Trapped samples of ultracold molecules are often short-lived, because close collisions between them result in trap loss. We investigate the use of shielding with static electric fields to create repulsive barriers between polar molecules to prevent such loss. Shielding is very effective even for RbCs, with a relatively low dipole moment, and even more effective for molecules such as NaK, NaRb and NaCs, with progressively larger dipoles. Varying the electric field allows substantial control over the scattering length, which will be crucial for the stability or collapse of molecular Bose-Einstein condensates. This arises because the dipole-dipole interaction creates a long-range attraction that is tunable with electric field. For RbCs, the scattering length is positive across the range where shielding is effective, because the repulsion responsible for shielding dominates. For NaK, the scattering length can be tuned across zero to negative values. For NaRb and NaCs, the attraction is strong enough to support tetraatomic bound states, and the scattering length passes through resonant poles where these states cross threshold. For KAg and CsAg, there are multiple bound states and multiple poles. For each molecule, we calculate the variation of scattering length with field and comment on the possibilities for exploring new physics.
We investigate the ground state properties and tunneling dynamics of ultracold dipolar bosons in a one dimensional triple well trap from a few-body ab-initio perspective. Our focus is primarily on the distinctive features of dipolar bosons compared to the contact interacting bosons. Formation of intra-well localization is observed for very strong dipolar interaction. General population rearangement as well as fragmentation and localization effects have been found, depending strongly on the particle number. The energy spectrum for two particles exhibits avoided crossings that lead to several di…
We study a quasi two dimensional dipolar gas at finite, but ultralow temperatures using the classical field approximation. The method, already used for a contact interacting gas, is extended here to samples with a weakly interacting long-range inter-atomic potential. We present statistical properties of the system for the current experiment with Chromium [Phys. Rev. A 84 053601 (2011)] and compare them with statistics for atoms with larger magnetic dipole moments. Significant enhancement of the third order correlation function, relevant for the particle losses, is found.
We report on the creation of bosonic NaCs molecules in their absolute rovibrational ground state via stimulated Raman adiabatic passage. We create ultracold gases with up to 22,000 dipolar NaCs molecules at a temperature of 300(50) nK and a peak density of $1.0(4) \times 10^{12}$ cm$^{-3}$. We demonstrate comprehensive quantum state control by preparing the molecules in a specific electronic, vibrational, rotational, and hyperfine state. Employing the tunability and strength of the permanent electric dipole moment of NaCs, we induce dipole moments of up to 2.6 D. Dipolar systems of NaCs molecu…
A previously developed approach for the numerical treatment of two particles that are confined in a finite optical-lattice potential and interact via an arbitrary isotropic interaction potential has been extended to incorporate an additional anisotropic dipole-dipole interaction. The interplay of a model but realistic short-range Born-Oppenheimer potential and the dipole-dipole interaction for two confined particles is investigated. A variation of the strength of the dipole-dipole interaction leads to diverse resonance phenomena. In a harmonic confinement potential some resonances show similar…
The object of study of this thesis are dipolar systems in the quantum degenerate regime. In general, dealing with many-body systems and evaluating their properties requires to deal with the Schrödinger equation. In the present study we employ different Monte Carlo methods, that are stochastic techniques that allow to find numerical solutions to it.
