Shiba bands formed by overlapping Yu-Shiba-Rusinov subgap states in magnetic impurities on a superconductor play an important role in topological superconductors. Here, we theoretically demonstrate the existence of a new type of Shiba bands (dubbed topological Shiba metal) on a magnetically doped $s$-wave superconducting surface with Rashba spin-orbit coupling in the presence of a weak in-plane magnetic field. Such topological gapless Shiba bands develop from gapped Shiba bands through Lifshitz phase transitions accompanied by second-order quantum phase transitions for the intrinsic thermal Hall conductance. We also find a mechanism in Shiba lattices that protects the first-order quantum phase transitions for the intrinsic thermal Hall conductance. Due to the long-range hopping in Shiba lattices, the topological Shiba metal exhibits intrinsic thermal Hall conductance with large nonquantized values. As a consequence, there emerge a large number of second-order quantum phase transitions.
Topological states of matter support quantized nondissipative responses and exotic quantum particles that cannot be accessed in common materials. The exceptional properties and application potential of topological materials have triggered a large-scale search for new realizations. Breaking away from the popular trend focusing almost exclusively on crystalline symmetries, we introduce the Shiba glass as a platform for amorphous topological quantum matter. This system consists of an ensemble of randomly distributed magnetic atoms on a superconducting surface. The collection of magnetic moments g…
Chains of magnetic impurities placed on a superconducting substrate and forming helical spin order provide a promising venue for realizing a topological superconducting phase. An effective tight-binding description of such helical Shiba chains involves long-range (power-law) hopping and pairing amplitudes which induce an unconventional topological critical point. At the critical point, we find exponentially localized Majorana bound states with a short localization length unrelated to a topological gap. Away from the critical point, this exponential decay develops a power-law tail. Our analytic…
Chains of magnetic atoms placed on the surface of an s-wave superconductor with large spin-orbit coupling provide a promising platform for the realization of topological superconducting states characterized by the presence of Majorana zero-energy modes. In this work we study the properties of the one-dimensional chain of Yu-Shiba-Rusinov states induced by magnetic impurities using a realistic model for the magnetic atoms that include the presence of multiple scattering channels. These channels are mixed by the spin-orbit coupling and, via the hybridization of the Yu-Shiba-Rusinov states at dif…
Recent experiments announced an observation of topological superconductivity and Majorana quasiparticles in Shiba chains, consisting of an array of magnetic atoms deposited on top of a superconductor. In this work we study helical Shiba chains and generalize the microscopic theory of subgap energy bands to a regime where the decoupled magnetic impurity energy and the hybridization of different impurity states can be significant compared to the superconducting gap of the host material. From exact solutions of the Bogoliubov-de Gennes equation we extract expressions for the topological phase bou…
A major challenge in developing topological superconductors for implementing topological quantum computing is their characterization and control. It has been proposed that a p-wave gapped topological superconductor can be fabricated with single-atom precision by assembling chains of magnetic atoms on s-wave superconductors with spin-orbit coupling. Here, we analyze the Bogoliubov quasiparticle interference in atom-by-atom constructed Mn chains on Nb(110) and for the first time reveal the formation of multi-orbital Shiba bands using momentum resolved measurements. We find evidence that one band…
We introduce three new analytical and semi-analytical tools that allow one to determine the topological character of impurity Shiba chains. The analytical methods are based on calculating the effective Green's function of an infinite embedded chain using the T-matrix formalism and describing the chain as a {\it line impurity}. We thus provide a solution to the longstanding size-effects problem affecting the only general alternative method, the numerical tight-binding analysis. As an example we consider a chain of magnetic impurities deposited on an s-wave superconducting substrate with Rashba …
