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arXiv 2603.18445cond-mat.str-el
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二维强关联半金属中的空间间接激子凝聚

Spatially Indirect Exciton Condensation in Two-Dimensional Strongly Correlated Semimetals

School of Physics, Sun Yat-sen University(中山大学物理学院)

Yao Zeng, Shi-Cong Mo, Xiang Chen, Wéi Wú

AI总结:

利用动力学平均场和行列式量子蒙特卡洛方法,研究三角晶格二维半金属中强在位库仑相互作用对空间间接激子凝聚的抑制效应,并发现轨道选择性的电子-空穴配对态。

摘要:

近年来,识别具有激子绝缘体基态的材料一直是凝聚态物理的主要追求之一。过渡金属硫族化合物(TMC)中的候选材料,包括$1T-\mathrm{TiSe_2}$、$\mathrm{Ta_2Pd_3Te_5}$和$\mathrm{Ta_2NiSe_5}$,共享一个关键共同特征:它们的低能物理由受强在位库仑相互作用的$d$轨道电子主导。在本工作中,我们研究了三角晶格二维半金属中的空间间接激子凝聚。通过结合动力学平均场理论和行列式量子蒙特卡洛方法,我们研究了包含强在位相互作用($U$)和轨道间相互作用($V$)的两轨道和三轨道哈伯德模型。我们的结果表明,在位哈伯德$U$可以强烈抑制凝聚温度$T_c$,这种效应在较高电子-空穴对密度时尤为显著。这种行为与没有在位$U$的情况形成鲜明对比,后者中$T_c$在固定$V$下随对密度增加而增长。此外,我们在三轨道模型中发现了多个电子-空穴配对通道之间的竞争,这也抑制了激子凝聚的$T_c$。我们识别出一种轨道选择性的电子-空穴配对态。这些发现可能有助于解释TMC材料中强结合能与间接激子相对较低转变温度之间的巨大差异,为理解和工程化具有强关联$d$壳层电子的材料中的激子凝聚提供了重要见解。

英文摘要:

Identifying materials hosting an excitonic insulator ground state has been one of the major pursuits in condensed matter physics in recent years. Promising candidates in transition metal chalcogenide compounds (TMC), including $1T-\mathrm{TiSe_2}$, $\mathrm{Ta_2Pd_3Te_5}$, and $\mathrm{Ta_2NiSe_5}$, share a crucial common characteristic: their low-energy physics is governed by electrons in $d-$ orbitals subject to strong on-site Coulomb interactions. In this work, we investigate spatially indirect exciton condensation in two-dimensional semimetals on triangular lattice. Using a combination of dynamical mean-field theory and the determinant quantum Monte Carlo method, we study two- and three-orbital Hubbard models incorporating strong on-site ($U$) and inter-orbital interactions ($V$). Our results demonstrate that on-site Hubbard $U$ can strongly suppress the condensation temperature $T_c$, an effect that is particularly pronounced at higher electron-hole pair densities. This behavior contrasts sharply with the case without on-site $U$, where $T_c$ grows with pair density at fixed $V$. Moreover, we uncover competition among multiple electron-hole pairing channels in the three-orbital model, which also acts to suppress $T_c$ of exciton condensation. An orbital-selective electron-hole pairing state is identified. These findings may help explain the large discrepancy between strong binding-energy and relative low transition temperature for indirect excitons in TMCs materials, offering important insights for understanding and engineering exciton condensation in materials with strongly correlated $d-$ shell electrons.

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