We study the linear excitations around typical energy minima of a mean-field disordered model with continuous degrees of freedom undergoing a Random First Order Transition (RFOT). Contrary to naive expectations, the spectra of linear excitations are ungapped and we find the presence of a pseudogap corresponding to localized excitations with arbitrary low excitation energy. Moving to deeper minima in the landscape, the excitations appear increasingly localized while their abundance decreases. Beside typical minima, there also exist rare ultra-stable minima, with an energy gap and no localised excitations.
We discuss the underlying connections among the thermodynamic properties of short-ranged spin glasses, their behavior in large finite volumes, and the interfaces that separate different pure states, and also ground states and low-lying excitations.
A detailed investigation of lowest excitations in two-dimensional Gaussian spin glasses is presented. We show the existence of a new zero-temperature exponent lambda describing the relative number of finite-volume excitations with respect to large-scale ones. This exponent yields the standard thermal exponent of droplet theory theta through the relation, theta=d(lambda-1). Our work provides a new way to measure the thermal exponent theta without any assumption about the procedure to generate typical low-lying excitations. We find clear evidence that theta < theta_{DW} where theta_{DW} is the t…
We address the question of geometrical as well as energetic properties of local excitations in mean field Ising spin glasses. We study analytically the Random Energy Model and numerically a dilute mean field model, first on tree-like graphs, equivalent to a replica symmetric computation, and then directly on finite connectivity random lattices. In the first model, characterized by a discontinuous replica symmetry breaking, we found that the energy of finite volume excitation is infinite whereas in the dilute mean field model, described by a continuous replica symmetry breaking, it slowly decre…
We present a general theorem restricting properties of interfaces between thermodynamic states and apply it to the spin glass excitations observed numerically by Krzakala-Martin and Palassini-Young in spatial dimensions d=3 and 4. We show that such excitations, with interface dimension smaller than d, cannot yield regionally congruent thermodynamic states. More generally, zero density interfaces of translation-covariant excitations cannot be pinned (by the disorder) in any d but rather must deflect to infinity in the thermodynamic limit. Additional consequences concerning regional congruence i…
The low-temperature thermal properties of dielectric crystals are governed by acoustic excitations with large wavelengths that are well described by plane waves. This is the Debye model, which rests on the assumption that the medium is an elastic continuum, holds true for acoustic wavelengths large on the microscopic scale fixed by the interatomic spacing, and gradually breaks down on approaching it. Glasses are characterized as well by universal low-temperature thermal properties, that are however anomalous with respect to those of the corresponding crystalline phases. Related universal anoma…
In amorphous materials, groups of particles can rearrange locally into a new stable configuration. Such elementary excitations are key as they determine the response to external stresses, as well as to thermal and quantum fluctuations. Yet, understanding what controls their geometry remains a challenge. Here we build a scaling description of the geometry and energy of low-energy excitations in terms of the distance to an instability, as predicted for instance at the dynamical transition in mean field approaches of supercooled liquids. We successfully test our predictions in ultrastable compute…
The nature of defects in amorphous materials, analogous to vacancies and dislocations in crystals, remains elusive. Here we explore their nature in a three-dimensional microscopic model glass-former which describes granular, colloidal, atomic and molecular glasses by changing the temperature and density. We find that all glasses evolve in a very rough energy landscape, with a hierarchy of barrier sizes corresponding to both localized and delocalized excitations. Collective excitations dominate in the jamming regime relevant for granular and colloidal glasses. By moving gradually to larger dens…
Several puzzling regularities concerning the low temperature excitations of glasses are quantitatively explained by quantizing domain wall motions of the random first order glass transition theory. The density of excitations agrees with experiment and scales with the size of a dynamically coherent region at $T_g$, being about 200 molecules. The phonon coupling depends on the Lindemann ratio for vitrification yielding the observed universal relation $l/λ\simeq 150$ between phonon wavelength $λ$ and mean free path $l$. Multilevel behavior is predicted to occur in the temperature range of the the…
We investigate the properties of the low-frequency spectrum in the density of states $D(ω)$ of a three-dimensional model glass former. To magnify the Non-Debye sector of the spectrum, we introduce a random pinning field that freezes a finite particle fraction in order to break the translational invariance and shifts all the vibrational frequencies of the extended modes towards higher frequencies. We show that Non-Debye soft localized modes progressively emerge as the fraction $p$ of pinned particles increases. Moreover, the low-frequency tail of $D(ω)$ goes to zero as a power law $ω^{δ(p)}$, w…
We study numerically the local low-energy excitations in the 3-d Edwards-Anderson model for spin glasses. Given the ground state, we determine the lowest-lying connected cluster of flipped spins with a fixed volume containing one given spin. These excitations are not compact, having a fractal dimension close to two, suggesting an analogy with lattice animals. Also, their energy does not grow with their size; the associated exponent is slightly negative whereas the one for compact clusters is positive. These findings call for a modification of the basic hypotheses underlying the droplet model.