Recently, it has been suggested that topological superconductivity and Majorana end states can be realized in a chain of magnetic impurities on the surface of an s-wave superconductor when the magnetic moments form a spin helix as a result of the RKKY interaction mediated by the superconducting substrate. Here, we investigate this scenario theoretically by developing a tight-binding Bogoliubov-de Gennes description starting from the Shiba bound states induced by the individual magnetic impurities. While the resulting model Hamiltonian has similarities with the Kitaev model for one-dimensional …
Inspired by the recent experimental observation of topological superconductivity in ferromagnetic chains, we consider a dilute 2D lattice of magnetic atoms deposited on top of a superconducting surface with a Rashba spin-orbit coupling. We show that the studied system supports a generalization of $p_x+ip_y$ superconductivity and that its topological phase diagram contains Chern numbers higher than $ξ/a$ $(\gg1)$, where $ξ$ is the superconducting coherence length and $a$ is the distance between the magnetic atoms. The signatures of nontrivial topology can be observed by STM spectroscopy in fini…
Time-reversal symmetric topological superconductivity in Machida-Shibata lattices
I. Institute for Theoretical Physics, University of Hamburg（汉堡大学第一理论物理研究所）；Centre for Ultrafast Imaging（超快成像中心）；RIKEN Interdisciplinary Theoretical and Mathematical Sciences (iTHEMS)（理化学研究所交叉理论与数学科学（iTHEMS））
We study a chain of magnetic moments exchange coupled to a conventional three dimensional superconductor. In the normal state the chain orders into a collinear configuration, while in the superconducting phase we find that ferromagnetism is unstable to the formation of a magnetic spiral state. Beyond weak exchange coupling the spiral wavevector greatly exceeds the inverse superconducting coherence length as a result of the strong spin-spin interaction mediated through the subgap band of Yu-Shiba-Rusinov states. Moreover, the simple spin-spin exchange description breaks down as the subgap band …
A Yu-Shiba-Rusinov (YSR) state is a localized in-gap state induced by a magnetic impurity in a superconductor. Recent experiments used an STM tip to manipulate the exchange coupling between an Fe adatom and the ${\rm FeTe}_{0.55}{\rm Se}_{0.45}$ superconductor possessing a $Z_2$ nontrivial band structure with topological surface states. As the tip moves close to the single Fe adatom, the energy of the in-gap state is modulated and exhibits two unusual zero-energy crossings, which cannot be understood by coupling the magnetic impurity to the superconducting topological surface Dirac cone. Here,…
Supercurrent detection and manipulation of topological phase transitions in Shiba-Majorana hybrid systems
Physical Research Laboratory（物理研究实验室）；Technische Universität Braunschweig（布伦瑞克工业大学）；The Hamburg Centre for Ultrafast Imaging（汉堡超快成像中心）；Universität Hamburg（汉堡大学）；International Research Centre MagTop, Institute of Physics, Polish Academy of Sciences（波兰科学院物理研究所磁拓扑国际研究中心）；University of Basel（巴塞尔大学）
Regular arrays of magnetic atoms on a superconductor provide a promising platform for topological superconductivity. In this work we study effects of disorder in these systems, focusing on vacancies realized by missing magnetic atoms. We develop approaches that allow treatment of ferromagnetic dense chains as well as long-range hopping ferromagnetic and helical Shiba chains at arbitrary subgap energies. Vacancies in magnetic chains play an analogous role to magnetic impurities in a clean $s$-wave superconductor. A single vacancy in a topological chain gives rise to a low-lying "anti-Shiba" sta…
Recent experimental investigations of arrays of magnetic atoms deposited on top of a superconductor have opened a new chapter in the search of topological superconductivity. We generalize the microscopic model derived by Pientka et al. [Phys. Rev. B \textbf{88}, 155420 (2013)] to accommodate the effects of finite supercurrent in the host material. Previously it was discovered that helical chains with nonplanar textures are plagued by a gapless phase. We show that by employing supercurrent it is possible to tune the chain from the gapless phase to the topological gapped phase. It is also possib…
Chains of magnetic adatoms on superconductors have been discussed as promising systems for realizing Majorana end states. Here, we show that dilute Yu-Shiba-Rusinov (YSR) chains are also a versatile platform for quantum magnetism and correlated electron dynamics, with widely adjustable spin values and couplings. Focusing on subgap excitations, we derive an extended $t-J$ model for dilute quantum YSR chains and use it to study the phase diagram as well as tunneling spectra. We explore the implications of quantum magnetism for the formation of a topological superconducting phase, contrasting it …