We produce ultracold dense trapped samples of 87Rb133Cs molecules in their rovibrational ground state, with full nuclear hyperfine state control, by stimulated Raman adiabatic passage (STIRAP) with efficiencies of 90%. We observe the onset of hyperfine-changing collisions when the magnetic field is ramped so that the molecules are no longer in the hyperfine ground state. A strong quadratic shift of the transition frequencies as a function of applied electric field shows the strongly dipolar character of the RbCs ground-state molecule. Our results open up the prospect of realizing stable bosoni…
A gas of ultracold molecules interacting via the long-range dipolar potential offers a highly controlled environment in which to study strongly correlated phases. However, at particle coalescence the divergent $1/r^3$ dipolar potential and associated pathological wavefunction hinder computational analysis. For a dipolar gas constrained to two dimensions we overcome these numerical difficulties by proposing a pseudopotential that is explicitly smooth at particle coalescence, resulting in a 2000-times speedup in diffusion Monte Carlo calculations. The pseudopotential delivers the scattering phas…
We study the relaxation and damping dynamics of an ultracold, but not quantum degenerate, gas consisting of dipolar particles. These simulations are performed using a direct simulation Monte Carlo method and employing the highly anisotropic differential cross section of dipoles in the Wigner threshold regime. We find that both cross-dimensional relaxation and damping of breathing modes occur at rates that are strongly dependent on the orientation of the dipole moments relative to the trap axis. The relaxation simulations are in excellent agreement with recent experimental results in erbium. Th…
We study the role of the Dipolar-Induced Resonance (DIR) in a quasi-one-dimensional system of ultracold bosons. We first describe the effect of the DIR on two particles in a harmonic trap. Then, we consider a deep optical lattice loaded with ultracold dipolar bosons. In order to describe this system, we introduce a novel atom-dimer extended Bose-Hubbard model, which is the minimal model correctly accounting for the DIR. We analyze the impact of the DIR on the phase diagram at T=0 by exact diagonalization of a small-sized system. We show that the DIR strongly affects this phase diagram. In part…
We investigate the occurence of Wigner-localization phenomena in bosonic dipolar ultracold few-body systems with Rashba-like spin-orbit coupling. We show that the latter strongly enhances the effects of the dipole-dipole interactions, allowing to reach the Wigner-localized regime for strengths of the dipole moment much smaller than those necessary in the spin-orbit-free case.
We develop a non-perturbative theoretical framework to treat collisions with generic anisotropic interactions in quasi-one-dimensional geometries. Our method avoids the limitations of pseudopotential theory allowing to include accurately long-range anisotropic interactions. Analyzing ultracold dipolar collisions in a harmonic waveguide we predict dipolar confinement-induced resonances (DCIRs) which are attributed to different angular momentum states. The analytically derived resonance condition reveals in detail the interplay of the confinement with the anisotropic nature of the dipole-dipole …
Ultracold dysprosium gases, with a magnetic moment ten times that of alkali atoms and equal only to terbium as the most magnetic atom, are expected to exhibit a multitude of fascinating collisional dynamics and quantum dipolar phases, including quantum liquid crystal physics. We report the first laser cooling and trapping of half a billion Dy atoms using a repumper-free magneto-optical trap (MOT) and continuously loaded magnetic confinement, and we characterize the trap recycling dynamics for bosonic and fermionic isotopes. The first inelastic collision measurements in the few partial wave, 10…
In a combined experimental and theoretical effort, we demonstrate a novel type of dipolar system made of ultracold bosonic dipolar molecules with large magnetic dipole moments. Our dipolar molecules are formed in weakly bound Feshbach molecular states from a sample of strongly magnetic bosonic erbium atoms. We show that the ultracold magnetic molecules can carry very large dipole moments and we demonstrate how to create and characterize them, and how to change their orientation. Finally, we confirm that the relaxation rates of molecules in a quasi-two dimensional geometry can be reduced by usi…
Analytic expressions for the differential cross sections of ultracold atoms and molecules that scatter primarily due to dipolar interactions are derived within the first Born approximation, and are shown to agree with the partial wave expansion. These cross sections are applied to the problem of cross-dimensional rethermalization. Strikingly, the rate of rethermalization can vary by as much as a factor of two, depending on the orientation of polarization of the dipoles. Thus the anisotropic dipole-dipole interaction can have a profound effect even on the behavior of a nondegenerate ultracold g…
We demonstrate microwave dressing on ultracold, fermionic ${}^{23}$Na${}^{40}$K ground-state molecules and observe resonant dipolar collisions with cross sections exceeding three times the $s$-wave unitarity limit. The origin of these collisions is the resonant alignment of the approaching molecules' dipoles along the intermolecular axis, which leads to strong attraction. We explain our observations with a conceptually simple two-state picture based on the Condon approximation. Furthermore, we perform coupled-channels calculations that agree well with the experimentally observed collision rate…