The relative importance of the contributions of droplet excitations and domain walls on the ordering of short-range Edwards-Anderson spin glasses in three and four dimensions is studied. We compare the overlap distributions of periodic and free boundary conditions using population annealing Monte Carlo. For system sizes up to about 1000 spins, spin glasses show non-trivial spin overlap distributions. Periodic boundary conditions can trap diffusive domain walls which can contribute to small spin overlaps, and the other contribution is the existence of low-energy droplet excitations within the s…
Excitations of three-dimensional spin glasses are computed numerically. We find that one can flip a finite fraction of an LxLxL lattice with an O(1) energy cost, confirming the mean field picture of a non-trivial spin overlap distribution P(q). These low energy excitations are not domain-wall-like, rather they are topologically non-trivial and they reach out to the boundaries of the lattice. Their surface to volume ratios decrease as L increases and may asymptotically go to zero. If so, link and window overlaps between the ground state and these excited states become ``trivial''.
We present new data on the nonequilibrium acoustic response of glasses to an applied dc electric field below 1K. When compared with the analogous dielectric response of the same material, the acoustic data show, within experimental precision, identical dependence on the perturbing field, but stronger temperature dependence. These data are difficult to reconcile with simple generalizations of the dipole gap model of two-level system (TLS) dielectric response, unless we assume that as T is decreased, interaction-based TLS collective effects increase.
We investigate the nature of the low-energy, large-scale excitations in the three-dimensional Edwards-Anderson Ising spin glass with Gaussian couplings and free boundary conditions, by studying the response of the ground state to a coupling-dependent perturbation introduced previously. The ground states are determined exactly for system sizes up to 12^3 spins using a branch and cut algorithm. The data are consistent with a picture where the surface of the excitations is not space-filling, such as the droplet or the ``TNT'' picture, with only minimal corrections to scaling. When allowing for ve…
We probe the droplet excitations in short range spin glasses by adding a perturbative long range interaction that decays with distance as a power law: $J/r^σ$. It is shown that if the power law exponent $σ$ is smaller than the spatial dimension $d$, the perturbation induces large scale avalanches which roll until they force the system to develop a pseudo gap in the excitation spectrum of the stabilities. This makes the perturbative long range interactions relevant for $σ< σ_c = d$. The droplet theory predicts that the critical exponent $σ_c$ depends on the droplet stiffness exponent as $σ_c=d-…
We solve the Sherrington-Kirkpatrick (SK) model in a transverse field Γdeep in its quantum glass phase at zero temperature. We show that the glass phase is critical everywhere, exhibiting collective excitations with a gapless Ohmic spectral function. Using an effective potential approach, we interpret the latter as being due to disordered spin waves which behave as weakly coupled, underdamped harmonic oscillators. In the limit of small transverse field the low frequency tail of the spectrum tends to a universal, Γ-independent limit.
Glassy solids exhibit a wide variety of generic thermomechanical properties, ranging from universal anomalous specific heat at cryogenic temperatures to nonlinear plastic yielding and failure under external driving forces, which qualitatively differ from their crystalline counterparts. For a long time, it has been believed that many of these properties are intimately related to nonphononic, low-energy quasilocalized excitations (QLEs) in glasses. Indeed, recent computer simulations have conclusively revealed that the self-organization of glasses during vitrification upon cooling from a melt le…
We numerically extract large-scale excitations above the ground state in the 3-dimensional Edwards-Anderson spin glass with Gaussian couplings. We find that associated energies are O(1), in agreement with the mean field picture. Of further interest are the position-space properties of these excitations. First, our study of their topological properties show that the majority of the large-scale excitations are sponge-like. Second, when probing their geometrical properties, we find that the excitations coarsen when the system size is increased. We conclude that either finite size effects are very…
The two-dimensional Edwards-Anderson model with Gaussian bond distribution is investigated at T=0 with a numerical method. Droplet excitations are directly observed. It turns out that the averaged volume of droplets is proportional to l^D with D = 1.80(2) where l is the spanning length of droplets, revealing their fractal nature. The exponent characterizing the l dependence of the droplet excitation energy is estimated to be -0.42(4), clearly different from the stiffness exponent for domain wall excitations.