We propose a new mechanism for topological superconductivity based on an antiferromagnetically ordered chain of magnetic atoms on the surface of a conventional superconductor. In a weak Zeeman field, a supercurrent in the substrate generates a staggered spin-current, which converts the preexisting topologically-unprotected Shiba states into Majorana fermions (MFs). The two experimental knobs can be finely tuned providing a platform with enhanced functionality for applications. Remarkably, the electronic spin-polarization of the arising edge MF wavefunctions depends solely on the parity of the …
There is presently a tremendous activity around the field of topological superconductivity and Majorana fermions. Among the many questions raised, it has become increasingly important to establish the topological or non-topological origin of features associated with Majorana fermions such as zero-bias peaks. Here, we compare in-gap features associated either with isolated magnetic impurities or with magnetic clusters strongly coupled to the atomically thin superconductor Pb/Si(111). We study this system by means of scanning tunneling microscopy and spectroscopy (STM/STS). We take advantage of …
Majorana fermions can be realized as quasiparticles in topological superconductors, with potential applications in topological quantum computing. Recently, lattices of magnetic adatoms deposited on the surface of s-wave superconductors - Shiba lattices - have been proposed as a new platform for topological superconductivity. These systems possess the great advantage that they are accessible via scanning-probe techniques, and thus enable the local manipulation and detection of Majorana modes. Realizing quantum bits on this basis will rely on the creation of nanoscopic Shiba lattices, so-called …
We demonstrate the formation of robust zero energy modes close to magnetic impurities in the iron-based superconductor FeSe$_{1-x}$Te$_x$. We find that the Zeeman field generated by the impurity favors a spin-triplet inter-orbital pairing as opposed to the spin-singlet intra-orbital pairing prevalent in the bulk. The preferred spin-triplet pairing preserves time-reversal symmetry and is topological, as robust, topologically-protected zero modes emerge at the boundary between regions with different pairing states. Moreover, the zero modes form Kramers doublets that are insensitive to the direct…
Monolayers of transition-metal dichalcogenides (TMDs) are two-dimensional materials whose low energy sector consists of two inequivalent valleys. The valence bands have a large spin splitting due to strong spin-orbit coupling. Furthermore the spin is polarized up in one valley and down in the other (in directions perpendicular to the two-dimensional crystal). We focus on lightly hole-doped systems where the Fermi surface consists of two disconnected circles with opposite spins. For both proximity induced and intrinsic local attractive interaction induced superconductivity, a fully gapped inter…
We consider a one-dimensional system combining local magnetic moments and a delocalized metallic band on top of a superconducting substrate. This system can describe a chain of magnetic impurities with both localized polarized orbitals and delocalized s-like orbitals or a conducting wire with embedded magnetic impurities. We study the interplay between the one-dimensional Shiba band physics arising from the interplay between magnetic moments and the substrate and the delocalized wire-like conduction band on top of the superconductor. We derive an effective low-energy Hamiltonian in terms of tw…
We investigate the possibility of realizing a topological state in the impurity band formed by a chain of classical spins embedded in a two-dimensional singlet superconductor with Rashba spin-orbit coupling. In contrast to similar proposals which require a helical spin texture of the impurity spins for a nontrivial topology, here we show that spin-flip correlations due to the spin-orbit coupling in the superconductor produces a topological state for ferromagnetic alignment of the impurity spins. From the Bogoliubov-de Gennes equations we derive an effective tight-binding model for the subgap s…
We theoretically investigate the phase transition from a non-trivial topological $p$-wave superconductor to a trivial $s$-wave like superconducting phase through a gapless phase, driven by different magnetic textures as an one-dimensional spin-chain impurity, e.g. Bloch-type, in-plane and out-of-plane Néel-type spin-chains etc. In our proposal, the chain of magnetic impurities is placed on a spin-triplet $p$-wave superconductor where we obtain numerically as well as analytically an effective $s$-wave like pairing due to spin rotation, resulting in gradual destruction of the Majorana zero modes…
