The upcoming deployment of JWST will dramatically advance our ability to characterize exoplanet atmospheres, both in terms of precision and sensitivity to smaller and cooler planets. Disequilibrium chemical processes dominate these cooler atmospheres, requiring accurate photochemical modeling of such environments. The host star's UV spectrum is a critical input to these models, but most exoplanet hosts lack UV observations. For cases in which the host UV spectrum is unavailable, a reconstructed or proxy spectrum will need to be used in its place. In this study, we use the MUSCLES catalog and UV line scaling relations to understand how well reconstructed host star spectra reproduce photochemically modeled atmospheres using real UV observations. We focus on two cases; a modern Earth-like atmosphere and an Archean Earth-like atmosphere that forms copious hydrocarbon hazes. We find that modern Earth-like environments are well-reproduced with UV reconstructions, whereas hazy (Archean Earth) atmospheres suffer from changes at the observable level. Specifically, both the stellar UV emission lines and the UV continuum significantly influence the chemical state and haze production in our modeled Archean atmospheres, resulting in observable differences in their transmission spectra. Our modeling results indicate that UV observations of individual exoplanet host stars are needed to accurately characterize and predict the transmission spectra of hazy terrestrial atmospheres. In the absence of UV data, reconstructed spectra that account for both UV emission lines and continuum are the next best option, albeit at the cost of modeling accuracy.
Although transit spectroscopy is a powerful method for studying the composition, thermal properties and dynamics of exoplanet atmospheres, only a few transiting terrestrial exoplanets will be close enough to allow significant transit spectroscopy. Thermal phase curves (variations of the apparent infrared emission of the planet with its orbital phase) have been observed for hot Jupiters in both transiting and nontransiting configurations, and could be observed for hot terrestrial exoplanets. We study the wavelength and phase changes of the thermal emission of a tidally-locked terrestrial planet…
With more than 4,300 confirmed exoplanets and counting, the next milestone in exoplanet research is to determine which of these newly found worlds could harbor life. Coronal Mass Ejections (CMEs), spawn by magnetically active, superflare-triggering dwarf stars, pose a direct threat to the habitability of terrestrial exoplanets as they can deprive them from their atmospheres. Here we develop a readily implementable atmosphere sustainability constraint for terrestrial exoplanets orbiting active dwarfs, relying on the magnetospheric compression caused by CME impacts. Our constraint focuses on a s…
Accurately measuring and modeling the Lyman-$α$ (Ly$α$; $λ$1215.67 Å) emission line from low mass stars is vital for our ability to build predictive high energy stellar spectra, yet interstellar medium (ISM) absorption of this line typically prevents model-measurement comparisons. Ly$α$ also controls the photodissociation of important molecules, like water and methane, in exoplanet atmospheres such that any photochemical models assessing potential biosignatures or atmospheric abundances require accurate Ly$α$ host star flux estimates. Recent observations of three early M and K stars (K3, M0, M…
Terrestrial planets formed within gaseous protoplanetary disks can accumulate significant hydrogen envelopes. The evolution of such an atmosphere due to XUV driven evaporation depends on the activity evolution of the host star, which itself depends sensitively on its rotational evolution, and therefore on its initial rotation rate. In this letter, we derive an easily applicable method for calculating planetary atmosphere evaporation that combines models for a hydrostatic lower atmosphere and a hydrodynamic upper atmosphere. We show that the initial rotation rate of the central star is of criti…
The nearby bright M-dwarf star L~98-59 has three terrestrial-sized planets. One challenge remaining in characterizing atmospheres around such planets is that it is not known a priori whether they possess any atmospheres. Here we report the study of the atmospheres of L~98-59~c and L~98-59~d using the near-infrared spectral data from the G141 grism of HST/WFC3. We can reject the hypothesis of a clear atmosphere dominated by hydrogen and helium at a confidence level of $\sim$ 3~sigma for both planets. Thus they may have a primary hydrogen-dominated atmosphere with an opaque cloud layer, or have …
Sulfur gases are common components in the volcanic and biological emission on Earth, and are expected to be important input gases for atmospheres on terrestrial exoplanets. We study the atmospheric composition and the spectra of terrestrial exoplanets with sulfur compounds (i.e., H2S and SO2) emitted from their surfaces. We use a comprehensive one-dimensional photochemistry model and radiative transfer model to investigate the sulfur chemistry in atmospheres ranging from reducing to oxidizing. The most important finding is that both H2S and SO2 are chemically short-lived in virtually all types…
