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arXiv 2209.01529math-phmath.MP
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热力学的仿射几何描述

Affine geometric description of thermodynamics

Shin-itiro Goto

摘要:

热力学提供了各种物质的热力学性质的统一观点。为了用复杂的数学语言来表述热力学,热力学可以用各种微分几何来描述,包括接触几何和辛几何。仿射几何是微分几何的一个分支,与信息几何相容,而信息几何与热力学相容。通过以上的结合,可以预期热力学与仿射几何是相容的,并且可以预期几种仿射几何工具可以被引入到热力学系统的分析中。本文提出了平衡态和非平衡态热力学的仿射几何描述。对于平衡系统,它表明,几个热力学量可以识别仿射几何中的几何对象,并可以在热力学中引入几个几何对象。这些例子包括:比热与仿射基本形式一致,在热力学相空间中引入平坦连接。对于非平衡系统,两类松弛过程中所示的仿射几何的扩展的语言来描述。最后,这种仿射几何描述的热力学平衡和非平衡系统的接触几何描述进行了比较。

英文摘要:

Thermodynamics provides a unified perspective of thermodynamic properties of various substances. To formulate thermodynamics in the language of sophisticated mathematics, thermodynamics is described by a variety of differential geometries, including contact and symplectic geometries. Meanwhile affine geometry is a branch of differential geometry and is compatible with information geometry, where information geometry is known to be compatible with thermodynamics. By combining above, it is expected that thermodynamics is compatible with affine geometry, and is expected that several affine geometric tools can be introduced in the analysis of thermodynamic systems. In this paper affine geometric descriptions of equilibrium and nonequilibrium thermodynamics are proposed. For equilibrium systems, it is shown that several thermodynamic quantities can be identified with geometric objects in affine geometry, and that several geometric objects can be introduced in thermodynamics. Examples of these include: specific heat is identified with the affine fundamental form, a flat connection is introduced in thermodynamic phase space. For nonequilibrium systems, two classes of relaxation processes are shown to be described in the language of an extension of affine geometry. Finally this affine geometric description of thermodynamics for equilibrium and nonequilibrium systems is compared with a contact geometric description.

机构、总结、中文摘要均由AI分析而来,可能存在错误,请以论文正文为准。

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