Motivated by recent proposals to realize Majorana bound states in chains and arrays of magnetic atoms deposited on top of a superconductor, we study the topological properties of various chain structures, ladders and two-dimensional arrangements exhibiting magnetic helices. We show that magnetic domain walls where the chirality of a magnetic helix is inverted support two protected Majorana states giving rise to a tunneling conductance peak twice the height of a single Majorana state. The topological properties of coupled chains exhibit nontrivial behaviour as a function of the number of chains…
NbSe$_2$ is a remarkable superconductor in which charge-density order coexists with pairing correlations at low temperatures. Here, we study the interplay of magnetic adatoms and their Yu-Shiba-Rusinov (YSR) bound states with the charge density order. Exploiting the incommensurate nature of the charge-density wave (CDW), our measurements provide a thorough picture of how the CDW affects both the energies and the wavefunctions of the YSR states. Key features of the dependence of the YSR states on adsorption site relative to the CDW are explained by model calculations. Several properties make Nb…
Magnetic impurities have a dramatic effect on superconductivity by breaking the time-reversal symmetry and inducing so-called Yu-Shiba-Rusinov (YSR) low energy bound states within the superconducting gap. The spatial extent of YSR states is greatly enhanced in 2D systems, which should facilitate the formation of coupled states. Here, we observe YSR states on single cobalt phthalocyanine (CoPC) molecules on a 2D superconductor NbSe$_2$ using low-temperature scanning tunneling microscopy (STM) and spectroscopy (STS). We use STM lateral manipulation to create controlled CoPc dimers and demonstrat…
A characteristic feature of Shiba impurities is the existence of a spin- and parity-changing quantum phase transition (known as "0-$π$" transition) which has been observed in scanning tunneling microscopy (STM) and transport experiments. Using the Abelian bosonization technique, here we analyze the ground-state properties and the quantum phase diagram of a classical (i.e., Ising-like) Shiba impurity. In particular, we analyze the cases of an impurity in a three- and a one-dimensional superconductor. Within the bosonization framework, the ground-state properties are determined by simple soliton…
Recent studies of mutually interacting magnetic atoms coupled to a superconductor have gained enormous interest due to the potential realization of topological superconductivity. The Kondo exchange coupling J_K of such atoms with the electrons in the superconductor has a pair-breaking effect which produces so-called Yu-Shiba-Rusinov (YSR) states within the superconducting energy gap, whose energetic positions are intimately connected with the requirements for topological superconductivity. Here, using the tip of a scanning tunneling microscope, we artificially craft a multi-impurity Kondo syst…
We present a study of Andreev Quantum Dots (QDots) fabricated with small-diameter (30 nm) Si-doped InAs nanowires where the Fermi level can be tuned across a mobility edge separating localized states from delocalized states. The transition to the insulating phase is identified by a drop in the amplitude and width of the excited levels and is found to have remarkable consequences on the spectrum of superconducting SubGap Resonances (SGRs). While at deeply localized levels, only quasiparticles co-tunneling is observed, for slightly delocalized levels, Shiba bound states form and a parity changin…
Theoretical descriptions of Yu-Shiba-Rusinov (YSR) states induced by magnetic impurities inside the gap of a superconductor typically rely on a classical spin model or are restricted to spin-1/2 quantum spins. These models fail to account for important aspects of YSR states induced by transition-metal impurities, including the effects of higher quantum spins coupled to several conduction-electron channels, crystal or ligand-field effects, and magnetic anisotropy. We introduce and explore a zero-bandwidth model, which incorporates these aspects, is readily solved numerically, and analytically t…
Local spins coupled to superconductors give rise to several emerging phenomena directly linked to the competition between Cooper pair formation and magnetic exchange. These effects are generally scrutinized using a spectroscopic approach which relies on detecting the in-gap bound modes arising from Cooper pair breaking, the so-called Yu-Shiba-Rusinov (YSR) states. However, the impact of local magnetic impurities on the superconducting order parameter remains largely unexplored. Here, we use scanning Josephson spectroscopy to directly visualize the effect of magnetic perturbations on Cooper pai…
