Quantum catalysts enable transformations that otherwise would be forbidden, offering a pathway to surpass conventional limits in quantum information processing. Among them, embezzling catalysts stand out for achieving near-perfect performance while tolerating only minimal disturbance, bridging the gap between ideal and practical catalysis. Yet, this superior capability comes at a cost: Each use slightly degrades the catalyst, leading to an inevitable accumulation of imperfection. This gradual decay defines their most distinctive property -- reusability -- which, despite its fundamental importance, remains largely unexplored. Here, we establish a quantitative framework to characterize the operational lifetime of embezzling catalysts, focusing on their role in entanglement distillation and extending the analysis to quantum teleportation. We show that the catalytic advantage inevitably diminishes with repeated use, deriving bounds on the maximum effective reuse rounds for a desired performance gain. Our results uncover the finite reusability of catalysts in quantum processes and point toward sustainable strategies for quantum communication.
We provide a reusability report of the method presented by Chen et al. in "Optimizing quantum annealing schedules with Monte Carlo tree search enhanced with neural networks" and add further benchmarks on Max-Cut problems.
By considering an unreliable oracle in a query-based model of quantum learning, we present a tradeoff relation between the oracle's reliability and the reusability of quantum state of the input data. The tradeoff relation manifests as the fundamental upper bound on the reusability. This limitation on the reusability would increase the quantum access to the input data, i.e., the usage of quantum random access memory (qRAM), repeating the preparation of a superposition of `big' input data on the query failure. However, it is found that, a learner can obtain a correct answer even from an unreliab…
Quantum resource manipulation may include an ancillary state called a catalyst, which aids the transformation while restoring its original form at the end, and characterizing the enhancement enabled by catalysts is essential to reveal the ultimate manipulability of the precious resource quantity of interest. Here, we show that allowing correlation among multiple catalysts can offer arbitrary power in the manipulation of quantum coherence. We prove that any state transformation can be accomplished with an arbitrarily small error by covariant operations with catalysts that may create a correlati…
Without additional resources, it is often impossible to transform one entangled quantum state into another with local quantum operations and classical communication. Jonathan and Plenio [Phys. Rev. Lett. 83, 3566(1999)] presented an interesting example showing that the presence of another state, called a catalyst, enables such a transformation without changing the catalyst. They also pointed out that in general it is very hard to find an analytical condition under which a catalyst exists. In this paper we study the existence of catalysts for two incomparable quantum states. For the simplest ca…
The viability of non-stoquastic catalyst Hamiltonians to deliver consistent quantum speedups in quantum adiabatic optimization remains an open question. The infinite-range ferromagnetic $p$-spin model is a rare example exhibiting an exponential advantage for non-stoquastic catalysts over its stoquastic counterpart. We revisit this model and note how the incremental changes in the ground state wavefunction give an indication of how the non-stoquastic catalyst provides an advantage. We then construct two new examples that exhibit an advantage for non-stoquastic catalysts over stoquastic catalyst…
Quantum catalysis is a fascinating concept which demonstrates that certain transformations can only become possible when given access to a specific resource that has to be returned unaffected. It was first discovered in the context of entanglement theory and since then applied in a number of resource-theoretic frameworks, including quantum thermodynamics. Although in that case the necessary (and sometimes also sufficient) conditions on the existence of a catalyst are known, almost nothing is known about the precise form of the catalyst state required by the transformation. In particular, it is…
We investigate the basic constraint on amplifying the asymmetry in quantum states with correlated catalysts. Here a correlated catalyst is a finite-dimensional auxiliary, which exactly preserves its reduced state while allowed to become correlated to the quantum system. Interestingly, we prove that under translationally invariant operations, catalysts in pure states are useless in any state transformation, while with a correlated catalyst in a mixed state, one can enlarge the set of accessible states from an initially asymmetric state. Moreover, we show that the power of a catalyst increases w…
Quantum catalytic transformations play important roles in the transformation of quantum entangled states under local operations and classical communications (LOCC). The key problems in catalytic transformations are the existence and the bounds on the catalytic states. We present the necessary conditions of catalytic states based on a set of points given by the Schmidt coefficients of the entangled source and target states. The lower bounds on the dimensions of the catalytic states are also investigated. Moreover, we give a detailed protocol of quantum mixed state transformation under entanglem…
The resource theory of quantum coherence is an important topic in quantum information science. Standard coherence distillation and dilution problems have been thoroughly studied. In this paper, we introduce and study the problem of one-shot coherence distillation with catalysts. In order to distill more coherence from a state of interest, a catalytic system can be involved and a jointly free operation is applied to both systems. The joint output state should be a maximally coherent state in tensor product with the unchanged catalysts, with some allowable fidelity error. We consider several dif…
The evolution of quantum hardware is highlighting the need for advances in quantum software engineering that help developers create quantum software with good quality attributes. Specifically, reusability has been traditionally considered an important quality attribute in terms of efficiency of cost and effort. Increasing the reusability of quantum software will help developers create more complex solutions, by reusing simpler components, with better quality attributes, as long as the reused components have also these attributes. This work focuses on the reusability of oracles, a well-known pa…