Detection of life on other planets requires identification of biosignatures, i.e., observable planetary properties that robustly indicate the presence of a biosphere. One of the most widely accepted biosignatures for an Earth-like planet is an atmosphere where oxygen is a major constituent. Here we show that lifeless habitable zone terrestrial planets around any star type may develop oxygen-dominated atmospheres as a result of water photolysis, because the cold trap mechanism that protects H2O on Earth is ineffective when the atmospheric inventory of non-condensing gases (e.g., N2, Ar) is low.…
The discovery of thousands of highly irradiated, low-mass, exoplanets has led to the idea that atmospheric escape is an important process that can drive their evolution. Of particular interest is the inference from recent exoplanet detections that there is a large population of low mass planets possessing significant, hydrogen dominated atmospheres, even at masses as low as $\sim 2$~M$_\oplus$. The size of these hydrogen dominated atmospheres indicates the the envelopes must have been accreted from the natal protoplanetary disc. This inference is in contradiction with the Solar System terrestr…
We use thermodynamic calculations to model atmospheric chemistry on terrestrial exoplanets that are hot enough for chemical equilibira between the atmosphere and lithosphere, as on Venus. The results of our calculations place constraints on abundances of spectroscopically observable gases, the surface temperature and pressure, and the mineralogy of the surface. These results will be useful in planning future observations of the atmospheres of terrestrial-sized exoplanets by current and proposed space observatories such as the Hubble Space Telescope (HST), Spitzer, James Webb Space Telescope (J…
Terrestrial exoplanets likely form initial atmospheres through outgassing during and after accretion, although there is currently no first-principles understanding of how to connect a planet's bulk composition to its early atmospheric properties. Important insights into this connection can be gained by assaying meteorites, representative samples of planetary building blocks. We perform laboratory outgassing experiments that use a mass spectrometer to measure the abundances of volatiles released when meteorite samples are heated to 1200 $^{\circ}$C. We find that outgassing from three carbonaceo…
We used chemical equilibrium and chemical kinetic calculations to model chemistry of the volatiles released by heating different types of carbonaceous, ordinary and enstatite chondritic material as a function of temperature and pressure. Our results predict the composition of atmospheres formed by outgassing during accretion of the Earth and other terrestrial planets. Outgassing of CI and CM carbonaceous chondritic material produces H2O-rich (steam) atmospheres in agreement with the results of impact experiments. However, outgassing of other types of chondritic material produces atmospheres do…
We present a comprehensive photochemistry model for exploration of the chemical composition of terrestrial exoplanet atmospheres. The photochemistry model is designed from the ground up to have the capacity to treat all types of terrestrial planet atmospheres, ranging from oxidizing through reducing, which makes the code suitable for applications for the wide range of anticipated terrestrial exoplanet compositions. The one-dimensional chemical transport model treats up to 800 chemical reactions, photochemical processes, dry and wet deposition, surface emission and thermal escape of O, H, C, N …
A terrestrial planet is molten during formation and may remain so if subject to intense insolation or tidal forces. Observations continue to favour the detection and characterisation of hot planets, potentially with large outgassed atmospheres. We aim to determine the radius of hot Earth-like planets with large outgassed atmospheres and explore differences between molten and solid silicate planets and their influence on the mass-radius relationship and transmission and emission spectra. An interior-atmosphere model, combined with static structure calculations, tracks the evolving radius of a r…
Upper atmosphere dynamics and drivers of volatiles loss from terrestrial-type (exo)planets
Austrian Academy of Sciences（奥地利科学院）；University of Bern（伯尔尼大学）；NASA Goddard Institute for Space Studies（美国宇航局戈达德太空研究所）；Uppsala University（乌普萨拉大学）；Institut de Recherche en Astrophysique et Planétologie, Université de Toulouse/CNRS/CNES（天体物理与行星学研究 institute，图卢兹大学/CNRS/CNES）；Center for Space Research and Technology, Academy of Athens（雅典科学院空间研究与技术中心）；INAF-Osservatorio Astrofisico di Catania（意大利国家天体物理研究所卡塔尼亚天文台）；Florida Institute of Technology（佛罗里达理工学院）；International Space Science Institute（国际空间科学研究所）；Swedish Institute of Space Physics（瑞典空间物理研究所）；Res
