Contemporary quantum materials research is guided by themes of topology and of electronic correlations. A confluence of these two themes is engineered in "moiré materials", an emerging class of highly tunable, strongly correlated two-dimensional (2D) materials designed by the rotational or lattice misalignment of atomically thin crystals. In moiré materials, dominant Coulomb interactions among electrons give rise to collective electronic phases, often with robust topological properties. Identifying the mechanisms responsible for these exotic phases is fundamental to our understanding of strongly interacting quantum systems, and to our ability to engineer new material properties for potential future technological applications. In this Review, we highlight the contributions of local spectroscopic, thermodynamic, and electromagnetic probes to the budding field of moiré materials research. These techniques have not only identified many of the underlying mechanisms of the correlated insulators, generalized Wigner crystals, unconventional superconductors, moiré ferroelectrics, and topological orbital ferromagnets found in moiré materials, but they have also uncovered fragile quantum phases that have evaded spatially averaged global probes. Furthermore, we highlight recently developed local probe techniques, including local charge sensing and quantum interference probes, that have uncovered new physical observables in moiré materials.
Starting from a continuum-model description, we develop a microscopic weak-coupling theory for superconductivity in twisted double-bilayer graphene. We study both electron-phonon and entirely electronic pairing mechanisms. In each case, the leading superconducting instability transforms under the trivial representation, $A$, of the point group $C_3$ of the system, while the subleading pairing phases belong to the $E$ channel. We explicitly compute the momentum dependence of the associated order parameters and find that the leading state has no nodal points for electron-phonon pairing but exhib…
Stacking monolayers of transition metal dichalcogenides into a heterostructure with a finite twist-angle gives rise to artificial moiré superlattices with a tunable periodicity. As a consequence, excitons experience a periodic potential, which can be exploited to tailor optoelectronic properties of these materials. While recent experimental studies have confirmed twist-angle dependent optical spectra, the microscopic origin of moiré exciton resonances has not been fully clarified yet. Here, we combine first principle calculations with the excitonic density matrix formalism to study transitions…
Moire superlattices in van der Waals (vdW) heterostructures could trap strongly bonded and long lived interlayer excitons. Assumed to be localized, these moire excitons could form ordered quantum dot arrays, paving the way for novel optoelectronic and quantum information applications. Here we perform first principles simulations to shed light on moire excitons in twisted MoS2/WS2 heterostructures. We provide the direct evidence of localized interlayer moire excitons in vdW heterostructures. The moire potentials are mapped out based on spatial modulations of energy gaps. Nearly flat valence ban…
Transition metal dichalcogenide (TMD) moiré heterostructures provide an ideal platform to explore the extended Hubbard model1 where long-range Coulomb interactions play a critical role in determining strongly correlated electron states. This has led to experimental observations of Mott insulator states at half filling2-4 as well as a variety of extended Wigner crystal states at different fractional fillings5-9. Microscopic understanding of these emerging quantum phases, however, is still lacking. Here we describe a novel scanning tunneling microscopy (STM) technique for local sensing and manip…
Different atomistic registry between the layers forming the inner and outer nanotubes can form one-dimensional (1D) van der Waals (vdW) moiré superlattices. Unlike the two-dimensional (2D) vdW moiré superlattices, effects of 1D vdW moiré superlattices on electronic and optical properties in 1D moiré superlattices are not well understood, and they are often neglected. In this Perspective, we summarize new experimental observations and theoretical perspectives related to interlayer interactions in double-walled carbon nanotubes (DWNTs), a representative 1D vdW moiré system. Our discussion will f…
Recent advances in the field of vertically stacked 2D materials have revealed a rich exciton landscape. In particular, it has been demonstrated that out-of-plane electrical fields can be used to tune the spectral position of spatially separated interlayer excitons. Other studies have shown that there is a strong hybridization of exciton states, resulting from the mixing of electronic states in both layers. However, the connection between the twist-angle dependent hybridization and field-induced energy shifts has remained in the dark. Here, we investigate on a microscopic footing the interplay …
Graphene-based moiré systems have attracted considerable interest in recent years as they display a remarkable variety of correlated phenomena. Besides insulating and superconducting phases in the vicinity of integer fillings of the moiré unit cell, there is growing evidence for electronic nematic order both in twisted bilayer graphene and twisted double-bilayer graphene (tDBG), as signaled by the spontaneous breaking of the threefold rotational symmetry of the moiré superlattices. Here, we combine symmetry-based analysis with a microscopic continuum model to investigate the structure of the n…
Controlling matter-light interactions with cavities is of fundamental importance in modern science and technology. It is exemplified in the strong-coupling regime, where matter-light hybrid modes form, with properties controllable via the photon component on the optical-wavelength scale. In contrast, matter excitations on the nanometer scale are harder to access. In two-dimensional van der Waals heterostructures, a tunable moiré lattice potential for electronic excitations may form, enabling correlated electron gases in lattice potentials. Excitons confined in moiré lattices have also been rep…