We propose a protocol for quantum adiabatic optimization, whereby an intermediary Hamiltonian that is diagonal in the computational basis is turned on and off during the interpolation. This `diagonal catalyst' serves to bias the energy landscape towards a given spin configuration, and we show how this can remove the first-order phase transition present in the standard protocol for the ferromagnetic $p$-spin and the Weak-Strong Cluster problems. The success of the protocol also makes clear how it can fail: biasing the energy landscape towards a state only helps in finding the ground state if th…
Coherent catalyst induced stabilization of ergotropy in open quantum batteries
Center for Quantum Materials and Computational Condensed Matter Physics, Faculty of Science, Kunming University of Science and Technology（昆明理工大学理学院量子材料与计算凝聚态物理中心）
The Ising model with a transverse field and an antiferromagnetic transverse interaction is represented as a matrix in the computational basis with non-zero off-diagonal elements with both positive and negative signs and thus may be regarded to be non-stoquastic. We show that the local Boltzmann factors of such a system under an appropriate Suzuki-Trotter representation can be chosen non-negative and thus may potentially be simulated classically without a sign problem if the parameter values are limited to a subspace of the whole parameter space. We then derive conditions for parameters to sati…
We introduce the general catalysts for pure entanglement transformations under local operations and classical communications in such a way that we disregard the profit and loss of entanglement of the catalysts per se. As such, the possibilities of pure entanglement transformations are greatly expanded. Remarkably, we find an interesting phenomenon that, in some situations, incomparable pairs ${| ψ> ,| ϕ> \} $ and ${| χ> ,| χ^{\prime}> \} $ can assist each other mutually so as to realize the transformation $| ψ> | χ> \to| ϕ> | χ^{\prime}>$. We also design an efficient algorithm to detect whethe…
We determine all $2\times 2$ quantum states that can serve as useful catalysts for a given probabilistic entanglement transformation, in the sense that they can increase the maximal transformation probability. When higher-dimensional catalysts are considered, a sufficient and necessary condition is derived under which a certain probabilistic transformation has useful catalysts.
The role of nonstoquasticity in the field of quantum annealing and adiabatic quantum computing is an actively debated topic. We study a strongly-frustrated quasi-one-dimensional quantum Ising model on a two-leg ladder to elucidate how a first-order phase transition with a topological origin is affected by interactions of the $\pm XX$-type. Such interactions are sometimes known as stoquastic (negative sign) and nonstoquastic (positive sign) "catalysts". Carrying out a symmetry-preserving real-space renormalization group analysis and extensive density-matrix renormalization group computations, w…
Randomness can help one to implement quantum maps that cannot be realized in a deterministic fashion. Recently, it was discovered that explicitly treating a randomness source as a quantum system could double the efficiency as a catalyst for some tasks. In this work, we first show that every quantum channel that can be implemented with a randomness source without leaking information to it must be a catalysis. For that purpose, we prove a new no-go theorem that generalizes the no-hiding theorem, the no-secret theorem that states no quantum information can be shared with other system as a secret …
In this work we show that the molecular chemical bond formation and dissociation in presence of the d-band of a metal catalyst can be described as a Quantum Dynamical Phase Transition (QDPT). This agree with DFT calculations that predict sudden jumps in some observables as the molecule breaks. According to our model this phenomenon emerges because the catalyst provides for a non- Hermitian Hamiltonian. We show that when the molecule approaches the surface, as occurs in the Heyrovsky reaction of H 2, the bonding H 2 orbital has a smooth crossover into a bonding molecular orbital built with the …
Quantum thermodynamics is a research field that aims at fleshing out the ultimate limits of thermodynamic processes in the deep quantum regime. A complete picture of quantum thermodynamics allows for catalysts, i.e., systems facilitating state transformations while remaining essentially intact in their state, very much reminding of catalysts in chemical reactions. In this work, we present a comprehensive analysis of the power and limitation of such thermal catalysis. Specifically, we provide a family of optimal catalysts that can be returned with minimal trace distance error after facilitating…
We study the weak-strong cluster problem for quantum annealing in its mean-field version as proposed by Albash [Phys. Rev. A 99 (2019) 042334] who showed by numerical diagonalization that non-stoquastic $XX$ interactions (non-stoquastic catalysts) remove the problematic first-order phase transition. We solve the problem exactly in the thermodynamic limit by analytical methods and show that the removal of the first-order transition is successfully achieved either by stoquastic or non-stoquastic $XX$ interactions depending on whether the $XX$ interactions are introduced within the weak cluster, …
The majorization relation has been shown to be useful in classifying which transformations of jointly held quantum states are possible using local operations and classical communication. In some cases, a direct transformation between two states is not possible, but it becomes possible in the presence of another state (known as a catalyst); this situation is described mathematically by the trumping relation, an extension of majorization. The structure of the trumping relation is not nearly as well understood as that of majorization. We give an introduction to this subject and derive some new re…
There are various physical scenarios in which one can only implement operations with a certain symmetry. Under such restriction, a system in a symmetry-breaking state can be used as a catalyst, e.g. to prepare another system in a desired symmetry-breaking state. This sort of (approximate) catalytic state transformations are relevant in the context of (i) state preparation using a bounded-size quantum clock or reference frame, where the clock or reference frame acts as a catalyst, (ii) quantum thermodynamics, where again a clock can be used as a catalyst to prepare states which contain coherenc…
Catalytic Stabilization of Ergotropy and Backflow Suppression in Open Many-Body Quantum Batteries
Center for Quantum Materials and Computational Condensed Matter Physics, Faculty of Science, Kunming University of Science and Technology（昆明理工大学理学院量子材料与计算凝聚态物理中心）
We show that in the presence of arbitrary catalysts, any pure bipartite entangled state can be converted into any other to unlimited accuracy without the use of any communication, quantum or classical.