Recent detection of exoplanets with Earth-like insolation attracts growing interest in how common Earth-like aqua planets are beyond the solar system. While terrestrial planets are often assumed to capture icy or water-rich planetesimals, a primordial atmosphere of nebular origin itself can produce water through oxidation of the atmospheric hydrogen with oxidising minerals from incoming planetesimals or the magma ocean. Thermodynamically, normal oxygen buffers produce water comparable in mole number to or more than hydrogen. Thus, the primordial atmosphere would likely be highly enriched with …
Cosmic rays may be linked to the formation of volatiles necessary for prebiotic chemistry. We explore the effect of cosmic rays in a hydrogen-dominated atmosphere, as a proof-of-concept that ion-neutral chemistry may be important for modelling hydrogen-dominated atmospheres. In order to accomplish this, we utilize Monte Carlo cosmic ray transport models with particle energies of $10^6$ eV $< E < 10^{12}$ eV in order to investigate the cosmic ray enhancement of free electrons in substellar atmospheres. Ion-neutral chemistry is then applied to a Drift-Phoenix model of a free-floating giant gas p…
TESS is expected to discover dozens of temperate terrestrial planets orbiting M dwarfs whose atmospheres could be followed up with the James Webb Space Telescope (JWST). Currently, the TRAPPIST-1 system serves as a benchmark to determine the feasibility and resources required to yield atmospheric constraints. We assess these questions and leverage an information content analysis to determine observing strategies for yielding high precision spectroscopy in transmission and emission. Our goal is to guide observing strategies of temperate terrestrial planets in preparation for the early JWST cycl…
The composition of planets is largely determined by the chemical and dynamical evolution of the disk during planetesimal formation and growth. To predict the diversity of exoplanet compositions, previous works modeled planetesimal composition as the equilibrium chemical composition of a proto- planetary disk at a single time. However, planetesimals form over an extended period of time, during which, elements sequentially condense out of the gas as the disk cools and are accreted onto planetesi- mals. To account for the evolution of the disk during planetesimal formation, we couple models of di…
We present a detailed analysis of the dayside atmosphere of the hot-Neptune GJ~436b, based on recent Spitzer observations. We report statistical constraints on the thermal and chemical properties of the planetary atmosphere, study correlations between the various molecular species, and discuss scenarios of equilibrium and non-equilibrium chemistry in GJ 436b. We model the atmosphere with a one-dimensional line-by-line radiative transfer code with parameterized molecular abundances and temperature structure. We explore the model parameter space with 10^6 models, using a Markov chain Monte Carlo…
In this chapter we describe chemistry of the early atmosphere of the Earth during and shortly after its formation where there is little if any geological record. We review the arguments for a secondary origin of the terrestrial atmosphere, that is by outgassing during and/or after accretion rather than by capture of solar nebula gas. Then we discuss sources of volatiles accreted by the Earth using meteorites as analogs for the material present in the solar nebula. The next section reviews heating during accretion of the Earth. Subsequently we describe chemistry of the silicate vapor, steam, an…
Atmospheric chemistry models have shown molecular oxygen can build up in CO2-dominated atmospheres on potentially habitable exoplanets without an input of life. Existing models typically assume a surface pressure of 1 bar. Here we present model scenarios of CO2-dominated atmospheres with the surface pressure ranging from 0.1 to 10 bars, while keeping the surface temperature at 288 K. We use a one-dimensional photochemistry model to calculate the abundance of O2 and other key species, for outgassing rates ranging from a Venus-like volcanic activity up to 20x Earth-like activity. The model maint…
The most widely-studied mechanism of mass loss from extrasolar planets is photoevaporation via XUV ionization, primarily in the context of highly irradiated planets. However, the EUV dissociation of hydrogen molecules can also theoretically drive atmospheric evaporation on low-mass planets. For temperate planets such as the early Earth, impact erosion is expected to dominate in the traditional planetesimal accretion model, but it would be greatly reduced in pebble accretion scenarios, allowing other mass loss processes to be major contributors. We apply the same prescription for photoionizatio…
Evidence of disequilibrium chemistry due to vertical mixing in the atmospheres of many T and Y-dwarfs has been inferred due to enhanced mixing ratios of CO and reduced NH$_3$. Atmospheric models of planets and brown dwarfs typically parameterize this vertical mixing phenomenon with the vertical eddy diffusion coefficient, $K_{\rm zz}$. While $K_{\rm zz}$ can perhaps be approximated in the convective regions in the atmosphere with mixing length theory, in radiative regions the strength of vertical mixing is uncertain by many orders of magnitude. With a new grid of self-consistent 1D model atmos…