Further testing the validity of generalized heterogeneous-elasticity theory for low-frequency excitations in structural glasses
Universität Mainz（美因茨大学）；Istituto Italiano di Tecnologia（意大利理工学院）；Universita’ di Roma “La Sapienza”（罗马第一大学）；Univ. of Oxford（牛津大学）；NOMATEN Centre of Excellence, National Center for Nuclear Research（国家核研究中心卓越中心）；Colorado State University（科罗拉多州立大学）
We report large effects of Parisi replica permutation symmetry breaking (RPSB) on elementary excitations of fermionic systems with frustrated magnetic interactions. The electronic density of states is obtained exactly in the zero temperature limit for (K=1)-step RPSB together with exact relations for arbitrary breaking K, which lead to a new fermionic and dynamical Parisi solution at K=\infty. The Ward identity for charge conservation indicates RPSB-effects on the conductivity in metallic quantum spin glasses. This implies that RPSB is essential for any fermionic system showing spin glass sect…
Besides the dynamical slowing down signaled by an enormous increase of the viscosity approaching the glass transition, structural glasses show interesting anomalous thermodynamic features at low temperatures that hint at peculiar deviations from Debye's law at low enough frequencies. Theory, numerical simulations, and experiments suggest that deviation from Debye's law is due to soft-localized glassy modes that populate the low-frequency spectrum. We study the localization properties of the low-frequency modes in a three-dimensional supercooled liquid model. The density of states $D(ω)$ is com…
We discuss temperature chaos in mean field and realistic 3D spin glasses. Our numerical simulations show no trace of a temperature chaotic behavior for the system sizes considered. We discuss the experimental and theoretical implications of these findings.
We report the results of Monte Carlo simulations on several spin glass models at low temperatures. By using the parallel tempering (Exchange Monte Carlo) technique we are able to equilibrate down to low temperatures, for moderate sizes, and hence the data should not be affected by critical fluctuations. Our results for short range models are consistent with a picture proposed earlier that there are large scale excitations which cost only a finite energy in the thermodynamic limit, and these excitations have a surface whose fractal dimension is less than the space dimension. For the infinite ra…
In these lectures I will review some theoretical results that have been obtained for spin glasses. I will concentrate my attention on the formulation of the mean field approach and on its numerical and experimental verifications. I will present the various hypothesis at the basis of the theory and I will discuss their mathematical and physical status.
The dynamic structure factor of glassy and liquid glycerol has been measured by inelastic X-ray scattering in the exchanged momentum ($Q$) region $Q$=2$÷$23 nm$^{-1}$ and in the temperature range 80$÷$570 K. Beside the propagating longitudinal excitations modes, at low temperature the spectra show a second non $Q$-dispersing peak at $\hbar Ω_T$$\approx$8.5 meV. We assign this peak to the transverse dynamics that, in topologically disordered systems, acquires a longitudinal symmetry component. This assignment is substantiated by the observation that, in the liquid, this peak vanishes when the s…
Structural glasses feature quasilocalized excitations whose frequencies $ω$ follow a universal density of states ${\cal D}(ω)\!\sim\!ω^4$. Yet, the underlying physics behind this universality is not fully understood. Here we study a mean-field model of quasilocalized excitations in glasses, viewed as groups of particles embedded inside an elastic medium and described collectively as anharmonic oscillators. The oscillators, whose harmonic stiffness is taken from a rather featureless probability distribution (of upper cutoff $κ_0$) in the absence of interactions, interact among themselves throug…
The low temperature phase of discontinuous mean-field spin glasses is characterized by the appearance of an exponential number of metastable states. Which ones among these states dominate the out-of-equilibrium dynamics of these systems? In order to answer this question, we compare high-precision numerical simulations of a diluted $p$-spin model with a cavity computation of the threshold energy. Our main conclusion is that the aging dynamics is dominated by different layers of metastable states depending on the cooling schedule. In order to perform our analysis, we present a method for computi…
We study the three-dimensional system of magnetic nanoparticle dipoles randomly oriented along quenched easy axes. Directions of the magnetic momenta are described by the Ising variables which allow the momenta to flip along their random orientations. Using the standard mean-field approximation and the replica technique it is shown that the system undergoes a finite temperature phase transition into a spin-glass phase.