By applying a circularly polarized and slightly blue-detuned microwave field with respect to the first excited rotational state of a dipolar molecule, one can engineer a long-range, shallow potential well in the entrance channel of the two colliding partners. As the applied microwave ac-field is increased, the long-range well becomes deeper and can support a certain numbers of bound states, which in turn bring the value of the molecule-molecule scattering length from a large negative value to a large positive one. We adopt an adimensional approach where the molecules are described by a rescale…
We introduce a density functional formalism to study the ground-state properties of strongly-correlated dipolar and ionic ultracold bosonic and fermionic gases, based on the self-consistent combination of the weak and the strong coupling limits. Contrary to conventional density functional approaches, our formalism does not require a previous calculation of the interacting homogeneous gas, and it is thus very suitable to treat systems with tunable long-range interactions. Due to its asymptotic exactness in the regime of strong correlation, the formalism works for systems in which standard mean-…
We study the collapse of ultracold fermionic gases into inhomogeneous states due to strong dipolar interaction in both 2D and 3D. Depending on the dimensionality, we find that two different types of inhomogeneous states are stabilized once the dipole moment reaches a critical value $d>d_c$: the {\it stripe phase} and {\it phase separation} between high and low densities. In 2D, we prove that the stripe phase is always favored for $d\gtrsim d_c$, regardless of the microscopic details of the system. In 3D, the one-loop perturbative calculation suggests that the same type of instability leads to …
The notion of topology in physical systems is associated with the existence of a nonlocal ordering that is insensitive to a large class of perturbations. This brings robustness to the behaviour of the system and can serve as a ground for developing new fault-tolerant applications. We discuss how to design and study a large variety of topology-related phenomena for phonon-like collective modes in arrays of ultracold polarized dipolar particles. These modes are coherently propagating vibrational excitations, corresponding to oscillations of particles around their equilibrium positions, which exi…
We optimize a collision-induced cooling process for ultracold atoms in the nondegenerate regime. It makes use of a Feshbach resonance, instead of rf radiation in evaporative cooling, to selectively expel hot atoms from a trap. Using functional minimization we analytically show that for the optimal cooling process the resonance energy must be tuned such that it linearly follows the temperature. Here, optimal cooling is defined as maximizing the phase-space density after a fixed cooling duration. The analytical results are confirmed by numerical Monte-Carlo simulations. In order to simulate more…
The dipolar collision between ultracold polar molecules is an important topic both by its own right from the fundamental point of view and for the successful exploration of many-body physics with strong and long-range dipolar interactions. Here, we report the investigation of collisions between ultracold ground-state sodium-rubidium molecules in electric fields with induced electric dipole moments as large as 0.7$\;$D. We observe a step-wise enhancement of losses due to the coupling between different partial waves induced by the increasingly stronger anisotropic dipolar interactions. Varying t…
We propose an effective Ising spin chain constructed with dipolar quantum gases confined in a one-dimensional optical superlattice. Mapping the motional degrees of freedom of a single particle in the lattice onto a pseudo-spin results in effective transverse and longitudinal magnetic fields. This effective Ising spin chain exhibits a quantum phase transition from a paramagnetic to a single-kink phase as the dipolar interaction increases. Particularly in the single-kink phase,a magnetic kink arises in the effective spin chain and behaves as a quasi-particle in a pinning potential exerted by the…
We report on the creation of an ultracold dipolar gas of fermionic $^{23}$Na$^{40}$K molecules in their absolute rovibrational and hyperfine ground state. Starting from weakly bound Feshbach molecules, we demonstrate hyperfine resolved two-photon transfer into the singlet ${\rm X}^1Σ^+ |v{=}0,J{=}0\rangle$ ground state, coherently bridging a binding energy difference of 0.65 eV via stimulated rapid adiabatic passage. The spin-polarized, nearly quantum degenerate molecular gas displays a lifetime longer than 2.5 s, highlighting NaK's stability against two-body chemical reactions. A homogeneous …
Ultracold ground state dipolar 40K-87Rb molecules have recently been produced in a loose harmonic trap by employing a magnetic field sweep across a Feshbach resonance followed by stimulated Raman adiabatic passage [K.-K. Ni et al., Science 322, 231 (2008)]. The overall experimental efficiency for molecule formation was around 20%. We show that the efficiency can be increased to nearly 100% if one first loads the atomic gases into an optical lattice of the appropriate depth and tunes the interspecies attraction to have exactly one atom of each species at an occupied lattice site. Our proposed s…
The self-consistent field approach for the electric dipolar ultracold spin-1/2 fermions is discussed. Contribution of the exchange part of the electric dipole interaction is found. Hence we obtain a model of dipolar fermions beyond the self-consistent field approximation. It is shown that the exchange interaction of electric dipolar fermions depends on the spin-polarisation of the system. For instance the electric dipole exchange interaction equals to zero for spin-unpolarised systems, namely all low laying quantum states occupied by two-particles with opposite spins. In opposite limit of the …
