An understanding of the abundance and distribution of water vapor in the innermost region of protoplanetary disks is key to understanding the origin of habitable worlds and planetary systems. Past observations have shown H2O to be abundant and a major carrier of elemental oxygen in disk surface layers that lie within the inner few au of the disk. The combination of high abundance and strong radiative transitions leads to emission lines that are optically thick across the infrared spectral range. Its rarer isotopologue H2-18O traces deeper into this layer and will trace the full content of the planet forming zone. In this work, we explore the relative distribution of H2-16O and H2-18O within a model that includes water self-shielding from the destructive effects of ultraviolet radiation. In this Letter we show that there is an enhancement in the relative H2-18O abundance high up in the warm molecular layer within 0.1-10 au due to self-shielding of CO, C18O, and H2O. Most transitions of H2-18O that can be observed with JWST will partially emit from this layer, making it essential to take into account how H2O self-shielding may effect the H2O to H2-18O ratio. Additionally, this reservoir of H2-18O-enriched gas in combination with the vertical "cold finger" effect might provide a natural mechanism to account for oxygen isotopic anomalies found in meteoritic material in the solar system
The rare CI carbonaceous chondrites are the most aqueously altered and chemically primitive meteorites but due to their porous nature and high abundance of volatile elements are susceptible to terrestrial weathering. The Ivuna meteorite, type specimen for the CI chondrites, is the largest twentieth-century CI fall and least affected by terrestrial alteration. The main mass of Ivuna (BM2008 M1) has been stored in a nitrogen atmosphere at least since 2008 and is the most pristine CI chondrite stone. We report the mineralogy, petrography and bulk elemental composition of BM2008 M1 and a second Iv…
Terrestrial exoplanets likely form initial atmospheres through outgassing during and after accretion, although there is currently no first-principles understanding of how to connect a planet's bulk composition to its early atmospheric properties. Important insights into this connection can be gained by assaying meteorites, representative samples of planetary building blocks. We perform laboratory outgassing experiments that use a mass spectrometer to measure the abundances of volatiles released when meteorite samples are heated to 1200 $^{\circ}$C. We find that outgassing from three carbonaceo…
Water condensed as ice beyond the water snowline, the location in the Sun's natal gaseous disk where temperatures were below 170 K. As the disk evolved and cooled, the snowline moved inwards. A low temperature in the terrestrial planet-forming region is unlikely to be the origin of water on the planets, and the distinct isotopic compositions of planetary objects formed in the inner and outer disks suggest limited early mixing of inner and outer Solar System materials. Water in our terrestrial planets has rather been derived from H-bearing materials indigenous to the inner disk and delivered by…
Outgassing Composition of the Murchison Meteorite: Implications for Volatile Depletion of Planetesimals and Interior-atmosphere Connections for Terrestrial Exoplanets
The evolution of the meteorite flux to the Earth can be studied by determining the terrestrial ages of meteorite collected in hot deserts. We have measured the terrestrial ages of 54 stony meteorites from the El Médano area, in the Atacama Desert, using the cosmogenic nuclide chlorine 36. With an average age of 710 ka, this collection is the oldest collection of non fossil meteorites at the Earth's surface. This allows both determining the average meteorite flux intensity over the last 2 Myr (222 meteorites larger than 10 g per km2 per Myr) and discussing its possible compositional variability…
On The Effect of Giant Planets on the Scattering of Parent Bodies of Iron Meteorite from the Terrestrial Planet Region into the Asteroid Belt: A Concept Study
The chemical composition of the inner region of protoplanetary disks can trace the composition of planetary building material. The exact elemental composition of the inner disk has not yet been measured and tensions between models and observations still exist. Recent advancements have shown UV-shielding to be able to increase emission of organics. Here, we expand on these models and investigate how UV-shielding may impact chemical composition in the inner 5 au. In this work, we use the model from arxiv:2204.07108 and expand it with a larger chemical network. We focus on the chemical abundances…
