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arXiv 2209.05073cond-mat.mtrl-sci
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Cu-Phenalenyl基磁性隧道结的界面辅助室温磁电阻效应

Interface-Assisted Room-Temperature Magnetoresistance in Cu-Phenalenyl-based Magnetic Tunnel Junctions

Neha Jha, Anand Paryar, Tahereh Sadat Parvini, Christian Denker, Pavan K. Vardhanapu, Gonela Vijaykumar, Arne Ahrens, Michael Seibt, Jagadeesh S. Moodera, Swadh… 展开作者

Neha Jha, Anand Paryar, Tahereh Sadat Parvini, Christian Denker, Pavan K. Vardhanapu, Gonela Vijaykumar, Arne Ahrens, Michael Seibt, Jagadeesh S. Moodera, Swadhin K. Mandal, Markus Münzenberg

摘要:

具有不成对自旋的离域碳基自由基物种,如非那烯基(phenalenyl)自由基,为开发多功能有机自旋电子器件开辟了途径。在此,我们发展了一种基于三维荫罩和原位沉积的新技术,制备了面积为3 × 8 μm2的Cu-Cu-Cu和Zn-Cu-Cu基有机磁性隧道结(OMTJ),并改善了其形貌。非线性和弱温度依赖性的电流-电压(I-V)特性与低有机势垒高度相结合,表明隧穿作为结构和尺寸优化的OMTJ中的主要传输机制。Cu-Cu基OMTJ在室温下表现出高达14%的显著磁阻,这是由于在称为spinterface的金属-分子界面处形成了杂化态,这揭示了自旋相关界面修饰在OMTJ设计中的重要性。特别是,Cu-SiOMTJ显示出稳定的电压驱动电阻开关响应,这表明它们可用作构建分子尺度量子忆阻器和处理器的新的可行且可扩展的平台。

英文摘要:

Delocalized carbon-based radical species with unpaired spin, such as phenalenyl (PLY) radical, opened avenues for developing multifunctional organic spintronic devices. Here we develop a novel technique based on a three-dimensional shadow mask and the in-situ deposition to fabricate PLY-, Cu-PLY-, and Zn-PLY-based organic magnetic tunnel junctions (OMTJs) with area 3x8 μm2 and improved morphology. The nonlinear and weakly temperature-dependent current-voltage (I-V) characteristics in combination with the low organic barrier height suggest tunneling as the dominant transport mechanism in the structurally and dimensionally optimized OMTJs. Cu-PLY-based OMTJs, show a significant magnetoresistance up to 14 percent at room temperature due to the formation of hybrid states at the metal-molecule interfaces called spinterface, which reveals the importance of spin-dependent interfacial modification in OMTJs design. In particular, Cu-PLY OMTJs shows a stable voltage-driven resistive switching response that suggests their use as a new viable and scalable platform for building molecular scale quantum memristors and processors.

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