We show that, quite generally, quantum geometry plays a major role in determining the low-energy physics in strongly correlated lattice models at fractional band fillings. We identify limits in which the Fubini Study metric dictates the ground states and show that this is highly relevant for Moiré materials leading to symmetry breaking and interaction driven Fermi liquids. This phenomenology stems from a remarkable interplay between the quantum geometry and interactions which is absent in continuum Landau levels but generically present in lattice models where these terms tend to destabilize e.…
A Catalogue of Topological Moiré Bands in Twisted Semiconductors
Beijing National Laboratory for Condensed Matter Physics and Institute of Physics, Chinese Academy of Sciences（中国科学院物理研究所与凝聚态物理北京国家实验室）；University of Chinese Academy of Sciences（中国科学院大学）；Condensed Matter Physics Data Center of Chinese Academy of Sciences（中国科学院凝聚态物理数据中心）
Light-matter interactions in layered materials and heterostructures: from moiré physics and magneto-optical effects to ultrafast dynamics and hybrid meta-photonics
We extend a field theoretic approach for the investigation of the electronic charge-current density response of crystalline systems to arbitrary applied electromagnetic fields. The approach leads to the introduction of microscopic polarization and magnetization fields, as well as free charge and current densities, the dynamics of which are described by a lattice gauge theory. The spatial averages of such quantities constitute the fields of macroscopic electrodynamics. We implement this formalism to study the orbital electronic response of a class of insulators to applied uniform dc electric an…
We present a theory of the spin Hall magnetoresistance of metals in contact with magnetic insulators. We express the spin-mixing conductances, which govern the phenomenology of the effect, in terms of the microscopic parameters of the interface and the spin-spin correlation functions of the local moments on the surface of the magnetic insulator. The magnetic field and temperature dependence of the spin-mixing conductances leads to a rich behaviour of the resistance due to an interplay between the Hanle effect and spin mixing at the interface. Our theory provides a useful tool for understanding…
Magic-angle twisted bilayer graphene (TBG) has attracted significant interest recently due to the discoveries of diverse correlated and topological states in this system. Despite the extensive research on the electron-electron interaction effects and topological properties of the electrons, the phonons of magic-angle TBG are relatively less explored. In this work, we study the phonon properties in magic-angle TBG based on \textit{ab} \textit{initio} deep potential molecular dynamics. We have calculated phonon band structures and density of states at the magic angle, and have systematically ana…
The pressure tensor (equivalent to the negative stress tensor) at both microscopic and macroscopic levels is fundamental to many aspects of engineering and science, including fluid dynamics, solid mechanics, biophysics, and thermodynamics. In this perspective paper, we review methods to calculate the microscopic pressure tensor. Connections between different pressure forms for equilibrium and non-equilibrium systems are established. We also point out several challenges in the field, including the historical controversies over the definition of the microscopic pressure tensor; the difficulties …
The quantised Josephson junction equation that underpins the behaviour of charge qubits and other tunnel devices is usually derived through cannonical quantisation of the classical macroscopic Josephson relations. However, this approach may neglect effects due to the fact that the charge qubit consists of a superconducting island of finite size connected to a large superconductor. We show that the well known quantised Josephson equation can be derived directly and simply from a microscopic many-body Hamiltonian. By choosing the appropriate strong coupling limit we produce a highly simplified H…
The interfacial Dzyaloshinskii-Moriya interaction (DMI) of a heavy metal (HM)/ferromagnetic (FM) metal heterostructure is vital to the current-induced domain wall motion (CIDWM) at an ultrahigh velocity. However, strong DMI also tilts the moving domain wall (DW) plane, and the mechanism for this tilting is not quite clear. In this work, we have found that this tilting may be understood based on a micromagnetic calculation from a microscopic dynamical perspective. The DMI-induced antisymmetric moment structure at the two boundaries of the track needs to be paid attention. In the early stage of …
A general formalism is presented to describe the turnover frequency (TOF) during heterogeneous catalysis beyond a mean field treatment. For every elementary reaction we define its multiplicity as the number of times the reaction can be performed in the current configuration of the catalyst surface, divided by the number of active sites. It is shown that any change in the multiplicity with temperature can be directly understood as a modification in configurational entropy. Based on this, we determine the probability of observing any particular elementary reaction, leading to a procedure for ide…
The photovoltaic reciprocity theory relates the electroluminescence spectrum of a solar cell under applied bias to the external photovoltaic quantum efficiency of the device as measured at short circuit conditions. Its derivation is based on detailed balance relations between local absorption and emission rates in optically isotropic media with non-degenerate quasi-equilibrium carrier distributions. In many cases, the dependence of density and spatial variation of electronic and optical device states on the point of operation is modest and the reciprocity relation holds. In nanostructure-based…