The macroturbulent atmospheric circulation of Earth-like planets mediates their equator-to-pole heat transport. For fast-rotating terrestrial planets, baroclinic instabilities in the mid-latitudes lead to turbulent eddies that act to transport heat poleward. In this work, we derive a scaling theory for the equator-to-pole temperature contrast and bulk lapse rate of terrestrial exoplanet atmospheres. This theory is built on the work of Jansen & Ferrari (2013), and determines how unstable the atmosphere is to baroclinic instability (the baroclinic "criticality") through a balance between the bar…
The ubiquity of M dwarfs, combined with the relative ease of detecting terrestrial-mass planets around them, has made them prime targets for finding and characterising planets in the "Habitable Zone" (HZ). However, Kepler finds that terrestrial-mass exoplanets are often born with voluminous H/He envelopes, comprising mass-fractions ($M_{env}/M_{core}$) $\gtrsim 1$%. If these planets retain such envelopes over Gyr timescales, they will not be "habitable" even within the HZ. Given the strong X-ray/UV fluxes of M dwarfs, we study whether sufficient envelope mass can be photoevaporated away for th…
We investigate the abiotic production of oxygen and its photochemical byproduct ozone through water vapor photolysis in moist atmospheres of temperate terrestrial exoplanets. The amount of water vapor available for photolysis in the middle atmosphere of a planet can be limited by an atmospheric cold-trap, the formation of which largely depends on the amount of non-condensable gases. We study this effect using a photochemical model coupled to a 1D radiative-convective equilibrium model in atmospheres with N2, CO2 and H2O as the main constituents. We find that in atmospheres with a low N2 invent…
It has been investigated the possibility of the various atmospheres over water oceans. We have considered the H$_2$ atmosphere and He atmosphere concerning to N$_2$ atmosphere over oceans. One of the main subjects in astrobiology is to estimate the habitable zone. If there is an ocean on the planet with an atmosphere, there is an upper limit to the outgoing infrared radiation called the Komabayashi-Ingersoll limit (KI-limit). This limit depends on the components of the atmospheres. We have investigated this dependence under the simple model, using the one-dimensional gray radiative-convective …
Some super Earths and mini Neptunes will likely have thick atmospheres that are not H2-dominated. We have developed a photochemistry-thermochemistry kinetic-transport model for exploring the compositions of thick atmospheres on super Earths and mini Neptunes, applicable for both H2-dominated atmospheres and non-H2-dominated atmospheres. Using this model to study thick atmospheres for wide ranges of temperatures and elemental abundances, we classify them into hydrogen-rich atmospheres, water-rich atmospheres, oxygen-rich atmospheres, and hydrocarbon-rich atmospheres. We find that carbon has to …
The discovery and characterization of Earth-sized planets that are in, or near, a tidally-locked state are of crucial importance to understanding terrestrial planet evolution, and for which Venus is a clear analog. Exoplanetary science lies at the threshold of characterizing hundreds of terrestrial planetary atmospheres, thereby providing a statistical sample far greater than the limited inventory of terrestrial planetary atmospheres within the Solar System. However, the model-based approach for characterizing exoplanet atmospheres relies on Solar System data, resulting in our limited inventor…
Most known terrestrial planets orbit small stars with radii less than 60% that of the Sun. Theoretical models predict that these planets are more vulnerable to atmospheric loss than their counterparts orbiting Sun-like stars. To determine whether a thick atmosphere has survived on a small planet, one approach is to search for signatures of atmospheric heat redistribution in its thermal phase curve. Previous phase curve observations of the super-Earth 55 Cancri e (1.9 Earth radii) showed that its peak brightness is offset from the substellar point $-$ possibly indicative of atmospheric circulat…
We present a new scaling law to predict the loss of atmosphere from planetary collisions for any speed, angle, impactor mass, target mass, and body compositions, in the regime of giant impacts onto broadly terrestrial planets with relatively thin atmospheres. To this end, we examine the erosion caused by a wide range of impacts, using 3D smoothed particle hydrodynamics simulations with sufficiently high resolution to directly model the fate of low-mass atmospheres around 1% of the target's mass. Different collision scenarios lead to extremely different behaviours and consequences for the plane…