Carbon Dioxide is an important tracer of the chemistry and physics in the terrestrial planet forming zone. Using a thermo-chemical model that has been tested against the mid-infrared water emission we re-interpret the CO2 emission as observed with Spitzer. We find that both water UV-shielding and extra chemical heating significantly reduce the total CO2 column in the emitting layer. Water UV-shielding is the more efficient effect, reducing the CO2 column by $\sim$ 2 orders of magnitude. These lower CO2 abundances lead to CO2-to-H2O flux ratios that are closer to the observed values, but CO2 em…
Mid-infrared spectroscopy is one of the few ways to observe the composition of the terrestial planet forming zone, the inner few au, of proto-planetary disks. The species currently detected in the disk atmosphere, for example CO, CO2, H2O and C2H2, are theoretically enough to constrain the C/O ratio in the disk surface. However, thermo-chemical models have difficulties in reproducing the full array of detected species in the mid-infrared simultaneously. In an effort to get closer to the observed spectra, we have included water UV-shielding as well as more efficient chemical heating into thermo…
This paper characterizes the first protein to be discovered in a meteorite. Amino acid polymers previously observed in Acfer 086 and Allende meteorites [1,2] have been further characterized in Acfer 086 via high precision MALDI mass spectrometry to reveal a principal unified structure of molecular weight 2320 Daltons that involves chains of glycine and hydroxy-glycine residues terminated by iron atoms, with additional oxygen and lithium atoms. Signal-to-noise ratios up to 135 have allowed the quantification of iron and lithium in the various MALDI fragments via the isotope satellites due to th…
Chondrites are undifferentiated sediments of material left over from the earliest solar system and are widely considered as representatives of the unprocessed building blocks of the terrestrial planets. The chondrites, along with processed igneous meteorites, have been divided into two broad categories based upon their isotopic signatures; these have been termed the CC and NC groups and have been interpreted as reflecting their distinctive birth places within the solar system. The isotopic distinctiveness of NC and CC meteorites document limited radial-mixing in the accretionary disk. The enst…
Mass-independent isotopic anomalies of carbonaceous and non-carbonaceous meteorites show a clear dichotomy suggesting an efficient separation of the inner and outer solar system. Observations show that ring-like structures in the distribution of mm-sized pebbles in protoplanetary disks are common. These structures are often associated with drifting pebbles being trapped by local pressure maxima in the gas disk. Similar structures may also have existed in the sun's natal disk, which could naturally explain the meteorite/planetary isotopic dichotomy. Here, we test the effects of a strong pressur…
Although spectral surveys and spacecraft missions provide information on small bodies, many important analyses can only be performed in terrestrial laboratories. For now, the total number of parent bodies represented in our meteorites collection is estimated to about 150 parent bodies, of which 50 parent bodies represented by the poorly studied ungrouped chondrites. Linking ungrouped meteorites to their parent bodies is thus crucial to significantly increase our knowledge of asteroids. To this end, the petrography of 25 ungrouped chondrites and rare meteorite groups was studied, allowing group…
We couple star cluster formation and feedback simulations of a Carina-like star forming region with 1D disc evolutionary models to study the impact of external photoevaporation on disc populations in massive star forming regions. To investigate the effect of shielding of young stellar objects by star forming material, we track the FUV field history at each star in the cluster with two methods: i) Monte Carlo radiative transfer accounting for the shielding of stars from the FUV by the star forming cloud ii) Geometric dilution of the radiation from other stars which ignores shielding effects. We…
We investigated the hydrogen isotopic compositions and water contents of pyroxenes in two recent ordinary chondrite falls, namely, Chelyabinsk (2013 fall) and Benenitra (2018 fall), and compared them to three ordinary chondrite Antarctic finds, namely Graves Nunataks GRA 06179, Larkman Nunatak LAR 12241, and Dominion Range DOM 10035. The pyroxene minerals in Benenitra and Chelyabinsk are hydrated ($\sim$0.018-0.087 wt.$\%$ H$_2$O) and show D-poor isotopic signatures ($δ$D$_{SMOW}$ from -444$\unicode{x2030}$ to -49$\unicode{x2030}$). On the contrary, the ordinary chondrite finds exhibit evidenc…