Mean-field models of 2-spin Ising spin glasses with interaction matrices taken from ensembles which are invariant under O(N) transformations are studied. A general study shows that the nature of the spin glass transition can be deduced from the eigenvalue spectrum of the interaction matrix. A simple replica approach is derived to carry out the average over the O(N) disorder. The analytic results are confirmed by extensive Monte Carlo simulations for large system sizes and by exact enumeration for small system sizes.
Structural glasses formed by quenching a melt are known to host a population of low-energy quasilocalized (nonphononic) excitations whose frequencies $ω$ follow a universal $\sim\!ω^4$ distribution as $ω\!\to\!0$, independently of the glass formation history, the interparticle interaction potential or spatial dimension. Here, we show that the universal quartic law of nonphononic excitations also holds in disordered crystals featuring finite long-range order, which is absent in their glassy counterparts. We thus establish that the degree of universality of the quartic law extends beyond structu…
The attenuation rate of vibrational excitations in various metallic liquids and glasses has been reported to change from the quadratic dependence on wavevector at low wavevectors to the linear dependence at high wavevectors. However, the origin of this behavior is not clear. Here, the analysis of this phenomenon through molecular dynamics is presented for prototypical metallic liquids, Cu56Zr44 and Fe. It is shown that the crossover wavevector is strongly correlated with the structural coherence length characterizing coarse-grained density correlations. We suggest that the linear dependence is…
Spectroscopic results on low frequency excitations of densified silica are presented and related to characteristic thermal properties of glasses. The end of the longitudinal acoustic branch is marked by a rapid increase of the Brillouin linewidth with the scattering vector. This rapid growth saturates at a crossover frequency Omega_co which nearly coincides with the center of the boson peak. The latter is clearly due to additional optic-like excitations related to nearly rigid SiO_4 librations as indicated by hyper-Raman scattering. Whether the onset of strong scattering is best described by h…
I discuss results from numerical simulations of finite dimensional spin glass models, and show that they show all signatures of a mean field like behavior, basically coinciding with the one of the Parisi solution. I discuss the Binder cumulant, the probability distribution of the order parameter, the non self-averaging behavior. The determination of correlation function and of spatially blocked observables quantities helps in qualifying the behavior of the system.
Phenomenologically assuming a sharp decrease of shear relaxation time for large wavevector $k>k_ξ$ density modes (where $k_ξ$ is of order of inverse of several interatomic distances $a$), I develop a general elasto-hydrodynamic theory describing the low-energy excitations of glassy and amorphous solids, which are responsible for anomalous specific heat and thermal conductivity. The theory explains the origin of collective two-level states and Boson peak. The ratio of the wavelength of the phonon, $λ$, to its mean free path, $l$, - universal property of sound absorption in glasses - is derived …
In this paper I report results for simulations of the three-dimensional gauge glass and the four-dimensional XY spin glass using the parallel tempering Monte Carlo method at low temperatures for moderate sizes. The results are qualitatively consistent with earlier work on the three- and four-dimensional Edwards-Anderson Ising spin glass. I find evidence that large-scale excitations may cost only a finite amount of energy in the thermodynamic limit. The surface of these excitations is fractal, but I cannot rule out for the XY spin glass a scenario compatible with replica symmetry breaking where…
We prove the impossibility of recent attempts to decouple the Replica Symmetry Breaking (RSB) picture for finite-dimensional spin glasses from the existence of many thermodynamic (i.e., infinite-volume) pure states while preserving another signature RSB feature --- space filling relative domain walls between different finite-volume states. Thus revisions of the notion of pure states cannot shield the RSB picture from the internal contradictions that rule out its physical correctness in finite dimensions at low temperature in large finite volume.