Aims: The secondary atmospheres of terrestrial planets form and evolve as a consequence of interaction with the interior over geological time. We aim to quantify the influence of planetary bulk composition on the interior--atmosphere evolution for Earth-sized terrestrial planets to aid in the interpretation of future observations of terrestrial exoplanet atmospheres. Methods: We used a geochemical model to determine the major-element composition of planetary interiors (MgO, FeO, and SiO2) following the crystallization of a magma ocean after planet formation, predicting a compositional profile …
Water photolysis and hydrogen loss from the upper atmospheres of terrestrial planets is of fundamental importance to climate evolution but remains poorly understood in general. Here we present a range of calculations we performed to study the dependence of water loss rates from terrestrial planets on a range of atmospheric and external parameters. We show that CO2 can only cause significant water loss by increasing surface temperatures over a narrow range of conditions, with cooling of the middle and upper atmosphere acting as a bottleneck on escape in other circumstances. Around G-stars, effi…
We show that by changing a single non-dimensional number, the thermal Rossby number, global atmospheric simulations with only axisymmetric forcing pass from an Earth-like atmosphere to a superrotating atmosphere that more resembles the atmospheres of Venus or Titan. The transition to superrotation occurs under conditions in which equatorward-propagating Rossby waves generated by baroclinic instability at intermediate and high latitudes are suppressed, which will occur when the deformation radius exceeds the planetary radius. At large thermal Rossby numbers following an initial, nearly axisymme…
Massive steam and CO$_2$ atmospheres have been proposed for magma ocean outgassing of Earth and terrestrial planets. Yet formation of such atmospheres depends on volatile exchange with the molten interior, governed by volatile solubilities and redox reactions. We determine the evolution of magma ocean--atmosphere systems for a range of oxygen fugacities, C/H ratios and hydrogen budgets that include redox reactions for hydrogen (H$_2$--H$_2$O), carbon (CO--CO$_2$), methane (CH$_4$), and solubility laws for H$_2$O and CO$_2$. We find that small initial budgets of hydrogen, high C/H ratios, and o…
Transit spectroscopy of terrestrial planets around nearby M dwarfs is a primary goal of space missions in coming decades. 3-D climate modeling has shown that slow-synchronous rotating terrestrial planets may develop thick clouds at the substellar point, increasing the albedo. For M dwarfs with Teff > 3000 K, such planets at the inner habitable zone (IHZ) have been shown to retain moist greenhouse conditions, with enhanced stratospheric water vapor (fH2O > 1E-3) and low Earth-like surface temperatures. However, M dwarfs also possess strong UV activity, which may effectively photolyze stratosphe…
In this work we study the effect of disequilibrium processes on mixing ratio profiles of neutral species and on the simulated spectra of a hot Jupiter exoplanet that orbits stars of different spectral types. We also address the impact of stellar activity that should be present to a different degree in all stars with convective envelopes. We used the VULCAN chemical kinetic code to compute number densities of species. The temperature-pressure profile of the atmosphere was computed with the HELIOS code. We also utilized the $τ$-ReX forward model to predict the spectra of planets in primary and s…
Terrestrial planets currently in the habitable zones around M dwarfs likely experienced a long-term runaway greenhouse condition because of a slow decline in host-stellar luminosity in its pre-main sequence phase. Accordingly, they might have lost significant portions of their atmospheres including water vapor at high concentration by hydrodynamic escape induced by the strong stellar XUV irradiation. However, the atmospheric escape rates remain highly uncertain due partly to a lack of understanding of the effect of radiative cooling in the escape outflows. Here we carry out 1-D hydrodynamic es…
The emergence of life on the Earth has required a prior organic chemistry leading to the formation of prebiotic molecules. The origin and the evolution of the organic matter on the early Earth is not yet firmly understood. Several hypothesis, possibly complementary, are considered. They can be divided in two categories: endogenous and exogenous sources. In this work we investigate the contribution of a specific endogenous source: the organic chemistry occurring in the ionosphere of the early Earth where the significant VUV contribution of the young Sun involved an efficient formation of reacti…
CO is an important component in many N2/CH4 atmospheres including Titan, Triton, and Pluto, and has also been detected in the atmosphere of a number of exoplanets. Numerous experimental simulations have been carried out in the laboratory to understand the chemistry in N2/CH4 atmospheres, but very few simulations have included CO in the initial gas mixtures. The effect of CO on the chemistry occurring in these atmospheres is still poorly understood. We have investigated the effect of CO on both gas and solid phase chemistry in a series of planetary atmosphere simulation experiments using gas mi…