Recent experimental studies have found that magnetic impurities deposited on superconducting monolayer NbSe$_2$ generate coupled Yu-Shiba-Rusinov bound states. Here we consider ferromagnetic chains of impurities which induce a Yu-Shiba-Rusinov band and harbor Majorana bound states at the chain edges. We show that these topological phases are stabilized by strong Ising spin-orbit coupling in the monolayer and examine the conditions under which Majorana phases appear as a function of distance between impurities, impurity spin projection, orientation of chains on the surface of the monolayer, and…
Magnetic impurities in $s$-wave superconductors lead to spin-polarized Yu-Shiba-Rusinov (YSR) in-gap states. Chains of magnetic impurities offer one of the most viable routes for the realization of Majorana bound states which hold a promise for topological quantum computing. However, this ambitious goal looks distant since no quantum coherent degrees of freedom have yet been identified in these systems. To fill this gap we propose an effective two-level system, a YSR qubit, stemming from two nearby impurities. Using a time-dependent wave-function approach, we derive an effective Hamiltonian de…
We study theoretically a chain of precessing classical magnetic impurities in an $s$-wave superconductor. Utilizing a rotating wave description, we derive an effective Hamiltonian that describes the emergent Shiba band. We find that this Hamiltonian shows non-trivial topological properties, and we obtain the corresponding topological phase diagrams both numerically and analytically. We show that changing the precession frequency offers a control over topological phase transitions and the emergence of Majorana bound states. We propose driving the magnetic impurities or magnetic texture into pre…
We theoretically consider the effect of a spatially periodic modulation of the superconducting order parameter on the formation of Majorana fermions induced by a one-dimensional system with magnetic impurities brought into close proximity to an $s$-wave superconductor. When the magnetic exchange energy is larger than the inter-impurity electron hopping we model the effective system as a chain of coupled Shiba states. While in the opposite regime, the effective system is accurately described by a quantum wire model. Upon including a spatially modulated superconducting pairing, we find, for suff…
We calculate the current as a function of applied voltage in non-topological s-wave superconductor-quantum dot-topological superconductor tunnel junction. We consider the type of TS which hosts two Majorana bound states (MBS) at the ends of a semiconductor quantum wire or of a chain of magnetic atoms in the proximity with s-wave superconductor. We find that the $I-V$ characteristic of such system in the regime of big voltages has a typical two dot shape and is ornamented by peaks of multiple Andreev reflections. We also consider the other options when the zero energy states are created by diso…
When a strongly correlated quantum dot is tunnel-coupled to a superconductor, it leads to the formation of Shiba bound states inside the superconducting gap. They have been measured experimentally in a superconductor-quantum dot-normal lead setup. Side coupling the quantum dot to a topological superconducting wire that supports Majorana bound states at its ends, drastically affects the structure of the Shiba states and induces supplementary in-gap states. The anomalous coupling between the Majorana bound states and the quantum dot gives rise to a characteristic imbalance in the spin resolved s…
We study the magnetic and electronic phases of a 1D magnetic adatom chain on a 2D superconductor. In particular, we confirm the existence of a `self-organized' 1D topologically non-trivial superconducting phase within the set of subgap Yu-Shiba-Rusinov (YSR) states formed along the magnetic chain. This phase is stabilized by incommensurate spiral correlations within the magnetic chain that arise from the competition between short-range ferromagnetic and long-range antiferromagnetic electron-induced exchange interactions, similar to a recent study for a 3D superconductor [M. Schecter et al. Phy…
We characterize parallel double quantum dot Josephson junctions based on closely-grown double nanowires bridged by in-situ deposited superconductors. The parallel double dot behavior occurs despite the closeness of the nanowires and the potential risk of nanowire clamping during growth. By tuning the charge filling and lead couplings, we map out the simplest parallel double quantum dot Yu-Shiba-Rusinov phase diagram. Our quasi-independent two-wire hybrids show promise for the realization of exotic topological phases.