The mathematically correct computation of the spin glasses free energy in the infinite range limit crowns 25 years of mathematic efforts in solving this model. The exact solution of the model was found many years ago by using a heuristic approach; the results coming from the heuristic approach were crucial in deriving the mathematical results. The mathematical tools used in the rigorous approach are quite different from those of the heuristic approach. In this note we will review the heuristic approach to spin glasses in the light of the rigorous results; we will also discuss some conjectures …
We study numerically a disordered model that interpolates among the Sherrington-Kirkpatrick mean field model and the three dimensional Edwards-Anderson spin glass. We find that averages over the disorder of powers of the overlap and of the full $P(q)$ are smooth, and do not show any discontinuity. Different lattice sizes are used to provide evidence for a smooth behavior of disorder averages in the thermodynamic limit. Quantities defined on a given realization of the disorder show a chaotic behavior. Our results support the validity of a Replica Symmetry Breaking description of finite dimensio…
The low-temperature phase of discontinuous mean-field spin glasses is generally described by a one-step replica symmetry breaking (1RSB) Ansatz. The Gardner transition, i.e. a very-low-temperature phase transition to a full replica symmetry breaking (FRSB) phase, is often regarded as an inessential, and somehow exotic phenomenon. In this paper we show that the metastable states which are relevant for the out-of-equilibrium dynamics of such systems are always in a FRSB phase. The only exceptions are (to the best of our knowledge) the p-spin spherical model and the random energy model (REM). We …
A controversial issue in spin glass theory is whether mean field correctly describes 3-dimensional spin glasses. If it does, how can replica symmetry breaking arise in terms of spin clusters in Euclidean space? Here we argue that there exist system-size low energy excitations that are sponge-like, generating multiple valleys separated by diverging energy barriers. The droplet model should be valid for length scales smaller than the size of the system (theta > 0), but nevertheless there can be system-size excitations of constant energy without destroying the spin glass phase. The picture we pro…
We compute analytically the probability distribution of large deviations in the spin-glass free energy for the Sherrington-Kirkpatrick mean field model, i.e. we compute the exponentially small probability of finding a system with intensive free energy smaller than the most likely one. This result is obtained by computing the average value of the partition function to the power $n$ as a function of $n$. At zero temperature this absolute prediction displays a remarkable quantitative agreement with the numerical data.
We analyze thermodynamic behavior of general $n$-component mean-field spin glass models in order to identify origin of the hierarchical structure of the order parameters from the replica-symmetry breaking solution. We derive a configurationally dependent free energy with local magnetizations and averaged local susceptibilities as order parameters. On an example of the replicated Ising spin glass we demonstrate that the hierarchy of order parameters in mean-field models results from the structure of inter-replica susceptibilities. These susceptibilities serve for lifting the degeneracy due to t…
We study chaotic size dependence of the low temperature correlations in the SK spin glass. We prove that as temperature scales to zero with volume, for any typical coupling realization, the correlations cycle through every spin configuration in every fixed observation window. This cannot happen in short-ranged models as there it would mean that every spin configuration is an infinite-volume ground state. Its occurrence in the SK model means that the commonly used `modified clustering' notion of states sheds little light on the RSB solution of SK, and conversely, the RSB solution sheds little l…
The role of reflection symmetry breaking for the character of the appearance of replica symmetric spin glass state is investigated. We establish the following symmetry rule for classical systems with one order parameter in the replica symmetric mean field approximation. If in the pure system the transition to the ordered phase is of the second order, then in the corresponding random system the glass regime appears as a result of a phase transition; if the transition in the pure system is of the first order, then glass and ordered regimes grow continuously in the random system on cooling.
By using numerical simulations we show that the 4D $J=\pm 1$ Edwards Anderson spin glass in magnetic field undergoes a mean field like phase transition. We use a dynamical approach: we simulate large lattices (of volume $V$) and work out the behavior of the system in limit where both $t$ and $V$ go to infinity, but where the limit $V \to \infty$ is taken first. By showing that the dynamic overlap $q$ converges to a value smaller than the static one we exhibit replica symmetry breaking. The critical exponents are compatible with the ones obtained by mean field computations.