Pebbles of millimeter sizes are abundant in protoplanetary discs around young stars. Chondrules inside primitive meteorites - formed by melting of dust aggregate pebbles or in impacts between planetesimals - have similar sizes. The role of pebble accretion for terrestrial planet formation is nevertheless unclear. Here we present a model where inwards-drifting pebbles feed the growth of terrestrial planets. The masses and orbits of Venus, Earth, Theia (which later collided with the Earth to form the Moon) and Mars are all consistent with pebble accretion onto protoplanets that formed around Mar…
Least-processed carbonaceous chondrites (carbonaceous chondrites that have experienced minimal aqueous alteration and thermal metamorphism) are characterized by their predominately amorphous iron-rich silicate interchondrule matrices and chondrule rims. The presence of abundant amorphous material in a meteorite indicates that the parent body, or at least a region of the parent body, experienced minimal processing since the time of accretion. The CO chemical group of carbonaceous chondrites has a significant number of these least-processed samples. We present visible/near-infrared and mid-infra…
Two fundamentally different processes of rocky planet formation exist, but it is unclear which one built the terrestrial planets of the solar system. Either they formed by collisions among planetary embryos from the inner solar system, or by accreting sunward-drifting millimeter-sized 'pebbles' from the outer solar system. We show that the isotopic compositions of Earth and Mars are governed by two-component mixing among inner solar system materials, including material from the innermost disk unsampled by meteorites, whereas the contribution of outer solar system material is limited to a few p…
The origin of fatty acids on the prebiotic Earth is important as they likely formed the encapsulating membranes of the first protocells. Carbon-rich meteorites (i.e., carbonaceous chondrites) such as Murchison and Tagish Lake are well known to contain these molecules, and their delivery to the early planet by intense early meteorite bombardments constitutes a key prebiotic source. We collect the fatty acid abundances measured in various carbonaceous chondrites from the literature and analyze them for patterns and correlations. Fatty acids in meteorites include straight-chain and branched-chain…
In the next decade, two rovers will characterize in situ the mineralogy of rocks on Mars, using for the first time near-infrared reflectance spectrometers: SuperCam onboard the Mars 2020 rover and MicrOmega onboard the ExoMars rover, although this technique is predominantly used in orbit for mineralogical investigations. Until successful completion of sample-return missions from Mars, Martian meteorites are currently the only samples of the red planet available for study in terrestrial laboratories and comparison with in situ data. However, the current spectral database available for these sam…
Combining isotopic constraints from meteorite data with dynamical models of planet formation proves to be advantageous in identifying the best model for terrestrial planet formation. Prior studies have shown that the probability of reproducing the distinct isotopic compositions of the Earth and Mars for both classical and Grand Tack models is very low. In the framework of the Grand Tack model, for Mars to be isotopically different from the Earth, it had to form under very specific conditions. Here, we subjected a fairly new and unexplored model--the depleted disc model--to the test. It presupp…
Aims. The existence of asteroid complexes produced by the disruption of these comets suggests that evolved comets could also produce high-strength materials able to survive as meteorites. We chose as an example comet 2P/Encke, one of the largest object of the so-called Taurid complex. We compare the reflectance spectrum of this comet with the laboratory spectra of some Antarctic ungrouped carbonaceous chondrites to investigate whether some of these meteorites could be associated with evolved comets. Methods. We compared the spectral behaviour of 2P/Encke with laboratory spectra of carbonaceous…
The formation and subsequent migration of gas giants could significantly affect the material mixing in the Solar System. In this study, we use N-body simulations to investigate how much water is transported into the region of the terrestrial planet formation during the growth and migration phases of Jupiter in the Grand Tack model. We found that Jupiter's growth was accompanied by significant mass transport, and that a substantial amount of water (about 10 times Earth's ocean mass for the initial planetesimal distribution based on the minimum-mass solar nebula) was transported into the terrest…