Heavy metals, such as Au, Ag, and Pb, often have sharp surface states that are split by strong Rashba spin-orbit coupling. The strong spin-orbit coupling and two-dimensional nature of these surface states make them ideal platforms for realizing topological superconductivity and Majorana fermions. In this paper, we further develop a proposal to realize Majorana fermions at the ends of quasi-one-dimensional metallic wires. We show how superconductivity can be induced on the metallic surface states by a combination of proximity effect, disorder, and interactions. Applying a magnetic field along t…
Magnetic atoms on heavy-element superconducting substrates are potential building blocks for realizing topological superconductivity in one- and two-dimensional atomic arrays. Their localized magnetic moments induce so-called Yu-Shiba-Rusinov (YSR) states inside the energy gap of the substrate. In the dilute limit, where the electronic states of the array atoms are only weakly coupled, proximity of the YSR states to the Fermi energy is essential for the formation of topological superconductivity in the band of YSR states. Here, we reveal via scanning tunnel spectroscopy and ab initio calculati…
We study a two-dimensional heterostructure comprised of a monolayer of the magnetic insulator chromium triiodide (CrI$_3$) on a superconducting lead (Pb) substrate. Through first-principles computation and a tight-binding model, we demonstrate that charge transfer from the Pb substrate dopes the CrI$_3$ into an effective half-metal, allowing for the onset of a gapless topological superconductivity phase via the proximity effect. This phase, in which there exists a superconducting gap only in part of the Fermi surface, is shown to occur generically in 2D half-metal-superconductor heterostructur…
We investigate the topological classification of the subgap bands induced in a two-dimensional superconductor by a densely packed chain of magnetic moments with ferromagnetic or spiral alignments. The wave functions for these bands are composites of Yu-Shiba-Rusinov-type states and magnetic scattering states and have a significant spatial extension away from the magnetic moments. We show that this spatial structure prohibits a straightforward extraction of a Hamiltonian useful for the topological classification. To address the latter correctly we construct a family of spatially varying topolog…
We report on several low temperature experiments supporting the presence of Majorana fermions in superconducting lead nanowires fabricated with a scanning tunneling microscope. These nanowires are the connecting bridges between the STM tip and the sample resulting from indentation processes. We show here that by a controlled tuning of the geometry of the nanowire region, in which superconductivity is confined by applied magnetic fields, the conductance curves obtained in these situations are indicative of topological superconductivity and Majorana fermions. The most prominent feature of this b…
We investigate the topological properties and the accessible Majorana fermion (MF) phases arising in a hybrid device consisting of a chain of magnetic adatoms placed on the surface of a conventional superconductor with Rashba spin-orbit coupling (SOC). By identifying the favored classical magnetic ground state of the adatom chain, we extract the corresponding phase diagram which exhibits an interplay of ferromagnetic (FM), antiferromagnetic (AFM) and spiral orders. We determine the parameter regime for which the FM or AFM phases dominate over the spiral and additionally become stable against t…
We investigate the influence of different spin-orbit couplings on topological phase transitions in the bilayer Kane-Mele model. We find that the competition between intrinsic spin-orbit coupling and Rashba spin-orbit coupling can lead to two dimensional topological metallic states with nontrivial topology. Such phases, although having a metallic bulk, still possess edge states with well-defined topological invariants. Specifically, we show that with preserved time reversal symmetry, the system can exhibit a $\mathbb{Z}_2$-metallic phase with spin helical edge states and a nontrivial $\mathbb{Z…
The lifetime of electrons on edge states of a two-dimensional topological insulator against the background of an allowed two-dimensional band has been determined. It has been shown that this time in the case of scattering on Coulomb impurities can be significantly larger than the mean free time of two-dimensional electrons. As a result, the conductivity of the metallic two-dimensional topological insulator strip can be determined primarily by edge states.
Recently, a new quantum phase, the topological insulator, has been vividly investigated in a variety of materials. Its unique bandstructure allows for optical generation and control of spin-polarized currents based on the circular photogalvanic effect. In this paper, we generate and distinguish the different photocurrent contributions via the the polarization of the driving light wave. We discuss the helicity-dependent spin-polarized current and the polarization independent thermoelectric current as spatially resolved maps, focusing on the influence of the topological insulator/metallic contac…
We study electronic structures at an interface between a topological insulator and a ferromagnetic insulator by using three-dimensional two-band model. In usual ferromagnetic insulators, the exchange potential is much larger than the bulk gap size in the topological insulators and electronic structures are asymmetric with respect to the fermi level. In such situation, we show that unusual metallic states appear under the magnetic moment pointing the perpendicular direction to the junction plane, which cannot be described by the two-dimensional effective model around the Dirac point. When the m…