We present results of Monte Carlo simulations, using parallel tempering, on the three- and four-dimensional Edwards-Anderson Ising spin glass with Gaussian couplings at low temperatures with free boundary conditions. Our results suggest that large-scale low-energy excitations may be space filling. The data implies that the energy of these excitations increases with increasing system size for small systems, but we see evidence in three dimensions, where we have a greater range of sizes, for a crossover to a regime where the energy is independent of system size, in accordance with replica symmet…
Key aspects of glasses are controlled by the presence of excitations in which a group of particles can rearrange. Surprisingly, recent observations indicate that their density is dramatically reduced and their size decreases as the temperature of the supercooled liquid is lowered. Some theories predict these excitations to cause a gap in the spectrum of quasi-localised modes of the Hessian that grows upon cooling, while others predict a pseudo-gap ${D_L(ω)} \sim ω^α$. To unify these views and observations, we generate glassy configurations of controlled gap magnitude $ω_c$ at temperature ${T=0…
Spin-charge conversion via inverse spin Hall effect (ISHE) is essential for enabling various applications of spintronics. The spin Hall response usually follows a universal scaling relation with longitudinal electric resistivity and has mild temperature dependence because elementary excitations play only a minor role in resistivity and hence ISHE. Here we report that the ISHE of metallic glasses shows nearly two orders of magnitude enhancements with temperature increase from a threshold of 80-100 K to glass transition points. As electric resistivity changes only marginally in the temperature r…
A new approach to exploring low-temperature excitations in finite-dimensional lattice spin glasses is proposed. By focusing on bond-diluted lattices just above the percolation threshold, large system sizes $L$ can be obtained which lead to enhanced scaling regimes and more accurate exponents. Furthermore, this method in principle remains practical for any dimension, yielding exponents that so far have been elusive. This approach is demonstrated by determining the stiffness exponent for dimensions $d=3$, $d=6$ (the upper critical dimension), and $d=7$. Key is the application of an exact reducti…
The aim of this paper is to discuss the main ideas of the Talagrand proof of the Parisi Ansatz for the free-energy of Mean Field Spin Glasses with a physicist's approach. We consider the case of the spherical $p$-spin model, which has the following advantages: 1) the Parisi Ansatz takes the simple ``one step replica symmetry breaking form'', 2) the replica free-energy as a function of the order parameters is simple enough to allow for numerical maximization with arbitrary precision. We present the essential ideas of the proof, we stress its connections with the theory of effective potentials f…
We study the energy minima of the fully-connected $m$-components vector spin glass model at zero temperature in an external magnetic field for $m\ge 3$. The model has a zero temperature transition from a paramagnetic phase at high field to a spin glass phase at low field. We study the eigenvalues and eigenvectors of the Hessian in the minima of the Hamiltonian. The spectrum is gapless both in the paramagnetic and in the spin glass phase, with a pseudo-gap behaving as $λ^{m-1}$ in the paramagnetic phase and as $\sqrtλ$ in the spin glass phase. Despite the long-range nature of the model, the eig…
We consider the effect of droplet excitations in the random first order transition theory of glasses on the configurational entropy. The contribution of these excitations is estimated both at and above the ideal glass transition temperature. The temperature range where such excitations could conceivably modify or `round-out' an underlying glass transition temperature is estimated, and found to depend strongly on the surface tension between locally metastable phases in the supercooled liquid. For real structural glasses this temperature range is found to be very narrow, consistent with the quan…
We discuss the problem of ultrametricity in mean field spin glasses by means of a hierarchical clustering algorithm. We complement the clustering approach with quantitative testing: we discuss both in some detail. We show that the elimination of the (in this context accidental) spin flip symmetry plays a crucial role in the analysis, since the symmetry hides the real nature of the data. We are able to use in the analysis disorder averaged quantities. We are able to exhibit a number of features of the low $T$ phase of the mean field theory, and to claim that the full hierarchical structure can …
We review a model--based rather than phenomenological approach to low--temperature anomalies in glasses. Specifically, we present a solvable model inspired by spin--glass theory that exhibits both, a glassy low--temperature phase, and a collection of double-- and single--well configurations in its potential energy landscape. The distribution of parameters characterizing the local potential energy configurations can be computed, and is found to differ from those assumed in the standard tunneling model and its variants. Still, low temperature anomalies characteristic of amorphous materials are r…
