all ions and strong dependences on ion charge are obtained at the beginning of the isoelectronic sequences.
We report on the observation of a strong perturbation of the electron gas induced by 20 MeV/u U$^{91+}$ ions and 13 MeV/u Pb$^{81+}$ ions channeled in silicon crystals. This collective response (wake effect) in-duces a shift of the continuum energy level by more than 100 eV, which is observed by means of Radiative Electron Capture into the K and L-shells of the projectiles. We also observe an increase of the REC probability by 20-50% relative to the probability in a non-perturbed electron gas. The energy shift is in agreement with calculations using the linear response theory, whereas the loca…
Polarization properties of the photons emitted in the two-photon decay of hydrogen-like ions are studied within the framework of the density matrix and second-order perturbation theory. In particular, we derive the polarization correlation function that gives the probability of the (two-photon) coincidence measurement performed by polarization-sensitive detectors. Detailed calculations of this function are performed for the $2s_{1/2} \to 1s_{1/2}$ transition in neutral hydrogen as well as Xe$^{53+}$ and U$^{91+}$ ions. The obtained results allow us to understand the influence of relativistic a…
We present visible spectra of Ag-like ($4d^{10}4f$) and Cd-like ($4d^{10}4f^2$) ions of Ho (atomic number $Z=67$), Er (68), and Tm (69) observed with a compact electron beam ion trap. For Ag-like ions, prominent emission corresponding to the M1 transitions between the ground state fine structure splitting $4f_{5/2}$--$4f_{7/2}$ is identified. For Cd-like ions, several M1 transitions in the ground state configuration are identified. The transition wavelength and the transition probability are calculated with the relativistic many-body perturbation theory and the relativistic CI + all-order appr…
Distribution of the entangled state of trapped atomic ions to long distance using quantum repeater protocol is considered. Indeed, the long distance is divided into short parts, and then using entanglement generation and entanglement swapping techniques in optomechanical cavities, the entanglement is distributed. To do the task, we perform interaction between trapped atomic ions in optomechanical cavities, operate proper measurements on trapped ions and also make Bell state measurement as a well-known way to swap the entanglement. Accordingly, the entanglement is distributed between target ion…
One- and two-photon transitions in the hydrogen atom are analytically evaluated in the absence and in the presence of an external electric field. The emission probabilities are different for the hydrogen and anti-hydrogen atoms due to the existence of contributions, linear in electric field. The magnitude of these contributions is evaluated within the nonrelativistic limit. The Coulomb Green function method is applied. Different nonrelativistic "forms" for the decay probabilities in combination with different gauge choices are considered. The three-photon E1E1E1 2p-1s transition probability is…
Electronic bridge excitation of the 76 eV nuclear isomeric state in $^{235}$U is shown to be strongly enhanced in the U$^{7+}$ ion, potentially enabling laser excitation of this nucleus. This is because the electronic spectrum has a very high level density near the nuclear transition energy that ensures the resonance condition is fulfilled. We present a quantum statistical theory based on many-body quantum chaos to demonstrate that typical values for the electronic factor increase the probability of electronic bridge in $^{235}$U$^{7+}$ by many orders of magnitude. We also extract the nuclear …
Spin effects in the tunneling regime of strong field ionization of hydrogenlike highly charged ions in linearly as well as circularly polarized laser fields are investigated. The impact of the polarization of a laser field on the spin effects are analyzed. Spin-resolved differential ionization rates are calculated employing the relativistic Coulomb-corrected strong-field approximation (SFA) developed in the previous paper of the series. Analytical expressions for spin asymmetries and spin flip probability, depending on the laser's polarization, are obtained for the photoelectron momentum corre…
Using trapped ion quantum bits in a scalable microfabricated surface trap, we perform the Bernstein-Vazirani algorithm. Our architecture relies upon ion transport and can readily be expanded to larger systems. The algorithm is demonstrated using two- and three-ion chains. For three ions, an improvement is achieved compared to a classical system using the same number of oracle queries. For two ions and one query, we correctly determine an unknown bit string with probability 97.6(8)%. For three ions, we succeed with probability 80.9(3)%.
The quantum electrodynamical theory of the two-photon transitions in hydrogenlike ions is presented. The emission probability for 2s1/2 -> 2E1+1s1/2 transitions is calculated and compared to the results of the previous calculations. The emission probabilities 2p12 -> E1E2+1s1/2 and 2p1/2 -> E1M1+1s1/2 are also calculated for the nuclear charge Z values 1-100. This is the first calculation of the two latter probabilities. The results are given in two different gauges.
Isotope effects in reactions between Mg+ in the 3p 2P3/2 excited state and molecular hydrogen at thermal energies are studied through single reaction events. From only ~250 reactions with HD, the branching ratio between formation of MgD+ and MgH+ is found to be larger than 5. From additional 65 reactions with H2 and D2 we find that the overall decay probability of the intermediate MgH2+, MgHD+ or MgD2+ complexes is the same. Our study shows that few single ion reactions can provide quantitative information on ion-neutral reactions. Hence, the method is well-suited for reaction studies involvin…
The delta function gauge of the electromagnetic potential allows semiclassical formulas to be obtained for the probability of exciting a single electron out of the ground state in an ultrarelativistic heavy ion reaction. Exact formulas have been obtained in the limits of zero impact parameter and large, perturbative, impact parameter. The perturbative impact parameter result can be exploited to obtain a semi-empirical cross section formula of the form, sigma = A ln(gamma) + B, for single electron ionization. A and B can be evaluated for any combination of target and projectile, and the resulti…
Hyperfine induced $2s2p~^3P_0 \rightarrow 2s^2~^1S_0$ transition rates in an external magnetic field for Be-like $^{47}$Ti were calculated based on the multiconfiguration Dirac-Fock method. It was found that the transition probability is dependent on the magnetic quantum number $M_F$ of the excited state, even in the weak field. The present investigation clarified that the difference of the hyperfine induced transition rate of Be-like Ti ions between experiment [Schippers {\sl et al.}, Phys Rev Lett {\bf 98}, (2007) 033001(4)] and theory does not result from the influence of external magnetic …
Ionization of hydrogen-like ions by intense, circularly polarized laser pulses is analyzed under the scope of the relativistic strong-field approximation. We show that, for specific parameters of the laser field, the energy spectra of photoelectrons present a broad region without interference (supercontinuum) which can be controlled by modifying the laser field intensity. The physical interpretation of the process is developed according to the Keldysh theory, emphasizing the importance of the complex-time saddle point contributions to the total probability of photoionization. The corresponding…