We model the formation of silicate atmospheres on hot volatile-free super-Earths. Our calculations assume that all volatile elements such as H, C, N, S, and Cl have been lost from the planet. We find that the atmospheres are composed primarily of Na, O2, O, and SiO gas, in order of decreasing abundance. The atmospheric composition may be altered by fractional vaporization, cloud condensation, photoionization, and reaction with any residual volatile elements remaining in the atmosphere. Cloud condensation reduces the abundance of all elements in the atmosphere except Na and K. We speculate that…
In this paper we present three-dimensional atmospheric simulations of the hot Jupiter HD~189733b under two different scenarios: local chemical equilibrium and including advection of the chemistry by the resolved wind. Our model consistently couples the treatment of dynamics, radiative transfer and chemistry, completing the feedback cycle between these three important processes. The effect of wind--driven advection on the chemical composition is qualitatively similar to our previous results for the warmer atmosphere of HD~209458b, found using the same model. However, we find more significant al…
Atmospheres play a crucial role in planetary habitability. Around M dwarfs and young Sun-like stars, planets receiving the same insolation as the present-day Earth are exposed to intense stellar X-rays and extreme-ultraviolet (XUV) radiation. This study explores the fundamental question of whether the atmosphere of present-day Earth could survive in such harsh XUV environments. Previous theoretical studies suggest that stellar XUV irradiation is sufficiently intense to remove such atmospheres completely on short timescales. In this study, we develop a new upper-atmospheric model and re-examine…
Terrestrial exoplanets orbiting M-dwarf stars are promising targets for transmission spectroscopy with existing or near-future instrumentation. The atmospheric composition of such rocky planets remains an open question, especially given the high X-ray and ultraviolet flux from their host M dwarfs that can drive atmospheric escape. The 1.3 $R_\oplus$ exoplanet GJ 486b ($T_{\rm{eq}} \sim$ 700 K), orbiting an M3.5 star, is expected to have one of the strongest transmission spectroscopy signals among known terrestrial exoplanets. We observed three transits of GJ 486b using three different high-res…
Nearby M dwarf systems currently offer the most favorable opportunities for spectroscopic investigations of terrestrial exoplanet atmospheres. The LTT~1445 system is a hierarchical triple of M dwarfs with two known planets orbiting the primary star, LTT~1445A. We observe four transits of the terrestrial world LTT~1445Ab ($R=1.3$ R$_\oplus$, $M=2.9$ M$_\oplus$) at low resolution with Magellan II/LDSS3C. We use the combined flux of the LTT~1445BC pair as a comparison star, marking the first time that an M dwarf is used to remove telluric variability from time-series observations of another M dwa…
The recently discovered low-density "super-Earths" Kepler-11b, Kepler-11f, Kepler-11d, Kepler-11e, and planets such as GJ 1214b represent most likely planets which are surrounded by dense H/He envelopes or contain deep H2O oceans also surrounded by dense hydrogen envelopes. Although these "super-Earths" are orbiting relatively close to their host stars, they have not lost their captured nebula-based hydrogen-rich or degassed volatile-rich steam protoatmospheres. Thus it is interesting to estimate the maximum possible amount of atmospheric hydrogen loss from a terrestrial planet orbiting within…
Terrestrial planets orbiting M dwarfs may soon be observed with the James Webb Space Telescope (JWST) to characterize their atmospheric composition and search for signs of habitability or life. These planets may undergo significant atmospheric and ocean loss due to the superluminous pre-main-sequence phase of their host stars, which may leave behind abiotically-generated oxygen, a false positive for the detection of life. Determining if ocean loss has occurred will help assess potential habitability and whether or not any O2 detected is biogenic. In the solar system, differences in isotopic ab…
We use thermochemical equilibrium calculations to model iron, magnesium, and silicon chemistry in the atmospheres of giant planets, brown dwarfs, extrasolar giant planets (EGPs), and low-mass stars. The behavior of individual Fe-, Mg-, and Si-bearing gases and condensates is determined as a function of temperature, pressure, and metallicity. Our results are thus independent of any particular model atmosphere. The condensation of Fe metal strongly affects iron chemistry by efficiently removing Fe-bearing species from the gas phase. Monatomic Fe is the most abundant Fe-bearing gas throughout the…
Outgassing Composition of the Murchison Meteorite: Implications for Volatile Depletion of Planetesimals and Interior-atmosphere Connections for Terrestrial Exoplanets