We present multi-epoch infrared photometry and spectroscopy obtained with warm Spitzer, Subaru and SOFIA to assess variability for the young ($\sim$20 Myr) and dusty debris systems around HD 172555 and HD 113766A. No variations (within 0.5%) were found for the former at either 3.6 or 4.5 $μ$m, while significant non-periodic variations (peak-to-peak of $\sim$10-15% relative to the primary star) were detected for the latter. Relative to the Spitzer IRS spectra taken in 2004, multi-epoch mid-infrared spectra reveal no change in either the shape of the prominent 10 $μ$m solid-state features or the…
Oxidation Constraints on Terrestrial Planet Formation from a Ring
Bayerisches Geoinstitut, University of Bayreuth（拜罗伊特大学地球科学研究所）；Université Côte d’Azur, Observatoire de la Côte d’Azur, CNRS, Laboratoire Lagrange（蔚蓝海岸大学，蔚蓝海岸天文台，法国国家科学研究中心，拉格朗日实验室）；Jet Propulsion Laboratory, California Institute of Technology（加州理工学院喷气推进实验室）；Department of Earth & Environmental Sciences, Michigan State University（密歇根州立大学地球与环境科学系）；Collège de France, CNRS, PSL Univ., Sorbonne Univ.（法兰西学院，法国国家科学研究中心，巴黎文理研究大学，索邦大学）；Solar System Science & Exploration Division, Southwest Research Institute（西南研究院太阳系科学与探索部）
The composition of an atmosphere has integrated the geological history of the entire planetary body. However, the long-term evolutions of the atmospheres of the terrestrial planets are not well documented. For Earth, there were until recently only few direct records of atmosphere's composition in the distant past, and insights came mainly from geochemical or physical proxies and/or from atmospheric models pushed back in time. Here we review innovative approaches on new terrestrial samples that led to the determination of the elemental and isotopic compositions of key geochemical tracers, namel…
Protoplanetary disks are dust-rich structures around young stars. The crystalline and amorphous materials contained within these disks are variably thermally processed and accreted to make bodies of a wide range of sizes and compositions, depending on the heliocentric distance of formation. The chondritic meteorites are fragments of relatively small and undifferentiated bodies, and the minerals that they contain carry chemical signatures providing information about the early environment available for planetesimal formation. A current hot topic of debate is the delivery of volatiles to terrestr…
Terrestrial planets grew in a series of similar-sized collisions that swept up most of the next-largest bodies. Theia was accreted by the Earth to form the Moon according to the theory. Planetesimals likewise may have finished their accretion in a sequence of 'junior giant impacts', scaled down in size and velocity. This chapter considers the complicated physics of pairwise accretion, as planetesimals grow to planetary scales, and considers how the inefficiency of that process influences the origin of planetesimals and the diversity of meteorites and primary asteroids.
A Collective Trigger for Widespread Planetesimal Formation Revealed by Accretion Ages
University of Oxford（牛津大学）；University of Oslo（奥斯陆大学）；University of California Santa Cruz（加州大学圣克鲁兹分校）；Université Clermont Auvergne（克莱蒙奥弗涅大学）；Lawrence Livermore National Laboratory（劳伦斯利弗莫尔国家实验室）；CNRS（法国国家科学研究中心）
We review the state of knowledge on the origin of Earth's water. Empirical constraints come from chemical and isotopic measurements of solar system bodies and of Earth itself. Dynamical models have revealed pathways for water delivery to Earth during its formation; most are anchored to specific models for terrestrial planet formation. Meanwhile, disk chemical models focus on determining how the isotopic ratios of the building blocks of planets varied as a function of radial distance and time, defining markers of material transported along those pathways. Carbonaceous chondrite meteorites -- re…
In order to link infrared observations of dust formed during planet formation in debris disks to mid-infrared spectroscopic data of planetary materials from differentiated terrestrial and asteroidal bodies, we obtained absorption spectra of a representative suite of terrestrial crustal and mantle materials, and of typical Martian meteorites. A series of debris disk spectra characterized by a strong feature in the 9.0-9.5 micron range (HD23514, HD15407a, HD172555 and HD165014), is comparable to materials that underwent shock, collision or high temperature events. These are amorphous materials s…
The Effects of M Star Age Dependent Ultraviolet Emission on Detecting and Interpreting Exoplanet Biosignatures
University of California Santa Cruz（加州大学圣克鲁兹分校）；SETI Institute（SETI研究所）；University of Washington（华盛顿大学）；NASA NExSS Virtual Planetary Laboratory（NASA NExSS虚拟行星实验室）；Arizona State University（亚利桑那州立大学）；University of Maryland, Baltimore County（马里兰大学巴尔的摩分校）；NASA Goddard Space Flight Center（美国宇航局戈达德太空飞行中心）；United States Naval Observatory（美国海军天文台）
