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arXiv 0901.1014cond-mat.mtrl-scicond-mat.str-el
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Fe $_{1-x}$ Co $_{x}$ Si中的电子-声子相互作用和光谱重量转移

Electron-phonon interaction and spectral weight transfer in Fe$_{1-x}$Co$_{x}$Si

D. Menzel, P. Popovich, N. N. Kovaleva, J. Schoenes, K. Doll, A. V. Boris

摘要:

对Fe $_{1-x}$ Co $_{x}$ Si单晶在0.01 eV ~ 6.2 eV的光谱范围内进行了全面的椭圆偏振研究。在7 K时,FeSi的直接带隙为73 meV,间接带隙为10 meV.四个红外线活跃的声子之一,在能量上接近直接吸收边耦合到电子和低能量声子。这是显而易见的,从声子线形状的不对称性和其频率的降低时,吸收边跨越声子能量由于直接带隙的温度依赖性的偏移。随着温度的升高,间接能隙改变符号,表现为从半导体到半金属的转变。在低能量下的光谱权重的相应增益在几个eV的能量范围内被恢复。目前的研究结果强烈支持该模型表明,Fe $_{1-x}$ Co $_{x}$ Si可以很好地描述在巡回图片,考虑到自能校正。

英文摘要:

A comprehensive ellipsometric study was performed on Fe$_{1-x}$Co$_{x}$Si single crystals in the spectral range from 0.01 eV to 6.2 eV. Direct and indirect band gaps of 73 meV and 10 meV, respectively, were observed in FeSi at 7 K. One of four infrared-active phonons that is energetically close to the direct absorption edge is coupled both to the electrons and to the low-energy phonon. This is evident from asymmetry in the phonon line shape and a reduction of its frequency when the absorption edge shifts across the phonon energy due to the temperature dependence of the direct band gap. As the temperature increases, the indirect gap changes sign, which manifests as a transition from a semiconductor to a semimetal. The corresponding gain of the spectral weight at low energies was recovered within an energy range of several eV. The present findings strongly support the model indicating that Fe$_{1-x}$Co$_{x}$Si can be well described in an itinerant picture, taking into account self-energy corrections.

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