化学反应的几何热力学
On the geometrical thermodynamics of chemical reactions
摘要：
几何热力学的形式结构进行审查，特别强调平衡子流形的几何。在这些子流形上，热力学度量被定义为热力学势的Hessian。几何和热力学之间的联系，探讨了单组分和多组分，封闭和开放系统。对于多组分封闭和开放体系，吉布斯自由能被用作热力学势，以研究几何和热力学之间的联系。吉布斯自由能被用来分析多组分体系，特别是化学反应。
英文摘要：
The formal structure of geometrical thermodynamics is reviewed with particular emphasis on the geometry of equilibria submanifolds. On these submanifolds thermodynamic metrics are defined as the Hessian of thermodynamic potentials. Links between geometry and thermodynamics are explored for single and multiple component, closed and open systems. For multi-component closed and open systems the Gibbs free energy is employed as the thermodynamic potential to investigate the connection between geometry and thermodynamics. The Gibbs free energy is chosen for the analysis of multicomponent systems and, in particular, chemical reactions.
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