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arXiv 2303.06322cond-mat.mes-hallcond-mat.mtrl-sci
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近场光学法快速鉴定ABC三层石墨烯纳米级结构

Quick Identification of ABC Trilayer Graphene at Nanoscale Resolution via a Near-field Optical Route

Peiyue Shen, Xianliang Zhou, Jiajun Chen, Aolin Deng, Bosai Lyu, Zhichun Zhang, Shuo Lou, Saiqun Ma, Binbin Wei, Zhiwen Shi

摘要:

ABC堆叠的三层石墨烯由于其相对平坦的能带和栅极可调的带隙而表现出各种相关现象。然而,仍然缺乏方便的方法来识别具有纳米级分辨率的ABC石墨烯。在这里,我们证明了在环境条件下工作的扫描近场光学显微镜(SNOM)可以快速识别ABC三层石墨烯,没有模糊性和出色的分辨率(~20 nm)。识别是基于ABA和ABC三层之间的近场红外(IR)响应的差异。我们发现,在大多数频率下,ABC三层的响应弱于ABA三层。然而,在石墨烯声子频率(~1585 cm-1)附近,ABC的响应在门控时急剧增加,并且表现出窄而尖锐的Fano形状的共振线,而ABA三层基本上是无羽毛的。因此,ABC和ABA之间的IR对比度变得相反,并且在石墨烯声子频率附近甚至可以是显著的(ABC/ABA~3)。所观察到的近场红外特征可以作为黄金法则来快速区分ABA和ABC三层,没有歧义,这可以在很大程度上推进ABC堆叠三层石墨烯中相关物理的探索。

英文摘要:

ABC-stacked trilayer graphene has exhibited a variety of correlated phenomena owing to its relatively flat bands and gate-tunable bandgap. However, convenient methods are still lacking for identifying ABC graphene with nanometer-scale resolution. Here we demonstrate that the scanning near-field optical microscope (SNOM) working in ambient conditions can provide quick recognition of ABC trilayer graphene with no ambiguity and excellent resolution (~20 nm). The recognition is based on the difference in their near-field infrared (IR) responses between the ABA and ABC trilayers. We show that in most frequencies, the response of the ABC trilayer is weaker than the ABA trilayer. However, near the graphene phonon frequency (~1585 cm-1), ABC's response increases dramatically when gated and exhibits a narrow and sharp Fano-shape resonant line, whereas the ABA trilayer is largely featherless. Consequently, the IR contrast between ABC and ABA becomes reversed and can even be striking (ABC/ABA~3) near the graphene phonon frequency. The observed near-field IR features can serve as a golden rule to quickly distinguish ABA and ABC trilayers with no ambiguity, which could largely advance the exploration of correlation physics in ABC-stacked trilayer graphene.

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