The symmetry properties of the Cooper pairing problem for multi-component ultra-cold dipolar molecular systems are investigated. The dipolar anisotropy provides a natural and robust mechanism for both triplet and singlet Cooper pairing to first order in the interaction strength. With a purely dipolar interaction, the triplet $p_z$-like polar pairing is the most dominant. A short-range attractive interaction can enhance the singlet pairing to be nearly degenerate with the triplet pairing. We point out that these two pairing channels can mix by developing a relative phase of $\pm\fracπ{2}$, thus…
Using the time-dependent density matrix renormalization group method, we calculate transport properties of an interacting Fermi gas in an optical lattice with a confining trap after a sudden displacement of the trap center. In the regime of attractive interactions, the dipolar motion after the displacement can be classified into underdamped oscillations and overdamped relaxations, depending on the interaction strength. These numerical calculations are consistent with experimental results. In the regime of repulsive interactions, we predict a revival of the oscillations of the center of mass wh…
The Fano effect (U. Fano, Phys. Rev. \textbf{15},1866 (1961) shows that an inelastic scattering process can be suppressed when the output channel (OC) is coupled to an isolated bound state. In this paper we investigate the application of this effect for the suppression of two-body collisional losses of ultracold atoms. The Fano effect is originally derived via a first-order perturbation treatment for coupling between the incident channel (IC) and the OC. We generalize the Fano effect to systems with arbitrarily strong IC--OC couplings. We analytically prove that, in a system with one IC and on…
We report the investigation on dipolar collisions in rotational state mixtures of ultracold bosonic $^{23}$Na$^{87}$Rb molecules. The large resonant dipole-dipole interaction between molecules in rotational states of opposite parities brings about significant modifications to their collisions, even when an electric field is not present. In this work, this effect is revealed by measuring the dramatically enhanced two-body loss rate constants in the mixtures. In addition, the dipolar interaction strength can be tuned by preparing the NaRb mixture in different rotational levels with microwave spe…
This tutorial is a theoretical work, in which we study the physics of ultra-cold dipolar bosonic gases in optical lattices. Such gases consist of bosonic atoms or molecules that interact via dipolar forces, and that are cooled below the quantum degeneracy temperature, typically in the nK range. When such a degenerate quantum gas is loaded into an optical lattice produced by standing waves of laser light, new kinds of physical phenomena occur. These systems realize then extended Hubbard-type models, and can be brought to a strongly correlated regime. The physical properties of such gases, domin…
This paper reviews recent advances in the study of strongly interacting systems of dipolar molecules. Heteronuclear molecules feature large and tunable electric dipole moments, which give rise to long-range and anisotropic dipole-dipole interactions. Ultracold samples of dipolar molecules with long-range interactions offer a unique platform for quantum simulations and the study of correlated many-body physics. We provide an introduction to the physics of dipolar quantum gases, both electric and magnetic, and summarize the multipronged efforts to bring dipolar molecules into the quantum regime.…
We design dipolar quantum many-body Hamiltonians that will facilitate the realization of exotic quantum phases under current experimental conditions achieved for polar molecules. The main idea is to modulate both single-body potential barriers and two-body dipolar interactions on a spatial scale of tens of nanometers to strongly enhance energy scales and, therefore, relax temperature requirements for observing new quantum phases of engineered many-body systems. We consider and compare two approaches. In the first, nanoscale barriers are generated with standing wave optical light fields exploit…
An impurity atom immersed in an ultracold atomic Fermi gas can form a quasiparticle, so-called Fermi polaron, due to impurity-fermion interaction. We consider a three-dimensional homogeneous dipolar Fermi gas as a medium, where the interatomic dipole-dipole interaction (DDI) makes the Fermi surface deformed into a spheroidal shape, and, using a Chevy-type variational method, investigate the ground-state properties of the Fermi polaron: the effective mass, the momentum distribution of a particle-hole (p-h) excitation, the drag parameter, and the medium density modification around the impurity. …
A supersolid is a fascinating phase of matter, combining the global phase coherence of a superfluid with hallmarks of solids, e.g. a spontaneous breaking of the translational symmetry. Recently, states with such counter-intuitive properties have been realized in experiments using ultracold quantum gases with strong dipolar interactions. Here, we investigate the response of a supersolid state to phase excitations which shatter the global phase coherence. After the creation of those excitations, we observe a rapid re-establishment of a global phase coherence, suggesting the presence of a superfl…
This article reviews the recent theoretical and experimental advances in the study of ultracold gases made of bosonic particles interacting via the long-range, anisotropic dipole-dipole interaction, in addition to the short-range and isotropic contact interaction usually at work in ultracold gases. The specific properties emerging from the dipolar interaction are emphasized, from the mean-field regime valid for dilute Bose-Einstein condensates, to the strongly correlated regimes reached for dipolar bosons in optical lattices.
Motivated by the search for quantum liquid crystal phases in a gas of ultracold atoms and molecules, we study the density wave and nematic instabilities of dipolar fermions on the two-dimensional square lattice (in the $x-y$ plane) with dipoles pointing to the $z$ direction. We determine the phase diagram using two complimentary methods, the Hatree-Fock mean field theory and the linear response analysis of compressibility. Both give consistent results. In addition to the staggered ($π$, $π$) density wave, over a finite range of densities and hopping parameters, the ground state of the system f…
The simultaneous presence of two competing inter-particle interactions can lead to the emergence of new phenomena in a many-body system. Among others, such effects are expected in dipolar Bose-Einstein condensates, subject to dipole-dipole interaction and short-range repulsion. Magnetic quantum gases and in particular Dysprosium gases, offering a comparable short-range contact and a long-range dipolar interaction energy, remarkably exhibit such emergent phenomena. In addition an effective cancellation of mean-field effects of the two interactions results in a pronounced importance of quantum-m…
Since the achievement of quantum degeneracy in gases of chromium atoms in 2004, the experimental investigation of ultracold gases made of highly magnetic atoms has blossomed. The field has yielded the observation of many unprecedented phenomena, in particular those in which long-range and anisotropic dipole-dipole interactions play a crucial role. In this review, we aim to present the aspects of the magnetic quantum-gas platform that make it unique for exploring ultracold and quantum physics as well as to give a thorough overview of experimental achievements.
Ultracold polar molecules offer the possibility of exploring quantum gases with interparticle interactions that are strong, long-range, and spatially anisotropic. This is in stark contrast to the dilute gases of ultracold atoms, which have isotropic and extremely short-range, or "contact", interactions. The large electric dipole moment of polar molecules can be tuned with an external electric field; this provides unique opportunities such as control of ultracold chemical reactions, quantum information processing, and the realization of novel quantum many-body systems. In spite of intense exper…
We study the extended Bose--Hubbard model describing an ultracold gas of dipolar molecules in an optical lattice, taking into account all on-site and nearest-neighbor interactions, including occupation-dependent tunneling and pair tunneling terms. Using exact diagonalization and the multiscale entanglement renormalization ansatz, we show that these terms can destroy insulating phases and lead to novel quantum phases. These considerable changes of the phase diagram have to be taken into account in upcoming experiments with dipolar molecules.
Understanding the sources of losses and chemical reactions of ultracold alkali-metal molecules is among the critical elements needed for their application in precision measurements and quantum technologies. Recent experiments with nonreactive systems have reported unexpectedly large loss rates, posing a challenge for theoretical explanation. Here, we examine the dynamics of intermediate four-atom complexes formed in bimolecular collisions. We calculate the nuclear spin--rotation, spin--spin, and quadrupole coupling constants for bialkali tetramers using ab intio quantum-chemical methods. We sh…
Strongly interacting dipolar bosons in optical lattices exhibit diverse quantum phases that are rich in physics. As the strength of the long-range boson-boson interaction increases, the system transitions across different phases: from a superfluid, through a Mott-insulator to a Tonks gas and, eventually, a crystal state. The signature of these phases and their transitions can be unequivocally identified by an experimentally detectable order parameter, recently described in arXiv:1708.07409. Herein, we calculate the momentum distributions and the normalized Glauber correlation functions of dipo…
The interplay between crystallinity and superfluidity is of great fundamental and technological interest in condensed matter settings. In particular, electronic quantum liquid crystallinity arises in the non-Fermi liquid, pseudogap regime neighboring a cuprate's unconventional superconducting phase. While the techniques of ultracold atomic physics and quantum optics have enabled explorations of the strongly correlated, many-body physics inherent in, e.g., the Hubbard model, lacking has been the ability to create a quantum degenerate Fermi gas with interparticle interactions---such as the stron…
